Synthesis and synthetic utilities of functionalized reaction system in ionic liquids
| Project/Area Number |
17073007
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
KITAZUME Tomoya Tokyo Institute of Technology, 大学院・生命理工学研究科, 教授 (30092547)
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| Co-Investigator(Kenkyū-buntansha) |
YAMAZAKI Takashi 東京農工大学, 大学院・共生科学技術研究院, 准教授 (40191267)
松田 知子 東京工業大学, 大学院・生命理工学研究科, 講師 (10319494)
岩井 伯隆 東京工業大学, 大学院・生命理工学研究科, 助教 (80376938)
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| Co-Investigator(Renkei-kenkyūsha) |
IWAI Noritaka 東京工業大学, 大学院・生命理工学研究科, 助教 (80376938)
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| Project Period (FY) |
2005 – 2009
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| Project Status |
Completed (Fiscal Year 2009)
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| Budget Amount *help |
¥78,200,000 (Direct Cost: ¥78,200,000)
Fiscal Year 2009: ¥9,500,000 (Direct Cost: ¥9,500,000)
Fiscal Year 2008: ¥10,600,000 (Direct Cost: ¥10,600,000)
Fiscal Year 2007: ¥19,600,000 (Direct Cost: ¥19,600,000)
Fiscal Year 2006: ¥19,200,000 (Direct Cost: ¥19,200,000)
Fiscal Year 2005: ¥19,300,000 (Direct Cost: ¥19,300,000)
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| Keywords | イオン液体 / 酵素反応 / フルオリナーゼ / 光学活性体 / 機能性反応場 / 生理活性 / フッ素系物質 / 構造活性相関 / 反応場 / グラム陽性菌 / グラム陰性菌 / 酵素阻害系 / 最小発育阻止濃度 / グーラム陰性菌 / 酵素阻害剤 / 活性点 / 水素結合 / 機能性イオン液体 / 進化型反応場 / 酸化反応 / 部位特異的変換 / 遺伝子組換え / フッ素化酵素 |
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| Research Abstract |
We have established new ionic liquid reaction systems for the organic reactions. 1) We have reported the utilities of ionic liquid-supported NHPI complexes as recoverable and recyclable systemfor the oxidation and nitration. 2) Ionic liquids have recognized as a solvent for Geotrichum candidum-catalyzed optical resolution and/or deracemization of rcemic secondary alcohols, giving optically active alcohols.
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Report
(6 results)
Research Products
(31 results)
