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Fabrication of Novel Biointerfaces Using High-Density Polymer Brushes

Research Project

Project/Area Number 17205022
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKyoto University

Principal Investigator

TSUJII Yoshinobu  Kyoto University, Inst. Chem. Res., Professor (00217308)

Co-Investigator(Kenkyū-buntansha) OHNO Khoji  Kyoto Univ., Inst. Chem. Res., Instructor (00335217)
GOTO Atsushi  Kyoto Univ., Inst. Chem. Res., Instructor (20335219)
KISHIDA Akio  Tokyo Medical and Dental Univ., Biomaterials and Bioengineering, Professor (60224929)
YAMAMOTO Kazuya  Kagoshima University, Graduate School of Science and Engineering, Instructor (40347084)
Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥49,530,000 (Direct Cost: ¥38,100,000、Indirect Cost: ¥11,430,000)
Fiscal Year 2007: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Fiscal Year 2006: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Fiscal Year 2005: ¥30,550,000 (Direct Cost: ¥23,500,000、Indirect Cost: ¥7,050,000)
Keywordsbiointerface / polymer brush / concentrated brush / living radical polymerization / surface modification / protein adsorption / cell adhesion / tribology / ポリマーブラン / 末端機能化 / グラフト重合 / 水溶性ポリマー / 潤滑 / 脂質膜 / コンビナトリアル手法
Research Abstract

Living radical polymerization has been applied to surface-initiated graft polymerization, allowing controlled grafting of well-defined polymers from various solid surfaces with dramatically high surface densities. This density was more than 1 order of magnitude higher than those of typical semidilute brushes, going deep into the concentrated brush regime. This project aimed at clarifying the properties of concentrated polymer brushes as novel biointerfaces. The main results are as follows.
(1) The protein adsorption as well as the cell adhesion could be much reduced on the concentrated brushes of hydrophilic polymers because of their size-exclusion effect and dynamic properties. This excellent inertness of the concentrated brush in the interaction with the proteins should afford the system long-term stability against biofauling.
(2) Photo-induced organotellurium-mediated living radical polymerization successfully applied to the preparation of the hydrophilic brushes.
(3) Combinatorial technique was established to fabricate a brush surface with continuous variation of graft density and chain length, clarifying the crossover density of concentrated/semi-dilute brushes.
(4) An excellent frictional property was macroscopically demonstrated fix the system of a concentrated-brush and gel surfaces.
(5) The concentrated brushes of poly (N-isopropylacrylamide) were synthesized and studied on their properties of swelling/deswelling, friction, and protein adhesion.
(6) A new and novel technique was established to immobilize initiators on polymeric substrates as well as various metal surfaces.

Report

(4 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (82 results)

All 2009 2008 2007 2006 2005 Other

All Journal Article (33 results) (of which Peer Reviewed: 12 results) Presentation (45 results) Book (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Phase-Separated Structures of Mixed LB Films of Silane-Coupling Agents with Polymerization Initiating Groups and Amphiphilic Carboxylic Acids2008

    • Author(s)
      T. Ishikawa
    • Journal Title

      Colloids and Surfaces A : Physicochemical and Engineering Aspects 321

      Pages: 76-81

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 濃厚ポリマーブラシとトライボロジー2008

    • Author(s)
      辻井敬亘
    • Journal Title

      繊維学会誌 64

      Pages: 144-146

    • NAID

      10021126990

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Phase-Separated Structures of Mixed LB Films of Silane-Coupling Agents with Polymerization Initiating Groups and Amphiphilic Carboxylic Acids2008

    • Author(s)
      T. Ishikawa, M. Ejaz, Y. Tsujii, H. Shibata, M. Matsumotoa
    • Journal Title

      Colloids and Surfaces A : Physicochemical and Engineering Aspects 321

      Pages: 76-81

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Size-exclusion Effect and Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-initiated Living Radical Polymerization2007

    • Author(s)
      C. Yoshikawa
    • Journal Title

      Macromol. Symp 248

      Pages: 189-198

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Surface Interaction of Well-defined, Concentrated Poly (2-hydroxyethyl methacrylate) Brushes with Proteins2007

