Mechanisms and applications of plasmon resonance-based photoelectrochemistry of metal nanoparticles

• Project/Area Number: 17350064
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Functional materials chemistry
• Research Institution: The University of Tokyo
• Principal Investigator: TATSUMA Tetsu The University of Tokyo, 生産技術研究所, 教授 (90242247)
• Co-Investigator(Kenkyū-buntansha): TAKADA Kazutake 東京大学, 生産技術研究所, 助手 (20361644) ; SAKAI Nobuyuki 東京大学, 生産技術研究所, 助教 (70431822)
• Project Period (FY): 2005 – 2008
• Project Status: Completed (Fiscal Year 2008)
• Budget Amount: ¥17,180,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥2,580,000); Fiscal Year 2008: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2007: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2006: ¥2,900,000 (Direct Cost: ¥2,900,000); Fiscal Year 2005: ¥3,100,000 (Direct Cost: ¥3,100,000)
• Keywords: プラズモン共鳴 / 金属ナノ粒子 / 酸化チタン / 光電変換 / フォトクロミック現象 / アクチュエータ / 金ナノ粒子 / 銀ナノ粒子 / 電気化学 / 光触媒 / 増感型太陽電池 / 半導体

Research Abstract

金や銀のナノ粒子のプラズモン共鳴に基づく光吸収により、金属ナノ粒子から酸化チタンなどの半導体への電子移動が起こることを明らかにした。この電子移動を利用した光電変換デバイスや可視光応答光触媒、親水・疎水表面パターニング法、還元エネルギー貯蔵型光触媒、光応答膨潤-収縮ゲルを用いたアクチュエータを開発した。また、銀ナノ粒子-酸化チタン系の多色フォトクロミズムでは、その色変化に銀ナノ粒子の粒径・形状変化が関与していることを明らかにした。

Research Products

• [Journal Article] Electrodeposition of Gold Nanoparticles on ITO : Control of Morphology and Plasmon Resonance-Based Absorption and Scattering (2009)
  • Author(s): 坂井伸行, 藤原祐輔, 新井道郎, 于克鋒, 立間徹
  • Journal Title: J. Electroanal. Chem 628 Pages: 7-15
  • Peer Reviewed
• [Journal Article] Plasmon Resonance-Based Generation of Cathodic Photocurrent at Electrodeposited Gold Nanoparticles Coated with TiO_2 Films (2009)
  • Author(s): 坂井伸行, 藤原祐輔, 高橋幸奈, 立間徹
  • Journal Title: ChemPhysChem 10 Pages: 766-769
  • Peer Reviewed
• [Journal Article] Electrodeposition of gold nanoparticles on ITO: Control of morphology and plasmon resonance-based absorption and scattering (2009)
  • Author(s): N. Sakai
  • Journal Title: Journal of Electroanalytical Chemistry 628 Pages: 7-15
  • Peer Reviewed
• [Journal Article] Plasmon-Resonance-Based Generation of Cathodic Photocurrent at Electrodeposited Gold Nanoparticles Coated with TiO2 Films (2009)
  • Author(s): N. Sakai
  • Journal Title: ChemPhysChem 10 Pages: 766-769
  • Peer Reviewed
• [Journal Article] Visible Light-Induced Photocatalysts with Reductive Energy Storage Abilities (2008)
  • Author(s): 高橋幸奈, 立間徹
  • Journal Title: Electrochem. Commun 10 Pages: 1404-1407
  • Peer Reviewed
• [Journal Article] Morphologies and Surface Plasmon Resonance Properties of Monodisperse Bumpy Gold Nanoparticles (2008)
  • Author(s): 于克鋒, K. L. Kelly, 坂井伸行, 立間徹
  • Journal Title: Langmuir 24 Pages: 5849-5854
  • Peer Reviewed
• [Journal Article] Effects of Adsorbed Water on Plasmon-Based Dissolution, Redeposition and Resulting Spectral Changes of Ag Nanoparticles on Single-Crystalline TiO_2 (2008)
  • Author(s): 松原一喜, K. L. Kelly, 坂井伸行, 立間徹
  • Journal Title: Phys. Chem. Chem. Phys 10 Pages: 2263-2269
  • Peer Reviewed
• [Journal Article] Plasmon Resonance-Based Solid-State Photovoltaic Devices (2008)
  • Author(s): 于克鋒, 坂井伸行, 立間徹
  • Journal Title: Electrochemistry 76 Pages: 161-164
