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Fabrication of two-dimensional electron gas with high mobility in SrTiO_3 to develop novel quantum

Research Project

Project/Area Number 17340103
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionThe University of Tokyo

Principal Investigator

HWANG H.Y  The University of Tokyo, Department of Frontier Science, Associate Professor, 大学院新領域創成科学研究科, 助教授 (30361611)

Co-Investigator(Kenkyū-buntansha) SUSAKI Tomofumi  Tokyo Institute of Technology, Materials and Structures Laboratory, Associate Professor, 応用セラミックス研究所, 助教授 (20332265)
Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥15,700,000 (Direct Cost: ¥15,700,000)
Fiscal Year 2006: ¥7,600,000 (Direct Cost: ¥7,600,000)
Fiscal Year 2005: ¥8,100,000 (Direct Cost: ¥8,100,000)
KeywordsStrongly correlated electron system / Crystal growth / Low-temperature physics / Low-dimensional physics
Research Abstract

This project is aimed at realizing a two-dimensional electron gas in SrTiO_3. For that purpose, it is essential to fabricate heterostructures and to understand electronic structures at the heterointerfaces. We report our results related to this purpose.
1. We have deposited LaAlO_3 films on SrTiO_3(100) substrates and probed the interface electronic structure by EELS. For SrO-terminated substrates, holes generated by the polar discontinuity were compensated by oxygen vacancies. This is the result of the removal of the band offset, which was also observed for an n-type interface originating from TiO_2-terminated substrates.
2. We have probed the interface electronic structure at an interface of strontium titanate and transition-metal oxides by measuring junction properties. As a result, we have found a chemical potential shift by magnetic field at the interface of manganite, which modulates the junction properties. Precise analysis has revealed the importance of electron tunneling in the junction properties.
3. We have observed the Schottky barrier height formed at SrRuO_3/Nb : SrTiO_3 interface by internal photoemission spectroscopy. As a result, the interface can be described by the Schottky-Mott model. We have found that this method can be generally applicable to other interfaces composed of transition-metal oxides.
4. We have fabricated a quantum well structure by a Mott insulator and probed the electronic states. We have used lanthanum vanadate. As a result, we have found the existence of tetravalent vanadium, which does not exist in a bulk form, at the top layer of the vanadate due to a charge reconstruction by x-ray photoemission spectroscopy. In addition, a competing phase of trivalent vanadium and pentavalent vanadium is formed by adjusting growth conditions. We have also found tetravalent vanadium at the phase boundary by EELS.

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (24 results)

All 2007 2006 2005

All Journal Article (24 results)

  • [Journal Article] Transport Mechanisms in Manganite-Titanate Heterojunctions2007

    • Author(s)
      T.Susaki
    • Journal Title

      Physical Review B 75

      Pages: 104409-104409

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Characterization of the Schottky Barrier in SrRuO_3/Nb : SrTiO_3 Junctions2007

    • Author(s)
      Y.Hikita
    • Journal Title

      Applied Physics Letters 90

      Pages: 143507-143507

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Transport Mechanisms in Manganite-Titanate Junctions2007

    • Author(s)
      T.Susaki
    • Journal Title

      Physical Review B 75

      Pages: 104409-104409

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Characterization of the Schottky barrier in SrRuO_3/Nb:SrTiO_3 junctions2007

    • Author(s)
      Y.Hikita
    • Journal Title

      Applied Physics Letters 90

      Pages: 143507-143507

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Interface Magnetoresistance in Manganite-Titanate Heterojunctions2007

    • Author(s)
      T.Susaki, N.Nakagawa, H.Y.Hwang
    • Journal Title

      Physical Review B 75

      Pages: 104409-104409

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Atomic Control of the Electronic Structure at Complex Oxide Heterointerfaces2006

    • Author(s)
      H.Y.Hwang
    • Journal Title

      MRS Bulletin 31

      Pages: 28-28

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Why Some Interfaces Cannot be Sharp2006

    • Author(s)
      N.Nakagawa
    • Journal Title

      Nature Materials 5

      Pages: 204-204

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Rectifying NdNiO_3/Nb : SrTiO_3 Junctions as a Probe of the Surface Electronic Structure of NdNiO_32006

