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Surfacede sign for highly efficient electrochemical detoxification of nitrate

Research Project

Project/Area Number 17350075
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionHokkaido University

Principal Investigator

SHIMAZU Katsuaki  Hokkaido University, Faculty of Environmental Earth Science, Professor (30109417)

Co-Investigator(Kenkyū-buntansha) YOSHINAGA Yusuke  Tokyo Gakugei University, 自然化学系, Associate Professor (60322848)
NAKATA Kou  Hokkaido University, Faculty of Environmental Earth Science, Assistant Professor (90250414)
Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥9,000,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2006: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 2005: ¥5,100,000 (Direct Cost: ¥5,100,000)
KeywordsNitrate nitrogen / Detoxification / Tin-modified noble metal electrodes / Adsorbed nitrate ion / Adsorbed NO / Metal nanoparticles / Cyclodextrin monolayer / Nanostructured surface / 電極触媒 / 赤外分光法 / ナノ構造 / シクロデキストリン / 金属ナノ粒子 / 金属ナノ粒子固定電極 / 硝酸イオン / 電気化学的 / イリジウム / ルテニウム / スズ / 表面界面物性 / 無害化
Research Abstract

1. Reduction of nitrate and nitrite ions was conducted on five kinds of tin-modified noble metal electrodes. The metal-dependences of electrocatalytic activity and the accessibility of the electrode to the selective N_2 production, which was calculated based on ratios of numbers of cleaved N-O bonds, formed N-N and N-H bonds to those required for the production of N_2, were determined. These results provide the important guide in designing highly active and high N_2-selective electrocatalysts.
2. Structure and reactivity of the adsorbed species formed from nitrate and nitrite ions, and NO were examined infrared spectroscopy. The following new and useful information about the reaction mechanism was obtained. (1) The adsorbed species from nitrate was unidentate nitrate. (2) The reduction rate of linear NO was faster than that of bridged NO. (3) Tin atoms used as the modification of Pd electrodes enhanced the reduction rate of the adsorbed NO.
3. Sn-noble metal binary metal electrodes were prepared by the successive adsorption of Sn^<2+> ion and Pt- or Pd-complexes on polycrystalline gold electrodes. Although the loading of noble metal was less than 0.3 g cm^<-2> because it was determined by the adsorption amount of the complexes at a monolayer level, these electrodes showed very high catalytic activity for nitrate reduction. Therefore, it is proved that this new method for reducing the loading of noble metal on the electrode is useful.
4. Multilayers of Sn/Pd/Au and Sn/Pt nanoparticles were constructed on self-assembled monolayers. The three-dimensional extension of reaction sites up to 2-3 layers was clarified. In addition, we develop the novel method of preparing nanostructured surface using cyclodextrin as a molecular template. The reduction of molecular oxygen was also accelerated on the nanostructured surface constructed using an atomic template. These results show that it is important to prepare electrocatalysts with the structure controlled at a molecular level.

Report

(4 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (97 results)

All 2008 2007 2006 2005

All Journal Article (12 results) (of which Peer Reviewed: 6 results) Presentation (85 results)

  • [Journal Article] Surface-Enhanced Infrared Absorption Spectroscopic Studies of Adsorbed Nitrate, Nitric Oxide, and Related Compounds 1: Reduction of Adsorbed NO on a Platinum Electrode2008

    • Author(s)
      K. Nakata, A. Okubo, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Journal Title

      Langmui 24

      Pages: 4352-4357

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Surface-Enhanced Infrared Absorption Spectroscopic Studies of Adsorbed Nitrate, Nitric Oxide, and Related Compounds 2: Nitrate Ion Adsorption at a Platinum Electrode2008

    • Author(s)
      K. Nakata, Y. Kayama, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Journal Title

      Langmui 24

      Pages: 4358-4563

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Surface-Enhanced Infrared Absorption Spectroscopic Studies of Adsorbed Nitrate, Nitric Oxide, and Related Compounds 1: Reduction of Adsorbed NO on a Platinum Electrode2008

    • Author(s)
      K. Nakata, A. Okubo, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Journal Title

