Development of Resonant Ionization Mass Spectrometry Combined with Inductively Coupled Plasma for Advanced Isotopic Analysis

• Project/Area Number: 17206099
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nuclear engineering
• Research Institution: Nagoya University
• Principal Investigator: IGUCHI Tetsuo Nagoya University, 大学院・工学研究科, 教授 (60134483)
• Co-Investigator(Kenkyū-buntansha): KAWARABAYASHI Jyun 名古屋大学, 大学院・工学研究科, 准教授 (80283414) ; WATANABE Ken-ichi 名古屋大学, 大学院・工学研究科, 准教授 (30324461)
• Research Collaborator: ITOH Tetsumasa セイコーインスツルメンツ(株), 技術本部, 副本部長、工学博士
• Project Period (FY): 2005 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥50,310,000 (Direct Cost: ¥38,700,000、Indirect Cost: ¥11,610,000); Fiscal Year 2008: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000); Fiscal Year 2007: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2006: ¥12,870,000 (Direct Cost: ¥9,900,000、Indirect Cost: ¥2,970,000); Fiscal Year 2005: ¥30,290,000 (Direct Cost: ¥23,300,000、Indirect Cost: ¥6,990,000)
• Keywords: 同位体計測 / 質量分析 / 誘導結合プラズマ / 共鳴イオン化 / 波長可変レーザー / 原子・分子物理 / 分析科学 / 量子ビーム / 量子光工学 / 同位体科学 / 同位体 / レーザーアブレーション / 同位体シフト / ドップラーシフト

Research Abstract

本研究は、新しい同位体分析技術として、誘導結合プラズマ質量分析(ICP-MS)とレーザー共鳴イオン化質量分析(RIMS)の測定原理を結合することで、それぞれの長所を活かしつつ弱点を相補う質量分析法 : 「誘導結合プラズマ共鳴イオン化質量分析(ICP-RIMS)」の概念を構築し、その原理実証に成功すると共に、分析能の最適化に向けた系統的な基礎実験・解析と実用化のためのシステム設計検討を行った。

