High-resolution soft-X-ray emission spectroscopy and photoemission spectroscopy of the interface between molecules and electrodes
Project/Area Number |
17069008
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Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
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Research Institution | The University of Tokyo |
Principal Investigator |
SHIN Shik The University of Tokyo, 物性研究所, 教授 (00162785)
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Co-Investigator(Kenkyū-buntansha) |
TAKATA Yasutaka 東京大学, 理化学研究所, 専任研究員 (90261122)
ISHIZAKA Kyoko 東京大学, 物性研究所, 助教 (20376651)
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Co-Investigator(Renkei-kenkyūsha) |
MIYAWAKI Jun 東京大学, 理化学研究所, 研究員
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Project Period (FY) |
2005 – 2009
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Project Status |
Completed (Fiscal Year 2009)
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Budget Amount *help |
¥119,200,000 (Direct Cost: ¥119,200,000)
Fiscal Year 2009: ¥15,700,000 (Direct Cost: ¥15,700,000)
Fiscal Year 2008: ¥14,900,000 (Direct Cost: ¥14,900,000)
Fiscal Year 2007: ¥27,100,000 (Direct Cost: ¥27,100,000)
Fiscal Year 2006: ¥32,800,000 (Direct Cost: ¥32,800,000)
Fiscal Year 2005: ¥28,700,000 (Direct Cost: ¥28,700,000)
|
Keywords | シンクロトロン放射光 / 光電子分光 / 化学結合 / 表面吸着 / 軟X線吸収 / 軟X線発光 / 電子状態 / 軟X線発行 |
Research Abstract |
We developed high-resolution photoemission spectroscopy and time-resolved photoemission spectroscopy using VUV laser and synchrotron radiation with sample preparation chamber where the molecules are adsorbed on the clean metal surface. We studied soft-X-ray-emission spectroscopy on SO_2 molecules on Ni(100) clean surface and these results are analyzed by the theoretical calculation of Tsuneyuki group. Furthermore, We also studied in a single iron(II)-phthalocyanine molecule on an oxidized Cu(110) surface with Kawai-Takagi group.
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Report
(6 results)
Research Products
(125 results)
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[Journal Article] Anomalous state sandwiched between fermi liquid and charge ordered mott-insulating phases of Ti4O72010
Author(s)
M. Taguchi, A. Chainani, M. Matsunami, R. Eguchi, Y. Takata, M. Yabashi, K. Tamasaku, Y. Nishino, T. Ishikawa, S. Tsuda, S. Watanabe, C.T. Chen, Y. Senba, H. Ohashi, K. Fujiwara, Y. Nakamura, H. Takagi, S. Shin
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Journal Title
Phys Rev. Lett. 104
Pages: 106401-4
Related Report
Peer Reviewed
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[Journal Article] Orbital-dependent modifications of electronic structure across the magnetostructural transition in BaFe2As22010
Author(s)
T. Shimojima, K. Ishizaka, Y. Ishida, N. Katayama, K. Ohgushi, T. Kiss, M. Okawa, T. Togashi, X.Y. Wang, C.T. Chen, S. Watanabe, R. Kadota, T. Oguchi, A. Chainani, S. Shin
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Journal Title
Phys Rev. Lett. 104
Pages: 54002-4
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Peer Reviewed
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[Journal Article] The inhomogeneous structure of water at ambient conditions2009
Author(s)
C. Huang, K.T. Wikfeldt, Y. Harada, U. Bergmann, M. Niebuhr, T.M. Weiss, Y. Horikawa, O. Takahashi, S. Shin, L.G.M. Pettersson, A. Nilsson
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Journal Title
PNAS 106
Pages: 15214-15218
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Peer Reviewed
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[Journal Article] Spectroscopic evidence for competing reconstructions in polar multilayers LaAlO3/LaVO3/LaAlO32009
Author(s)
M. Takizawa, Y. Hotta, T. Susaki, Y. Ishida, H. Wadati, Y. Takata, K. Horiba, M. Matsunami, S. Shin, M. Yabashi, K. Tamasaku, Y. Nishino, T. Ishikawa, A. Fujimori, H.Y. Hwang
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Journal Title
Phys Rev. Lett. 102
Pages: 236401-4
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Peer Reviewed
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[Journal Article] Ligand energy controls the heme-Fe valence in aqueous myoglobins2009
Author(s)
