Super-hierarchical Structure Control of Conjugated Polymers Based on Inorganic Nanostructures

• Project/Area Number: 17067013
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyushu University
• Principal Investigator: OTSUKA Hideyuki Kyushu University, 先導物質化学研究所, 准教授 (00293051)
• Project Period (FY): 2005 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥31,300,000 (Direct Cost: ¥31,300,000); Fiscal Year 2008: ¥4,200,000 (Direct Cost: ¥4,200,000); Fiscal Year 2007: ¥8,500,000 (Direct Cost: ¥8,500,000); Fiscal Year 2006: ¥8,800,000 (Direct Cost: ¥8,800,000); Fiscal Year 2005: ¥9,800,000 (Direct Cost: ¥9,800,000)
• Keywords: 共役ポリマー / 階層構造制御 / 無機ナノファイバー / 表面修飾 / 無機ナノフアイバー

Research Abstract

導電性を持つ高分子に代表される共役ポリマーをサブミクロンからナノメートルレベルで微細加工あるいは階層構造の精密制御することは、次世代の光・電子材料への展開を進める上で、必要不可欠な科学技術である。本研究では、無機ナノ構造体(無機ナノチューブ、無機ナノ粒子など)を巧みに利用することで、共役ポリマーの形態および階層構造の制御を行い、新規な機能性材料の作製法の一つとなる方法を提案することができた。