      Langmuir 24

      Pages: 4352-4357

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Surface-Enhanced Infrared Absorption Spectroscopic Studies of Adsorbed Nitrate, Nitric Oxide, and Related Compounds 2: Nitrate Ion Adsorption at a Platinum Electrode2008

    • Author(s)
      K. Nakata, Y. Kayama, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Journal Title

      Langmuir 24

      Pages: 4358-4363

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Surface-Enhanced Infrared Absorption Spectroscopic Studies of Adsorbed Nitrate, Nitric Oxede, and Related Compounds 1: Reduction of Adsorbed NO on a Platinum Electrode.2008

    • Author(s)
      K. Nakata, A. Okubo, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Journal Title

      Langmuir 24

      Pages: 4352-4357

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface-Enhanced Infrared Absorption Spectroscopic Studies of Adsorbed Nitrate, Nitric Oxede, and Related Compounds 2: Nitrate Ion Adsorption at a Platinum Electrode.2008

    • Author(s)
      K. Nakata, Y. Kayama, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Journal Title

      Langmuir 24

      Pages: 4358-4363

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reduction nitrate ions on tin-modified palladium thin film electrodes2007

    • Author(s)
      K. Shimazu, R. Goto, S. Piao, Y. Kayama, K. Nakata, Y. Yoshinaga
    • Journal Title

      Journal of Electroanalytical Chemistry 601

      Pages: 161-168

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Reductionnitrate ions on tin-modified palladium thin film electrodes2007

    • Author(s)
      K. Shimazu, R. Goto, S. Piao, Y. Kayama, K. Nakata, Y. Yoshinaga
    • Journal Title

      J. Electroanal. Chem. 601

      Pages: 161-168

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Reduction of nitrate ions on tin-modified palladium thin film electrodes2007

    • Author(s)
      K.Shimazu, R.Goto, S.Piao, Y.Kayama, K.Nakata, Y.Yoshinaga
    • Journal Title

      Journal of Electroanalytical Chemistry 601

      Pages: 161-168

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 電気化学環境修復硝酸性窒素の電解還元除去2006

    • Author(s)
      嶋津克明, 中田 耕, 吉永裕介, 田口 哲
    • Journal Title

      電気化学 74

      Pages: 774-778

    • NAID

      10017534257

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Electrolytic reduction removal of nitric acid nitrogen2006

    • Author(s)
      K. Shimazu, K. Nakata, Y. Yoshinaga, S. Taguchi
    • Journal Title

      Electrochemistry 74

      Pages: 774-778

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 電気化学環境修復-硝酸性窒素の電解還元除去-2006

    • Author(s)
      嶋津克明, 中田耕, 吉永裕介, 田口哲
    • Journal Title

      電気化学 74

      Pages: 774-778

    • NAID

      10017534257

    • Related Report
      2006 Annual Research Report
  • [Presentation] 白金電極上に吸着した亜硝酸イオンおよびその酸化/還元化学種の表面増強赤外分光法による評価2008

    • Author(s)
      Rima Falhana Rafman・中田 耕・嶋津克明・山方 啓・叶 深・大澤雅俊
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-30
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] SEIRA characterization of adsorbed nitrite ion and its reduced/oxidized-species on Pt Electrodes2008

    • Author(s)
      F. R. Rima, K. Nakata, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Organizer
      75th Annual meeting of Electrochemical Society of Japan
    • Place of Presentation
      Yamanashi Univ.
    • Year and Date
      2008-03-30
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シクロデキストリン単分子層上での酸化還元反応に対する硫酸イオンの反応阻害効果2008

    • Author(s)
      道見康弘・嶋津克明
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] パラジウム電極上に吸着したNOの表面増強赤外分光法によるキャラクタリゼーション2008

    • Author(s)
      大久保彰訓・中田 耕・嶋津克明・山方 啓・叶 深・大澤雅俊
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学
    • Year and Date
      2008-03-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Inhibition effect of sulfate ion on redox reactions on thiolated cyclodextrin SAMs2008