    • Author(s)
      C. Yoshikawa
    • Journal Title

      J. Polym. Sci., Part A, Polym. Chem. 45

      Pages: 4795-4803

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Living Radical Polymerizations with Germanium, Tin, and Phosphorus Catalysts-Reversible Chain Transfer Catalyzed Polymerizations (RTCPs)2007

    • Author(s)
      A. Goto
    • Journal Title

      J. Am. Chem. Soc. 129

      Pages: 13347-13354

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Monodisperse Silica Particles Grafted with Concentrated Oxetane-carrying Polymer Brushes : Their Synthesis by Surface-initiated Atom Transfer Radical Polymerization and Use for Fabrication of Hollow Spheres2007

    • Author(s)
      T. Morinaga
    • Journal Title

      Macromolecules 40

      Pages: 1159-1164

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 界面に注目した新しい医用材料開発2007

    • Author(s)
      岸田晶夫
    • Journal Title

      バイオマテリアル 25

      Pages: 93-104

    • NAID

      10019505618

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Size-exclusion Effect and Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-initiated Living Radical Polymerization2007

    • Author(s)
      C. Yoshikawa, A. Goto, N. Ishizuka, K. Nakanishi, A. Kishida, Y. Tsujii, T. Fukuda
    • Journal Title

      Macromol. Symp. 248

      Pages: 189-198

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Surface Interaction of Well-defined, Concentrated Poly(2-hydroxyethyl methacrylate) Brushes with Proteins2007

    • Author(s)
      C. Yoshikawa, A. Goto, Y. Tsujii, N. Ishizuka, K. Nakanishi, T. Fukuda
    • Journal Title

      J. Polym, Sci., Part A, Polym. Chem. 45

      Pages: 4795-4803

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Living Radical Polymerizations with Germanium, Tin, Phosphorus Catalysts - Reversible Chain Transfer Catalyzed Polymerizations (RTCPs)2007

    • Author(s)
      A. Goto, H. Zushi, N. Hirai, T. Wakada, Y. Tsujii, T. Fukuda
    • Journal Title

      J. Am. Chem. Soc 129

      Pages: 13347-13354

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Monodisperse Silica Particles Grafted with Concentrated Oxetanecarrying Polymer Brushes: Their Synthesis by Surface-initiated Atom Transfer Radical Polymerization and Use for Fabrication of Hollow Spheres2007

    • Author(s)
      T. Morinaga, M. Ohkura, K. Ohno, Y Tsujii, T. Fukuda
    • Journal Title

      Macromolecules 40

      Pages: 1159-1164

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization2007

    • Author(s)
      C. Yoshikawa, A. Goto, A. Kishida, Y. Tsujii, T. Fukuda
    • Journal Title

      The Science and Technology of Well-Controlled Polymer Assemblies (Proceedings of ICRIS'07)

      Pages: 123-124

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Grafting and Polymer Brushes on Solid Surfaces2007

    • Author(s)
      T. Fukuda, Y. Tsujii, K. Ohno
    • Journal Title

      Macromolecular Engineering : Precise Synthesis, Materials Properties, Applications (K. Matyjaszewski, Ed., Wiley-VCH, Weinheim)

      Pages: 1137-1178

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 90. Size-exclusion Effect and Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-2007

    • Author(s)
      C. Yoshikawa, et. al.
    • Journal Title

      Macromol. Symp. 248

      Pages: 189-198

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Interaction of Well-defined, Concentrated Poly (2-hydroxyethyl methacrylate) Brushes with Proteins2007

    • Author(s)
      C. Yoshikawa, et. al.
    • Journal Title

      J. Polym. Sci., Part A, Polym.Chem. 45

      Pages: 4795-4803

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Protein Repellency of Well-defined, Concentrated Poly (2-hydroxyethyl methacrylate) Brushes by the Size-exclusion Effect2006

    • Author(s)
      C. Yoshikawa
    • Journal Title

      Macromolecules 39

      Pages: 2284-2290

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Structure and Properties of High-density Polymer Brushes Prepared by Surface-initiated Living Radical Polymerization2006

