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Deciphering the surface environment of the primitive Earth from nitrogen isotopes trapped in Archean sedimentary rocks-Investigation of its trapping forms in the rocks.

Research Project

Project/Area Number 17340168
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Geochemistry/Astrochemistry
Research InstitutionOsaka University

Principal Investigator

HASHIZUME Ko  Osaka University, Graduate School of Science, Assistant Professor, 大学院理学研究科, 助手 (90252577)

Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥12,900,000 (Direct Cost: ¥12,900,000)
Fiscal Year 2006: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 2005: ¥10,000,000 (Direct Cost: ¥10,000,000)
KeywordsPrimitive Earth / Surface Environments / Nitrogen Isotopes / Sedimentary Rocks / Archean / Chert / Banded Iron Formations / 粘土鉱物 / アンモニウム
Research Abstract

In this study, search of the surface environments of the primitive earth was performed using the information of nitrogen isotopes obtained from Archean sedimentary rocks. Though the nitrogen isotopes trapped in the rock samples have potential of providing such information, it is not always clear how we may obtain and interprete the raw data. We studied 3.5 Ga old chert samples from western Australia (from Kitty's gap and Marble bar), and a 2.7-2.9 Ga old samples of the banded iron formation from Dhawar Craton of India. Volatile compounds (N_2, Ar, C and H_2O) were extracted from samples using a stepwise combustion method, and their elemental and/or isotopic compositions were analysed.We were able to specify or infer three trapping sites/forms of nitrogen by combining the information of different volitile compounds. In Kitty's gap chert, nitrogen concentrations were observed to be correlated well with those of radiogenic ^<40>Ar, suggesting that nitrogen is trapped in K-bearing clay minerals. The δ15N values showed a wide range between-4 to +10 permil, and were correlated with the ^<40>Ar/N ratio, suggesting existence of two different types of trapping sites among the clay minerals. In Marble bar chert, nitrogen with δ^<15>N values between +6.0 to +7.3 permil was observed, associated with carbon, suggesting that nitrogen in this sample is trapped in organic form. Furthur investigations imply that the N-bearing organic matter is protected by inorganic minerals. Among the BIF samples, N with δ^<15>N values around +10 permil was observed. There seem to exist two types of N-bearing C-associated host phases with different C/N ratios. Discrimination of the N isotopic components in different chemical forms among the Archean rocks may largly help us to decipher the isotopic evolution of nitrogen of the primitive biosphere.

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (15 results)

All 2007 2006 2005

All Journal Article (15 results)

  • [Journal Article] Biogenic nitrogen and carbon in Fe-Mn-oxyhydroxides from an Archean chert, Marble Bar, Western Australia.2007

    • Author(s)
      Pinti D. L.
    • Journal Title

      Geochemistry, Geophysics, Geosystems 8

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Biogenic nitrogen and carbon in Fe-Mn-oxyhydroxides from an Archean chert, Marble Bar, Western Australia.2007

    • Author(s)
      Pinti D.L.et al.
    • Journal Title

      Geochemistry, Geophysics, Geosystems 8

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Biogenic nitrogen and carbon in Fe-Mn-oxyhydroxides from an Archean chert, Marble Bar, Western Australia.2007

    • Author(s)
      Pinti D.L., Hashizume K., Orberger B., Gallien J., Cloquet C., Massault M.
    • Journal Title

      Geochemistry, Geophysics, Geosystems 8

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Micro-facies and origin of some Archaean Cherts (Pilbara, Australia).2006

    • Author(s)
      Orberger B.
    • Journal Title

      The Geological Society of America Special Papers 8

      Pages: 133-156

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Search for primordial biogenic isotopic signatures of nitrogen in Archean sedimentary rocks2006

    • Author(s)
      Hashizume K.
    • Journal Title

      Geochimica et Cosmochimica Acta 18

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Biomarkers in Archaean banded iron formations from Pilbara and Dhawar Craton2006

    • Author(s)
      Orberger B.
    • Journal Title

      Geochimica et Cosmochimica Acta 18

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Micro-facies and origin of some Archaean Cherts (Pilbara, Australia).2006

    • Author(s)
      Orberger B. et al.
    • Journal Title

      The Geological Society of America Special Papers 8

      Pages: 133-156

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Search for primordial biogenic isotopic signatures of nitrogen in Archean sedimentary rocks.2006

    • Author(s)
      Hashizume K. et al.
    • Journal Title

      Geochimica et Cosmochimica Acta 67

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Biomarkers in Archaean banded iron formations from Pilbara and Dhawar Craton.2006

    • Author(s)
      Orberger B. et al.
    • Journal Title

      Geochimica et Cosmochimica Acta 67

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Micro-facies and origin of some Archaean Cherts (Pilbara, Australia).2006

    • Author(s)
      Orberger B., Rouchon V., Westall F., deVries S.T., Pinti D.L., Wagner Ch., Wirth R., Hashizume K.
    • Journal Title

      The Geological Society of America Special Papers 405

      Pages: 133-156

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Micro-facies and origin of some Archaean Cherts (Pilbara, Australia).2006

    • Author(s)
      Orberger B., Rouchon V., Westall F., deVries S.T., Pinti D.L., Wagner Ch., Wirth R., Hashizume K.
    • Journal Title

      The Geological Society of America Special Papers (印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Biogeochemical cycles of sulfur and nitrogen in the Archean ocean and atmosphere.2005

    • Author(s)
      Shen Y.
    • Journal Title

      AGU Geophysical Monographs 164

      Pages: 305-320

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Biogeochemical cycles of sulfur and nitrogen in the Archean ocean and atmosphere.2005

    • Author(s)
      Shen Y.et al.
    • Journal Title

      AGU Geophysical Monographs 164

      Pages: 305-320

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] A non-terrestrial ^<16>O-rich isotopic composition for the protosolar nebula.2005

    • Author(s)
      Hashizume, K., Chaussidon, M.
    • Journal Title

      Nature 434

      Pages: 619-622

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Biogeochemical cycles of sulfur and nitrogen in the Archean ocean and atmosphere.2005

    • Author(s)
      Shen, Y., Pinti D.L., Hashizume, K.
    • Journal Title

      AGU Geophysical Monographs 164

      Pages: 305-320

    • Related Report
      2005 Annual Research Report

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Published: 2005-04-01   Modified: 2016-04-21  

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