Science and Function of Organic Amorphous Materials-An Approach from Precise Analysis of Static and Dynamic Structures-

• Project/Area Number: 17205018
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Functional materials/Devices
• Research Institution: Kyoto University
• Principal Investigator: KAJI Hironori Kyoto University, Institute for Chemical Research, Associate Professor (30263148)
• Co-Investigator(Kenkyū-buntansha): GOTO Atsushi KYOTO UNIVERSITY, Institute for Chemical Research, Assistant Professor (20335219)
• Project Period (FY): 2005 – 2007
• Project Status: Completed (Fiscal Year 2007)
• Budget Amount: ¥48,750,000 (Direct Cost: ¥37,500,000、Indirect Cost: ¥11,250,000); Fiscal Year 2007: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000); Fiscal Year 2006: ¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000); Fiscal Year 2005: ¥20,410,000 (Direct Cost: ¥15,700,000、Indirect Cost: ¥4,710,000)
• Keywords: Organic LEDs / Nuclear Magnetic Resonanc / Molecular Solids / Amorphous Materials

Research Abstract

The purpose of this project is to establish solid-state NMR methodology which enables us the detailed analysis of static and dynamic structures of organic amorphous materials. In this study, the structure analysis of organic low-molecular-weight materials and polymers including synthetic and natural rubbers was performed. Among the series of researches, we especially focused on the analysis of materials for organic light-emitting diodes (OLEDs). For a light-emitting OLED material, a clear relationship was obtained between the light-emitting properties and the isomeric states. Since the isomeric states of Alga are difficult by X-ray diffraction experiments, the results obtained in this study clearly show the validity of the structure analysis by solid-state NMR On the basis of the relationship, OLEDs were fabricated from α-Alq3, δ-Alq3, and the mixture powders of α-, γ-, and δ-Alq3 It was found that the devices fabricated from δ-Alq3 and the mixture powders exhibit higher luminescence compared to those from standard α-Alq3. For a hole-transport OLED material, the intermolecular distance was determined by solid-state NMR with a supercycle R26411 pulse sequence. This is a first example, which experimentally determines the hopping distance for the carrier transport of the OLED material.

Research Products

• [Journal Article] Electron-Vibration Interactions in Carrier-Transport Material: Vibronic Coupling Density Analysis in TPD (2008)
  • Author(s): Tohru Sato, Katsuyuki Shizu, Takako Kuga, Kazuyoshi Tanaka, and Hironori Kaji
  • Journal Title: Chemical Physics Letters
  • NAID: 120001750136
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Relationship between Resistivity and Structure of Photosensitive Organic Silsesquioxanes by Impedance Spectroscopy and Solid-State 29Si NMR (2008)
  • Author(s): Yasunari Kusaka, Shigeru Nakamura, Kenichi Azuma, Taku Sasaki, Takao Unate, Yasuhiro Nakatani, Akira Nakasuga, Kimihiro Matsukawa, Naoki watanabe, Hiroyoshi Naito, and Hironori Kaji
  • Journal Title: Japanese Journal of Applied Physics 47 Pages: 1377-1381
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Relationship between resistivity and structure of photosensitive organic silsesquioxanes by impedance Spectroscopy and solid-state 29Si nuclear magnetic resonance (2008)
  • Author(s): Y., Kusaka, S., Nakamura, K., Azuma, T., Sasaki, T., Unate, Y., Nakatani, A., Nakasuga, K., Matsukawa, N., Watanabe, H., Naito, H., Kaji
  • Journal Title: Jpn. J Appl. Phys 47 Pages: 1377-1381
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Relationship between Resistivity and Structure of Photosensitive Organic Silsesquioxanes by Impedance Spectroscopy and Solid-State 29Si NMR (2008)
  • Author(s): Yasunari Kusaka, Shigeru Nakamura, Kenichi Azuma, Taku Sasaki, Takao Unate, Yasuhiro Nakatani, Akira Nakasuga, Kimihiro Matsukawa, Naoki Watanabe, Hiroyoshi Naito, and Hironori Kaji
  • Journal Title: Japanese Journal of Applied Physics 47 Pages: 1377-1381
  • Peer Reviewed
• [Journal Article] Origin of the different emission wavelengths in Alq_3 analyzed by solid-state NMR (2007)
  • Author(s): Hironori Kaji, Tatsuya Fukushima, Kousuke Takami, Yasunari Kusaka
  • Journal Title: Proceedings of SPIE 6655 Pages: 1-10
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Characterization of Carbon Filler Distribution Ratio in Polyisoprene/Polybutadiene Rubber Blends by High-Resolution Solid-State 13C NMR (2007)