    • Author(s)
      Y. Tsujii
    • Journal Title

      Adv. Polym. Sci. 197

      Pages: 1-45

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] 濃厚ポリマーブラシの構造と物性2006

    • Author(s)
      福田猛
    • Journal Title

      化繊講演集 63

      Pages: 61-68

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Protein Repellency of Well-defined, Concentrated Poly(2-hydroxyethyl methacrylate) Brushes by the Size-exclusion Effect:2006

    • Author(s)
      C. Yoshikawa, A. Goto, Y. Tsujii, T. Fukuda, T. Kimura, K. Yamamoto, A. Kishida
    • Journal Title

      Macromolecules 39

      Pages: 2284-2290

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Structure and Properties of High-density Polymer Brushes Prepared by Surface-initiated Living Radical Polymerization2006

    • Author(s)
      Y. Tsujii, K. Ohno, S. Yamamoto, A. Goto, T. Fukuda
    • Journal Title

      Adv. Polym. Sci. 197

      Pages: 1-45

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Protein Repellency of Well-Defined, Concentrated Poly(2-hydroxyethl methacrylate) Brushes by Size-Exclusion Effect2006

    • Author(s)
      C.Yoshikawa et al.
    • Journal Title

      Macromolecules 39

      Pages: 2284-2290

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Germanium- and Tin-Catalyzed Living Radical Polymerizations of Styrene2006

    • Author(s)
      A.Goto et al.
    • Journal Title

      ACS Symp. Ser. 944

      Pages: 595-603

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Structure and Properties of Concentrated Polymer Brushes2006

    • Author(s)
      T.Fukuda et al.
    • Journal Title

      Ann. Rep. Res. Inst. Chem. Fib. 63

      Pages: 61-68

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Protein Repellency of Well-Defined, Concentrated Poly(2-hydroxyethyl methacrylate) Brushes by the Size-Exclusion Effect2006

    • Author(s)
      C.Yoshikawa
    • Journal Title

      Macromolecules 39

      Pages: 2284-2290

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Structure and Properties of High-Density Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization2006

    • Author(s)
      Y.Tsujii
    • Journal Title

      Adv.Polym.Sci. 197

      Pages: 1-45

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Fabrication of High-density Polymer Brush on Polymer Substrate by Surface-initiated Living Radical Polymerization2005

    • Author(s)
      C. Yoshikawa
    • Journal Title

      Macromolecules 38

      Pages: 4604-4610

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Physicochemical Characterization of an Anatase TiO2 Surface and the Adsorption of a Nonionic Surfactant : An Atomic Force Microscopy Study2005

    • Author(s)
      C. E. McNamee
    • Journal Title

      Langmuir 21

      Pages: 11283-11288

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Precision Synthesis of a Fluorinated Polyhedral Oligomeric Silsesquioxane-terminated Polymer and Surface Characterization of Its Blend Film with Poly (methyl methacrylate)2005

    • Author(s)
      K. Koh
    • Journal Title

      Macromolecules 38

      Pages: 1264-1270

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] リビングラジカル重合法による精密表面改質に関する研究2005

    • Author(s)
      辻井敬亘
    • Journal Title

      繊維学会誌 61

      Pages: 260-263

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Fabrication of High-density Polymer Brush on Polymer Substrate by Surface-initiated Living Radical Polymerization2005

    • Author(s)
      C. Yoshikawa, A. Goto, Y. Tsujii, T. Fukuda, K. Yamamoto, A. Kishida
    • Journal Title

      Macromolecules 38

      Pages: 4604-4610

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Physicochemical Characterization of an Anatase TiO2 Surface and the Adsorption of a Nonionic Surfactant : An Atomic Force Microscopy Study2005

    • Author(s)
      C. B. McNamee, Y. Tsujii, M. Matsumoto
    • Journal Title

      Langmuir 21

      Pages: 11283-11288

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Precision Synthesis of a Fluorinated Polyhedral Oligomeric Silsesquioxane-terminated Polymer and Surface Characterization of Its Blend Film with Poly (methyl methacrylate)2005