Research Products

• [Journal Article] Preparation of Hybrid Films of Aluminosilicate Nanofiber and Conjugated Polymer (2009)
  • Author(s): Nattha Jiravanichanun, Kazuya Yamamoto, Atsushi Irie, Hideyuki Otsuka, Atsushi Takahara
  • Journal Title: Synth. Metals 159 Pages: 885-888
  • Peer Reviewed
• [Journal Article] Preparation of Hybrid Films of Aluminosilicate Nanofiber and Conjugated Polymer (2009)
  • Author(s): N. Jiravanichanun
  • Journal Title: Synth. Metals 159(印刷中)
  • Peer Reviewed
• [Journal Article] Fabrication of Conjugated Polymer Hybrid Thin Films with Radially Oriented Aluminosilicate Nanofibers by Spin-Assembly (2008)
  • Author(s): Nattha Jiravanichanun, Kazuya Yamamoto, Hiroaki Yonemura, Sunao Yamada, Hideyuki Otsuka, Atsushi Takahara
  • Journal Title: Bull. Chem. Soc. Jpn 81 Pages: 1663-1668
  • Peer Reviewed
• [Journal Article] Control of Dispersion State of Silsesquioxane Nanofillers for Stabilization of Polystyrene Thin Films (2008)
  • Author(s): N. Hosaka
  • Journal Title: Langmuir 24 Pages: 5766-5772
  • Peer Reviewed
• [Journal Article] Fabrication of Conjugated Polymer Hybrid Thin Films with Radially Oriented Aluminosilicate Nanofibers by Spin?Assembly (2008)
  • Author(s): N. Jiravanichanun
  • Journal Title: Bull. Chem. Soc. Jpn 81 Pages: 1663-1668
  • Peer Reviewed
• [Journal Article] Control of Dispersion State of Slisesquioxane Nanofillers for Stabilization of Polystyrene Thin Films (2008)
  • Author(s): N., Hosaka
  • Journal Title: Langmuir (印刷中)
  • Peer Reviewed
• [Journal Article] Surface and Intrfacial Structures of Silsesquioxane-terminated Polystyrene Thin Films (2007)
  • Author(s): K., Miyamoto
  • Journal Title: Trans. Mater. Res. Soc. Jpn. 32 Pages: 267-270
  • Peer Reviewed
• [Journal Article] Dewetting Inhibition and Interfacial Structures of Silsesquioxane-terminated Polystyrene Thin Films (2007)
  • Author(s): K., Miyamoto
  • Journal Title: Polymer. Journal 39 Pages: 1247-1252
  • Peer Reviewed
• [Journal Article] Structure and Dewetting Behavior of Polyhedral Oligomeric Silsesquioxane-Filled Polystyrene Thin Films (2007)
  • Author(s): N.Hosaka et al.
  • Journal Title: Langmuir 23 Pages: 902-907
• [Journal Article] Analysis of Molecular Aggregation States in Pentacene Thin Films Prepared from Soluble Precursor (2006)
  • Author(s): Takahiro Akinaga, Shigekazu Yasutake, Sono Sasaki, Osami Sakata, Hideyuki Otsuka, Atsushi Takahara
  • Journal Title: Chem. Lett 35 Pages: 1098-1099
  • Peer Reviewed
• [Journal Article] Polystyrene-Grafted Titanium Oxide Nanoparticles Prepared through Surface-Initiated Nitroxide-Mediated Radical Polymerization and Their Application to Polymer Hybrid Thin Films (2006)
  • Author(s): R.Matsuno et al.
  • Journal Title: Soft Matter 2 Pages: 415-421
• [Journal Article] Stabilization of Polystyrene Thin Films against Dewetting by Silsesquioxane-terminated Polystyrene Additives (2006)
  • Author(s): K.Miyamoto et al.
  • Journal Title: Chem. Lett. 35 Pages: 1098-1099
• [Journal Article] Analysis of Molecular Aggregation States in Pentacene Thin Films Prepared from Soluble Precursor (2006)
  • Author(s): T.Akinaga et al.
  • Journal Title: Chem. Lett. 35 Pages: 1162-1163
• [Journal Article] (Inorganic Nanofiber/Enzyme) Hybrid Hydgogel : Preparation, Characterization, and Enzyme Activity of Imogolite/Pepsin Conjugate (2006)
  • Author(s): N.Inoue et al.
  • Journal Title: Chem.Lett. Vol.35 Pages: 194-195
• [Journal Article] Preparation and Properties of [Poly(methyl methacrylate)/Imogolite] Hybrid via Surface Modification using Phosphoric Acid Ester (2005)
  • Author(s): K.Yamamoto et al.
  • Journal Title: Polymer Vol.146 Pages: 12386-12392
• [Journal Article] Transparent Polymer Prepared by in situ Synthesis of Aluminosilicate Nonfibers in Poly (vinyl alcohol) Solution (2005)
  • Author(s): K.Yamamoto et al.
  • Journal Title: Soft Matter Vol.1 Pages: 372-377
• [Journal Article] Preparation and Properties of Polymer Hybrids Containing Nanoparticles with Controlled Interfacial Structure (2005)
  • Author(s): R.Matsuno et al.
  • Journal Title: Trans.Mater.Res.Soc.Jpn. Vol.30 Pages: 723-726
• [Journal Article] Aggregation Structure and functional Properties of (Inorganic Nanofiber/Pepin) Hybrid Hydrogel (2005)
  • Author(s): N.Inoue et al.
  • Journal Title: Trans.Mater.Res.Soc.Jpn. Vol.30 Pages: 727-730