Research Products

• [Journal Article] Conceptual Study on New Isotope Analysis Technique with Resonance Ionization Mass Spectrometry Using Inductively Coupled Plasma as an Atomic Source (ICP-RIMS) (2009)
  • Author(s): K. Watanabe, Y. Higuchi, H. Tomita, J. Kawarabayashi, A. Uritani, and T. Iguchi
  • Journal Title: AIP Conf. Proc 1104 Pages: 108-113
  • Peer Reviewed
• [Journal Article] Study on Mass Discrimination Effect of Resonance Ionization Mass Spectrometry Using an Inductively Coupled Plasma as an Atomic Source (ICP-RIMS) (2009)
  • Author(s): Y. Higuchi, K. Watanabe, H. Tomita, J. Kawarabayashi, and T. Iguchi
  • Journal Title: AIP Conf. Proc 1104 Pages: 179-184
  • Peer Reviewed
• [Journal Article] Conceptual Study on New Isotope Analysis Technique with Resonance Ionization Mass Spectrometry Using Inductively Coupled Plasma as an Atomic Source (ICP-RIMS) (2009)
  • Author(s): K. Watanabe, Y. Higuchi, H. Tomita, J. Kawarabayashi, A. Uritani, T. Iguchi
  • Journal Title: AIP Conference Proceedings 1104 Pages: 108-113
  • Peer Reviewed
• [Journal Article] Study on Mass Discrimination Effect of Resonance Ionization Mass Spectrometry Using an Inductively Coupled Plasma as an Atomic Source (ICP-RIMS) (2009)
  • Author(s): Y. Higuchi, K. Watanabe, H. Tomita, J. Kawarabayashi, T. Iguchi
  • Journal Title: AIP Conference Proceedings 1104 Pages: 179-184
  • Peer Reviewed
• [Journal Article] Resonance Ionization Mass Spectrometry using Inductively Coupled Plasma as an Atom Source (2008)
  • Author(s): Y. Higuchi, K. Watanabe, T. Hasegawa, H. Tomita, J. Kawarabayashi, T. Iguchi
  • Journal Title: J. Nucl. Sci. Technol. Supplement 5 Pages: 93-96
  • Peer Reviewed
• [Journal Article] Resonance Ionization Mass Spectrometry using Inductively Coupled Plasma as an Atom Source (2008)
  • Author(s): Y. Higuchi, K. Watanabe, T. Hasegawa, H. Tomita。J. Kawarabayashi, T. Iguchi
  • Journal Title: J. Nucl. Sci. Technol. Supplement 6 Pages: 93-96
  • Peer Reviewed
• [Journal Article] Resonance Ionization Mass Spectrometry using Inductively Coupled Plasma as an Atom Source (2008)
  • Author(s): Y. Higuchi, K. Watanabe, T. Hasegawa, H. Tomita, J. Kawarabayashi, and T. Iguchi
  • Journal Title: J. Nucl. Sci. Technol. (印刷中)
  • Peer Reviewed
• [Journal Article] Development of the isotope analysis technique for inorganic trace elements using laser ablation assisted resonance (2006)
  • Author(s): K. Watanabe, Y. Higuchi, J. Kawarabayashi and T. Iguchi
  • Journal Title: J. Nucl. Sci. Technol Vol. 43, No. 4 Pages: 325-329
  • Peer Reviewed
• [Journal Article] Development of Trace Isotope Analysis Using Resonance Ionization Mass Spectrometry Based on Isotope Selection with Doppler Shift of Laser Ablated Atoms (2006)
  • Author(s): Y. Higuchi, K. Watanabe, J. Kawarabayashi and T. Iguchi
  • Journal Title: J. Nucl. Sci. Technol Vol. 43, No. 4 Pages: 334-338
  • NAID: 10016800802
  • Peer Reviewed
• [Journal Article] Development of Trace Isotope Analysis Using Resonance Ionization Mass Spectrometry Based on Isotope Selection with Doppler Shift of Laser Ablated Atoms (2006)
  • Author(s): Y.Higuchi, K.Watanabe, J.Kawarabayashi, T.Iguchi
  • Journal Title: J. Nucl. Sci. Technol. Vol.43, No.4 Pages: 334-338
  • NAID: 10016800802
• [Journal Article] Development of the isotope analysis technique for inorganic trace elements using laser ablation assisted resonance (2006)
  • Author(s): Watanabe K, Higuchi Y, Kawarabayashi J, Iguchi T
  • Journal Title: J. Nucl. Sci. Technol. Vol.43, No.4 Pages: 325-329
• [Journal Article] Development of Trace Isotope Analysis Using Resonance Ionization Mass Spectrometry Based on Isotope Selection with Doppler Shift of Laser Ablated Atoms (2006)
  • Author(s): Y.Higuchi, K.Watanabe, J.Kawarabayashi, T.Iguchi
  • Journal Title: J.Nucl.Sci.Technol.(Proc. ISE2005) Vol.43,No.4(To be published)
  • NAID: 10016800802
• [Presentation] 誘導結合プラズマの原子源としての特性と共鳴イオン化質量分析への適用検討 (2009)