Y. Harada, M. Taguchi, Y. Miyajima, T. Tokushima, Y. Horikawa, A. Chainani, Y. Shiro, Y. Senba, H. Ohashi, H. Fukuyama, S. Shin
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Journal Title
J. Phys. Soc. Jpn 78
Pages: 44802-5
Related Report
Peer Reviewed
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[Journal Article] Adsorption-induced switching of magnetic anisotropy in a single iron(II) phthalocyanine molecule on an oxidized Cu(110) surface2009
Author(s)
N. Tsukahara, K. Noto, M. Ohara, S. Shiraki, N. Takagi, Y. Takata, J. Miyawaki, M. Taguchi, A. Chainani, S. Shin, M. Kawai
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Journal Title
Phys Rev. Lett. 102
Pages: 167203-4
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Peer Reviewed
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[Journal Article] Mapping of chemical bonding states of Ag/Si(111) with synchrotron radiation photo emission electron microscopy2008
Author(s)
M. Hashimoto, F.Z. Guo, M. Suzuki, M. Ueda, Y. Matsuoka, T. Kinoshita, K. Kobayashi, S. Shin, M. Oura, T. Takeuchi, Y. Saito, T. Matsushita, T. Yasue, T. Koshikawa
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Journal Title
Surf. Interface Anal. 40
Pages: 1772-1776
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Peer Reviewed
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[Journal Article] Recoil effect of photoelectrons in the fermi edge of simple metals2008
Author(s)
Y. Takata, Y. Kayanuma, S. Oshima, S. Tanaka, M. Yabashi, K. Tamasaku, Y. Nishino, M. Matsunami, R. Eguchi, T. Takeuchi, Y. Senba, H. Ohashi, S. Shin, T. Ishikawa
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Journal Title
Related Report
Peer Reviewed
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[Journal Article] σ-bonding contribution of a strongπ-acceptor molecule: surface chemical bond of SO2 on Ni(100)2008
Author(s)
T. Tokushima, K. Sodeyama, Y. Harada, Y. Takata, M. Nagasono, Y. Kitajima, Y. Tamenori, H. Ohashi, S. Tsuneyuki, A. Hiraya, S. Shin
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Journal Title
Related Report
Peer Reviewed
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[Journal Article] Revisiting the valence-band and core-level photoemission spectra of NiO2008
Author(s)
M. Taguchi, M. Matsunami, Y. Ishida, R. Eguchi, A. Chainani, Y. Takata, M. Yabashi, K. Tamasaku, Y. Nishino, T. Ishikawa, Y. Senba, H. Ohashi, S. Shin
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Journal Title
Phys Rev. Lett. 100
Pages: 206401-4
Related Report
Peer Reviewed
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[Journal Article] Temperature-dependent localized excitations of doped carriers in superconducting diamond2008
Author(s)
K. Ishizaka, R. Eguchi, S. Tsuda, A. Chainani, T. Yokoya, T. Kiss, T. Shimojima, T. Togashi, S. Watanabe, C.T. Chen, Y. Takano, M. Nagao, I. Sakaguchi, T. Takenouchi, H. Kawarada, S. Shin
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Journal Title
Phys Rev. Lett. 100
Pages: 166402-4
Related Report
Peer Reviewed
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[Journal Article] A versatile system for ultrahigh resolution, low temperature, and polarization dependent laser-angle-resolved photoemission specteoscopy2008
Author(s)
T. Kiss, T. Shimojima, K. Ishizaka, A. Chainani, T. Togashi, T. Kanai, X.Y. Wang, C.T. Chen, S. Watanabe, S. Shin
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Journal Title
Rev. Sci. Instrum. 79
Pages: 23106-7
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Peer Reviewed
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[Journal Article] Bulk electronic structure of the antiferromagnetic superconducting phase in ErNi2B2C2008
Author(s)
T. Baba, T. Yokoya, S. Tsuda, T. Kiss, T. Shimojima, K. Ishizaka, T. Watanabe, M. Nohara, H. Takagi, N. Nakai, K. Machida, T. Togashi, S. Watanabe, X.Y. Wang, S. Shin
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Journal Title
Phys Rev. Lett. 100
Pages: 17003-4
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Peer Reviewed
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[Journal Article] Interplay of superconductivity and rattling phenomena in β-pyrochlore KOs2O2 studied by photoemission spectroscopy2007
Author(s)