  • NAID: 10019916347
  • Peer Reviewed
• [Journal Article] Visible light-induced photocatalysts with reductive energy storage abilities (2008)
  • Author(s): Y. Takahashi
  • Journal Title: Electrochemistry Communications 10 Pages: 1404-1407
  • Peer Reviewed
• [Journal Article] Plasmon Resonance-Based Solid-State Photovoltaic Devices (2008)
  • Author(s): Kefeng Yu
  • Journal Title: Electrochemistry 76 Pages: 161-164
  • Peer Reviewed
• [Journal Article] Effects of Adsorbed Water on Plasmon-based Dissolution, Redeposition and Resulting Spectral Changes of Ag Nanoparticles on Single-crystalline TiO2 (2008)
  • Author(s): Kazuki Matsubara
  • Journal Title: Physical Chemistry Chemical Physics 16 Pages: 2263-2269
  • Peer Reviewed
• [Journal Article] Morphologies and Surface Plasmon Resonance Properties of Monodisperse Bumpy Gold Nanoparticles (2008)
  • Author(s): Kefeng Yu
  • Journal Title: Langmuir 24 Pages: 5849-5854
  • Peer Reviewed
• [Journal Article] Morphological Changes and Multicolor Photochromism of Ag Nanoparticles Deposited on Single-crystalline TiO_2 Surfaces (2007)
  • Author(s): 松原一喜, 立間徹
  • Journal Title: Adv. Mater 19 Pages: 2802-2806
  • Peer Reviewed
• [Journal Article] UV Light-Induced Swelling and Visible Light-Induced Shrinking of a TiO_2-Containing Redox Gel (2007)
  • Author(s): 立間徹, 高田主岳, 宮崎太地
  • Journal Title: Adv. Mater 19 Pages: 1249-1251
  • Peer Reviewed
• [Journal Article] Photoelectrochromic Cell with a Ag-TiO_2 Nanocomposite : Concepts of Drawing and Display Modes (2007)
  • Author(s): 立間徹, 鈴木健太郎
  • Journal Title: Electrochem. Commun 9 Pages: 574-576
  • Peer Reviewed
• [Journal Article] Photoelectrochromic Cell with a Ag-TiO_2 Nanocomposite : Concepts of Drawing and Display Modes (2007)
  • Author(s): T.Tatsuma
  • Journal Title: Electrochem. Commun. 9 Pages: 574-576
• [Journal Article] 高分子ゲルを用いた光電気化学アクチュエータ (2007)
  • Author(s): 立間 徹
  • Journal Title: 科学と工業 60 Pages: 440-443
  • NAID: 10018915777
• [Journal Article] Size Effects of Gold Nanoparticles on Plasmon-Induced Photocurrents of Gold-TiO_2 Nanocomposites (2006)
  • Author(s): 于克鋒, 田陽, 立間徹
  • Journal Title: Phys. Chem. Chem. Phys 8 Pages: 5417-5420
  • Peer Reviewed
• [Journal Article] Shape-Controlled Electrodeposition of Gold Nanostructures (2006)
  • Author(s): 田陽, H. Liu, G. Zhao, 立間徹
  • Journal Title: J. Phys. Chem. B 110 Pages: 23478-23481
  • Peer Reviewed
• [Journal Article] Size Effects of Gold Nanaoparticles on Plasmon-Induced Photocurrents of Gold-TiO_2 Nanocomposites (2006)
  • Author(s): K.Yu
  • Journal Title: Phys. Chem. Chem. Phys. 8 Pages: 5417-5420
• [Journal Article] Shape-Controlled Electrodeposition of Gold Nanostructures (2006)
  • Author(s): Y.Tian
  • Journal Title: J. Phys. Chem. B 110 Pages: 23478-23481
• [Journal Article] Electron Transport in Silver-Semiconductor Nanocomposite Films Exhibiting Multicolor Photochromism (2005)
  • Author(s): 川原敬祐, 鈴木健太郎, 大古善久, 立間徹
  • Journal Title: Phys. Chem. Chem. Phys 7 Pages: 3851-3855
  • Peer Reviewed
• [Journal Article] Visible-Light-Induced Patterning of Au-and Ag-TiO_2 Nanocomposite Film Surfaces on the Basis of Plasmon Photoelectrochemistry (2005)