    • Author(s)
      K. Koh, S. Sugiyama, T. Morinaga, K. Ohno, Y. Tsujii, T. Fukuda, M. Yamahiro, T. Iijima, H. Oikawa, K. Watanabe, T. Miyashita
    • Journal Title

      Macromolecules 38

      Pages: 1264-1270

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 濃厚ポリマーブラシの生体適合性2009

    • Author(s)
      吉川千晶
    • Organizer
      第13回高分子表面研究討論会
    • Place of Presentation
      東京工業大学百年記念館
    • Year and Date
      2009-01-30
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Bio-compatibility of Concentrated Polymer Brushes2009

    • Author(s)
      C. Yoshikawa, et al.
    • Organizer
      13^<th> Symposium on Polymer Surface
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2009-01-30
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 親水性濃厚ポリマーブラシの合成とその表面特性2008

    • Author(s)
      野村晃敬
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2008-09-24
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] リビングラジカル重合法による精密表面改質2008

    • Author(s)
      辻井敬亘
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2008-09-24
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Novel Properties of Concentrated Polymer Brushes2008

    • Author(s)
      Y. Tsujii
    • Organizer
      International Conference on Advanced Functional Polymers and Self-Organized Materials 2008
    • Place of Presentation
      Busan, Korea
    • Year and Date
      2008-09-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 典型元素を触媒として利用する新しい型のリビングラジカル重合-可逆移動触媒重合-の開発2008

    • Author(s)
      後藤淳
    • Organizer
      第54回高分子研究発表会
    • Place of Presentation
      兵庫県中央労働センター
    • Year and Date
      2008-07-18
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] A New Type of Living Radical Polymerization using representative-element catalyst2008

    • Author(s)
      A. Goto
    • Organizer
      54^<th> Annual Kobe Polymer Research Symposium
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      2008-07-18
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Super Lubrication of Concentrated Polymer Brushes in Solvents2008

    • Author(s)
      辻井敬亘
    • Organizer
      トライボロジー国際フォーラム
    • Place of Presentation
      産業技術総合研究所臨海副都心センター
    • Year and Date
      2008-05-15
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Super Lubrication of Concentrated Polymer Brushes in Solvents2008

    • Author(s)
      Y. Tsujii
    • Organizer
      International Forum on Tribology
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2008-05-15
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 医用高分子研究の未来を考える2008

    • Author(s)
      岸田晶夫
    • Organizer
      第58回医用高分子研究会
    • Place of Presentation
      大阪
    • Year and Date
      2008-03-12
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Prospective for Research on Biomedical Polymers2008

    • Author(s)
      A. Kishida
    • Organizer
      58^<th> 23^<rd> Symposium by Research Group on Biomedical Polymers
    • Place of Presentation
      Osaka, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Precision Surface Modification by Living Radical Polymerization2008

    • Author(s)
      Y. Tsujii
    • Organizer
      57^<th> Symposium on Macromolecules
    • Place of Presentation
      Osaka, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 濃厚ポリマーブラシとバイオインターフェース2007

    • Author(s)
      辻井敬亘
    • Organizer
      第29回日本バイオマテリアル学会大会
    • Place of Presentation
      大阪千里ライフサイエンスセンター
    • Year and Date
      2007-11-26
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] リン化合物を用いたリビングラジカル重合2007

    • Author(s)
      平井規晋
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-19
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 新規開始基導入法を用いた高分子基材表面からのリビングラジカル重合2007

    • Author(s)
      佳山祐造
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2007-09-19
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] 水中におけるポリ(N-イソプロピルアクリルアミド)濃厚ブラシのトライポロジー特性2007

    • Author(s)
      W. Gao
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 有機テルル化合物を用いた表面開始光誘起型リビングラジカル重合2007

    • Author(s)
      手塚美穂
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] フェニルホウ酸担持ビニルモノマーのリビングラジカル重合2007

    • Author(s)
      Y. Ma
    • Organizer
      第56回高分子学会年次大会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2007-05-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 新しい表面特性を生み出す濃厚ポリマーブラシ2007

