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VUV microfabrication

Research Project

Project/Area Number 17206073
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionKyoto University

Principal Investigator

SUGIMURA Hiroyuki  Kyoto University, Graduate School of Engineering, Professor (10293656)

Co-Investigator(Kenkyū-buntansha) MURASE Kuniaki  Kyoto University, Graduate School of Engineering, Associate Professor (30283633)
LEE Kyung-Hwang  Kyoto University, Graduate School of Engineering, Assistant Professor (00378796)
ICHII Takashi  Kyoto University, Graduate School of Engineering, Assistant Professor (30447908)
TESHIMA Katsuya  Shinshu University, Faculty of Engineering, Assistant Professor (00402131)
Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥48,620,000 (Direct Cost: ¥37,400,000、Indirect Cost: ¥11,220,000)
Fiscal Year 2007: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2006: ¥31,200,000 (Direct Cost: ¥24,000,000、Indirect Cost: ¥7,200,000)
Fiscal Year 2005: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
KeywordsMicrofabrication / Surface modification / Vacuum ultra-violet / Organic materials / Photolithography / Excimer lamp / Photochemistry / Oxygen-amplified photoexposure / 多層膜1 / 接合 / リソグラフィ / めっき
Research Abstract

This research has been conducted in order to develop the microfabrication technology using vacuum ultra-violet (VUV) light at 172 nm in wavelength. A Xe excimer lamp was employed as a light source for photofabrication. Since this VUV light has a high photon energy of 7.2 eV, photochemical reactions can be induced various organic material surfaces. Thus, by simply irradiating a material surface through a photomask, the photomask pattern is directly transferred onto the surface without complicated photolithography processes. Furthermore, we have developed a novel photofabrication process, that is. oxygen-amplified VUV microfabrication, In this process, atmospheric oxygen molecules are excited and dissociated to atomic oxygen. These VUV-generated oxygen atoms oxidize a material surface so the an oxidized pattern is formed on the surface. Atomic oxygen is so oxidative that it can oxidize any types of organic materials. Thus, oxidized patterns can be formed on organic material surfaces which has no photosensitivity to 172 nm VUV light, for example, saturated hydrocarbons. By optimizing VUV patterning conditions, we have succeeded in fabricating 0.5 μm-class fine patterns.

Report

(4 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (43 results)

All 2008 2007 2006 2005 Other

All Journal Article (22 results) (of which Peer Reviewed: 9 results) Presentation (17 results) Book (1 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Surface Chemical Conversion of Organosilane Self-Assembled Monolayers with Active Oxygen Species Generated by Vacuum Ultraviolet Irradiation of Atmospheric Oxygen Molecules2008

    • Author(s)
      Young-Jong Kim, Kyung-Hwang Lee, Hikaru Sano, Jiwon Han, Takashi Ichii, Kuniaki Murase, and Hiroyuki Sugimura
    • Journal Title

      Jpn. J. Appl. Phys. 47

      Pages: 307-312

    • NAID

      120001887653

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Spatially Controlled Functionalization and Chemical Manipulation to Fabricate 2D Arrays of Gold Nanoparticles onto ITO2008

    • Author(s)
      Om Parakash Khatri, Kuniaki Murase and Hiroyuki Sugimura
    • Journal Title

      Jpn. J. Appl. Phys. 47(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Surface Chemical Conversion of Organosilane Self-Assembled Monolayers with Active Oxygen Species Generated by Vacuum Ultraviolet Irradiation of Atmospheric Oxygen Molecules2008

    • Author(s)
      Young-Jong, Kim, Kyung-Hwang, Lee, Hikaru, Sano, Jiwon, Han, Takashi, Ichii, Kuniaki, Murase, Hiroyuki, Sugimura
    • Journal Title

      Jpn. J. Appl. Phys Vol. 47, No.1

      Pages: 307-312

    • NAID

      120001887653

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Spatially Controlled Functionalization and Chemical Manipulation to Fabricate 2D Arrays of Gold Nanoparticles onto ITO2008

    • Author(s)
      Om, Prakash, Khatri, Kuniaki, Murase, Hiroyuki, Sugimura
    • Journal Title

      Jpn. J. Appl. Phys (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Surface Chemical Conversion of Organosilane Self-Assembled Monolayers with Active Oxygen Species Generated2008