    • Author(s)
      Y. Domi, K. Shimazu
    • Organizer
      75th Annual meeting of Electrochemical Society of Japan
    • Place of Presentation
      Yamanashi Univ.
    • Year and Date
      2008-03-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Characterization of Adsorbed NO on Pd Electrodes by Surface-Enhanced Infrared Spectroscopy2008

    • Author(s)
      A. Okubo, K. Nakata, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Organizer
      75th Annual meeting of Electrochemical Society of Japan
    • Place of Presentation
      Yamanashi Univ.
    • Year and Date
      2008-03-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] パラジウム電極上に吸着したNOの表面増強赤外分光法による評価2008

    • Author(s)
      大久保彰訓・中田 耕・嶋津克明・山方 啓・叶 深・大澤雅俊
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      2008-03-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Adsorbed NO on the Pd Electrodes Studied by Surface-Enhanced Infrared Spectroscopy2008

    • Author(s)
      A. Okubo, K. Nakata, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Organizer
      88th Spring meeting of Chemical Society of Japan
    • Place of Presentation
      Rikkyo Univ.
    • Year and Date
      2008-03-28
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Thiol-Derivatized β-Cyclodextrin Monolayers as Moleculer Templates and Reaction Sites2008

    • Author(s)
      K. Shimazu, Y Domi
    • Organizer
      International mini-symposium on "Control and analysis of reaction on electrode/solution interface with atomic/molecular resolution"
    • Place of Presentation
      北海道大学
    • Year and Date
      2008-03-10
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Thiol-Derivatized b-Cyclodextrin Monolayers as Moleculer Templates and Reaction Sites2008

    • Author(s)
      K. Shimazu, Y. Domi
    • Organizer
      International mini-symposium on "Control and analysis of reaction on electrode/solution Interface with atomic/molecular resolution"
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2008-03-10
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 炭素担持Sn/Pt電極による硝酸イオンの還元2008

    • Author(s)
      山木邦亮・中田 耕・嶋津克明
    • Organizer
      2008年三学協会北海道支部研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2008-01-30
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Reduction of nitrate on carbon supported Sn/Pt electrodes2008

    • Author(s)
      K. Yamaki, K. Nakata, K. Shimazu
    • Organizer
      2008 Annual meeting of three societies of Hokkaido branches
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2008-01-30
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 表面増強赤外分光法によるPd電極上のNOの吸着状態2008

    • Author(s)
      大久保彰訓・中田 耕・嶋津克明・山方 啓・叶 深・大澤雅俊
    • Organizer
      北海道支部2008年冬季研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2008-01-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] 金および白金ナノ粒子修飾電極のキャラクタリゼーション2008

    • Author(s)
      清水 遼・嶋津克明
    • Organizer
      北海道支部2008年冬季研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2008-01-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] ゲスト分子共存下でのシクロデキストリン単分子層へのPd析出2008

    • Author(s)
      道見康弘・嶋津克明
    • Organizer
      北海道支部2008年冬季研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2008-01-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] A dsorption state of NO on Pd electrodes studied by Surface-Enhanced Infrared Spectroscopy2008

    • Author(s)
      A. Okubo, K. Nakata, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Organizer
      2008 Winter meeting of Hokkaido branch
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2008-01-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Characterization of gold and platinum nanoparticle modified electrodes2008

    • Author(s)
      R. Shimizu, K. Shimazu
    • Organizer
      2008 Winter meeting of Hokkaido branch
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2008-01-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Palladium-deposition into the cavities of thiolated cyclodextrin SAMs in the presence of guest molecules2008

    • Author(s)
      Y. Domi, K. Shimazu
    • Organizer
      2008 Winter meeting of Hokkaido branch
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2008-01-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Sn修飾Pd電極における硝酸イオン及びNOの吸着状態評価-表面増強赤外分光法の検討-2007

    • Author(s)
      大久保彰訓・中田 耕・嶋津克明・山方 啓・叶 深・大澤雅俊
    • Organizer
      2007年電気化学会秋季大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-09-15
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] ゲスト分子共存下におけるシクロデキストリン単分子層への金属析出挙動のEQCMによる解析2007

    • Author(s)
      道見康弘・嶋津克明
    • Organizer
      2007年電気化学会秋季大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-09-15
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] SEIRA study on the adsorption states of nitrates and NO at Sn-modified Pd electrodes2007