    • Author(s)
      Y.Kozuka
    • Journal Title

      Applied Physics Letters 88

      Pages: 142111-142111

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Lattice Polarization Effects on Electron-Gas Charge Densities in Ionic Superlattices2006

    • Author(s)
      D.R.Hamann
    • Journal Title

      Physical Review B 73

      Pages: 195603-195603

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Growth and Electronic Structure of LaVO_x Films2006

    • Author(s)
      Y.Hotta
    • Journal Title

      Applied Physics Letters 89

      Pages: 31918-31918

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Nanometer Scale Electronic Reconstruction at the Interface between LaVO_3 and LaVO_42006

    • Author(s)
      L.Fitting
    • Journal Title

      Physical Review Letters 97

      Pages: 256803-256803

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Electronic Structure of the Mott Insulator LaVO_3 in a Quantum-Well Geometry2006

    • Author(s)
      Y.Hotta
    • Journal Title

      Applied Physics Letters 89

      Pages: 251916-251916

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Rectifying NdNiO_3/Nb:SrTiO_3 Junctions as a Probe of the Surface Electronic Structure of NdNiO_32006

    • Author(s)
      Y.Kozuka
    • Journal Title

      Applied Physics Letters 88

      Pages: 142111-142111

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Nanometer Scale Electronic Reconstruction at the Interface between LaVO_3 and LaVO_42006

    • Author(s)
      L.Fitting
    • Journal Title

      Physics Review Letters 97

      Pages: 256803-256803

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Rectifying NdNio_3/nb : SrTiO_3 Junctions as a Probe of the Surface Electronic Structure of NdNiO_32006

    • Author(s)
      Y.Kozuka, T.Susaki, H.Y.Hwang
    • Journal Title

      Applied physics Letters 88

      Pages: 142111-142111

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Lattice Polarization Effects on Electron-Gas Charge Densties in Ionic Superlattices2006

    • Author(s)
      D.R.Hamann, D.A.Muller, H.Y.Hwang
    • Journal Title

      Physical Review B 73

      Pages: 195403-195403

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Growth and Electronic Structure of LaVO_x Films2006

    • Author(s)
      Y.Hotta, Y.Mukunoki, T.Susaki, H.Y.Hwang, L.Fitting, D.A.Muller
    • Journal Title

      Applied Physics Letters 89

      Pages: 31918-31918

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Nanometer Scale Electronic Reconstruction at he Interface between LaVO_3 and LaVO_42006

    • Author(s)
      L.Fitting, Y.Hotta, T.Susaki, H.Y.Hwang, D.A.Muller
    • Journal Title

      Physics Review Letters 97

      Pages: 256803-256803

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electronic Structure of the Mott Insulator LaVO_3 in a Quantum-Well Geometry2006

    • Author(s)
      Y.Hotta, H.Wadati, A.Fujimori, T.Susaki, H.Y.Hwang
    • Journal Title

      Applied Physics Letters 89

      Pages: 251916-251916

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Why Some Interfaces Cannot be Sharp2006

    • Author(s)
      N.Nakagawa, H.Y.Hwang, D.A.Muller
    • Journal Title

      Nature Materials 5

      Pages: 204-204

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Atomically Flat (110) SrTiO_3 and Heteroepitaxy2005

    • Author(s)
      Y.Mukunoki
    • Journal Title

      Applied Physics Letters 86

      Pages: 171908-171908

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Atomically Flat (110) SrTiO_3 and Heteoepitaxy2005

    • Author(s)
      Y.Mukunoki
    • Journal Title

      Applied Physics Letters 86

      Pages: 171908-171908

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Atomically Flat(110)SrTiO3 and Heteroepitaxy2005

    • Author(s)
      Y.Mukunoki, N.Nakagawa, T.Susaki, H.Y.Hwang
    • Journal Title

      Applied Physics Letters 86

      Pages: 171908-171908

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Oxygen Vacancies Shine Blue2005

    • Author(s)
      H.Y.Hwang
    • Journal Title

      Nature Materials 4

      Pages: 803-803

    • Related Report
      2005 Annual Research Report

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Published: 2005-04-01   Modified: 2020-05-15  

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