T. Shimojima, Y. Shibata, K. Ishizaka, T. Kiss, A. Chainani, T. Yokoya, T. Togashi, X. Y Wang, C. T Chen, S. Watanabe, J. Yamaura, S. Yonezawa, Y. Muraoka, Z. Hiroi, T. Saitoh, S. Shin
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Journal Title
Phys Rev. Lett. 99
Pages: 117003-4
Related Report
Peer Reviewed
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[Journal Article] Recoil effects of photoelectrons in a solid2007
Author(s)
Y. Takata, Y. Kayanuma, M. Yabashi, K. Tamasaku, S. Shin, S. Tanaka, E. Ikenaga, K. Kobayashi, Y. Senba, H. Ohashi, T. Ishikawa
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Journal Title
Phys Rev. B 75
Pages: 233404-4
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Peer Reviewed
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[Journal Article] Observation of a superconducting gap in boron-doped diamond by laser-excited photoemission spectroscopy2007
Author(s)
K. Ishizaka, R. Eguchi, S. Tsuda, T. Yokoya, A. Chainani, T. Kiss, T. Shimojima, T. Togashi, S. Watanabe, C.T. Chen, C.Q. Zhang, Y. Takano, M. Nagao, I. Sakaguchi, T. Takenouchi, H. Kawarada, S. Shin
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Journal Title
Phys Rev. Lett. 98
Pages: 47003-4
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Peer Reviewed
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[Journal Article] Observation of a Superconducting Gap in Boron-Doped Diamond by Laser-Excited Photoemission Spectroscopy2007
Author(s)
K. Ishizaka, R. Eguchi, S. Tsuda, T. Yokoya, A. Chainani, T. Kiss, T. Shimojima, T. Togashi, S. Watanabe, C.-T. Chen, C. Q. Zhang, Y. Takano, M. Nagao, I. Sakaguchi, H. Kawarada, and S. Shin
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Journal Title
Phys. Rev. Lett. 98
Pages: 47003-47006
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Peer Reviewed
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[Journal Article] Interplay of superconducdvity and rattling phenomena in β-pyrochlore KOs_2O_6 studied by photoemission spectroscopy2007
Author(s)
T. Shimojima, Y. Shibata, K. Ishizaka, T. Kiss, A. Chainani, T. Yokoya, T. Togashi, X.-Y. Wang, C. T. Chen, S. Watanabe, J. Yonezawa, Y. Muraoka, Z. Hiroi, T. Saitoh, S. Shin
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Journal Title
Phys. Rev. Lett. 98
Pages: 117003-117006
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Peer Reviewed
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[Journal Article] Direct observation of site-specific valence electronic structure at the SiO2/Si interface2006
Author(s)
Y. Yamashita, S. Yamamoto, K. Mukai, J. Yoshinobu, Y. Harada, T. Tokushima, T. Takeuchi, Y. Takata, S. Shin, K. Akagi, S. Tsuneyuki
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Journal Title
Phys Rev. B 73
Pages: 45336-4
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Peer Reviewed
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[Journal Article] Heavy-Fermion-like State in a Transition Metal Oxide LiV_2O_4 Single Crystal : Indication of Kondo Resonance in the Photoemission Spectrum2006
Author(s)
A.Shimoyamada, S.Tsuda, K.Ishizaka, T.Kiss, T.Shimojima, T.Togashi, S.Watanabe, C.Q.Zhang, C.T.Chen, Y.Matsushita, H.Ueda, S.Shin
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Journal Title
Phys. Rev. Lett. 96
Pages: 26403-26406
Related Report
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[Journal Article] Direct observation of site-specific valence electronic structure at the SiO_2/Si interface2006
Author(s)
Y.Yamashita., S.Yamamoto, K.Mukai, J.Yoshinobu, Y.Harada, T.Tokushima, T.Takeuchi, Y.Takata, S.Shin, K.Akagi, S.Tsuneyuki
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Journal Title
Phys. Rev. B 73
Pages: 45336-45339
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[Journal Article] Bulk-and Surface-Sensitive High-Resolution Photoemission Study of Two Mott-Hubbard Systems : SrVO_3 and CaVO_32006
Author(s)
R.Eguchi, T.Kiss, S.Tsuda, T.Shimojima, T.Mizokami, T.Yokoya, A.Chainani, S.Shin, I.H.Inoue, T.Togashi, S.Watanabe, C.Q.Zhang, C.T.Chen, M.Arita, K.Shimada, H.Namatame, M.Taniguchi
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Journal Title
Phys. Rev. Lett. 96
Pages: 76402-76405