    • Author(s)
      A. Okubo, K. Nakata, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Organizer
      2007 Autumn meeting of Electrochemical Society of Japan
    • Place of Presentation
      Tokyo Institute of Technology
    • Year and Date
      2007-09-15
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] EQCM study on metal deposition into the cavities of thiolated cyclodextrin SAMs in the presence of guest molecules2007

    • Author(s)
      Y. Domi, K. Shimazu
    • Organizer
      2007 Autumn meeting of Electrochemical Society of Japan
    • Place of Presentation
      Tokyo Institute of Technology
    • Year and Date
      2007-09-15
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] スズ修飾白金電極上に吸着した硝酸イオンおよびその還元化学種の表面増強赤外分光法によるキャラクタリゼーション2007

    • Author(s)
      中田 耕・大久保彰訓・嶋津克明・山方 啓・叶 深・大澤雅俊
    • Organizer
      2007年電気化学会秋季大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-09-14
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Characterization of Adsorbed Nitrate and its Reduction Species on Sn/Pt Electrodes by Surface-Enhanced Infrared Spectroscopy2007

    • Author(s)
      K. Nakata, A. Okubo, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Organizer
      2007 Autumn meeting of Electrochemical Society of Japan
    • Place of Presentation
      Tokyo Institute of Technology
    • Year and Date
      2007-09-14
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 表面増強赤外分光法によるPd電極上の窒素の酸化物及びオキソ酸の吸着状態2007

    • Author(s)
      大久保彰訓・中田 耕・嶋津克明・山方 啓・叶 深・大澤雅俊
    • Organizer
      日本化学会北海道支部夏季研究発表会
    • Place of Presentation
      旭川工業高等専門学校
    • Year and Date
      2007-07-21
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] SEIRA study of nitrogen oxides and oxoacids on Pd electrodes2007

    • Author(s)
      A. Okubo, K. Nakata, K. Shimazu, A. Yamakata, S. Ye, M. Osawa
    • Organizer
      2007 Summer meeting of Hokkaido branch
    • Place of Presentation
      Asahikawa college of Technology
    • Year and Date
      2007-07-21
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Palladium-deposition into the cavities of thiolated cyclodextrin molecules adsorbed on gold2007

    • Author(s)
      K. Shimazu, Y Domi
    • Organizer
      International Conference on Electrified Interfaces(ICEI)
    • Place of Presentation
      上川郡新得町北海道十勝サホロリゾート
    • Year and Date
      2007-06-25
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Palladium-deposition into the cavities of thiolated cyclodextrin molecules adsorbed on gold2007

    • Author(s)
      K. Shimazu, Y. Domi
    • Organizer
      International Conference on Electrified Interfaces (ICEI)
    • Place of Presentation
      Sahoro resort
    • Year and Date
      2007-06-25
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Palladium-deposition into the cavities of thiolated cyclodextrin molecules adsorbed on golg2007

    • Author(s)
      K. Shimazu, Y Domi
    • Organizer
      International Conference on Electrified Interfaces(ICEI)
    • Place of Presentation
      上川郡新得町北海道十勝サホロリゾート
    • Year and Date
      2007-06-25
    • Related Report
      2007 Annual Research Report
  • [Presentation] Reduction of nitrate ions on Sn/noble metal binary electrode2007

    • Author(s)
      K. Shimazu
    • Organizer
      Joint symposium on fundamental aspects of nanostructured materials and electrocatalysis
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-06-23
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] Reduction of nitrate ions on Sn/noble metalbinary electrode2007

    • Author(s)
      K. Shimazu
    • Organizer
      Joint symposium on fundamental aspects of nanostructured materials and electrocatalysis
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2007-06-23
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 多結晶白金電極上に吸着したNOの表面増強赤外分光法によるキャラクタリゼーション2007

    • Author(s)
      中田 耕・嶋津克明・山方 啓・大澤雅俊
    • Organizer
      北海道支部2007年冬季研究発表会
    • Place of Presentation
      東京理科大(野田)
    • Year and Date
      2007-03-30
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Characterization of Adsorbed NO Species on Pt Electrodes by Surface-Enhanced Infrared Spectroscopy2007

