Physical-property study of low-dimensional layered actinide compounds
Project/Area Number |
17350032
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Japan Atomic Energy Agency |
Principal Investigator |
NAKAMURA Akio Japan Atomic Energy Agency, 先端基礎研究センター, 研究主幹 (80370443)
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Co-Investigator(Kenkyū-buntansha) |
SHIOKAWA Yosinobu 東北大学, 金属材料研究所, 教授 (50111307)
HOMMA YOSHIYA 東北大学, 金属材料研究所, 教授 (00260448)
YAMAMOTO Etsuji 独立行政法人日本原子力研究開発機構, 先端基礎研究センター, 研究副主幹 (50343934)
NAKADA Masami 独立行政法人日本原子力研究開発機構, 原子力基礎基盤研究部門, 研究副主幹 (60370441)
YOSHII Kenji 独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究副主幹 (90354985)
SAKAI Hironori 独立行政法人日本原子力研究開発機構, 先端基礎研究センター, 研究職 (80370401)
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Co-Investigator(Renkei-kenkyūsha) |
IKEDA Shugo 兵庫県立大学大学院, 物質理学研究科, 助教 (80414580)
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Research Collaborator |
ONUKI Yoshichika 大阪大学, 理学研究科, 教授 (40118659)
AKABORI Mitsuo 独立行政法人日本原子力研究開発機構, 原子力基礎基盤研究部門, 研究主幹 (10469801)
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Project Period (FY) |
2005 – 2008
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Project Status |
Completed (Fiscal Year 2008)
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Budget Amount *help |
¥14,820,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥720,000)
Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2007: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2006: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2005: ¥10,500,000 (Direct Cost: ¥10,500,000)
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Keywords | アクチノイド / 層状化合物 / 物質創成 / 構造 / 磁性 / 電気伝導性 / 超伝導 / 物質創製 / 低次元化合物 / ウラン / 窒化ハロゲン化物 / 強磁性 |
Research Abstract |
5f電子を持つアクチノイド(An)系の多様な低次元の層状化合物、例えば、トリウム(Th), ウラン(U), ネプツ二ウム(Np)などの窒化塩化物AnNCl、錯体、カルコゲナイド(硫化物)、プニクタイト(リン化物)、酸化物、金属間化合物などを対象に、物質創製と、5f電子特有の低次元構造に由来する新規な電子物性(磁性、電気伝導性、超伝導など)を探索、両者の相関を明らかにする研究に取り組んだ。窒化ハロゲン化物研究では、UNClがキュウリー温度T_C=32Kの強磁性体であり、Li挿入によりネール温度T_N=180Kまでの反強磁性体へと変化することを明らかにした。特異な陽イオン-陽イオン結合を持つネプツニル錯体研究では、対応するランタノイド(4f電子系)のツリウム(Tm)錯体を含め、その特異な分子磁性挙動を、構造の次元性(0、1、2次元)との関連で系統的に明らかにし、未開拓のアクチノイド分子磁性研究に大きな進展をもたらした。同時に、Np化合物研究の有力な武器である^<237>Npメスバウアー分光測定法の開発・整備を大きく前進させた。またNpPd5Al_2単結晶を育成しこれがNp 系で世界初の重い電子系超伝導体であるここを発見するとともに、U硫化物がAn系ではきわめて稀有な大きな磁気抵抗効果を示すことを見出した。
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Report
(5 results)
Research Products
(60 results)
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[Journal Article] The low-energy spectrum of a Tm-based double-decker complex2009
Author(s)
N. Magnani, R. Caciuffo, E. Colineau, F. Wastin, A. Baraldi, E. Buffagni, R. Capelletti, S. Carretta, M. Mazzera, D. T. Adroja, M. Watanabe and A. Nakamura
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[Journal Article] The low-energy spectrum of a Tm-based double-decker complex2009
Author(s)
N. Magnani, R. Caciuffo, E. Colineau, F. Wastin, A. Baraldi, E. Buffagni, R. Capelletti, S. Carretta, M. Mazzera, D. T. Adroja, M. Watanabe, A. Nakamura
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[Journal Article] Hyperfine interactions in the itinerant system UFeGa_52009
Author(s)