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[Journal Article] Direct observation of the site-specific valence electronic structure at SiO_2/Si(111) interface2006
Author(s)
Y.Yamashita, S.Yamamoto, K.Mukai, J.Yoshinobu, Y.Harada, T.Tokushima, T.Takeuchi, Y.Takata, S.Shin, K.Agaki, S.Tsuneyuki
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Journal Title
e-J. Surf. Sci. Nanotech 4
Pages: 280-284
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[Journal Article] Laser-excited ultrahigh-resolution photoemission spectroscopy of superconducting Na_<0.35>CoO_2・1.3H_2O2006
Author(s)
T.Shimojima, T.Yokoya, T.Kiss, A.Chainani S.Shin, T.Togashi, C.Zhang, C.Chen, S.Watanabe, K.Takada, T.Sasaki, H.Sakurai, E.Takayama-Muromachi
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Journal Title
Journal of Physics and Chemistry of Solids 67
Pages: 282-285
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[Journal Article] Laser-excited ultrahigh-resolution photoemission study of anisotropic s-wave superconductor YNi_2B_2C2006
Author(s)
T.Baba, Y.Yokoya, S.Tsuda, T.Kiss, T.Shimojima, S.Shin, T.Togashi, C.T.Chen, C.Q.Zhang, S.Watanabe, T.Watanabe, M.Nohara, H.Takagi
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Journal Title
Physica B 378-380
Pages: 469-470
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[Journal Article] Laser-excited ultrahigh-resolution photoemission spectroscopy of borocarbide superconductor RNi_2B_2C (R=Y and Er)2006
Author(s)
T.Baba, T.Yokoya, S.Tsuda, T.Kiss, T.Shimojima, S.Shin, T.Togashi, C.T.Chen, C.Q.Zhang, S.Watanabe, T.Watanabe, M.Nohara, H.Takagi
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Journal Title
Physica C 445-448
Pages: 46-49
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[Journal Article] Low-Energy Charge-Density Excitations in MgB_2 : Striking Interplay between Single-Particle and Collective Behavior for Large Momenta2006
Author(s)
Y.Q.Cai, P.C.Chow, O.D.Restepo, Y.Takano, K.Togano, H.Kito, H.Ishii, C.C.Chen, K.S.Liang, C.T.Chen, S.Tsuda, S.Shin, C.C.Kao, W.Ku, A.G.Eguiluz
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Journal Title
Phys. Rev. Lett. 97
Pages: 176402-176405
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[Journal Article] Photoemission spectroscopic evidence of gap anisotropy in an f-electron superconductor2005
Author(s)
T. Kiss, F. Kanetaka, T. Yokoya, T. Shimojima, K. Kanai, S. Shin, Y. Onuki, T. Togashi, C. Zhang, C.T. Chen, S. Watanabe
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Journal Title
Phys Rev. Lett. 94
Pages: 57001-4
Related Report
Peer Reviewed
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[Journal Article] Evidence for suppressed screening on the surface of high temperature La2-xSrxCuO4 and Nd2-xCexCuO4 superconductors2005
Author(s)
M. Taguchi, A. Chainani, K. Horiba, Y. Takata, S. Shin, T. Yokoya, E. Ikenaga, K. Kobayashi, T. Mochiku, K. Hirata, J. Hori, T. Suzuki
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Journal Title
Phys Rev. Lett. 95
Pages: 177002-4
Related Report
Peer Reviewed
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[Journal Article] Direct observation of a neutral Mn acceptor in Ga_<1-x>Mn_xAs by resonant x-ray emission spectroscopy2005
Author(s)
Y.Ihiwata, T.Takeuchi, R.Eguchi, M.Watanabe, Y.Harada, K.Kanai, A.Chanani, M.Taguchi, S.Shin, M.C.Debnath, I.Souma, Y.OKa, T.Hayashi, Y.Hashimoto, S.Katsumoto, Y.Iye
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Journal Title
Related Report
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[Journal Article] Ultrahigh-resolution Photoemission Spectroscopy of superconductors using a VUV laser2005
Author(s)
T.Kiss, T.Shimojima, N.Kanetaka, K.Kanai, T.Yokoya, S.Shin, Y.Onuki, T.Togashi, C.Q.Zhang, C.T.Chen, S.Watanabe
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Journal Title
Journal of Electron Spectroscopy and Related Phenomena 144-147
Pages: 953-956
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[Journal Article] Interface reaction of poly-Si/high-k insulator systems studied by hard X-ray photoemission spectroscopy2005
Author(s)
E.Ikenaga, I.Hirosawa, A.Kitano, Y.Takata, A.Muro, T.Maeda, K.Torri, H.Kitajima, M.Awaji, K.Tamasaku, T.Ishikawa, S.Komiya, K.Kobayashi
