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Development of cross-correlation highly sensitive electron spectroscopy and real-time measurement of chemical reactions at interface

Research Project

Project/Area Number 17205001
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

OHNO Koichi  Tohoku University, 大学院・理学研究科, 教授 (60012499)

Co-Investigator(Kenkyū-buntansha) 山北 佳宏  東北大学, 大学院・理学研究科, 助教 (30272008)
岸本 直樹  東北大学, 大学院・理学研究科, 講師 (60302080)
Co-Investigator(Renkei-kenkyūsha) YAMAKITA Yoshihiro  東北大学, 大学院・理学研究科, 助教 (30272008)
KISHIMOTO Naoki  東北大学, 大学院・理学研究科, 講師 (60302080)
Project Period (FY) 2005 – 2008
Project Status Completed (Fiscal Year 2008)
Budget Amount *help
¥49,140,000 (Direct Cost: ¥37,800,000、Indirect Cost: ¥11,340,000)
Fiscal Year 2008: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2007: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2006: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Fiscal Year 2005: ¥29,770,000 (Direct Cost: ¥22,900,000、Indirect Cost: ¥6,870,000)
Keywords電子分光 / 準安定励起原子 / 衝突エネルギー / 表面反応過程 / 電子構造 / 電子相関効果 / 分子軌道 / 化学反応 / 量子化学計算 / 電子状態 / 相互作用ポテンシャル / 反応機構 / 衝突イオン化反応 / 固体表面 / 分子配向 / 吸着 / 界面反応過程 / リアルタイム観測 / 低速原子ビーム
Research Abstract

準安定励起原子と分子の衝突反応過程において、時間相関超高感度電子分光法を開発することで、衝突エネルギーと電子エネルギーの2パラメーターを分解する2次元電子分光法を固体表面に適用することに初めて成功し、界面での化学反応過程をリアルタイムで観測すること、並びに、分子表面に関する研究を推進することが出来た。

Report

(5 results)
  • 2008 Annual Research Report   Final Research Report ( PDF )
  • 2007 Annual Research Report
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (43 results)

All 2009 2008 2007 2006 2005

All Journal Article (34 results) (of which Peer Reviewed: 22 results) Presentation (9 results)

  • [Journal Article] Penning ionization electron spectra of pyrene, chrysene, and coronene in collision with metastable He(2^3S)atoms in the gas phase2009

    • Author(s)
      Yoshihiro Yamakita, Masayo Yamauchi, and Koichi Ohno
    • Journal Title

      J.Chem.Phys 130

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stereodynamics and Outer Valence Ionic States of Ferrocene in Collisional Ionization with a He*(2^3S)Metastable Atom by Two-Dimensional Penning Ionization Electron Spectroscopy2009

    • Author(s)
      Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      J.Phys.Chem.A 113

      Pages: 521-526

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular Vibrational Frequencies of Water Clusters (H_2O)_n (n=2-5) : Anharmonic Analyses Using Accurate Potential Functions based on the Scaled Hvpersphere Search Method2008

    • Author(s)
      Y. Watanabe, et.al.
    • Journal Title

      Journal of Chemical Physics 129

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Automated Exploration of Reaction Channels2008

    • Author(s)
      K. Ohno, et.al.
    • Journal Title

      Physica Scripta 78

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lowest Transition State for the Chirality-Determining Step in Ru{(R)-BINAP}-Catalyzed Asymmetric Hydrogenation of Methyl-3-Oxobutanoate2008

    • Author(s)
      S. Maeda, et.al.
    • Journal Title

      Journal of American Chemical Society 130

      Pages: 17228-17229

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of anisotropic interactions and molecular orbitals of CO upon collision with He*(2^3S)atoms by two-dimensional Penning ionization electron spectroscopy2007

    • Author(s)
      Naoki Kishimoto, Masakazu Yamazaki, Yoshinori Hanzawa, Takuya Horio, and Koichi Ohno
    • Journal Title

      J.Phys.Conf.Ser. 88

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Determination of outer molecular orbitals by collisional experiments2007

    • Author(s)
      Masakazu Yamazaki, Takuya Horio, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      Phys.Rev.A 75

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Observation of Anisotropic Interactions between Metastable Atoms and Target Molecules by Two-Dimensional Collisional Ionization Electron Spectroscopy2007