K. Kambe, H. Sakai, Y. Tokunaga, H. Chudo, H. Yasuoka, T. D. Matsuda, Y. Haga, S. Ikeda, A. Nakamura, E. Yamamoto, D. Aoki, Y. Hommna, Y. Shiokawand, Y. Onuki
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Journal Title
J. Nucl. Mater. 385
Pages: 1-3
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Peer Reviewed
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[Journal Article] Crystal structure and magnetic properties of the new ternary actinide compounds AnPd5Al2 (An=U,Np)2008
Author(s)
Y. Haga, D. Aoki, Y. Homma, S. Ikeda, T. D. Matsuda, E. Yamamoto, H. Sakai, N. Tateiwa, N. D. Dung, A. Nakamura, Y. Shiokawa and Y. Onuki
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Journal Title
J. Alloys and. Compounds 464
Pages: 47-50
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Peer Reviewed
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[Journal Article] Pressure effect on paramagnet β-US_22008
Author(s)
S. Ikeda, H. Sakai, T. D. Matsuda, N. Tateiwa, A. Nakamura, E. Yamamoto, D. Aoki, Y. Homma, Y. Shiokawa, M. Hedo, Y. Uwatoko, Y. Haga, Y. Ounki
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Journal Title
Physica B : Condensed Matter. 403
Pages: 893-894
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[Journal Article] Pressure effect on paramagnet β-US_22008
Author(s)
S. Ikeda, H. Sakai, T.D. Matsuda, N. Tateiwa, A. Nakamura, E. Yamamoto, D. Aoki, Y. Homma, Y. Shiokawa, M. Hedo, Y. Uwatoko, Y. Haga, Y. Onuki
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Journal Title
Physica B:Condensed Matter 403
Pages: 893-894
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[Journal Article] NMR Studies of Actinide Dioxides2007
Author(s)
Y. Tokunaga, H. Sakai, T. Fujimoto, S. Kambe, R.E. Walstedt, K. Ikushima, H. Yasuoka, D. Aoki, Y. Homma, Y. Haga, T.D. Matsuda, S. Ikeda, E. Yamamoto, A. Nakamura, Y. Shiokawa, K. Nakajima, Y. Arai and Y. Onuki
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Journal Title
J. Alloys and Compounds 444-445
Pages: 241-245
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[Journal Article] Unconventional heavy-fermion superconductivity of a new transuranium compound NpPd5Al22007
Author(s)
D. Aoki, Y. Haga, T. D. Matsuda, N. Tateiwa, S. Ikeda, Y. Homma, H. Sakai, Y. Shiokawa, E. Yamamoto, A. Nakamura, R. Settai and Y. Onuki
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Journal Title
NAID
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[Journal Article] Defect-fluorite oxides M_1-yLn_yO_2-y/2(Ln=lanthanide;M=HF,Zr,Ce,U,Th):Structure,property and applications2007
Author(s)
A. Nakatnura, N. Masaki, H. Otobe, Y., Hinatsu, J. Wang, M. Takeda
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Journal Title
Pure and Applied Chemistry 79
Pages: 1691-1729
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[Journal Article] Itinerant 5f electrons and the Fermi surface properties in neptunium compounds2007
Author(s)
D. Aoki, H. Yamagami, Y. Homma, H. Sakai, S. Ikeda, Y. Shiokawa, E. Yamamoto, A. Nakamura, Y. Haga, R. Settai, Y. Onuki
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Journal Title
J.Magnetism and Magnetic Materials 310
Pages: 1678-1783