  • Author(s): 田陽, 野津英男, 立間徹
  • Journal Title: Photochem. Photobiol. Sci 4 Pages: 598-601
  • Peer Reviewed
• [Journal Article] Mechanisms and applications of Plasmon-Induced Charge Seperation at TiO_2 Films Loaded with Gold Nanoparticles (2005)
  • Author(s): Y.Tian
  • Journal Title: J.Am.Chem.Soc. 127 Pages: 7632-7635
• [Journal Article] Visible-Light-Induced Patterning of Au- and Ag-TiO_2 Nanocomposite Film Surfaces on the Basis of Plasmon Photoelectrochemistry (2005)
  • Author(s): Y.Tian
  • Journal Title: Photochem.Photobiol.Sci. 4 Pages: 598-601
• [Journal Article] Electron Transport in silver Semiconductor Nanocomposite Films Exhibiting Multicolor Photochromism (2005)
  • Author(s): K.Kawahara
  • Journal Title: Phys.Chem.Chem.Phys. 7 Pages: 3851-3855
• [Journal Article] 金属ナノ粒子-半導体材料の光電変換・光触媒への応用 (2005)
  • Author(s): 立間 徹
  • Journal Title: 色材協会誌 78 Pages: 359-364
  • NAID: 10017462696
• [Journal Article] Plasmon Resonance-Based Photoelectrochemical Tailoring of Spectrum,Morphology and Orientation of Ag Nanoparticles on TiO_2 Single Crystals
  • Author(s): 松原一喜, K. L. Kelly, 坂井伸行, 立間徹
  • Journal Title: J.Mater. ChemMater. Chem (印刷中)
  • Peer Reviewed
• [Journal Article] Photocatalytic Growth and Plasmon Resonance-Assisted Photoelectrochemical Toppling of Upright Ag Nanoplates on a Nanoparticulate TiO_2 Film
  • Author(s): 田邉一郎, 松原一喜, S. D. Standridge, 数間恵弥子, K. L. Kelly, 坂井伸行, 立間徹
  • Journal Title: Chem. Commun (印刷中)
  • Peer Reviewed
• [Journal Article] Morphological Changes and Multicolor Photochromism of Ag Nanoparticles Deposited on Single-crystalline TiO_2 Surfaces
  • Author(s): K.Matsubara
  • Journal Title: Adv. Mater (印刷中)
• [Journal Article] UV Light-Induced Swelling and Visible Light-Induced Shrinking of a TiO_2-Containing Redox Gel
  • Author(s): T.Tatsuma
  • Journal Title: Adv. Mater (印刷中)
• [Presentation] 酸化チタン多孔膜上への銀ナノプレートの垂直成長とプラズモン共鳴に基づく光電気化学的挙動 (2009)
  • Author(s): 田邉一郎
  • Organizer: 電気化学76回大会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-31
• [Presentation] TiO_2 被覆電析Au ナノ粒子の光電気化学応答 (2009)
  • Author(s): 高橋幸奈
  • Organizer: 電気化学76回大会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-31
• [Presentation] TiO_2 単結晶上における異方性Ag ナノ粒子のプラズモン共鳴特性を利用した配向制御 (2009)
  • Author(s): 松原一喜
  • Organizer: 電気化学76回大会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-31
• [Presentation] ナノ構造界面に基づく光電気化学的エネルギー変換システムの構築 (2009)
  • Author(s): 立間徹
  • Organizer: 日本化学会第89春季年会
  • Place of Presentation: 船橋
  • Year and Date: 2009-03-27
• [Presentation] Photoelectrochemistry and Applications of Metal Nanoparticle-Semiconductor Composites (2008)
  • Author(s): 立間徹
  • Organizer: The 2nd Japan-Taiwan Joint Symposium on Organized Nanomaterials and Nanostructures Related to Photoscience
  • Place of Presentation: 京都
  • Year and Date: 2008-11-05
• [Presentation] Plasmon Resonance-Based Photocathodic Responses of Au Nanoparticles Coated with TiO_2 (2008)
  • Author(s): 高橋幸奈
  • Organizer: Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME) 2008
  • Place of Presentation: 米国
  • Year and Date: 2008-10-15