    • Author(s)
      Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      Int.Rev.Phys.Chem. 26

      Pages: 93-138

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Observation of Anisotropic Interactions between Metastable Atoms and Target Molecules by Two-Dimensional Collisional Ionization Electron Spectroscopy2007

    • Author(s)
      N. Kishimoto and K. Ohno
    • Journal Title

      International Review of Physical Chemistry 26

      Pages: 93-138

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of outer molecular orbitals by collisional ionization experiments and comparison with Hartree-Fock, Kohn-Sham,and Dyson orbitals2007

    • Author(s)
      M. Yamazaki, 他
    • Journal Title

      Physical Review A 75

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of anisotropic interactions and molecular orbitals of CO upon collision with He*(2^3S)atoms by two-dimensional Penning ionization electron spectroscopy2007

    • Author(s)
      N. Kishimoto, 他
    • Journal Title

      Journal of Physics: Conference Series 88

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of Anisotropic Interactions between Metastable Atoms and Target Molecules by Two-Dimensional Collisional Ionization Electron Spectroscopy2007

    • Author(s)
      N.Kishimoto, K.Ohno
    • Journal Title

      International Review of Physical Chemistry 26・1-3

      Pages: 93-138

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Determination of outer molecular orbitals by collisional ionization experiments and comparison with Hartree-Fock, Kohn-Sham, and Dyson orbitals2007

    • Author(s)
      M.Yamazaki, 他
    • Journal Title

      Physical Review A 75・3

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Collision-Energy-Resolved Penning Ionization Electron Spectroscopy of Toluene and Chlorotoluenes : Stereodynamics in Collisional Ionization and Anisotropic Interactions with He*(2^3S)Atoms2006

    • Author(s)
      Naoki Kishimoto, Makoto Matsumoto, Eiichi Matsumura, and Koichi Ohno
    • Journal Title

      Euro.Phys.J.D 38

      Pages: 75-84

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Collision-Energy-Resolved Penning Ionization Electron Spectroscopy of Styrene, 2-Vinylpyridine, and 4-Vinylpyridine with He*(2^3S) Metastable Atoms2006

    • Author(s)
      Masakazu Yamazaki, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      Euro.Phys.J.D 38

      Pages: 47-58

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anisotropic interaction and stereo reactivity in a chemi-ionization process of OCS by collision with He*(2^3S)metastable atoms2006

    • Author(s)
      Takuya Horio, Satoshi Maeda, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      J.Phys.Chem.A 110

      Pages: 11010-11017

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Collision-Energy-Resolved Penning Ionization Electron Spectroscopy of Thiazole and Benzothiazole : Study of Ionic States and Anisotropic Interactions between a Metastable He*(2^3S)Atom and Hetero Cyclic Compounds2006

    • Author(s)
      Masakazu Yamazaki, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      J.Phys.Chem.A 110

      Pages: 7097-7104

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Collision-Energy-Resolved Penning Ionization Electron Spectroscopy of Phenylacetylene and Diphenylacetylene by Collision with He*(2^3S)Metastable Atoms2006

    • Author(s)
      Andriy Borodin, Masakazu Yamazaki, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      J.Phys.Chem.A 110

      Pages: 1783-1790

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Probing anisotropic interaction potentials of unsaturated hydrocarbons with He*(2^3S)metastable atom : Attractive-site preference of σ-direction in C_2H_2 and π-direction in C_2H_42006

    • Author(s)
      Takuya Horio, Takuro Hatamoto, Satoshi Maeda, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      J.Chem.Phys. 124

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Collision-energy-resolved angular distribution of Penning electrons for N_2-He*(2^3S)2006

    • Author(s)
      Yoshinori Hanzawa, Naoki Kishimoto, Masakazu Yamazaki, and Koichi Ohno
    • Journal Title

      Chem.Phys.Lett. 426

      Pages: 43-48

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anisotropic interaction and stereo reactivity in a chemi-ionization process of OCS by collision with He(2^3S) metastable atoms2006

    • Author(s)
      T.Horio, 他
    • Journal Title

      The Journal of Physical Chemistry A 110・38

      Pages: 11010-11017

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Collision-energy-resolved angular distribution of Penning electrons for N_2-He(2^3S)2006