  • Author(s): Marina Kotani, Hidehiko Dohi, Hideaki Kimura, Kiyoshige Muraoka, and Hironori Kaji
  • Journal Title: Macromolecules 40 Pages: 9451-9454
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Photo-induced formation of wrinkled microstructures with long-range order in thin oxide film (2007)
  • Author(s): Masahide Takahashi, Takahiro Maeda, Koji Uemura, Jianxi Yao, Yomei Tokuda, Toshinobu Yoko, Hironori Kaji, Augusto Marcelli, and Plinio Innocenzi
  • Journal Title: Adv. Mat. 19 Pages: 4343-4346
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Effects of Porphyrin Substituents on Film Structure and Photoelectrochemical Properties of Porphyrin/Fullerene Composite Clusters Electrophoretically Deposited on Nanostructured SnO_2 Electrodes (2007)
  • Author(s): Hiroshi Imahori, Masahiro Ueda, Soonchul Kang, Hironobu Hayashi, Shinya Hayashi, Hironori Kaji, Shu Seki, Akinori Saeki, Seiichi Tagawa, Tomokazu Umeyama, Yoshihiro Matano, Kaname Yoshida, Seiji Isoda, Motoo Shiro, Nikolai V. Tkachenko, and Helge Lemmetyinen
  • Journal Title: Chem. Eur. J 13 Pages: 10182-10193
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Investigation of Dynamics of Poly(dimethylsilane)in the Mesophase by Solid-State^<29>Si NMR:Evidence for Rotator Phase (2007)
  • Author(s): Hironori Kaji and Fumitaka Horii
  • Journal Title: Macromolecules 40 Pages: 5420-5423
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Characterization of Molecular Orientation of Stretched Natural Bubber by Solid-State 13C NMR (2007)
  • Author(s): Hidehiko Dohi, Hideaki Kimura, Marina Kotani, Takanobu Matsunaga, Kazuo Yamauchi, Hironori Kaji, and Tetsuo Asakura
  • Journal Title: Polymer Journal 39 Pages: 502-503
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] 高分子科学の現在過去未来「高分子科学の未来を予想する-若手からの提言」 (2007)
  • Author(s): 梶 弘典
  • Journal Title: 高分子 56 Pages: 35-35
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Characterization of molecular orientation of stretched natural rubber by solid-state 13C NMR (2007)
  • Author(s): H., Dohi, H., Kimura, M., Kotani, T., Matsunaga, K., Yamauchi, H., Kaji, T., Asakura
  • Journal Title: Polym. J 39 Pages: 502-503
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Effects of porphyrin substituents on film structure and photoelectrochemical properties of porphyrin/fullerene composite clusters electrophoretically deposited on nanostructured SnO2 electrodes (2007)
  • Author(s): H., Imahori, M., Ueda, S., Kang, H., Hayashi, S., Hayashi, H., Kaji, S., Seki, A., Saeki, S., Tagawa, T., Umeyama, Y., Matano, K., Yoshida, S., Isoda, M., Shiro, N. V., Tkachenko, H., Lemmetyinen
  • Journal Title: Chem. Eur. J 13 Pages: 10182-10193
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Origin of the different emission wavelengths in Alga analyzed by solid-state NMR, Organic Light Emitting Materials and Devices XI. SPIE (2007)
  • Author(s): H., Kaji, T., Fukushima, K., Takami, Y., Kusaka
  • Journal Title: San Diego, CA, USA 6655 Pages: 66550401-66550410
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Investigation of dynamics of poly(dimethylsilane) in the mesophase by solid-state 29Si NMR : Evidence for rotator phase (2007)
  • Author(s): H., Kaji, F., Horii
  • Journal Title: Macromolecules 40 Pages: 5420-5423
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Characterization of carbon filler distribution ratio in polyisoprene/polybutadiene rubber blends by high-resolution solid-state 13C NMR (2007)
  • Author(s): M., Kotani, H., Dohi, H., Kimura, K., Muraoka, H., Kaji
  • Journal Title: Macromolecules 40 Pages: 9451-9454
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] A. Marcelli, and P. Innocenzi, Photoinduced formation of wrinkled microstructures with long-range order in thin oxide films (2007)
  • Author(s): M., Takahashi, T., Maeda, K., Uemura, J. X., Yao, Y. M., Tokuda, T., Yoko, H., Kaji
  • Journal Title: Adv. Mater 19 Pages: 4343-4346
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Origin of the different emission wavelengths in Alg_3 analyzed by solid-state NMR (2007)
  • Author(s): Hironori Kaji, Tatsuya Fukushima, Kousuke Takami, Yasunari Kusaka
  • Journal Title: Proceedings of SPIE 6655 Pages: 1-10
  • Peer Reviewed
• [Journal Article] Effects of Porphyrin Substituents on Film Structure and Photoelectrochemical Properties of Porphyrin/Fullerene l Composite Clusters Electrophoretically Deposited on Nanostructured SnO_2 Electrodes (2007)