    • Author(s)
      K. Nakata, K. Shimazu, A. Yamakata, M. Osawa
    • Organizer
      74th Annual meeting of Electrochemical Society of Japan
    • Place of Presentation
      Tokyo Univ. of Science
    • Year and Date
      2007-03-30
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 白金電極上に吸着したNOの表面増強赤外分光法による評価2007

    • Author(s)
      中田 耕・嶋津克明・山方 啓・大澤雅俊
    • Organizer
      日本化学会第87春季年会
    • Place of Presentation
      関西大学
    • Year and Date
      2007-03-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Adsorbed NO on Pt Electrode Studied by Surface-Enhanced Infrared Spectroscopy2007

    • Author(s)
      K. Nakata, K. Shimazu, A. Yamakata, M. Osawa
    • Organizer
      87th Spring meeting of Chemical Society of Japan
    • Place of Presentation
      Kansai Univ.
    • Year and Date
      2007-03-27
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 金単結晶電極上でのメルカプトシラン自己組織化単分子膜の構築と評価2007

    • Author(s)
      斎藤拓也・嶋津克明
    • Organizer
      北海道支部2007年冬季研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-02-07
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シクロデキストリン単分子層への金属析出挙動のQCMによる解析2007

    • Author(s)
      道見康弘・嶋津克明
    • Organizer
      北海道支部2007年冬季研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-02-07
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Preparation and evaluation of mercaptosilane self-assembled monolayer on Au single crystal electrodes2007

    • Author(s)
      T. Saito, K. Shuimazu
    • Organizer
      2007 Winter meeting of Hokkaido branch
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2007-02-07
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] QCM study of metal deposition into the cavities in thiolated cyclodextrin SAMs2007

    • Author(s)
      Y. Domi, K. Shimazu
    • Organizer
      2007 Winter meeting of Hokkaido branch
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2007-02-07
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 白金電極上におけるNO_3^-およびNO吸着の表面増強赤外分光法による評価2007

    • Author(s)
      中田 耕・嶋津克明・山方 啓・大澤雅俊
    • Organizer
      2007年三学協会北海道支部研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-02-06
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] ジチオール自己組織化単分子層の構築と電気化学的キャラクタリゼーション2007

    • Author(s)
      野添裕右、嶋津克明
    • Organizer
      2007年三学協会北海道支部研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-02-06
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] イオンの逐次吸着によるPt-SnおよびPd-Snニ成分金属電極の調製と硝酸イオンの還元2007

    • Author(s)
      中村喜重・中田 耕・嶋津克明
    • Organizer
      北海道支部2007年冬季研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2007-02-06
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Surface-Enhanced Infrared Spectroscopic Study of Adsorbed NO_3 and NO on Pt Electrode2007

    • Author(s)
      K. Nakata, K. Shimazu, A. Yamakata, M. Osawa
    • Organizer
      2007 Annual meeting of three societies of Hokkaido branches
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2007-02-06
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Preparation and characterization of dithiol self-assembled monolayers2007

    • Author(s)
      Y. Nozoe, K. Shimazu
    • Organizer
      2007 Annual meeting of three societies of Hokkaido branches
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2007-02-06
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Preparation of Pt-Sn and Pd-Sn electrodes by stepwise adsorption method and reduction of nitrate2007

    • Author(s)
      N. Nakamura, K. Nakata, K. Shimazu
    • Organizer
      2007 Winter meeting of Hokkaido branch
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2007-02-06
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 逐次吸着による貴金属/スズ電極の調製と硝酸イオンの還元2006

    • Author(s)
      中村喜重・中田 耕・嶋津克明
    • Organizer
      2006年電気化学会秋季大会
    • Place of Presentation
      同志社大学
    • Year and Date
      2006-09-15
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Preparation of noble metal/Sn/Au electrodes by successive adsorption of precursor ionic species and electrochemical reduction of nitrate ion2006

