Creation of Organic-Inorganic Semiconductor Hybrid by Using Super-Hierarchical Structure

• Project/Area Number: 17067016
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Sophia University
• Principal Investigator: RIKUKAWA Masahiro Sophia University, 理工学部, 教授 (10245798)
• Project Period (FY): 2005 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥26,800,000 (Direct Cost: ¥26,800,000); Fiscal Year 2008: ¥6,700,000 (Direct Cost: ¥6,700,000); Fiscal Year 2007: ¥6,700,000 (Direct Cost: ¥6,700,000); Fiscal Year 2006: ¥6,700,000 (Direct Cost: ¥6,700,000); Fiscal Year 2005: ¥6,700,000 (Direct Cost: ¥6,700,000)
• Keywords: 高分子構造 / 高分子合成 / 半導体物性 / 複合材料 / 量子閉じ込め / 高分子構造・物性 / 円二色性 / 発光特性 / らせん構造 / 液晶性 / 高公子構造・物性高分子構造・物性 / 光導電性 / フラーレン / 太陽電池 / LB法 / 光学活性 / ポリチオフェン / シーケンス / LB膜 / 超階層構造 / 有機・無機ハイブリッド / 共役ポリマー / 量子閉じ込め構造 / エネルギー移動 / 次元性材料 / オリゴチオフェン

Research Abstract

無機半導体と有機共役系分子が有する優れた特性をあわせ持つ次世代材料を創成するために、フラーレン、ポリチオフェンをもとに自己組織性を有する共役系分子を合成した。これと、金属ハライドとのハイブリッド化を試み、目的とする分子レベルでハイブリッド化された複合材料の合成に成功した。さらに、それらの特性と超階層性について調査した。