  • Author(s): Hiroshi Imahori, Masahiro Ueda, Soonchul Kang, Hironobu Hayashi, Shinya Hayashi, Hironori Kaji, Shu Seki, Akinori Saeki, Seiichi Tagawa, Tomokazu Umeyama, Yoshihiro Matano, Kaname Yoshida, Seiji Isoda, Motoo Shiro, Nikolai V. Tkachenko, and Helge Lemmetyinen
  • Journal Title: Chem. Eur. J 13 Pages: 10182-10193
  • Peer Reviewed
• [Journal Article] Investigation of Dynamics of Poly (dimethylsilane) in the Mesophase by Solid-State 29Si NMR: Evidence for Rotator Phase (2007)
  • Author(s): Hironori Kaji and Fumitaka Horii
  • Journal Title: Macromolecules 40 Pages: 5420-5423
  • Peer Reviewed
• [Journal Article] 高分子科学の現在過去未来 「高分子科学の未来を予想する-若手からの提言」 (2007)
  • Author(s): 梶 弘典
  • Journal Title: 高分子 56 Pages: 35-35
• [Journal Article] Solid-state 13C NMR investigation of the structure and dynamics of highly drawn polyethylene-detection of the oriented non-crystalline component (2006)
  • Author(s): Nattawut Chaiyut, Taweechai Amornsakchai, Hironori Kaji, and Fumitaka Horii
  • Journal Title: Polymer 47 Pages: 2470-2481
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Dynamics of Monofunctional Polybutadienyl Lithium Chains Aggregated in Benzene (2006)
  • Author(s): Yohei Oishi, Hiroshi Watanabe, Toshiji Kanaya, Hironori Kaji, and Fumitaka Horii
  • Journal Title: Polymer Journal 38 Pages: 277-288
  • NAID: 10017315126
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] CP/MAS 13C NMR Characterization of the Isomeric States and Intermolecular Packing in Tris(8-hydroxyquinoline)Aluminum(III)(Alq_3) (2006)
  • Author(s): Hironori Kaji, Yasunari Kusaka, Goro Onoyama, and Fumitaka Horii
  • Journal Title: Journal of the American Chemical Society 128 Pages: 4292-4297
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] 固体NMR法による高分子材料の精密解析,高分子科学最近の進歩 (2006)
  • Author(s): 三好利一, 梶 弘典
  • Journal Title: 高分子 55 Pages: 744-749
  • Description: 「研究成果報告書概要(和文)」より
• [Journal Article] Solid-state 13C NMR investigation of the structure and dynamics of highly drawn polyethylene-detection of the oriented non-crystalline component (2006)
  • Author(s): N., Chaiyut, T., Amornsakchai, H., Kaji, F., Horii
  • Journal Title: Polymer 47 Pages: 2470-2480
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Quantitative Analysis of Conformations in Disordered Polymers by Solid-State Multiple-Quantum NMR (2006)
  • Author(s): H., Kaji
  • Journal Title: Modern Magnetic. Resonance Pages: 559-562
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] CP/MAS 13C NMR characterization of the isomeric states and intermolecular packing in tris(8-hydroxyquinoline) aluminum(III) (Alq3) (2006)
  • Author(s): H., Kaji, Y., Kusaka, G., Onoyama, F., Horii
  • Journal Title: J. Am Chem. Soc 128 Pages: 4292-4297
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Dynamics of monofunctional polybutadienyl lithium chains aggregated in benzene (2006)
  • Author(s): Y., Oishi, H., Watanabe, T., Kanaya, H., Kaji, F., Horii
  • Journal Title: Polym. J 38 Pages: 277-288
  • NAID: 10017315126
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] Solid-state ^<13>C NMR investigation of the structure and dynamics of highly drawn polyethylene-detection of the oriented non-crystalline component (2006)
  • Author(s): Nattawut Chaiyut, Taweechai Amornsakchai, Hironori Kaji, Fumitaka Horii
  • Journal Title: Polymer 47 Pages: 2470-2481
• [Journal Article] Dynamics of Monofunctional Polybutadienyl Lithium Chains Aggregated in Benzene (2006)
  • Author(s): Yohei Oishi, Hiroshi Watanabe, Toshiji Kanaya, Hironori Kaji, Fumitaka Horii
  • Journal Title: Polymer Journal 38 Pages: 277-288
  • NAID: 10017315126
• [Journal Article] CP/MAS ^<13>C NMR Characterization of the Isomeric States and Intermolecular Packing in Tris(8-hydroxyquinoline) Aluminum(III) (Alq_3) (2006)
  • Author(s): Hironori Kaji, Yasunari Kusaka, Goro Onoyama, Fumitaka Horii
  • Journal Title: Journal of the American Chemical Society 128 Pages: 4292-4297
• [Journal Article] 固体NMR法による高分子材料の精密解析、高分子科学最近の進歩 (2006)
  • Author(s): 三好利一, 梶 弘典
  • Journal Title: 高分子 55 Pages: 744-749
• [Journal Article] CP/MAS ^<13>C NMR Characterization of the Isomeric States and Intermolecular Packing in Tris(8-hydroxyquinoline) Aluminum(III)(Alq_3) (2006)
  • Author(s): Hironori Kaji, Yasunari Kusaka, Goro Onoyama, Fumitaka Horii
  • Journal Title: Journal of the American Chemical Societ 128 Pages: 4292-4297
