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Synthesis of Novel Nanocarbon Materials(PPhS) and its Application to High Power Li-Ion Battery and Capacitor

Research Project

Project/Area Number 17350094
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionNagasaki Institute of Applied Science

Principal Investigator

YAMABE Tokio  Nagasaki Institute of Applied Science, Professor, 工学部, 教授 (80025965)

Co-Investigator(Kenkyū-buntansha) YOSHINO Katsumi  Nagasaki Institute of Applied Science, Professor, 工学部, 教授 (70029205)
FURUYA Yoshio  Nagasaki University, Professor, 教育学部, 教授 (70181469)
ISHIKAWA Shigeru  Tokai University, Associnte professor, 理学部, 准教授 (90256660)
YAMABE Toshio  Research Institute for Production Development, Senior research Scientist, 環境科学研究部, 主任研究員 (80399344)
KAWAUCHI Susumu  Tokyo Institute of Technology, Associate Professor, 大学院理工学研究科, 准教授 (80204676)
藤井 光廣  長崎総合科学大学, 工学部, 教授 (90086455)
加藤 貴  長崎総合科学大学, 新技術創成研究所, 助手 (10399214)
Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥15,400,000 (Direct Cost: ¥15,400,000)
Fiscal Year 2006: ¥5,100,000 (Direct Cost: ¥5,100,000)
Fiscal Year 2005: ¥10,300,000 (Direct Cost: ¥10,300,000)
KeywordsLi ion battery / Novel high power capacitor / Hydrogen-storage / Fuel cell / Novel nanocarbon / ナノカーボン / ハイドログラフェン / ポリフェン系有機半導体 / 水素吸蔵
Research Abstract

The novel nanocarbon, polyphonic organic semiconductor (PPhS) was prepared from xylene resin under relatively low pyrolitic temperature (550℃-750℃). It contains some hydrogen atoms (0.39-0.24 H/C molar ratio) and even small amount of oxygen atoms (0.05-0.08 O/C molar ratio). The materials are amouphous and very porous, mainly in micropores. The charge-discharge characteristic in the electric cell is 1040 mAh/g and 680 mAh/g for Li+/Li standard, respectively, when the materials are used in the negative electrode. It is available for high power capacitance and also effective carbonaceous materials to reduce largely the amount of Pt in the full cell.

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (34 results)

All 2007 2006 2005 Other

All Journal Article (23 results) Book (6 results) Patent(Industrial Property Rights) (5 results)

  • [Journal Article] 新規ハイドログラフェンPPhSの作製とリチウムイオンニ次電池への応用2007

    • Author(s)
      藤井, 矢田, 山邊
    • Journal Title

      長崎総合科学大学新技術創成研究所 所報 第2号

      Pages: 41-47

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 固体高分子燃料電池(PEFC)のドット状および新規ナノカーボンを用いた多孔質触媒層形成による触媒量低減に関する研究2007

    • Author(s)
      奥村, 阿南, 藤井, 杉田, 山邊
    • Journal Title

      長崎総合科学大学新技術創成研究所 所報 第2号

      Pages: 33-39

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Electron-Phonon Interactions and Intra- and Intermolecular Charge Mobility in the Monocations of Annulenes2007

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      Journal of Physical Chemistry B 110

      Pages: 18166-18179

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Chemically Fixed Nurse Cells for Culturing Murine or Primate Embryonic Stem Cells2007

    • Author(s)
      T.Yamabe, et al.
    • Journal Title

      Journal of Bioscience and Bioengineering 103

      Pages: 113-121

    • NAID

      110006239218

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] 新規ハイドログラフェンPPhSの作製とリチウムイオン二次電池への応用2007

    • Author(s)
      藤井, 矢田, 山邊
    • Journal Title

      長崎総合科学大学新技術創成研究所 所報 第2号

      Pages: 41-47

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electron-Phonon Interactions and Intra-and Intermolecular Charge Mobility in the Monocations of Annulenes2007