Research Products

• [Journal Article] イオン液体中における酵素触媒重合 (2009)
  • Author(s): 藤田正博, 他1名
  • Journal Title: 化学工業 59 Pages: 222-226
  • Peer Reviewed
• [Journal Article] Hydration Behavior of Perfluorinated and Hydrocarbon-Type Proton Exchange Membranes : Relationship between Morphology and Proton Conduction (2008)
  • Author(s): N. Takimoto, L. Wu, A. Ohira, Y. Takeoka, M. Rikukawa
  • Journal Title: Polymer 50 Pages: 534-540
  • Peer Reviewed
• [Journal Article] Surface Morphology and Proton Conduction Imaging of Nafion Membrane (2008)
  • Author(s): N. Takimoto, A. Ohira, Y. Takeoka, M. Rikukawa
  • Journal Title: Chem. Lett 37 Pages: 164-165
  • NAID: 10021077397
  • Peer Reviewed
• [Journal Article] Lipase-catalyzed polymerization of L-lactide in ionic liquids (2008)
  • Author(s): M. Yoshizawa-Fujita, 他4名
  • Journal Title: Polym. Adv. Technol 19 Pages: 1396-1400
  • Peer Reviewed
• [Journal Article] Molecular recognition of Langmuir-Blodgett polymer films containing uracil groups (2008)
  • Author(s): N. Sugiyama, 他5名
  • Journal Title: Colloids and Surfaces, A 321 Pages: 60-64
  • Peer Reviewed
• [Journal Article] Hydration behavior of perfluorinated and hydrocarbon-type proton exchange membranes (2008)
  • Author(s): N. Takimoto, 他5名
  • Journal Title: Polymer 50 Pages: 534-540
  • Peer Reviewed
• [Journal Article] Surface morphology and proton conduction imaging of Nafion membrane (2008)
  • Author(s): N., Takimoto, 他3名
  • Journal Title: Chemistry Letter 37 Pages: 164-165
  • Peer Reviewed
• [Journal Article] Ring-opening Bulk Polymerization of L-Lactide in Porous Hydroxyapatite (2007)
  • Author(s): N. Sugiyama, R. Kunibu, M. Yoshizawa-Fujita, Y. Takeoka, M. Aizawa, M. Rikukawa
  • Journal Title: Chem. Lett 36 Pages: 1476-1477
  • NAID: 10020012134
  • Peer Reviewed
• [Journal Article] Ring-opening bulk polymerization of L-lactide in porous hydroxyapatite (2007)
  • Author(s): N., Sugiyama, 他5名
  • Journal Title: Chemistry Letter 36 Pages: 1476-1477
  • Peer Reviewed
• [Journal Article] Systematic Studies on Chain Lengths, Halide Species, and Well Thicknesses for Lead Halide Layered Perovskit Thin Films (2006)
  • Author(s): Y. Takeoka, K. Asai, M. Rikukawa, K. Sanui
  • Journal Title: Bull. Chem. Soc. Jpn 79 Pages: 1607-1613
  • NAID: 10020528427
  • Peer Reviewed
• [Journal Article] Systematic Studies on Chain Lengths, Halide Species, and Well Thicknesses for Lead Halide Layered Perovskit Thin Films (2006)
  • Author(s): Y.Takeoka他3名
  • Journal Title: Bulletin of the Chemical Society of Japan 79 Pages: 1607-1613
• [Journal Article] Fabrication of Artificial Bone Materials Using Bioceramics and Polymers Having Phosphoric Acid Groups (2006)
  • Author(s): N.Sugiyama他4名
  • Journal Title: Archives of BioCeramics Research 6 Pages: 315-318
• [Journal Article] Intercalated Formation of Two-Dimensional and Multi-layered Perovskites in Organic Thin Films (2005)
  • Author(s): Y. Takeoka, M. Fukasawa, T. Matsui, K. Kikuchi, M. Rikukawa, K. Sanui
  • Journal Title: Chem. Commun Pages: 378-379
  • Peer Reviewed
• [Journal Article] synthesis and Optical Properties of Poly(thiophene) Derivatives with Benzothiazole Moiety (2005)
  • Author(s): M.Toba
  • Journal Title: Synthetic Metals 152 Pages: 197-197
• [Journal Article] Fabrication of Polycondensed Multilayer Thin Films by a self-Assembly Method (2005)
  • Author(s): Y.Takeoka
  • Journal Title: Colloids and Surfaces A 257-258 Pages: 485-485
• [Journal Article] Self-Assembled Multilayer Films Based on Functionalized Poly(thiophene)s (2005)
  • Author(s): Y.Takeoka
  • Journal Title: Synthetic Metals 154 Pages: 109-109
• [Journal Article] Intercalated Formation of Two-Dimensional and Multi-layered Perovskites in Organic Thin Films (2005)
  • Author(s): Y.Takeoka
  • Journal Title: Chem.Commun. Pages: 378-378
• [Journal Article] Hydrothermal Synthesis and Structure of Zero-Dimensional Organic-Inorganic Perovskites (2005)