• [Journal Article] A combined experimental and theoretical study of the conformation of N, N'-diphenyl-N, N'-di(m-tolyl)benzidine(TPD)using solid-state 15N NMR and DFT calculations (2005)
  • Author(s): Hironori Kaji, Tomonori Yamada, Naoki Tsukamoto, and Fumitaka Horii
  • Journal Title: Chemical Physics Letters 401 Pages: 246-253
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Relation between Light-Emitting Properties and Different Isomers in Polymorphs of Tris(8-hydroquinoline)Aluminum(III)(Alq_3)Analyzed by Solid-Sate 27Al NMR and DFT Calculations (2005)
  • Author(s): Hironori Kaji, Yasunari Kusaka, Goro Onoyama, and Fumitaka Horii
  • Journal Title: Japanese Journal of Applied Physics 44 Pages: 3706-3711
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Relationships between light-emitting properties and different isomers in polymorphs of tris(8-hydroxyquinoline) aluminum(III) (Alq3) analyzed by solid-state 27Al NMR and density functional theory (DFT) calculations (2005)
  • Author(s): H., Kaji, Y., Kusaka, G., Onoyama, F., Horii
  • Journal Title: Jpn. J. Appl. Phys 44 Pages: 3706-3711
  • NAID: 130004534124
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] A combined experimental and theoretical study of the conformation of N,N-diphenyl-N,N-di(m-tolyli)benzidine using solid-state 15N NMR and DFT calculations (2005)
  • Author(s): H., Kaji, T., Yamada, N., Tsukamoto, F., Horii
  • Journal Title: Chem. Phys. Lett 401 Pages: 246-253
  • Description: 「研究成果報告書概要(欧文)」より
• [Journal Article] A combined experimental and theoretical study of the conformation of N,N'-diphenyl-N,N'-di(m-tolyl)benzidine (TPD) using solid-state 15N NMR and DFT calculations (2005)
  • Author(s): Hironori Kaji, Tomonori Yamada, Naoki Tsukamoto, Fumitaka Horii
  • Journal Title: Chemical Physics Letters 401 Pages: 246-253
• [Journal Article] Relation between Light-Emitting Properties and Different Isomers in Polymorphs of Tris(8-hydroquinoline) Aluminum(III) (Alq_3) Analyzed by Solid-State ^<27>Al NMR and DFT Calculations (2005)
  • Author(s): Hironori Kaji, Yasunari Kusaka, Goro Onoyama, Fumitaka Horii
  • Journal Title: Japanese Journal of Applied Physics 44 Pages: 3706-3711
• [Presentation] Structure of materials in organic light-emitting diodes studied by solid-state NMR (2008)
  • Author(s): Hironori Kaji(Invited)
  • Organizer: 235th Spring 2008 ACS meeting,. 2008 NMR Spectroscopy of Polymers Symposium
  • Place of Presentation: Hilton New Orleans Riverside, Grand Salon 9, New Orleans, LA
  • Year and Date: 2008-04-09
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Structure of materials in organic light-emitting diodes studied by solid-state NMR (2008)
  • Author(s): Hironori Kaji (Invited)
  • Organizer: 235th Spring 2008 ACS meeting, . 2008 NMR Spectroscopy of Polymers Symposium
  • Place of Presentation: Hilton New Orleans Riverside, Grand Salon 9, New Orleans, LA
  • Year and Date: 2008-04-09
• [Presentation] 「応用物理学の将某ビジョン-2040年に向けたアカデミックロードマップ-」有機・分子エレクトロニクスの将来ビジョン・ロードマップ (2008)
  • Author(s): 梶 弘典(依頼講演)
  • Organizer: 2008年 春季第55回応用物理学関係連合講演会特別企画シンポジウム
  • Place of Presentation: 日本大学理工学部船橋校舎(千葉,船橋市)
  • Year and Date: 2008-03-28
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 「応用物理学の将来ビジョン-2040年に向けたアカデミックロードマップ-」有機・分子エレクトロニクスの将来ビジョン・ロードマップ (2008)
  • Author(s): 梶 弘典(依頼講演)
  • Organizer: 2008年春季第55回応用物理学関係連合講演会特別企画シンポジウム
  • Place of Presentation: 日本大学理工学部船橋校舎(千葉,船橋市)
  • Year and Date: 2008-03-28
• [Presentation] 有機半導体材料の固体NMR解析とデバイス応用への展開 (2008)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 分子研ナノフォーラム「有機半導体の基礎科学とデバイス応用に関する研究会」
  • Place of Presentation: 分子科学研究所・研究棟201号室(明大寺地区)
  • Year and Date: 2008-03-13
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 「有機ELおよび有機太陽電池材料の固体NMR解析」 (2008)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 富士フィルム講演会
  • Place of Presentation: 富士フィルム株式会社 神奈川工場足柄サイト
  • Year and Date: 2008-03-06
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 「有機ELおよび有機太陽電池材料の固体NMR解析」 (2008)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 富士フィルム講演会
  • Place of Presentation: 富士フィルム株式会社神奈川工場足柄サイト
  • Year and Date: 2008-03-06
• [Presentation] Structure of materials in organic light-emitting diodes studied by solid state NMR, 235th New Orleans Spring (2008)
  • Author(s): Hironori, Kaji
  • Organizer: 2008 ACS meeting, New Orleans
  • Place of Presentation: LA, USA (Invited)
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Takashi Yamashita, Toshiyuki Watanabe, Reversible thermoresponsive on-off recording of strong long lived room temperature phosphorescence in organic materials under atmosphere (2008)