    • Author(s)
      N. Nakamura, K. Nakata, K. Shimaz
    • Organizer
      2006 Autumn meeting of Electrochemical Society of Japan
    • Place of Presentation
      Doshisha Univ.
    • Year and Date
      2006-09-15
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シクロデキストリン単分子層の空隙への金属析出2006

    • Author(s)
      道見康弘・嶋津克明
    • Organizer
      2006年電気化学会秋季大会
    • Place of Presentation
      同志社大学
    • Year and Date
      2006-09-14
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metal deposition into the cavities in thiolated cyclodextrin SAMs2006

    • Author(s)
      Y. Domi, K. Shimazu
    • Organizer
      2006 Autumn meeting of Electrochemical Society of Japan
    • Place of Presentation
      Doshisha Univ.
    • Year and Date
      2006-09-14
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シクロデキストリン自己組織化単分子層の包接能評価2006

    • Author(s)
      道見康弘・嶋津克明
    • Organizer
      第59回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2006-09-13
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Evaluation of inclusion capability of thiolated cyclodextrin self-assembled monolayers2006

    • Author(s)
      Y. Domi, K. Shimazu
    • Organizer
      59th Annual meeting of colloid and surface chemistry
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2006-09-13
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Evaluation of Packing State of Thiolated Cyclodextrin Self-Assembled Monolayers and Electrodeposition of Metal into the Cavities2006

    • Author(s)
      Y. Domi, K. Shimazu
    • Organizer
      Hokkaido University International Symposium on Sustainable Development
    • Place of Presentation
      北海道大学
    • Year and Date
      2006-08-08
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Evaluation of Packing State of Thiolated Cyclodextrin Self-Assembled Monolayers and Electrodeposition of Metal into the Cavities2006

    • Author(s)
      Y. Domi, K. Shimazu
    • Organizer
      Hokkaido University International Symposium on Sustainable Development
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2006-08-08
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Evaluation of the inclusion property of ferrocene in cyclodextrin SAMs2006

    • Author(s)
      Y. Domi, Y. Yoshinaga, K. Shimazu
    • Organizer
      2006 Summer meeting of Hokkaido branch
    • Place of Presentation
      Muroran Institute of Technology
    • Year and Date
      2006-07-24
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シクロデキストリン自己組織化単分子層におけるフェロセンの包接特性評価2006

    • Author(s)
      道見康弘・吉永裕介・嶋津克明
    • Organizer
      北海道支部2006年夏季研究発表会
    • Place of Presentation
      室蘭工業大学
    • Year and Date
      2006-07-23
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シクロデキストリン単分子層のパッキング状態と包接特性評価2006

    • Author(s)
      道見康弘・嶋津克明
    • Organizer
      第23回ライラックセミナー第12回若手研究者交流会
    • Place of Presentation
      有珠郡大滝村大滝セミナーハウス
    • Year and Date
      2006-06-17
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Evaluation of the packing state and the inclusion property of cyclodextrin SAMs2006

    • Author(s)
      Y. Domi, K. Shimazu
    • Organizer
      23th Lilac seminar
    • Place of Presentation
      Otaki seminar house
    • Year and Date
      2006-06-17
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 硝酸イオンの還元に対するスズールテニウムニ元金属の電極触媒特性2006

    • Author(s)
      中野悠哉・中田 耕・吉永裕介・嶋津克明
    • Organizer
      電気化学会第73回大会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2006-04-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 金単結晶電極上でのメルカプトシラン自己組織化単分子膜の構築とキャラクタリゼーション2006

    • Author(s)
      斎藤拓也・吉永裕介・嶋津克明
    • Organizer
      電気化学会第73回大会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2006-04-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シクロデキストリン自己組織化単分子層における空隙量評価2006

    • Author(s)
      道見康弘・吉永裕介・嶋津克明
    • Organizer
      電気化学会第73回大会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2006-04-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Reduction of nitrate on Sn-Ru bimetallic electrodes2006

    • Author(s)
      Y. Nakano, K. Nakata, Y. Yoshinaga, K. Shimaz
    • Organizer
      73th Annual meeting of Electrochemical Society of Japan
    • Place of Presentation
      Tokyo Metropolitan Univ.
    • Year and Date
      2006-04-01
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Preparation and characterization of mercaptosilane self-assembled monolayer on Au single crystal electrodes2006