    • Author(s)
      Y.Hanzawa, 他
    • Journal Title

      Chemical Physics Letters 426・1-3

      Pages: 43-48

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Collision-Energy-Resolved Penning Ionization Electron Spectroscopy of Thiazole and Benzothiazole : Study of Ionic States and Anisotropic Interactions between a Metastable He(2^3S) Atom and Hetero Cyclic Compounds2006

    • Author(s)
      M.Yamazaki, 他
    • Journal Title

      The Journal of Physical Chemistry A 110・22

      Pages: 7097-7104

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Probing anisotropic interaction potentials of unsaturated hydrocarbons with He(2^3S) metastable atom : Attractive-site preference of σ-direction in C_2H_2, and π-direction in C_2H_42006

    • Author(s)
      T.Horio, 他
    • Journal Title

      The Journal of Chemical Physics 124・10

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Collision-Energy-Resolved Penning Ionization Electron Spectroscopy of Phenylacetylene and Diphenylacetylene by Collision with He^*(2^3S) Metastable Atoms2006

    • Author(s)
      A.Borodin, 他
    • Journal Title

      Journal of Physical Chemistry A 110・5

      Pages: 1783-1790

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Development of a Cooled He*(2^3S)Beam Source for Measurements of State-Resolved Collision Energy Dependence of Penning Ionization Cross Sections : Evidence for a Stereo Specific Attractive Well Around Methyl Group in CH_3CN2005

    • Author(s)
      Takuya Horio, Masakazu Yamazaki, Satoshi Maeda, Takuro Hatamoto, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      J.Chem.Phys. 123

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Penning ionization electron spectroscopy of C_6H_6 by collision with He*(2^3S)metastable atoms and classical trajectory calculations : Optimization of ab initio model potentials2005

    • Author(s)
      Masakazu Yamazaki, Satoshi Maeda, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      J.Chem.Phys. 122

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Probing the Shape and Stereochemistry of Molecular Orbitals in Locally Flexible Aromatic Chains : A Penning Ionization Electron Spectroscopy and Green's Function Study of the Electronic Structure of Biphenyl2005

    • Author(s)
      Naoki Kishimoto, Yusuke Hagihara, Koichi Ohno, Stefan Knippenberg, Jean-Pierre Francois, and Michael S. Deleuze
    • Journal Title

      J.Phys.Chem.A 109

      Pages: 10535-10546

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Collision-Energy- Resolved Penning Ionization Electron Spectroscopy of HCOOH, CH_3COOH, and HCOOCH_3 by Collision with He*(2^3S)Metastable Atoms2005

    • Author(s)
      Andriy Borodin, Masakazu Yamazaki, Naoki Kishimoto, and Koichi Ohno
    • Journal Title

      J.Phys.Chem.A 109

      Pages: 4721-4727

    • Related Report
      2008 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensional Penning Ionization Electron Spectroscopic Study on Outer Characteristics of Molecules2005

    • Author(s)
      K.Ohno, 他
    • Journal Title

      J. Electron Spectroscopy and Related Phenomena 142・3

      Pages: 283-293

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Penning Ionization Electron Spectroscopy of C_6H_6 with He^*(2^3S) Metastable Atoms and Classical Trajectory Calculations : Optimization of ab initio Model Potentials2005

    • Author(s)
      M.Yamazaki, 他
    • Journal Title

      Journal of Chemical Physics 122・4

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Collision-Energy-Resolved Penning Ionization Electron Spectroscopy of HCOOH, CH_3COOH, and HCOOCH_3 by Collision with He^*(2^3S) Metastable Atoms2005

    • Author(s)
      A.Borodin, 他
    • Journal Title

      Journal of Physical Chemistry A 109・21

      Pages: 4721-4727

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Probing the Shape and Stereochemistry of Molecular Orbitals in Locally Flexible Aromatic Chains : A Penning Ionization Electron Spectroscopy and Green's Function Study of the Electronic Structure of Biphenyl2005

    • Author(s)
      N.Kishimoto, 他
    • Journal Title

      Journal of Physical Chemistry A 109・46

      Pages: 10535-10546

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Development of a Cooled He*(2^3S) Beam Source for Measurements of State-Resolved Collision Energy Dependence of Penning Ionization Cross Sections : Evidence for a Stereo Specific Attractive Well around Methyl Group in CH_3CN2005