    • Author(s)
      Young-Jong Kim, 他
    • Journal Title

      Jpn. J. Appl. Phys. 47

      Pages: 307-312

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spatially Controlled Functionalization and Chemical Manipulation to Fabricate 2D Arrays of Gold Nanobarticles2008

    • Author(s)
      Om Parakash Khatri, Kuniaki Murase and Hiroyuki Sugimura
    • Journal Title

      Jpn. J. Appl. Phys. 47(印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Patterning of Self-assembled Thin Films Using Vacuum Ultraviolet Irradiation Through Anodic Porous Alumina Mask2007

    • Author(s)
      Masahiro Harada, Sunao Murata, Takashi Yanagishita, Hiroyuki Sugimura, Kazuyuki Nishio and Hideki Masuda
    • Journal Title

      Chem. Lett. 36

      Pages: 1266-1267

    • NAID

      10019961919

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Patterning of Self-assembled Thin Films Using Vacuum Ultraviolet Irradiation Through Anodic Porous Alumina Mask2007

    • Author(s)
      Masahiro, Harada, Sunao, Murata, Takashi, Yanagishita, Hiroyuki, Sugimura, Kazuyuki, Nishio, Hideki, Masuda
    • Journal Title

      Chem. Lett Vol. 36, No.10

      Pages: 1266-1267

    • NAID

      10019961919

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Patterning of Self-assembled Thin Films Using Vacuum Ultraviolet Irradiation Through Anodic Porous Alumina2007

    • Author(s)
      Masahiro Harada, 他
    • Journal Title

      Chem. Lett. 36

      Pages: 1266-1267

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic Monolayers Covalently Bonded to Si as Ultra Thin Photoresist Films in Vacuum Ultra-Violet Lithography2006

    • Author(s)
      Hiroyuki Sugimura, Hikaru Sano, Kyung-Hwang Lee, Kuniaki Murase
    • Journal Title

      Jpn. J. Appl. Phys. 45

      Pages: 5456-5460

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Micropatterning of self-assembled monolayers on silicon amplified with photochemically generated atomic oxygen2006

    • Author(s)
      Hiroyuki Sugimura, Kyung-Hwang Lee, Hikaru Sano, and Ryohei Toyokaw
    • Journal Title

      Colloids and Surfaces A 284-285

      Pages: 561-566

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Organic Monolayers Covalently Bonded to Si as Ultra Thin Photoresist Films in Vacuum Ultra-Violet Lithography2006

    • Author(s)
      Hiroyuki, Sugimura, Hikaru, Sano, Kyung-Hwang, Lee, Kuniaki, Murase
    • Journal Title

      Jpn. J. Appl. Phys Vol. 45, No.6

      Pages: 5456-5460

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Micropatteming of self-assembled monolayers on silicon amplified with photochemically generated atomic oxygen2006

    • Author(s)
      Hiroyuki, Sugimura, Kyung-Hwang, Lee, Hikaru, Sano, Ryohei, Toyokawa
    • Journal Title

      Colloids and Surfaces A Vol. 284-285

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Self-Assembled Monolayers on Si2006

    • Author(s)
      Hiroyuki, Sugimura
    • Journal Title

      Nanocrystalline Materials : Their Synthesis-Structure-Property Relationships and Applications (Edited by S.C. Tjong, Elesevier, Oxford)

      Pages: 75-91

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Micropatterning of self-assembled monolayers on silicon amplified with photochemically generated atomic oxygen2006

    • Author(s)
      H.Sugimura, K.-H.Lee, H.Sano, R.Toyokawa
    • Journal Title

      Colloids and Surfaces A 284-285

      Pages: 561-566

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Organic Monolayers Covalently Bonded to Si as Ultra Thin Photoresist Films in Vacuum Ultra-Violet Lithography2006

    • Author(s)
      H.Sugimura, H.Sano, K.-H.Lee, K.Murase
    • Journal Title

      Jpn. J. Appl. Phys. 45

      Pages: 5456-5460

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Micropatterning of chloromethylphenylsiloxane self-assembled monolayer photochemically amprified with atmospheric oxygen2005

    • Author(s)
      Hiroyuki Sugimura, Lan Hong and Kyung-Huwang Lee
    • Journal Title

      Jpn. J. Appl. Phys. 44

      Pages: 5185-5187

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Micropatteming of chloromethylphenylsiloxane self-assembled monolayer photochemically amplified with atmospheric oxygen2005