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[Journal Article] NMR observation of quadrupolar order parameter in NpO_22007
Author(s)
Y. Tokunaga, D. Aoki, Y. Homma, S. Kambe, H. Sakai, S. Ikeda, T. Fujimoto, R.E. Walstedt, H. Yasuoka, Y. Shiokawa, E. Yamamoto, A. Nakamura
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Journal Title
J.Magnetism and Magnetic Materials 310
Pages: 1678-1783
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[Journal Article] Magnetism,superconductivity and Fermi surfaces of Pu compounds2007
Author(s)
Y. Tokunaga, D. Aoki, H. Yamagami, T. D.. Matsuda, K. Nakajima, Y. Arai, Y.. Homma, Y. Shiokawa E. Yamamoto, A. Nakamura, Y. Onuki
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Journal Title
J.Magnetism and Magnetic Materials 310
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[Journal Article] Enhancement of relaxation rates in the normal state of superconductor PuRhGa_5;NQR relaxation study2007
Author(s)
H. Sakai, S. Kambe, Y. Tokunaga, T. Fujunoto, R.E. Walstedt, H. Yasuoka, D. Aoki, Y. Homma, E. Yamamoto, A. Nakamura, Y. Shiokawa, K. Nakajima, Y. Arai, T.D. Matsuda, Y. Haga, Y. Onuki
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Journal Title
J.Magnetism and Magnetic Materials 310
Related Report
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[Journal Article] High-field magnetization in transuranium compound2007
Author(s)
S. Sugiyama, H. Nakashima, D. Aoki, S. Ikeda, Y. Haga, E. Yamamoto, A. Nakamura, Y. Homma, Y. Shiokawa, K. Kindo, M. Hagiwara, Y. Onuki
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Journal Title
J.Magnetism and Magnetic Materials 310
Pages: 178901791-178901791
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[Journal Article] Magnetic properties and Fermi surfaces in NpIn_32007
Author(s)
D. Aoki, H. Yamagami, Y. Homma, H. Sakai, S. Ikeda, Y. Shiokawa, E. Yamamoto, ANakamura, Y. Haga, R. Settai, Y. Onuki
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Journal Title
J.Magnetism and Magnetic Materials 310
Pages: 385-388
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[Journal Article] Anisotropic spin fluctuations and anomalies of nuclear quadyupole interactions in the itinerant antiferromagnetic NpCoGa_5:59Co NMR and 69,71Ca NMR/NQR studies2007
Author(s)
H. Sakai, S. Kambe, Y. Tokunaga, T. Fujimori, R.E. Walstedt, H. Yasuoka, D. Aoki, Y. Homma, E. Yamamoto, A. Nakamura, Y. Shiokawa, Y. Onuki
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[Journal Article] Single Crystal Growth,Superconductivity and Fermi Surface Study of Plutonium Compounds2007
Author(s)
Y. Haga, D. Aoki, H. Yamagami, T.D. Matsuda, K. Nakajima, Y. Arai, E. Yamamoto, A. Nakamura, Y. Homma, Y. Shiokawa, Y. Onuki
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Journal Title
J. Alloys and Compounds 444-445
Pages: 114-118
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[Journal Article] NMR,Studies of Actinide Dioxides2007
Author(s)
Y. Tokunaga, H. Sakai, T. Fujunoto, S. Kambe, R.E. Walstedt, K. Ikushima, H. Yasuoka, D. Aoki, Y. Houuna, Y. Haga, T.D. Matsuda, S. Ikeda, E. Yamamoto, A. Nakamura, Y. Shiokawa K. Nakajima, Y. Arai, Y. Onuki