  • Author(s): Shuzo, Hirata, Takashi, Sesei, Hironori, Kaji
  • Organizer: International Conference on Organic Photonics and Electronics 2008 (ICOPE2008), Santa Fe, New Mexico
  • Place of Presentation: USA
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Geometric and Electronic Structures of a Hole-Transport Material, TPD (2008)
  • Author(s): Hironori, Kaji
  • Organizer: Studied by DFT Calculations and Solid-State NMR SPIE Symposium on Photonic Devices+Applications "Organic Light-Emitting Materials and Devices XII" (0P112), San Diego Convention Center in San Diego
  • Place of Presentation: CA (to be presented, Invited)
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Solid-state NMR and DFT studies of a hole-transport material, TPD (2008)
  • Author(s): Hironori, Kaji
  • Organizer: The 8th International Meeting on Information Display(iMiD 2008), Korea International Exhibition Center (KINTEX) at Than, Gyeonggi Province (to be presented, Invited)
  • Place of Presentation: Korea
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] 有機EL材料の固体NMR解析 (2007)
  • Author(s): 梶 弘典
  • Organizer: 「有機EL集中ディスカッション」
  • Place of Presentation: 早稲田大学先進理工学部(大久保キャンパス)
  • Year and Date: 2007-12-27
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 有機光電変換材料の固体NMR解析 (2007)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 「NEDO有機太陽電池研究会」
  • Place of Presentation: 京都大学京都大学宇治キャンパス
  • Year and Date: 2007-12-21
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 有機光電変換材料の固体NMR解析 (2007)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 「科学技術交流財団 ナノ有機分子エレクトロニクス創成研究会」
  • Place of Presentation: 名古屋大学
  • Year and Date: 2007-12-19
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 有機光電変換材料の固体NMR解析 (2007)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 「科学技術交流財団ナノ有機分子エレクトロニクス創成研究会」
  • Place of Presentation: 名古屋大学
  • Year and Date: 2007-12-19
• [Presentation] 応用物理学会における有機エレクトロニクスへの取組み-基礎科学の構築とこれからの領域融合的展開 (2007)
  • Author(s): 梶 弘典(依頼講演)
  • Organizer: 「SEMICOM JAPAN 2007」
  • Place of Presentation: 幕張メッセ特設イノベーションホール(イベントホール)
  • Year and Date: 2007-12-06
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 有機ELの基礎科学-分子レベルの構造からEL特性を紐解く- (2007)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 早稲田大学 理工学部/大学院理工学研究科 講演会
  • Place of Presentation: 早稲田大学理工学部
  • Year and Date: 2007-10-19
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Origin of the different emission wavelengths in Alq_3 analyzed by solid-state NMR (2007)
  • Author(s): Hironori Kaji(Invited)
  • Organizer: SPIE Symposium on Photonic Devices+Applications "Organic Light-Emitting Materials and Devices XI"(OP122)
  • Place of Presentation: San Diego Convention Center in San Diego, CA, USA
  • Year and Date: 2007-08-26
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Origin of the different emission wavelengths in Alq_3 analyzed solid-state NMR (2007)
  • Author(s): Hironori Kaji (Invited)
  • Organizer: SPIE Symposium on Photonic Devices + Applications "Organic Light-Emitting Materials and Devices XI" (OP122)
  • Place of Presentation: San Diego Convention Center in San Diego, CA, USA
  • Year and Date: 2007-08-26
• [Presentation] 有機光電変換材料の固体NMR 解析 (2007)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 有機太陽電池研究会 第3回有機太陽電池シンポジウム 主題:「有機薄膜太陽電池-新材料、新素子構造、理論-」
  • Place of Presentation: 京大会館(京都市左京区)
  • Year and Date: 2007-07-16
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 有機光電変換材料の固体NMR 解析 (2007)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 有機太陽電池研究会 第3回有機太陽電池シンポジウム主題:「有機薄膜太陽電池-新材料、新素子構造、理論-」
  • Place of Presentation: 京大会館(京都市左京区)
  • Year and Date: 2007-07-16
• [Presentation] 核磁気共鳴測定は、有機エレクトロニクスにいかに役立つか? (2007)
  • Author(s): 梶 弘典
  • Organizer: 応用物理学会 有機分子バイオエレクトロニクス分科会(M&BE研究会)「学際的融合に向けた有機分子・バイオエレクトロニクスの新たな展開」
  • Place of Presentation: 山形県上山市市民会館
  • Year and Date: 2007-06-30
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 有機EL材料の固体NMR解析 (2007)
  • Author(s): 梶 弘典(Invited)
  • Organizer: 実環境計測・診断システム協議会平成19年度第一回表面・界面技術研究会主催講演会
  • Place of Presentation: 産総研九州センター
  • Year and Date: 2007-05-25
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] クライオプローブを用いたNMR測定による有機EL材料の劣化解析 (2007)
  • Author(s): 梶弘典
  • Organizer: 有機EL討論会 第5回例会
  • Place of Presentation: 九州大学筑紫キャンパス CUBE 1階 筑紫ホール
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] TPDにおける非弾性電流に関する理論的研究 (2007)
  • Author(s): 佐藤徹