  • Author(s): Y.Takeoka
  • Journal Title: Chem.Lett. 34 Pages: 602-602
• [Journal Article] Polymer Network Fabricated by Topochemical Polymerization of Self-assembly Films Composed of a Diacetylene Derivative (2005)
  • Author(s): K.Sasada
  • Journal Title: Chem.Lett. 34 Pages: 156-156
• [Presentation] Circular polarized fluorescence from chiral cholesteric phase constructed from chiral polymers (2008)
  • Author(s): T. Hirahara, 他4名
  • Organizer: 18th Iketani Conferenc
  • Place of Presentation: 淡路島
  • Year and Date: 2008-10-21
• [Presentation] 高分子電解質の高次構造制御とPEFC特性の関係 (2008)
  • Author(s): 陸川政弘
  • Organizer: 高分子学会燃料電池材料研究会講座(招待講演)
  • Place of Presentation: 化学会館
  • Year and Date: 2008-10-02
• [Presentation] 炭化水素系高分子電解質膜の構造と機能の関係 (2008)
  • Author(s): 陸川政弘
  • Organizer: 日本化学会第88春季年会(招待講演)
  • Place of Presentation: 立教大学
  • Year and Date: 2008-03-27
• [Presentation] Super-hierarchical Structures and Their Properties Fabricated by Fullerene Derivatives (2007)
  • Author(s): M. Rikukawa
  • Organizer: The 2nd International Workshop on Super-Hierarchical Structures
  • Place of Presentation: Osaka University
  • Year and Date: 2007-09-30
• [Presentation] Super-hierarchical structures and their properties fabricated by fullerene derivatives (2007)
  • Author(s): M., Rikukawa
  • Organizer: The 2nd International Workshop on Super-Hierarchical Structures
  • Place of Presentation: 大阪
  • Year and Date: 2007-09-30
• [Presentation] ポリ(4-フェノキシベンゾイル-1,4-フェニレン)の高分子量化の検討(II)-プロセスの最適化- (2007)
  • Author(s): 殿塚勲、他4名
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-09-21
• [Presentation] 光学活性基を有するポリチオフェンの有機太陽電池への応用(II)-水酸基の効果- (2007)
  • Author(s): 老久保雄太、他5名
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-09-21
• [Presentation] ベンゾチアゾール環を側鎖に有するポリチオフェンの合成と評価(I) (2007)
  • Author(s): 江刺家勝弘、他4名
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-09-21
• [Presentation] フラーレンを用いた有機・無機ハイブリッド材料の合成と特性(I) (2007)
  • Author(s): 川畑幸美、他4名
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-09-20
• [Presentation] ポリフェニレン-ポリエーテルケトンブロック共重合体の合成と評価(III)-オリゴマーDMFCへの応用- (2007)
  • Author(s): 久保田靖浩、他4名
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-09-19
• [Presentation] 燃料電池用高分子電解質膜:デザインと機能 (2007)
  • Author(s): 陸川政弘
  • Organizer: 第56回高分子学会年次大会(招待)
  • Place of Presentation: 国立京都国際会館
  • Year and Date: 2007-05-31
• [Presentation] ポリ(4-フェノキシベンゾイル-1,4-フェニレン)の高分子量化の検討(II)-重合条件の最適化- (2007)
  • Author(s): 殿塚勲、他4名
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 国立京都国際会館
  • Year and Date: 2007-05-30
• [Presentation] 光学基を有するポリチオフェンの電界発光特性(III)-電圧依存性- (2007)
  • Author(s): 藤波弘樹、他4名
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 国立京都国際会館
  • Year and Date: 2007-05-29
• [Presentation] 光学基を有するポリチオフェンの有機太陽電池への応用(I) (2007)
  • Author(s): 老久保雄太、他5名
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 国立京都国際会館
  • Year and Date: 2007-05-29
• [Presentation] ポリフェニレン・ポリエーテルケトンブロック共重合体の合成と評価(II)-オリゴマー導入量と鎖長の効果- (2007)
  • Author(s): 久保田靖浩、他4名
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 国立京都国際会館
  • Year and Date: 2007-05-29
• [Presentation] ポリフェニレン(エーテルスルホン)ブロック共重合体の合成と評価【II】〜共重合比の影響〜 (2007)
  • Author(s): 新田円菜、他4名
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 国立京都国際会館
  • Year and Date: 2007-05-29
• [Presentation] 炭化水素系高分子電解質のデザイン (2006)
  • Author(s): 陸川政弘
  • Organizer: 第15回ポリマー材料フォーラム(招待講演)
  • Place of Presentation: 千里ライフサイエンスセンター
  • Year and Date: 2006-11-16
• [Book] 次世代共役ポリマーの超階層制御と革新機能 (2009)
  • Author(s): 竹岡裕子、陸川政弘
  • Publisher: CMC出版
• [Book] 次世代共役ポリマーの超階層制御と革新機能 (2009)
  • Author(s): 赤木和夫, 他
  • Publisher: シーエムシー出版
• [Book] 機能物質の集積膜と応用展開 (2006)
  • Author(s): 陸川政弘
  • Publisher: CMC出版
• [Book] 機能物質の集積膜と応用展開"半導体-有機層状複合体と光学機能" (2006)
  • Author(s): 陸川政弘 他1名
  • Total Pages: 12
  • Publisher: CMC
• [Remarks]
  • URL: http://www.ch.sophia.ac.jp/polymer/
• [Remarks]
  • URL: http://www.ch.sophia.ac.jp/polymer/
• [Remarks]
  • URL: http://www.ch.sophia.ac.jp/polymer/