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Journal Title
J.Alloys and Colnpounds 444-445
Pages: 241-245
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[Journal Article] Ga NQR relaxation rates in sup erconductor PuRhGa_52007
Author(s)
H. Sakai, S. Kambe, Y. Tokunaga, T. Fujimoto, R.E.Walstedt, H. Yasuoka, D. Aoki, Y. Homma, E.Yamamoto., A. Nakamura, Y. Shiolcawa, K. Nakajima, Y. Arai, T.D. Matsuda, Y. Haga, Y. Onuki
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Journal Title
J.Phys.Chem.Solids 68
Pages: 2103-2106
Related Report
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[Journal Article] Unconventional heavy-fermion superconductivity of a new transuranium compound NpPd_5Al_22007
Author(s)
D.Aoki, Y.Haga, T.D.Matsuda, N.Tateiwa, S.Ikeda, Y.Homma, H.Sakai, Y.Shiokawa, E.Yamamoto, A.Nakamura, R.Settai, Y.Onuki
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Journal Title
J. Phys. Soc. Jpn 76(in press)
NAID
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[Journal Article] Hyperfine interqactions of NpFeGa_5 observed by ^<237>Np and ^<57>Fe Mossbauer spectroscopy2006
Author(s)
Y.Homma, S.nasu, A.Nakamura, M.Nakada, D.Aoki, N.Metoki, E.Yamamoto, H.Sakai, S.Ikeda, Y.Haga, Y.Onuki, Y.Shiokawa
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Journal Title
J. Phy. Soc. Jpn. Suppl. 75
Pages: 44-46
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[Presentation] 新規超伝導体NpPd_5Al_2の27Al NMRによる研究22008
Author(s)
中堂 博之, 酒井 宏典, 徳永 陽, 神戸 振作, 青木 大, 本間 佳哉, 塩川 佳伸, 芳賀 芳範, 松田 達磨, 池田 修悟, 立岩 尚之, 山本 悦嗣, 中村 彰夫, 大貫 惇陸
Organizer
日本物理学会第63回年次大会
Place of Presentation
近畿大学(大阪)
Related Report
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[Presentation] NpPd_3単結晶の低温物性2008
Author(s)
本間 佳哉, 芳賀 芳範, 青木 大, 酒井 宏典, 松田 達磨, 池田 修悟, 山本 悦嗣, 中村 彰夫, 塩川 佳伸, 大貫 惇睦
Organizer
日本物理学会第63回年次大会
Place of Presentation
近畿大学(大阪)
Related Report
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[Presentation] Pressure effect on paramagnet β-US22007
Author(s)
S. Ikeda, H. Sakai, T.D. Matsuda, N. Tateiwa, A. Nakamura, E. Yamamoto, D. Aoki, Y. Homma, Y. Shiokawa, M. Hedo, Y. Uwatoko, Y. Haga and Y. Ounki
Organizer
Int'l Symp. Strongly-Correlated Electron Systems (SCES)-2007
Place of Presentation
Houston, USA
Related Report
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[Presentation] Pressure effect on paramagnet β-US_2 and ferromagnet UTeS2007
Author(s)
S. Ikeda, H. Sakai, T.D. Matsuda, N. Tateiwa, D. Aolti, Y. Homma, E. Yamamoto, A. Nakamura, Y. Shiokawa, T. Yamada, Y. Ohta, K. Sugiyama, K. Matsubayashi, M. Hedo, Y. Uwatoko, M. Hedo, Y. Haga, Y. Onuki
Organizer
The Int'1 Conf on Strongly Correlated Electron Systems 2007
Place of Presentation
Houston(米国)
Related Report
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[Presentation] 7O NMR spin-lattice relaxation in NpO2: Field-dependent cross-relaxation process driven by 237Np spins2006
Author(s)
Y. Tokunaga, R. E. Walstedt, Y. Homma, D. Aoki, S. Kambe, H. Sakai, T. Fujimoto, S. Ikeda, E. Yamamoto, A. Nakamura, Y. Shiokawa, and H. Yasuoka
Organizer
Int'l Symp. Quantum Beam Science Directorate of JAEA (QuBS)
Place of Presentation
Tokai, Japan
Related Report
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