  • Organizer: 有機EL討論会 第5回例会
  • Place of Presentation: 九州大学筑紫キャンパスC-CUBE 1階 筑紫ホール
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] ラマン分光によるAlq3のmer/fac幾何異性と固体構造に関する研究 (2007)
  • Author(s): 椙山卓郎
  • Organizer: 有機EL討論会 第5回例会
  • Place of Presentation: 九州大学筑紫キャンパスC-CUBE 1階 筑紫ホール
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Solid-State 29Si NMR Characterization of Poly(dimethylsilane)in the Mesophase (2007)
  • Author(s): H. Kaji
  • Organizer: ICRIS'07 The International Symposium Organized by Institute for Chemical Research(ICR), Kyoto University, "The Scinence and Technology of Well-Controlled Polymer Assemblies"
  • Place of Presentation: Shiran Kaikan, Kyoto University(Yoshida, Sakyo-ku, Kyoto)
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Molecular and Electronic Structure Analyses of N, N'-diphenyl-N, N'-di(m-tolyl)benzidine by Solid-State NMR and Quantum Chemical Calculations (2007)
  • Author(s): T. Yamada
  • Organizer: ICRIS'07 The International Symposium Organized by Institute for Chemical Research(ICR), Kyoto University, "The Scinence and Technology of Well-Controlled Polymer Assemblies"
  • Place of Presentation: Shiran Kaikan, Kyoto University(Yoshida, Sakyo-ku, Kyoto)
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Solid-State NMR Characterization of Structure and Hydrogen Bonding of Polymer Materials (2007)
  • Author(s): Qing Luo
  • Organizer: ICRIS'07 The International Symposium Organized by Institute for Chemical Research(ICR), Kyoto University, "The Scinence and Technology of Well-Controlled Polymer Assemblies"
  • Place of Presentation: Shiran Kaikan, Kyoto University(Yoshida, Sakyo-ku, Kyoto)
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 有機EL正孔輸送材料TPDにおけるコンホメーション-電子状態の相関 (2007)
  • Author(s): 山田知典
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 国立京都国際会館(京都市左京区宝ヶ池)
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Synthesis and Photoelectronic Properties of Benzoxazole-Based Charge-Transport Materials (2007)
  • Author(s): 賈 迎鋼
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 国立京都国際会館(京都市左京区宝ヶ池)
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 溶液および固体NMRによる有機EL材料の劣化および構造解析 (2007)
  • Author(s): 梶 弘典(依頼講演)
  • Organizer: 日本化学会第87回春季年会 アドバンスト・テクノロジー・プログラム(ATP)シンポジウム 「ATP T2ディスプレイ材料の開発最前線」
  • Place of Presentation: 関西大学千里山キャンパス
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Shigeru Nakamura, Kenichi Azuma, Taku Sasaki, Takao Unate, Yasuhiro Nakatani, Akira Nakasuga, Kimihiro Matsukawa, Naoki Watanabe, Hiroyoshi Naito, Hironori Kaji, A Study on Relationship between Resistivity and Structures of Photosensitive Organic Silsesquioxanes by Impedance Spectroscopy and Solid-State 29Si NMR (2007)
  • Author(s): Yasunari, Kusaka
  • Organizer: Fourth International Conference on Molecular Electronics and Bioelectronics (M&BE4), Takeda Hall,Hongo Campus, The University of Tokyo
  • Place of Presentation: Tokyo, Japan
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Solid-State NMR Characterization of Poly(dimethylsilane) in the Mesophase, The International Symposium Organized by Institute for Chemical Research, Kyoto University (ICRIS '07) (2007)
  • Author(s): H., Kaji, A., Mino, T., Yamada, E., Horii
  • Organizer: "The Scinence and Technology of Well-Controlled Polymer Assemblies", Shiran Kaikan, Kyoto University
  • Place of Presentation: Kyoto University
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Molecular and Electronic Structure Analyses of N, N'-diphenyl-N,N'-di(m-tolyl)benzidine by Solid-State NMR and Quantum Chemical Calculations, The International Symposium Organized by Institute for Chemical Research, Kyoto University (ICRIS '07) (2007)
  • Author(s): T., Yamada, H., Kaji, E., Horii
  • Organizer: "The Scinence and Technology of Well-Controlled Polymer Assemblies", Shiran Kaikan
  • Place of Presentation: Kyoto University
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Tadashi Shimizu, Masataka Tansho, Kiyonori Takegoshi, Takahiro Nemoto, and Takashi Mizuno, Solid-State NMR Characterization of Structure and Hydrogen Bonding of Polymer Materials, The International Symposium Organized by Institute for Chemical Research, Kyoto University (ICRIS '07) (2007)
  • Author(s): Qing, Luo, Shinji, Suzuki, Yasumasa, Kanie, Hironori, Kaji, Fumitaka, Horii
  • Organizer: "The Scinence and Technology of Well-Controlled Polymer Assemblies", Shiran Kaikan
  • Place of Presentation: Kyoto University