    • Author(s)
      T. Saito, Y. Yoshinaga, K. Shuimazu
    • Organizer
      73th Annual meeting of Electrochemical Society of Japan
    • Place of Presentation
      Tokyo Metropolitan Univ.
    • Year and Date
      2006-04-01
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Evaluation of the packing state of thiolated cyclodextrin SAMs2006

    • Author(s)
      Y. Domi, Y. Yoshinaga, K. Shimazu
    • Organizer
      73th Annual meeting of Electrochemical Society of Japan
    • Place of Presentation
      Tokyo Metropolitan Univ.
    • Year and Date
      2006-04-01
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Au(111)上でのメルカプトシラン自己組織化単分子膜の構築とキャラクタリゼーション2006

    • Author(s)
      斎藤拓也・吉永裕介・嶋津克明
    • Organizer
      日本化学会第86春季年会
    • Place of Presentation
      日大理工
    • Year and Date
      2006-03-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Preparation and characterization of mercaptosilane self-assembled monolayer on Au (111)2006

    • Author(s)
      T. Saito, Y. Yoshinaga, K. Shuimazu
    • Organizer
      86th Spring meeting of Chemical Society of Japan
    • Place of Presentation
      Nihon Univ.
    • Year and Date
      2006-03-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] スズ修飾イリジウム電極を用いた電気化学的還元による硝酸イオンの除去2006

    • Author(s)
      中田 耕・香山陽太・吉永裕介・嶋津克明
    • Organizer
      日本化学会第86春季年会
    • Place of Presentation
      日大理工
    • Year and Date
      2006-03-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Removal of nitrate by electrochemical reduction using Sn modified Ir electrode2006

    • Author(s)
      K. Nakata, Y. Kayama, Y. Yoshinaga, K. Shuimazu
    • Organizer
      86th Spring meeting of Chemical Society of Japan
    • Place of Presentation
      Nihon Univ.
    • Year and Date
      2006-03-28
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Sn修飾Ir電極のキャラクタリゼーションと硝酸イオンの還元2006

    • Author(s)
      香山陽太・中田 耕・吉永裕介・嶋津克明
    • Organizer
      2006年三学協会北海道支部研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2006-01-31
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 白金およびスズ修飾白金電極による硝酸イオン還元の電極吸着化学種の表面 増強赤外分光法による検討2006

    • Author(s)
      中田 耕・香山陽太・嶋津克明・山方 啓・大澤雅俊
    • Organizer
      北海道支部2006年冬季研究発表会
    • Place of Presentation
      北海道大学
    • Year and Date
      2006-01-31
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Characterization of tin modified Ir electrodes and reduction of nitrate2006

    • Author(s)
      Y. Kayama, K. Nakata, Y. Yoshinaga, K. Shuimazu
    • Organizer
      2006 Annual meeting of three societies of Hokkaido branches
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2006-01-31
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Surface-Enhanced Infrared Spectroscopic Study of Adsorbed Species on Pt and Sn/Pt Electrode in Nitrate Reduction2006

    • Author(s)
      K. Nakata, Y. Kayama, K. Shimazu, A. Yamakata, M. Osawa
    • Organizer
      2006 Winter meeting of Hokkaido branch
    • Place of Presentation
      Hokkaido Univ.
    • Year and Date
      2006-01-31
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] スズ修飾白金電極上の硝酸イオン還元における吸着化学種の表面増強赤外分光法による検討2005

    • Author(s)
      中田 耕・香山陽太・嶋津克明・山方 啓・大澤雅俊
    • Organizer
      2005年電気化学会秋季大会
    • Place of Presentation
      千葉大学
    • Year and Date
      2005-09-09
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Adsorbed Species on Sn/Pt Electrode in Nitrate Reduction Studied by Surface-Enhanced Infrared Spectroscopy2005

    • Author(s)
      K. Nakata, Y. Kayama, K. Shimazu, A. Yamakata, M. Osawa
    • Organizer
      2005 Autumn meeting of Electrochemical Society of Japan
    • Place of Presentation
      Chiba Univ.
    • Year and Date
      2005-09-09
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Sn修飾Ir電極上における硝酸イオンの還元-生成物分布の電位および組成依存性2005