  • Author(s): 樋口雄紀, 富田英生, 河原林順, 渡辺賢一, 井口哲夫
  • Organizer: 2009年春季第56回応用物理学関係連合講演会
  • Place of Presentation: 筑波大学
  • Year and Date: 2009-03-30
• [Presentation] 誘導結合プラズマを原子源とした共鳴イオン化質量分析における質量差別効果の検討 (2008)
  • Author(s): 樋口雄紀, 渡辺賢一, 富田英生, 河原林順, 井口哲夫
  • Organizer: 2008年度質量分析学会同位体比部会
  • Place of Presentation: 愛知県民の森(モリトピア愛知)
  • Year and Date: 2008-11-05
• [Presentation] 誘導結合プラズマ-共鳴イオン化質量分析法(ICP-RIMS)の概念検討 (2008)
  • Author(s): 渡辺賢一、樋口雄紀、富田英生、河原林順、瓜谷章、井口哲夫
  • Organizer: 2008年度質量分析学会同位体比部会
  • Place of Presentation: 愛知県民の森(モリトピア愛知)
  • Year and Date: 2008-11-05
• [Presentation] Conceptual Study on New Isotope Analysis Technique with Resonance Ionization Mass Spectrometry Using Inductively Coupled Plasma as an Atomic Source (ICP-RIMS) (2008)
  • Author(s): K. Watanabe, Y. Higuchi, H. Tomita, J. Kawarabayashi, A. Uritani, and T. Iguchi
  • Organizer: The 4th International Conference on Laser Probing
  • Place of Presentation: Nagoya Univ
  • Year and Date: 2008-10-09
• [Presentation] Study on Mass Discrimination Effect of Resonance Ionization Mass Spectrometry Using an Inductively Coupled Plasma as an Atomic Source (ICP-RIMS) (2008)
  • Author(s): Y. Higuchi, K. Watanabe, H. Tomita, J. Kawarabayashi, and T. Iguchi
  • Organizer: The 4th International Conference on Laser Probing
  • Place of Presentation: Nagoya Univ
  • Year and Date: 2008-10-09
• [Presentation] CONCEPTUAL STUDY ON NEW ISOTOPE ANALYSIS TECHNIQUE WIIH RESONANCE IONIZ ATION MASS SPECTROMEITY USING INDUCTIVELY COUPLED PLASMA AS AN ATOMIC SOURCE (ICP-RIMS) (2008)
  • Author(s): K Watanabe, Y. Higuchi, J. Kawarabayashi, A. Uritani, T. Iguchi
  • Organizer: The 4th International Conference on Laser Probing
  • Place of Presentation: Nagoya University
  • Year and Date: 2008-10-09
• [Presentation] STUDY on Mass Discnimina Effect of Resonance Ionizaticn Mass Spectrometry using an Inductively Coupled Plasrra as an Atomic Source (ICP-RIMS) (2008)
  • Author(s): Y. Higuchi, K. Watanabe, H. Tomita, J. Kawarabayashi, T. Iguchi
  • Organizer: The 4th International Conference on Laser Probing
  • Place of Presentation: Nagoya University
  • Year and Date: 2008-10-09
• [Presentation] 誘導結合プラズマを原子源とした共鳴イオン化質量分析における質量差別効果の検討 (2008)
  • Author(s): 樋口雄紀, 渡辺賢一, 富田英生, 河原林順, 井口哲夫
  • Organizer: 2009年度質量分析学会同位体比部会
  • Place of Presentation: 愛知邸ぬ森缶リトピア愛知
  • Year and Date: 2008-10-05
• [Presentation] 誘導結合プラズマ-共鳴イオン化質量分析法(ICP・RIMS)の概念検討 (2008)
  • Author(s): 渡辺賢一, 樋口雄紀, 富田英生, 河原林順, 瓜谷章, 井口哲夫
  • Organizer: 2009年度質量分析学会同位体比部会
  • Place of Presentation: 愛知県民の森(モリトピア愛知)
  • Year and Date: 2008-10-05
• [Presentation] 誘導結合プラズマを原子源とした共鳴イオン化質量分析法の開発 (2008)
  • Author(s): 樋口雄紀, 渡辺賢一, 富田英生, 河原林 順, 井口哲夫
  • Organizer: 第55回応用物理学関係連合講演
  • Place of Presentation: 日本大学
  • Year and Date: 2008-03-30
• [Presentation] 誘導結合プラズマを原子源とした共鳴イオン化質量分析法の開発 (2008)
  • Author(s): 樋口雄紀, 渡辺賢一, 富田英生, 河原林 順, 井口哲夫
  • Organizer: 第55回応用物理学関係連合講演会
  • Place of Presentation: 日本大学 理工学部 船橋キャンパス
  • Year and Date: 2008-03-30
• [Presentation] 誘導結合プラズマを原子源とした共鳴イオン化質量分析法の基礎研究 (2008)
  • Author(s): 樋口雄紀, 渡辺賢一, 長谷川拓也, 富田英生, 河原林順, 井口哲夫
  • Organizer: 第6回同位体科学研究会
  • Place of Presentation: 名古屋大学
  • Year and Date: 2008-03-04
• [Presentation] 誘導結合プラズマ・共鳴イオン化質量分析法の開発基礎研究 (2007)
  • Author(s): 樋口雄紀, 渡辺賢一, 富田英生, 河原林順, 井口哲夫
  • Organizer: 質量分析学会同位体比部会
  • Place of Presentation: 定山渓グランドホテル瑞苑
  • Year and Date: 2007-10-05
• [Presentation] 誘導結合プラズマ共鳴イオン化質量分析法の基礎研究 (2007)
  • Author(s): 樋口雄紀, 渡辺賢一, 河原林順, 井口哲夫
  • Organizer: 日本原子力学会2007年秋の大会
  • Place of Presentation: 北九州国際会議場
  • Year and Date: 2007-09-28
• [Presentation] Study on Resonance Ionization Mass Spectrometry Pre-excited by Inductively Coupled Plasma, 3rd Int. Symp (2007)
  • Author(s): Y. HIGUCHI, K. WATANABE, T. HASEGAWA, H. TOMITA, J. KAWARABAYASHI, T. IGUCHI
  • Organizer: on Isotope Science and Engineering from Basics to Applications
  • Place of Presentation: Nagoya Univ
  • Year and Date: 2007-09-19