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Origin of the different emission wavelengths in Alq3 analyzed by solid-state NMR, SPIE Symposium on Photonic Devices+Applications (2007)
  • Author(s): Hironori, Kaji
  • Organizer: "Organic Light-Emitting Materials and Devices XI" (0P122),San Diego Convention Center in San Diego
  • Place of Presentation: CA (Invited)
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] クライオプローブを用いたNMR測定による有機EL材料の劣化解析 (2007)
  • Author(s): 梶弘典
  • Organizer: 有機EL討論会 第5回例会
  • Place of Presentation: 九州大学筑紫キャンパス C-CUBE 1階 筑紫ホール
• [Presentation] TPDにおける非弾性電流に関する理論的研究 (2007)
  • Author(s): 佐藤徹
  • Organizer: 有機EL討論会 第5回例会
  • Place of Presentation: 九州大学筑紫キャンパス C-CUBE l階 筑紫ホール
• [Presentation] ラマン分光によるAlq3のmer/fac幾何異性と固体構造に関する研究 (2007)
  • Author(s): 椙山卓郎
  • Organizer: 有機EL討論会 第5回例会
  • Place of Presentation: 九州大学筑紫キャンパス C-CUBE l階 筑紫ホール
• [Presentation] Solid-State 29Si NMR Characterization of Poly (dimethylsilane) in the Mesophase (2007)
  • Author(s): H. Kaji
  • Organizer: ICRIS '07 The International Symposium Organized by Institute for Chemical Research (ICR), Kyoto University, "The Scinence and Technology of Well-Controlled Polymer Assemblies"
  • Place of Presentation: Shiran Kaikan, Kyoto University (Yoshida, Sakyo-ku, Kyoto)
• [Presentation] Molecular and Electronic Structure Analyses of N, N'-diphenyl-N, N'-di (m-tolyl) benzidine by Solid-State NMR and Quantum Cheemical Calculations (2007)
  • Author(s): T. Yamada
  • Organizer: ICRIS '07 The International Symposium Organized by Institute for Chemical Research (ICR), Kyoto University, "The Scinence andTechnology of Well-Controlled Polymer Assemblies"
  • Place of Presentation: Shiran Kaikan, Kyoto University (Yoshida, Sakyo-ku, Kyoto)
• [Presentation] Solid-State NMR Characterization of Structure and Hydrogen Bonding of Polymer Materials (2007)
  • Author(s): Qing Luo
  • Organizer: ICRIS '07 The International Symposium Organized by Institute for Chemical Research (ICR), Kyoto University, "The Scinence and Technology of Well-Controlled Polymer Assemblies"
  • Place of Presentation: Shiran Kaikan, Kyoto University (Yoshida, Sakyo-ku, Kyoto)
• [Presentation] 有機EL正孔輸送材料TPDにおけるコンホメーション-電子状態の相関 (2007)
  • Author(s): 山田知典
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 国立京都国際会館(京都市左京区宝ケ池)
• [Presentation] Synthesis and Photoelectronic Properties of Benzoxazole-Based Charge-Transport Materials (2007)
  • Author(s): 賈 迎鋼
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 国立京都国際会館(京都市左京区宝ケ池)
• [Presentation] Characterization of Carrier Transport and Light-Emitting Materials in Organic LEDs (2006)
  • Author(s): Hironori, Kaji, Solid-State, NMR
  • Organizer: 20th Anniversary (40th) Meeting of the Society of Solid-State NMR for Materials/5th Strong Magnetic Field Solid-State NMR Forum Joint Symposium
  • Place of Presentation: Kyoto Garden Palace
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Materials in Organic LEDs (2006)
  • Author(s): Hironori, KAJI, Tomonori, YAMADA, Naoki, TSUKAMOTO, Yasunari, KUSAKA, Goro, ONOYAMA
  • Organizer: Relationship between Structure and Light/Carrier-Transport Properties, Sixth Japan-America Frontiers of Engineering (JAFoE) Symposium
  • Place of Presentation: Epochal Tsukuba, Ibaraki
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] the Analysis of Structure and Dynamics of Materials in Organic Devices (2006)
  • Author(s): Hironori, Kaji, From, Simple to Advanced, Solid-State, NMR
  • Organizer: The 45th Annual Meeting of the NMR Society of Japan The Clock Tower Centennial Hall
  • Place of Presentation: Kyoto University (Invited)
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] 13C-13C Homonuclear Cross Polarization through Dipolar Coupling or J Coupling : a Potential Solid-State NMR method (2006)
  • Author(s): Qing, Luo, Yuichi, Shimoikeda, Hironori, Kaji, Fumitaka, Horii
  • Organizer: The 45th Annual Meeting of the NMR Society of Japan The Clock Tower Centennial Hall
  • Place of Presentation: Kyoto University (Invited)
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Tadashi Shimizu, Masataka Tansho, Takahiro Nemoto, Takashi Mizuno, and Kiyonori Takegoshi, The characterization of hydrogen bonding in native cellulose by high-field solid-state NMR (2006)
  • Author(s): Qing, Luo, Shinji, Suzuki, Yasumasa, Kanie, Hironori, Kaji, Fumitaka, Horii
  • Organizer: The 45th Annual Meeting of the NMR Society of Japan, The Clock Tower Centennial Hall
  • Place of Presentation: Kyoto University