    • Author(s)
      香山陽太・中田 耕・吉永裕介・嶋津克明
    • Organizer
      2005年電気化学会秋季大会
    • Place of Presentation
      千葉大学
    • Year and Date
      2005-09-08
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 白金電極上におけるの硝酸イオン吸着の表面増強赤外分光法による評価2005

    • Author(s)
      中田 耕・香山陽太・嶋津克明・山方 啓・大澤雅俊
    • Organizer
      2005年電気化学会秋季大会
    • Place of Presentation
      千葉大学
    • Year and Date
      2005-09-08
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] チオール化シクロデキストリンSAMの構築とキャラクタリゼーション2005

    • Author(s)
      道見康弘・吉永裕介・嶋津克明
    • Organizer
      2005年電気化学会秋季大会
    • Place of Presentation
      千葉大学
    • Year and Date
      2005-09-08
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Reduction of nitrate ions over Sn-modified Ir electrode -Potential and Composition dependence of reduction products-2005

    • Author(s)
      Y. Kayama, Y. Yoshinaga, K. Nakata, K. Shuimazu
    • Organizer
      2005 Autumn meeting of Electrochemical Society of Japan
    • Place of Presentation
      Chiba Univ.
    • Year and Date
      2005-09-08
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Adsorbed Nitrate on Pt Electrode Studied by Surface-Enhanced Infrared Spectroscopy2005

    • Author(s)
      K. Nakata, Y. Kayama, K. Shimazu, A. Yamakata, M. Osawa
    • Organizer
      2005 Autumn meeting of Electrochemical Society of Japan
    • Place of Presentation
      Chiba Univ.
    • Year and Date
      2005-09-08
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Construction and characterization of thiolated cyclodextrin SAMs2005

    • Author(s)
      Y. Domi, Y. Yoshinaga, K. Shimazu
    • Organizer
      2005 Autumn meeting of Electrochemical Society of Japan
    • Place of Presentation
      Chiba Univ.
    • Year and Date
      2005-09-08
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Sn/Ir電極上での硝酸イオンの還元2005

    • Author(s)
      香山陽太・吉永裕介・中田 耕・嶋津克明
    • Organizer
      北海道支部2005年夏季研究発表会
    • Place of Presentation
      函館未来大学
    • Year and Date
      2005-07-24
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Reduction of nitrate ion on Sn/Ir electrodes2005

    • Author(s)
      Y. Kayama, Y. Yoshinaga, K. Nakata, K. Shuimazu
    • Organizer
      2005 Summer meeting of Hokkaido branch Future Univ.
    • Place of Presentation
      Hakodate
    • Year and Date
      2005-07-24
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] スズ修飾イリジウム電極上における硝酸イオンの還元2005

    • Author(s)
      香山陽太・吉永裕介・中田 耕・嶋津克明
    • Organizer
      電気化学会第72回大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2005-04-03
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Reduction of nitrate ions over Sn-modified Ir electrode2005

    • Author(s)
      Y. Kayama, Y. Yoshinaga, K. Nakata, K. Shuimazu
    • Organizer
      72th Annual meeting of Electrochemical Society of Japan
    • Place of Presentation
      Kumamoto Univ.
    • Year and Date
      2005-04-03
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] イオン逐次吸着によるPd/Sn/多結晶Au電極の調製と硝酸イオンの電解還元除去2005

    • Author(s)
      道見康弘・吉永裕介・中田 耕・嶋津克明
    • Organizer
      電気化学会第72回大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2005-04-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Preparation of Pd/Sn/Polycrystalline Au electrodes by successive adsorption of precursor ionic species and electrochemical reduction of nitrate ions2005

    • Author(s)
      Y. Domi, Y. Yoshinaga, K. Nakata, K. Shuimazu
    • Organizer
      72th Annual meeting of Electrochemical Society of Japan
    • Place of Presentation
      Kumamoto Univ.
    • Year and Date
      2005-04-01
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2005-04-01   Modified: 2016-04-21  

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