• [Presentation] Photoelectrochemical Control of Plasmon Resonance-Based Coloration and Morphologies of Ag Nanoparticles on TiO2 Single Crystals (2008)
  • Author(s): 松原一喜
  • Organizer: Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME) 2008
  • Place of Presentation: 米国
  • Year and Date: 2008-10-15
• [Presentation] Plasmon Resonance-Based Photoelectrochemical Properties of Size and Shape-Controlled Gold Nanoparticles on TiO_2 (2008)
  • Author(s): 坂井伸行
  • Organizer: Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME) 2008
  • Place of Presentation: 米国
  • Year and Date: 2008-10-14
• [Presentation] 酸化チタン光触媒の新しい展開 (2008)
  • Author(s): 立間徹
  • Organizer: 第102回触媒討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2008-09-25
• [Presentation] TiO_2 単結晶上へのAg ナノロッドの配向析出とプラズモン共鳴特性 (2008)
  • Author(s): 数間恵弥子
  • Organizer: 2008年光化学討論会
  • Place of Presentation: 堺
  • Year and Date: 2008-09-11
• [Presentation] ITO 上に電解析出させたAu ナノ粒子のプラズモン吸収に基づく電荷分離(2) (2008)
  • Author(s): 藤原祐輔
  • Organizer: 電気化学75回大会
  • Place of Presentation: 甲府
  • Year and Date: 2008-03-31
• [Presentation] 酸化チタン単結晶上における銀ナノ粒子の形態とプラズモン共鳴波長の光電気化学的制御 (2008)
  • Author(s): 松原一喜
  • Organizer: 電気化学75回大会
  • Place of Presentation: 甲府
  • Year and Date: 2008-03-31
• [Presentation] ナノ構造界面に基づく光電気化学的エネルギー変換システムの構築 (2008)
  • Author(s): 立間徹
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 東京
  • Year and Date: 2008-03-30
• [Presentation] ナノ構造界面に基づく光電気化学的エネルギー変換システムの構築 (2008)
  • Author(s): 立間徹
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学 池袋キャンパス
  • Year and Date: 2008-03-30
• [Presentation] 可視光照射で機能する還元エネルギー貯蔵型光触媒の可能性 (2007)
  • Author(s): 高橋幸奈
  • Organizer: 第14回シンポジウム光触媒反応の最近の展開
  • Place of Presentation: 川崎
  • Year and Date: 2007-11-04
• [Presentation] 酸化チタンで被覆した電析Auナノ粒子のプラズモン吸収に基づく電荷分離 (2007)
  • Author(s): 藤原祐輔
  • Organizer: 第14回シンポジウム光触媒反応の最近の展開
  • Place of Presentation: 川崎
  • Year and Date: 2007-11-04
• [Presentation] 光触媒含有ナノコンポジットゲルの光誘起膨潤および収縮(2) (2007)
  • Author(s): 今後徹
  • Organizer: 第14回シンポジウム光触媒反応の最近の展開
  • Place of Presentation: 川崎
  • Year and Date: 2007-11-04
• [Presentation] Correlated Analyses between Multicolor Photochromism and Morphological Changes of Ag Nanoparticles Photocatalytically Deposited on Single-crystalline TiO_2 Surfaces (2007)
  • Author(s): 松原一喜
  • Organizer: 212th ECS Meeting
  • Place of Presentation: 米国
  • Year and Date: 2007-10-08
• [Presentation] 金ナノ粒子のプラズモン共鳴を利用した光電変換の粒子形状依存性 (2007)
  • Author(s): 于克鋒
  • Organizer: 2007年光化学討論会
  • Place of Presentation: 松本
  • Year and Date: 2007-09-27
• [Presentation] ITO 上に電解析出させたAu ナノ粒子のプラズモン吸収に基づく電荷分離 (2007)
  • Author(s): 藤原祐輔
  • Organizer: 2007年光化学討論会
  • Place of Presentation: 松本
  • Year and Date: 2007-09-26
• [Presentation] 有機高分子ゲルを用いた電気化学および光電気化学アクチュエータ (2007)
  • Author(s): 立間徹
  • Organizer: 2007年電気化学秋季大会
  • Place of Presentation: 東京
  • Year and Date: 2007-09-20
• [Presentation] 電解析出による金ナノ粒子の形状制御と光学特性との相関 (2007)
  • Author(s): 藤原祐輔
  • Organizer: 2007年電気化学秋季大会
  • Place of Presentation: 東京
  • Year and Date: 2007-09-20
• [Presentation] 光触媒含有ナノコンポジットゲルの光誘起膨潤および収縮 (2007)
  • Author(s): 今後徹
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2007-09-20