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Detection of amorphous thin films in organic LEDs by Solid-State 2H NMR (2006)
  • Author(s): Akira, Mino, Takashi, Sesei, Hironori, Kaji, Fumitaka, Horii
  • Organizer: The 45th Annual Meeting of the NMR Society of Japan, The Clock Tower Centennial Hall
  • Place of Presentation: Kyoto University
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Naoki Tsukamoto, Yasunari Kusaka, Hironori Kaji, Fumitaka Horii, Diamagnetic, paramagnetic, and Fermi contact shifts of N,N'diphenyl-N,N'-di(m-tolyl)benzidine in neutral, cationic, and dicationic states (2006)
  • Author(s): Tomonori, Yamada
  • Organizer: The 45th Annual Meeting of the NMR Society of Japan, The Clock Tower Centennial Hall
  • Place of Presentation: Kyoto University
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Yasunari Kusaka, Hironori Kaji, Goro Onoyaraa, Fumitaka Horii, Two-Dimensional Double-Quantum 15N Solid-State NMR Characterization of the Isomeric States in Tris(8-hydroxyquinoline) Aluminum(III) (Alq3) (2006)
  • Author(s): Takako, Kuga
  • Organizer: The 45th Annual Meeting of the NMR Society of Japan, The Clock Tower Centennial Hall
  • Place of Presentation: Kyoto University
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] One-dimensional solid-state NMR methods using selective soft pulses to detect the through-space 13C-13C correlation : Homonuclear cross polarization (2005)
  • Author(s): Quing, Luo, Hironori, KAJI, Fumitaka, HORIL
  • Organizer: The 44th Annual Meeting of Japanese NMR Society and The 1st Asia-Pacific NMR. Symposium
  • Place of Presentation: Yokohama Osanbashi Hall
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Dynamics Analysis of a Hole-Transport Material for Organic LEDs by Solid-State 13C NMR (2005)
  • Author(s): Junya, SIUMADA, Naoki, TSUKAMOTO, Hironori, FUJI, Fumitaka, HORII
  • Organizer: The 44th Annual Meeting of Japanese NMR Society and The 1st Asia-Pacific NMR Symposium
  • Place of Presentation: Yokohama Osanbashi Hall
  • Description: 「研究成果報告書概要(欧文)」より
• [Presentation] Conformational analysis of TPD by two-dimensional solid-state double-quantum NMR spectroscopy and quantum chemical calculations (2005)
  • Author(s): Tomonori, YAMADA, Naoki, TSUKAMOTO, Hironori, KAJI, Fumitaka, HORII
  • Organizer: The 44th Annual Meeting of Japanese NMR, Society and The 1st Asia-Pacific NMR Symposium
  • Place of Presentation: Yokohama Osanbashi Hall
  • Description: 「研究成果報告書概要(欧文)」より
• [Book] 有機ELのデバイス物理・材料化学・デバイス応用 (2007)
  • Author(s): 梶 弘典(分担執筆)
  • Total Pages: 296
  • Publisher: シーエムシー出版
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 有機エレクトロニクスの展開 最新開発状況と実用化への課題 (2007)
  • Author(s): 梶 弘典(分担執筆)
  • Total Pages: 263
  • Publisher: 情報機構
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 図解 適用事例にみる高分子材料の最先端技術 なぜ高分子材料を使うのか (2007)
  • Author(s): 梶 弘典(分担執筆)
  • Total Pages: 338
  • Publisher: 工業調査会
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 有機ELのデバイス物理・材料化学・デバイス応用 (2007)
  • Author(s): 梶 弘典 (分担執筆)
  • Total Pages: 296
  • Publisher: シーエムシー出版
• [Book] 有機エレクトロニクスの展開 最新開発状況と実用化への課題 (2007)
  • Author(s): 梶 弘典 (分担執筆)
  • Total Pages: 263
  • Publisher: 情報機構
• [Book] 第5版 実験化学講座 8巻「NMR・ESR」 (2006)
  • Author(s): 梶 弘典(分担執筆)
  • Total Pages: 553
  • Publisher: 日本化学会編 丸善
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 基礎高分子科学 (2006)
  • Author(s): 梶 弘典(分担執筆)
  • Total Pages: 450
  • Publisher: 高分子学会編 東京化学同人
  • Description: 「研究成果報告書概要(和文)」より
• [Book] Modern Magnetic Resonance(Quantitative Analysis of Conformations in Disordered Polymers by Solid-State Multiple-Quantum NMR) (2006)
  • Author(s): Hironori Kaji(分担執筆)
  • Total Pages: 1924
  • Publisher: Kluwer Academic Publishers
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 第5版 実験化学講座 8巻「NMR・ESR」(日本化学会編) (2006)
  • Author(s): 梶 弘典(分担執筆)
  • Total Pages: 553
  • Publisher: 丸善
• [Book] 基礎高分子科学(高分子学会編) (2006)
  • Author(s): 梶 弘典(分担執筆)
  • Total Pages: 450
  • Publisher: 東京化学同人
• [Book] Modern Magnetic Resonance (Quantitative Analysis of Conformations in Disordered Polymers by Solid-State Multiple-Quantum NMR) (2006)
  • Author(s): Hironori Kaji(分担執筆)
  • Total Pages: 1924
  • Publisher: Kluwer Academic Publishers
• [Book] 高分子辞典第3版 (2005)
  • Author(s): 梶 弘典(分担執筆)
  • Total Pages: 830
  • Publisher: 高分子学会編 朝倉書店
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 高分子辞典第3版(高分子学会編) (2005)
  • Author(s): 梶 弘典(分担執筆)
  • Total Pages: 830
  • Publisher: 朝倉書店