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Journal Title
Journal of Electron Spectroscopy and Related Phenomena 144-147
Pages: 491-494
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[Journal Article] Electronic structure of the Ga_<1-X>Cr_XN studied by high-energy photoemission spectroscopy2005
Author(s)
J.J.Kim, H.Makino, T.Yao, Y.Takata, K.Kobayashi, T.Yamamoto, T.Hanada, M.W.Cho, E.Ikenaga, D.Miwa, Y.Nishino, K.Tamasaku, T.Ishikawa, S.Shin
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Journal Title
Journal of Electron Spectroscopy and Related Phenomena 144-147
Pages: 561-564
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[Journal Article] Bulk screening in core-level photoemission from Mott-Hubbard and charge-transfer systems2005
Author(s)
M.Taguchi, A.Chanani, N.Kamakura K.Horiba, Y.Takata, M.Yabashi, K.Tamasaku, Y.Nishino, D.Miwa, T.Ishikawa, S.Shin, E.Ikenaga, T.Yokoya, K.Kobayashi, I.Mochiku, H.Hirata, K.Motoya
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Journal Title
Phys.Rev.B 71
Pages: 155102-155106
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[Journal Article] Laser-excited ultrahigh-resolution photoemission spectroscopy of Na_xCoO_2 ・yH_2O: Evidence for pseudogap formation2005
Author(s)
T.Shimojima, T.Yokoya, T.Kiss, A.Chainani, S.Shin, T.Togashi, S.Watanabe, C.Zhang, C.T.Chen, K.Takada, T.Sadsaki, H.Sakurai, E.Takayama-Muromachi
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Journal Title
Related Report
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[Journal Article] Hard-X-ray photoelectron spectroscopy of Na_xCoO_2・yH_2O2005
Author(s)
A.Chainani, T.Yokoya, Y.Takata, K.Tamasaku, M.Taguchi, T.Shimojima, N.Kanakura, K.Horiba, S.Tsuda, S.Shin, D.Miwa, Y.Nishino, T.Ishikawa, M.Yabashi, K.Kobayashi, H.Namatame, M.Taniguchi, K.Takada, T.Sasaki, H.Sakurai, E.Takayama-Muromachi
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Journal Title
Nuclear Instruments and Methods in Physics Research A 547
Pages: 163-168
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[Journal Article] Development of hard X-ray photoelectron spectroscopy at BL29XU in Spring-82005
Author(s)
Y.Takata, M.Yabashi, K.Tamasaku, Y.Nishino, D.Miwa, T.Ishikawa, E.Ikenaga, K.Horiba, S.Shin, M.Arita, K.Shimada, H.Namatame, M.Taniguchi, H.Nohira, T.Hattori, S.Sodergren, B.Wannberg, K.Kobayashi
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Journal Title
Nuclear Instruments and Methods in Physics Research A 547
Pages: 50-55
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[Journal Article] Carbon-substitution dependent multiple superconducting gap of MgB_2:A sub-meV resolution photoemission study2005
Author(s)
S.Tsuda, T.Yokoya, T.Kiss, T.Shimojima, S.Shin, T.Togashi, S.Watanabe, C.Zhan, C.T.Chen, S.Lee, H.Uchiyama, S.Tajima, N.Nakai, K.Machida
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Journal Title
Phys.Rev.B 72
Pages: 64527-64531
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[Journal Article] Temperature-dependent Eu 3d-4f x-ray absorption and resonant photoemission study of the valence transition in EuNi_2(Si_<0.2>Ge_<0.8>)_22005
Author(s)
K.Yamamoto, K.Horiba, M.Taguchi, M.Matsunami, N.Kamakura, A.Chainani, Y.Takata, K.Miura, M.Shiga, H.Wada, Y.Senba, H.Ohashi, S.Shin
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[Journal Article] Evidence for Suppressed Screening on the Surface of High Temperature La_<2-x>Sr_xCuO_4 and Nd_<2-x>Ce_xCuO_4 Superconductors2005
Author(s)
M.Taguchi, A.Chainani, K.Horiba, Y.Takata, M.Yabashi, K.Tamasaku, Y.Nishino, D.Miwa, T.Ishikawa, T.Takeuchi, K.Yamamoto, M.Matsunami, S.Shin, T.Yokoya, E.Ikenaga, K.Kobayashi, T.Mochiku, K.Hirata, J.Hori, K.Ishii, F.Nakamura, T.Suzuki
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Journal Title
Phys.Rev.Lett. 95
Pages: 177002-177055
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[Journal Article] Ultraviolet laser photoemission spectroscopy of FeSi: Observation of a opening in density of states2005
Author(s)
K.Ishizaka, T.Kiss, T.Shimojima, T.Yokoya, T.Togashi, S.Watanabe, C.Q.Zhang, C.Chen, Y.Onose, Y.Tokura, S.Shin
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Journal Title
Phys.Rev.B 72
Pages: 233202-233205
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