    • Author(s)
      辻井敬亘
    • Organizer
      次世代接着材料研究会
    • Place of Presentation
      大阪国際YMCA文化会館
    • Year and Date
      2007-04-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Concentrated Polymer Brushes Providing New Surface Properties2007

    • Author(s)
      Y. Tsujii
    • Organizer
      Symposium by Research Group on Next-Generation Adhesive Materials
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2007-04-20
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 新しい表面特性を生み出す"濃厚"ポリマーブラシ2007

    • Author(s)
      辻井敬亘
    • Organizer
      次世代接着材料研究会
    • Place of Presentation
      大阪国際YMCA文化会館
    • Year and Date
      2007-04-20
    • Related Report
      2007 Annual Research Report
  • [Presentation] Tribological Properties of Well-Defined Concentrated Poly(N-isopropylacryamide) Brushes in Water2007

    • Author(s)
      W. Gao, et al.
    • Organizer
      56th SPSJ Annual Meeting
    • Place of Presentation
      Kyoto, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Surface-initiated, Photo-induced organotellurium-mediated living radical polymerizations2007

    • Author(s)
      M. Tezuka, et al.
    • Organizer
      56th SPSJ Annual Meeting
    • Place of Presentation
      Kyoto, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Living Radical Polymerization ofVinyl Monomer with Phenylboronic Acid2007

    • Author(s)
      Y. Ma, et al.
    • Organizer
      56th SPSJ Annual Meeting
    • Place of Presentation
      Kyoto, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Living Radical Polymerization using Phosphorus Catalysts2007

    • Author(s)
      N. Hirai, et al.
    • Organizer
      56th SPSJ Annual Meeting
    • Place of Presentation
      Kyoto, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] A New Initiator Fixation Method for Surface-Initiated Living Radical Polymerization on Polymer Substrates2007

    • Author(s)
      Y. Kayama, et al.
    • Organizer
      56th SPSJ Annual Meeting
    • Place of Presentation
      Kyoto, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Concentrated Polymer Brushes and Biointerfaces2007

    • Author(s)
      Y. Tsujii, et al.
    • Organizer
      29^<th> Annual Meeting of Japanese Society for Biomaterials
    • Place of Presentation
      Osaka, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 新規開始基導入法を用いた表面開始リビングラジカル重合2007

    • Author(s)
      佳山祐造、ビンセント・ラドミラル、大野工司、辻井敬亘、福田 猛
    • Organizer
      平成19年度繊維学会秋季研究発表
    • Place of Presentation
      京都工芸繊維大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] 濃厚ポリマーブラシの膨潤特性とトライボロジー2007

    • Author(s)
      野村晃敬、岡安賢治、Gao Weiping、大野工司、辻井敬亘、福田 猛
    • Organizer
      第56回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2007 Annual Research Report
  • [Presentation] Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-Initiated Living Radical2007

    • Author(s)
      吉川千晶、後藤 淳、岸田晶夫、辻井敬亘、福田 猛
    • Organizer
      ICRIS'07
    • Place of Presentation
      京都大学芝蘭会館
    • Related Report
      2007 Annual Research Report
  • [Presentation] コンビナトリアル法による濃厚ポリマーブラシの構造制御と解析2006

    • Author(s)
      有田稔彦
    • Organizer
      第55回高分子討論会
    • Place of Presentation
      富山大学
    • Year and Date
      2006-09-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 水中における(N-イソプロピルアクリルアミド)濃厚ブラシの相転移挙動2006

    • Author(s)
      W. Gao
    • Organizer
      第55回高分子討論会
    • Place of Presentation
      富山大学
    • Year and Date
      2006-09-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] マクロスケール接触下での濃厚ポリマーブラシの摩擦特性2006

    • Author(s)
      倉本守
    • Organizer
      第55回高分子討論会
    • Place of Presentation
      富山大学
    • Year and Date
      2006-09-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Protein Repellency of Concentrated Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization2006

    • Author(s)
      C. Yoshikawa
    • Organizer
      4th IUPAC, International Symposium on Free Radical Polymerization : Kinetics and Mechanism
    • Place of Presentation
      Lucca, Italy
    • Year and Date
      2006-09-04
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Chromatographic Study on Surface Interaction of Well-Defined, Concentrated Poly (2-hydroxyethyl methacrylate) Brushes with Proteins2006