• [Presentation] Au-TiO_2 光触媒を用いた可視光照射による還元エネルギー貯蔵の可能性 (2007)
  • Author(s): 高橋幸奈
  • Organizer: 2007年電気化学秋季大会
  • Place of Presentation: 東京
  • Year and Date: 2007-09-19
• [Presentation] 2007年電気化学秋季大会金属ナノ粒子-半導体複合系が示す光電気化学機能 (2007)
  • Author(s): 立間徹
  • Organizer: 第68回応用物理学会学術講演会
  • Place of Presentation: 札幌
  • Year and Date: 2007-09-05
• [Presentation] 酸化チタン単結晶上の銀ナノ粒子が示す多色フォトクロミズムと形態変化の相関 (2007)
  • Author(s): 松原一喜
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 吹田
  • Year and Date: 2007-03-25
• [Presentation] Size effects of gold nanoparticles on plasmon-induced photocurrents of gold-TiO_2 nanocomposites (2006)
  • Author(s): 于克鋒
  • Organizer: 第13回シンポジウム光触媒反応の最近の展開
  • Place of Presentation: 東京
  • Year and Date: 2006-12-13
• [Presentation] 酸化チタン単結晶上に光触媒析出させたAg ナノ粒子の多色フォトクロミズムに伴う形態変化(2) (2006)
  • Author(s): 松原一喜
  • Organizer: 第13回シンポジウム光触媒反応の最近の展開
  • Place of Presentation: 東京
  • Year and Date: 2006-12-13
• [Presentation] 金属-半導体ナノ複合材料のプラズモン共鳴に基づく光電気化学機能 (2006)
  • Author(s): 立間徹
  • Organizer: 第17回日本MRS学術シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2006-12-10
• [Presentation] プラズモン共鳴を利用した固体光電変換デバイスの開発 (2006)
  • Author(s): 于克鋒
  • Organizer: 2006年電気化学秋季大会
  • Place of Presentation: 京田辺
  • Year and Date: 2006-09-15
• [Presentation] TiO_2 単結晶に担持したAg ナノ粒子の多色フォトクロミズムに伴う形態変化 (2006)
  • Author(s): 松原一喜
  • Organizer: 2006年電気化学秋季大会
  • Place of Presentation: 京田辺
  • Year and Date: 2006-09-14
• [Presentation] 酸化チタン単結晶表面における銀ナノ粒子の析出と多色フォトクロミズム (2006)
  • Author(s): 立間徹
  • Organizer: 第59回コロイド及び界面化学討論会
  • Place of Presentation: 札幌
  • Year and Date: 2006-09-13
• [Presentation] プラズモンに基づく光電気化学材料・デバイス (2006)
  • Author(s): 立間徹
  • Organizer: 2006年光化学討論会
  • Place of Presentation: 仙台
  • Year and Date: 2006-09-11
• [Presentation] Ag ナノ粒子を担持したTiO_2単結晶における多色フォトクロミズムの解析 (2006)
  • Author(s): 松原一喜
  • Organizer: 電気化学会第73回大会
  • Place of Presentation: 東京
  • Year and Date: 2006-04-03
• [Presentation] 銀担持酸化チタン膜が示す多色フォトクロミック特性の制御 (2005)
  • Author(s): 鈴木健太郎
  • Organizer: 第12回シンポジウム光触媒反応の最近の展開
  • Place of Presentation: 東京
  • Year and Date: 2005-12-05
• [Presentation] 酸化チタン-銀ナノ粒子系におけるプラズモン光電気化学 (2005)
  • Author(s): 南高一
  • Organizer: 第12回シンポジウム光触媒反応の最近の展開
  • Place of Presentation: 東京
  • Year and Date: 2005-12-05
• [Presentation] 金及び銀ナノ粒子-半導体系のプラズモン光電気化学に基づくエネルギー変換 (2005)
  • Author(s): 立間徹
  • Organizer: 2005 年光化学討論会
  • Place of Presentation: 福岡
• [Presentation] 銀担持酸化チタン膜が示す多色フォトクロミック現象の発色特性の向上と着色速度の制御 (2005)
  • Author(s): 鈴木健太郎
  • Organizer: 2005年光化学討論会
  • Place of Presentation: 福岡
• [Book] Metal Nanoclusters in Catalysis and Materials Science : the Issue of Size Control"(13."Photocatalytic Deposition and Plasmon-Induced Dissolution of Metal Nanoparticles on TiO2) (2008)
  • Author(s): Tetsu Tatsuma
  • Total Pages: 5
  • Publisher: Elsevier B. V., Amsterdam
• [Book] 光触媒〜基礎・材料・応用〜",("1.2.5気相系光触媒反応の基礎","1.4.1光触媒による非接触反応","2,4.3エネルギー貯蔵型光触媒",""2.4.4銀/酸化チタン複合系光触媒の多色フォトクロミズム") (2005)
  • Author(s): 立間 徹
  • Total Pages: 24
  • Publisher: エヌ・ティー・エス
• [Book] 電子ペーバー実用化最前線",(1.5.1."フォトクロミズム") (2005)
  • Author(s): 立間 徹
  • Total Pages: 7
  • Publisher: エヌ・ティー・エス
• [Remarks]
  • URL: http://www.iis.u-tokyo.ac.jp/-tatsuma/