Solvation and cluster structure of ionic liquids
Project/Area Number |
17073006
|
Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
|
Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
|
Research Institution | Tokyo Institute of Technology |
Principal Investigator |
SHIBUYA Kazuhiko Tokyo Institute of Technology, 大学院・理工学研究科化学専攻, 教授 (30126320)
|
Co-Investigator(Kenkyū-buntansha) |
KAWAI Akio 東京工業大学, 大学院・理工学研究科, 准教授 (50262259)
|
Project Period (FY) |
2005 – 2009
|
Project Status |
Completed (Fiscal Year 2009)
|
Budget Amount *help |
¥37,900,000 (Direct Cost: ¥37,900,000)
Fiscal Year 2009: ¥6,800,000 (Direct Cost: ¥6,800,000)
Fiscal Year 2008: ¥7,800,000 (Direct Cost: ¥7,800,000)
Fiscal Year 2007: ¥7,800,000 (Direct Cost: ¥7,800,000)
Fiscal Year 2006: ¥7,800,000 (Direct Cost: ¥7,800,000)
Fiscal Year 2005: ¥7,700,000 (Direct Cost: ¥7,700,000)
|
Keywords | クラスター・溶媒和 / 磁気共鳴 / 化学反応 / ダイナミクス / クラスター / 溶媒和 / グリーンケミストリー / 溶液 |
Research Abstract |
We have carried out research on diffusion of molecular oxygen in ILs and the relaxation of triplet states, rotational diffusion in ILs and their analysis by a fractional Stokes-Einstein-Debye Law, cryogenic neon matrix-isolation FTIR spectroscopy of evaporated ILs, and geometrical structure of cation-anion 1:1 pair in the gas phase, the electronic spectra of vaporized ILs based on imidazolium and pyridinium cations, and photochromism of 3-butyl-1-methyl-2- phenylazoimidazolium in room temperature.
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Report
(6 results)
Research Products
(63 results)