| Project/Area Number |
17206081
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | The University of Tokyo |
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Principal Investigator |
DOMEN Kazunari The University of Tokyo, Graduate School of Engineering, Professor (10155624)
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| Co-Investigator(Kenkyū-buntansha) |
高田 剛 東京大学, 大学院工学系研究科, 講師 (80334499)
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| Project Period (FY) |
2005 – 2007
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| Project Status |
Completed (Fiscal Year 2007)
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| Budget Amount *help |
¥49,400,000 (Direct Cost: ¥38,000,000、Indirect Cost: ¥11,400,000)
Fiscal Year 2007: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Fiscal Year 2006: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Fiscal Year 2005: ¥24,960,000 (Direct Cost: ¥19,200,000、Indirect Cost: ¥5,760,000)
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| Keywords | oxynitride / photocatalyst / thin film / photochemical cells / visible light / hydrogen production / photoelectric conversion / device |
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| Research Abstract |
The hydrogen production by a photocatalyst from sunlight and water is a potential approach to solve the energy problems essentially. The purpose of this projict is the development of photocatalitic films based on d^0 and/of d^10 group (oxy)nitrides for water splitting under visible light illumination without bias voltage. First, we carried out the development of photoelectrode based on a solid solution of GaN and ZnO. The photoelectrodes were prepared by pasting (Ga_<1x>Zn_x)(N_<1x>O_x) powder onto conducting glass. We intensively surveyed the effects of surface modification. As a result, we found that photocurrent is extremely enhanced by the loading of IrO_2 as a cocatalyst. Moreover, the gas evolved from the photoelectrode was found to be O_2, while the gas evolved from the counter electrode was found to be H_2. The amount of evolved gases is consistent with the photocurrent. Next, we expanded target materials in oxysulfide. Sulfides are known as a photofunctional material. They are, however, generally unstable in water and believed to be unsuitable for a photocatalyst in water. We explore the potential possibilities of oxysulfides as a photocatalyst in water. We found that La_5Ti_2AgS_5O_7 have promising potential for H_2 production from water. Photoelectrodes were prepared by pasting powder and/or by RF magnetron sputtering on conducting substrates. By photoelectrochemical measurements, La_5Ti_2AgS_5O_7 was found to p-type semiconductor. P-type photoelectrodes are expected to evolve H_2 without self-degradation. These photoelectrodes have practical potential to produce H_2 and O_2 from water and sunlight, and more extensive studies are required.
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