• [Presentation] Molecular Aggregation State and Photovoltaic Properties of Chlorophyll Doped Conducting Poly(hexylthiophene)/ MCM-41 Nanocomposites (2009)
  • Author(s): Yah Weng On et al.,
  • Organizer: 5th International Conference on Molecular Electronics and Bioelectronics
  • Place of Presentation: Miyazaki, Japan
• [Presentation] Preparation and Characterization of Chlorophyll Doped Conducting Poly (hexylthiophene)/MCM Nanocomposites (2009)
  • Author(s): Yah Weng On
  • Organizer: 2009年帝人21世紀フォーラム
  • Place of Presentation: 静岡県裾野市
• [Presentation] Molecular Aggregation State and Photovoltaic Properties of Chlorophyll Doped Conducting Poly(hexylthiophene)/MCM-41 Nanocomposites (2009)
  • Author(s): Yah Weng On
  • Organizer: 5^<th> International Conference on Molecular Electranics and Bioelectronics
  • Place of Presentation: Miyazaki, Japan
• [Presentation] Fabrication of Conjugated Polymer Hybrid Thin Films with Radically Oriented Aluminosilicate Nanofibers by Spin-assembly (2008)
  • Author(s): Nattha Jiravanichanun et al.,
  • Organizer: 18th Iketani Conference
  • Place of Presentation: Hyogo, Japan
  • Year and Date: 2008-10-22
• [Presentation] Preparation and Characterization of Organic-Inorganic Hybrid Oligothio phene/Aluminosilicate Nanofibers (2008)
  • Author(s): Atsushi Irie
  • Organizer: 18^<th> Iketani Conference
  • Place of Presentation: Hyogo, Japan
  • Year and Date: 2008-10-22
• [Presentation] Fabrication of Conjugated Polymer Hybrid Thin Films with Radically Oriented Aluminosilicate Nanofibers by Spin-assembly (2008)
  • Author(s): Nattha Jiravanichanun
  • Organizer: 18^<th> Iketani Conference
  • Place of Presentation: Hyogo, Japan
  • Year and Date: 2008-10-22
• [Presentation] ボスホン酸基と無機ナノファイバー表面の特異的相互作用を利用した(有機/無機)ハイブリッドの調製とその特性解析 (2008)
  • Author(s): 入江惇史
  • Organizer: 第45回化学関連支部合同九州大会
  • Place of Presentation: 福岡県北九州市
  • Year and Date: 2008-07-05
• [Presentation] Molecular Aggregation Structure of Terthiophene Derivative with a Phosphonic Acid Group on the Surface of Aluminosilicate Nanofiber (2008)
  • Author(s): Atsushi Irie et al.,
  • Organizer: IUMRS-ICA 2008
  • Place of Presentation: Nagoya, Japan
• [Presentation] Preparation and Characterization of Chlorophyll Doped Comducting Poly (hexylthiophene)/MCM Nanocomposite (2008)
  • Author(s): Yah Weng On
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: 神奈川県横浜市
• [Presentation] 無機ナノファイバーとチオフェン誘導体の特異的相互作用を利用したハイブリッド材料の調製とその分子凝集状態解析 (2008)
  • Author(s): 入江惇史
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: 神奈川県横浜市
• [Presentation] 高分子組織体ナノ構造制御 (2008)
  • Author(s): 白波瀬朋子
  • Organizer: 第54回高分子夏季大学
  • Place of Presentation: 鹿児島市
• [Presentation] Molecular Aggregation State and Photovoltaic Properties of Chlorophyll Doped Conducting Poly(hexylthiophene)/MCM-41 Nanocomposites (2008)
  • Author(s): Yah Weng On
  • Organizer: 第57回高分子討論会
  • Place of Presentation: 大阪市住吉区
• [Presentation] Super-hierarchical Structure Control of Conjugated Polymers Based on Inorganic Nanostructures (2008)
  • Author(s): Hideyuki Otsuka
  • Organizer: The 3rd International Workshop on Super-Hierarchical Structures
  • Place of Presentation: Hyogo, Japan
• [Presentation] Molecular Aggregation State and Photovoltaic Properties of Chlorophyll Doped Conducting Poly(hexylthiophene)/MCM-41 Nanocomposites (2008)
  • Author(s): Yah Weng On
  • Organizer: IUMRS-ICA 2008
  • Place of Presentation: Nagoya, Japan
• [Presentation] Preparation of(Conjugated Polymer/ Inorganic Nanofiber) Hybrids Utilizing Specific Surface Interactions (2007)
  • Author(s): Kazuya, Yamamoto
  • Organizer: 10th Pacific Polymer Conference
  • Place of Presentation: Kobe, Japan
  • Year and Date: 2007-12-05
• [Book] 無機ナノ構造体を基盤とする共役ポリマーの超階層制御 (2009)
  • Author(s): 大塚英幸
  • Total Pages: 450
  • Publisher: シーエムシー出版
• [Book] 超分子サイエンス&テクノロジー (2009)
  • Author(s): 大塚英幸、高原淳
  • Total Pages: 1340
  • Publisher: イモゴライトチューブ
• [Book] 次世代共役ポリマーの超階層制御と革新機能(分担執筆) (2009)
  • Author(s): 大塚英幸
  • Total Pages: 450
  • Publisher: シーエムシー出版
• [Book] 超分子サイエンス&テクノロジー(分担執筆) (2009)
  • Author(s): 大塚英幸
  • Total Pages: 1340
  • Publisher: エヌ・ティー・エス
• [Book] かご型シルセスキオキサン添加高分子薄膜の分子凝集状態と熱的性質.(分担執筆) (2007)
  • Author(s): 穗坂 直
  • Total Pages: 12
  • Publisher: シーエムシー出版
• [Book] 第2章 精密高分子合成を用いた表面ナノ構造の精密制御,モレキュラーインフォーマティクスを拓く分子機能材料(新海征治 編著) (2006)
  • Author(s): 高原 淳, 大塚英幸
  • Total Pages: 9
  • Publisher: 日刊工業新聞社
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