    • Author(s)
      Hiroyuki, Sugimura, Lan, Hong, Kyung-Hwang, Lee
    • Journal Title

      Jpn. J. Appl. Phys Vol. 44, No.7

      Pages: 5185-5187

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Micropatterning of chloromethylphenylsiloxane self-assembled monolayer photochemically amprified with atmospheric oxygen2005

    • Author(s)
      H.Sugimura, et al.
    • Journal Title

      Jpn.J.Appl.Phys. 44(7A)

      Pages: 5185-5187

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Photolithographic Patterning of Dendrimer Monolayer and pattern-Selective Adsorption of Linear Macromolecules2005

    • Author(s)
      T.Yamazaki, et al.
    • Journal Title

      Journal of Nanoscience and Nanotechnology 5(11)

      Pages: 314-317

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Micropatterning of self-assembled monolayers on silicon amplified with photochemically generated atomic oxygen

    • Author(s)
      H.Sugimura, et al.
    • Journal Title

      Colloids and Surfaces A (印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Organic Monolayers Covalently Bonded to Si as Ultra Thin Photoresist Films in Vacuum Ultra-Violet Lithography

    • Author(s)
      H.Sugimura, et al.
    • Journal Title

      Jpn.J.Appl.Phys. (印刷中)

    • Related Report
      2005 Annual Research Report
  • [Presentation] 自己集積化単分子膜のVUVマイクロ加工における基板-フォトマスク間微小ギャップの影響2008

    • Author(s)
      畑中剛司, 一井崇, 邑瀬邦明, 杉村博之, 大井暁彦, 中桐伸行
    • Organizer
      第55回応用物理学関係連合講演会
    • Place of Presentation
      日本大学
    • Year and Date
      2008-03-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] Photochemical surface oxidation of alkylsilane self-assembled monolayers for multilayer fabrication and micropatterning2007

    • Author(s)
      Y. J. Kim, T. Ichii, K. Murase, H. Sugimura
    • Organizer
      12th International Conference on ORGANIZED MOLECULAR FILMS(LB-12)
    • Place of Presentation
      Krakow
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Spatially Controlled Functionalization and Chemical Manipulation to Fabricate 2D Arrays of Gold Nanoparticles onto ITO2007

    • Author(s)
      Om Parakash Khatri, Kuniaki Murase and Hiroyuki Sugimura
    • Organizer
      20th International Microprocesses and Nanotechnology Conference(MNC2007)
    • Place of Presentation
      Kyoto
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Photochemical surface oxidation of alkylsilane self-assembled monolayers for multilayer fabrication and micropatteming2007

    • Author(s)
      Y., J., Kim, T., Ichii, K., Murase, H., Sugimura
    • Organizer
      12th International Conference on ORGANIZED MOLECULAR FILMS (LB-l2)
    • Place of Presentation
      KrakOw
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Spatially Controlled Functionalization and Chemical Manipulation to Fabricate 2D Arrays of Gold Nanoparticles onto ITO2007

    • Author(s)
      Om, Prakash, Khatri, Kuniaki, Murase, Hiroyuki, Sugimura
    • Organizer
      20th International Microprocesses and Nanotechnology Conference (MNC2007)
    • Place of Presentation
      Kyoto
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Surface potential microscopy for photochemical degradation of self-assembled hexadecyl monolayers on silicon2006

    • Author(s)
      Hikaru Sano, Shosuke Fujii, Yoshio Yagi, Kyung-Hwang Lee, Hiroyuki Sugimura
    • Organizer
      9th International Conference on Non-Contact Atomic Force Microscopy(NC-AFM2006
    • Place of Presentation
      Kobe
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Photochemical Surface Modification of Alkyl Monolayers by Vacuum Ultra-violet Irradiation for Stacking Organosilan monolayers2006

    • Author(s)
      Kim Young-Jong, Kyung-Hwang Lee, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      Joint Symposium on Materials Science and Engineering for the 21st Century
    • Place of Presentation
      Oosaki
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Surface potential microscopy for photochemical degradation of self-assembled hexadecyl monolayers on silicon2006

    • Author(s)
      Hikaru, Sano, Shosuke, Fujii, Yoshio, Yagi, Kyung-Hwang, Lee, Hiroyuki, Sugimura
    • Organizer
      9th International Conference on Non-Contact Atomic Force Microscopy (NC-AFM2006)
    • Place of Presentation
      Kobe
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Microstructuring of Organic Self-Assembled Monolayers Directly Bonded to Silicon Surface by Means of Photolithographic Method2005