    • Author(s)
      T.Horio, 他
    • Journal Title

      Journal of Chemical Physics 123・19

    • Related Report
      2005 Annual Research Report
  • [Presentation] Global Reaction Route Mapping on the Potential Energy Surface via the Anharmonic Downward Distortion Following2008

    • Author(s)
      Koichi Ohno
    • Organizer
      The World Association of Theoretical and Computational Chemists(WATOC)2008
    • Place of Presentation
      Sydney, Australia
    • Year and Date
      2008-09-18
    • Related Report
      2008 Final Research Report
  • [Presentation] Global Reaction Route Mapping on the Potential Energy Surface via the Anharmonic Downward Distortion Following2008

    • Author(s)
      K. Ohno, et.al.
    • Organizer
      The World Association of Theoretical and Computational Chemists (WATOC) 2008
    • Place of Presentation
      Sydney Convention and Exhibition Centre, Sydney, Australia
    • Year and Date
      2008-09-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] Development of New Techniques to Study Collisional Reaction Dynamics and Interaction Potential Energy Surfaces2008

    • Author(s)
      Koichi Ohno, Naoki Kishimoto, and Satoshi Maeda
    • Organizer
      The 8th Asian International Seminar on Atomic and Molecular Physics(AISAMP8)
    • Place of Presentation
      Perth, Australia
    • Related Report
      2008 Final Research Report
  • [Presentation] Collision-energy-resolved metastable impact electron spectroscopy of molecules adsorbed on a metal surface2008

    • Author(s)
      Naoki Kishimoto, Yasuhiko Kudo, and Koichi Ohno
    • Organizer
      The 12th International Symposium of Stereodynamics of Chemical Reactions
    • Place of Presentation
      Dalian, China
    • Related Report
      2008 Final Research Report
  • [Presentation] Observation of Molecular Orbitals and Anisotropic Interactions by Two-Dimensional Collisional Ionization Electron Spectroscopy2008

    • Author(s)
      Naoki Kishimoto
    • Organizer
      The 2nd Imaging Techniques in Atomic and Molecular Physics Symposium
    • Place of Presentation
      Hefei, China
    • Related Report
      2008 Final Research Report
  • [Presentation] Observation of Anisotropic Interactions and Molecular Orbitals by Two-Dimensional Penning Ionization Electron Spectroscopy2007

    • Author(s)
      N. Kishimoto
    • Organizer
      ICPEAC XXV(International Conference on Photonic, Electronic and Atomic Collisions)
    • Place of Presentation
      Freiburg(ドイツ国)
    • Year and Date
      2007-07-30
    • Related Report
      2007 Annual Research Report
  • [Presentation] Observation of Anisotropic Interactions and Molecular Orbitals by Two-Dimensional Penning Ionization Electron Spectroscopy2007

    • Author(s)
      Naoki Kishimoto, Takuya Horio, Masakazu Yamazaki, Koichi Ohno
    • Organizer
      ICPEAC XXV(International Conference on Photonic, Electronic and Atomic Collisions)Special
    • Place of Presentation
      Reports, Freiburg
    • Related Report
      2008 Final Research Report
  • [Presentation] Anisotropic interactions between a metastable atom and a target molecule by two-dimensional Penning ionization electron spectroscopy2006

    • Author(s)
      Naoki Kishimoto, and Koichi Ohno
    • Organizer
      MOLEC XVI(European Conference on Dynamics of Molecular Systems)
    • Place of Presentation
      Italy
    • Related Report
      2008 Final Research Report
  • [Presentation] Determination of anisotropic interactions and valence ionic states by collision-energy/electron-energy-resolved Penning ionization electron spectroscopy2006

    • Author(s)
      Naoki Kishimoto, Takuya Horio, and Koichi Ohno
    • Organizer
      The ICQC2006 Satellite Symposium in Sendai on Recent Advances in Theoretical and Spectroscopic Studies on Electron Dynamics and Related Phenomena
    • Place of Presentation
      Matsushima
    • Related Report
      2008 Final Research Report

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Published: 2005-04-01   Modified: 2016-04-21  

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