    • Author(s)
      C. Yoshikawa
    • Organizer
      14th Polychar World Forum on Advanced Materials
    • Place of Presentation
      奈良
    • Year and Date
      2006-04-17
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Chromatographic Study on Surface Interaction of Well-Defined, Concentrated Poly(2-hydroxyethyl methacrylate) Brushes with Proteins2006

    • Author(s)
      C. Yoshikawa, et al.
    • Organizer
      14th Polychar World Forum on Advanced Materials
    • Place of Presentation
      Nara, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Protein Eepellency of Concentrated Polymer Brushes Prepared by Surface-Initiated Living Radical Polymerization2006

    • Author(s)
      C. Yoshikawa, et al.
    • Organizer
      4th IUPAC, International Symposium on Free Radical Polymerization: Kinetics and Mechanism
    • Place of Presentation
      Lucca, Italy
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Combinatorial study on structure of concentrated polymer brushes2006

    • Author(s)
      T. Arita, et al.
    • Organizer
      55^<th> Symposium on Macromolecules
    • Place of Presentation
      Toyama, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Phase Transition of Well-Defined Concentrated Poly(N-isopropylacryamide.) Brushes in Water2006

    • Author(s)
      W. Gao, et al.
    • Organizer
      55^<th> Symposium on Macromolecules
    • Place of Presentation
      Toyama, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Frictional Properties of Concentrated Polymer Brushes Studied by Rheometer2006

    • Author(s)
      M. Kuramoto, et al.
    • Organizer
      55^<th> Symposium on Macromolecules
    • Place of Presentation
      Toyama, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 医療デバイス開発における医用高分子2005

    • Author(s)
      岸田晶夫
    • Organizer
      第23回医用高分子研究会講座
    • Place of Presentation
      東京
    • Year and Date
      2005-11-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 高密度ポリマーブラシを用いた新規バイオインターフェースーサイズ排除によるタンパクの吸着制御2005

    • Author(s)
      吉川千晶
    • Organizer
      第34回高分子討論会
    • Place of Presentation
      山形大学
    • Year and Date
      2005-09-20
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Novel biointerface using high-density polymer brushes - Protein repellency by size-exclusion effect2005

    • Author(s)
      C. Yoshikawa, et al.
    • Organizer
      54^<th> symposium on Macromolecules
    • Place of Presentation
      Yamagata, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Biomedical polymers for biomedical devices2005

    • Author(s)
      A. Kishida
    • Organizer
      23^<rd> Symposium by Research Group on Biomedical Polymers
    • Place of Presentation
      Tokyo, Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Synthesis and Surface Properties of Hydrophilic Concentrated Polymer Brushes

    • Author(s)
      A. Nomura, et al.
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] Macromolecular Engineering, Precise Synthesis, Materials Properties, Application(Chapter 11 in Volume 2)2007

    • Author(s)
      T.Fukuda et al.
    • Total Pages
      41
    • Publisher
      Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
    • Related Report
      2006 Annual Research Report
  • [Book] 機能物質の集積膜と応用展開(第8章 濃厚ポリマーブラシの調製と特性)2006

    • Author(s)
      辻井敬亘, 福田 猛
    • Total Pages
      10
    • Publisher
      シーエムシー出版
    • Related Report
      2006 Annual Research Report
  • [Book] グラフト重合による精密表面設計(第6偏、第1章2.3節)2006

    • Author(s)
      辻井敬亘, 福田 猛
    • Total Pages
      7
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2006 Annual Research Report
  • [Patent(Industrial Property Rights)] 高分子ブラシ複合体およびその製造方法2008

    • Inventor(s)
      堤祐介, 南広祐, 岸田晶夫, 塙隆夫
    • Industrial Property Rights Holder
      国立大学法人, 東京医科歯科大学
    • Industrial Property Number
      2008-247361
    • Filing Date
      2008-09-26
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2005-04-01   Modified: 2016-04-21  

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