    • Author(s)
      Kyung Hwang Lee, Hikaru Sano, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      Kyoto-TUM Workshop Bioinspired Materials
    • Place of Presentation
      Kyoto
    • Year and Date
      2005-10-07
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Vacuum ultraviolet micropatterning of organic material surfaces2005

    • Author(s)
      Hiroyuki Sugimura
    • Organizer
      New Materials Science Kyoto/UCSB Workshop 2005
    • Place of Presentation
      Kyoto
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Micropatterning of self-assembled monolayers on silicon amplified with photochemically generated atomic oxygen2005

    • Author(s)
      Hiroyuki Sugimura, Kyung-Hwang Lee, Hikaru Sano, Ryohei Toyokawa
    • Organizer
      The 11th International Conference on Organized Molecular Films(LB11
    • Place of Presentation
      Sapporo
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Nano and Micro-patterning of Self-Assembled Monolayers on Silicon: Chemical and Electrical Properties of the Modified Surfaces and Interfaces as Studied by Scanning Probe Microscopy2005

    • Author(s)
      Kyung-Hwang Lee, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      13th International Conference on Scanning Tunneling Microscopy/Spectroscopy and Related Techniques(STM'05)
    • Place of Presentation
      Sapporo
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Organic Monolayers Covalently Bonded to Si as Ultra Thin Photoresist Films in Vacuum Ultra-Violet Lithography2005

    • Author(s)
      Hiroyuki Sugimura, Hikaru Sano, Kyung-Hwang Lee, Kuniaki Murase
    • Organizer
      2005 International Microprocesses and Nanotechnology Conference(MNC2005)
    • Place of Presentation
      Tokyo
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Vacuum ultraviolet micropatteming of organic material surfaces2005

    • Author(s)
      Hiroyuki, Sugimura
    • Organizer
      New Materials Science Kyoto/UCSB Workshop 2005
    • Place of Presentation
      Kyoto
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Micropatteming of self-assembled monolayers on silicon amplified with photochemically generated atomic oxygen2005

    • Author(s)
      Hiroyuki, Sugimura, Kyung-Hwang, Lee, Hikaru, Sano, Ryohei, Toyokawa
    • Organizer
      The 11th International Conference on Organized Molecular Films (LBII)
    • Place of Presentation
      Sapporo
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Nano and Micro-patterning of Self-Assembled Monolayers on Silicon : Chemical and Electrical Properties of the Modified Surfaces and2005

    • Author(s)
      Kyung-Hwang, Lee, Kuniaki, Murase, Hiroyuki, Sugimura
    • Organizer
      13th International Conference on Scanning Tunneling Microscopy/Spectroscopy and Related Techniques (STM'05)
    • Place of Presentation
      Sapporo
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Organic Monolayers Covalently Bonded to Si as Ultra Thin Photoresist Films in Vacuum Ultra-Violet Lithography2005

    • Author(s)
      Hiroyuki, Sugimura, Hikaru, Sano, Kyung-Hwang, Lee, Kuniaki, Murase
    • Organizer
      2005 International Microprocesses and Nanotechnology Conference (MNC2005)
    • Place of Presentation
      Tokyo
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] Self-Assembled Monolayers on Si Nanocrystalline Materials: Their Synthesis-Structure-Property Relationships and Applications(Edited by S.C. Tjong)2006

    • Author(s)
      Hiroyuki Sugimura
    • Total Pages
      17
    • Publisher
      Elesevie
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Remarks] 「研究成果報告書概要(和文)」より

    • URL

      http://www.mtl.kyoto-u.ac.jp/groups/sugimura-g/

    • Related Report
      2007 Final Research Report Summary
  • [Remarks]

    • URL

      http://www.mtl.kyoto-u.ac.jp/groups/sugimura-g/

    • Related Report
      2007 Annual Research Report
  • [Patent(Industrial Property Rights)] 光照射による樹脂の接着方法および樹脂部品の製造方法2006

    • Inventor(s)
      杉村博之, 李庚晃, 谷口義尚, 田口好弘
    • Industrial Property Rights Holder
      京都大学, アルプス電気
    • Industrial Property Number
      2006-001926
    • Filing Date
      2006-07-13
    • Related Report
      2006 Annual Research Report

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Published: 2005-04-01   Modified: 2016-04-21  

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