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      Journal of Physical Chemistry B 110

      Pages: 18166-18179

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Electron-molecular-vibration interactions and charge transfer in negatively charged chloroacenes2006

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      Chem. Phys. 321

      Pages: 149-158

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Pore size dependence of field emission from nanoscale porous carbon2006

    • Author(s)
      M.Ojima, S.Hiwatashi, H.Araki, A.Fujii, M.Ozaki, K.Yoshino
    • Journal Title

      Appl. Phys. Lett. 88

      Pages: 53103-53103

    • NAID

      120006840953

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Improvement of Sensitivity in Long-Wavelengths Range in Organic Thin-Film Solar Cell with Interpenetrating Semilayered Structure2006

    • Author(s)
      T.Umeda, Y.Hashimoto, H.Mizukami, H.Noda, A.Fujii, M.Ozaki, K.Yoshino
    • Journal Title

      Jpn. J. Appl. Phys. 45

      Pages: 538-541

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 固体高分子燃料電池のドット触媒層形成に関する研究2006

    • Author(s)
      阿南悠太, 奥村典男, 杉田勝, 山邊時雄
    • Journal Title

      長崎総合科学大学工学研究センター所報、第20号 3月

      Pages: 1-8

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Preparation and Properties of Nano-scale Periodic Porous Carbon as Electrode Material2006

    • Author(s)
      K.Yoshino, H.Take
    • Journal Title

      Journal of the Society of Electrical Materials Engineering 15

      Pages: 13-22

    • NAID

      120006881690

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Pore Size Dependence of Field Emission from Nanoscale Porous Carbon2006

    • Author(s)
      K.Yoshino, et al.
    • Journal Title

      Applied Physics Letters 88

    • NAID

      120006840953

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Electron-molecular-vibration interactions and charge transfer in negatively charged chloroacenes2006

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      Chem.Phys. 321

      Pages: 149-158

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Pore size dependence of field emission from nanoscale porous carbon2006

    • Author(s)
      M.Ojima, S.Hiwatashi, H.Araki, A.Fujii, M.Ozaki, K.Yoshino
    • Journal Title

      Appl.Phys.Lett. 88

      Pages: 53103-53103

    • NAID

      120006840953

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Improvement of Sensitivity in Long-Wavelengths Range in Organic Thin-Film Solar Cell with Interpenetrating Semilayered Structure2006

    • Author(s)
      T.Umeda, Y.Hashimoto, H.Mizukami, H.Noda, A.Fujii, M.Ozaki, K.Yoshino
    • Journal Title

      Jpn.J.Appl.Phys. 45

      Pages: 538-541

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Electron-phonon interactions in photoinduced excited electronic states in fluoroacenes2005

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      J. Chem. Phys. 123

      Pages: 24301-24301

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Vibronic interactions and possible electron pairing in positively charged cyanodienes2005

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      J. Chem. Phys. 123

      Pages: 94701-94701

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] The essential role of the electronegativity perturbation in the electron-phonon interactions in positively charged B, N-substituted acenes2005

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      Chem. Phys. 315

      Pages: 97-108

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] The effects of H-F and H-D substitutions on Jahn-Teller effects and charge transfer in the monocations of B, N-substituted acenes2005

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      Chem. Phys. 315

      Pages: 109-120

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] electron-phonon interactions in photoinduced excited electronic states in fluoroacenes2005

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      J.Chem.Phys. 123

      Pages: 24301-24301

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Vibronic interactions and possible electron pairing in positively charged cyanodienes2005

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      J.Chem.Phys. 123

      Pages: 94701-94701

    • Related Report
      2005 Annual Research Report
  • [Journal Article] The Essential role of the electronegativity perturbation in the electron-phonon interactions in positively charged B, N-substituted acenes2005

    • Author(s)
      T.Kato, T.Yamabe
    • Journal Title

      Chem.Phys. 315

      Pages: 97-108

    • Related Report
      2005 Annual Research Report
  • [Journal Article] The effects of H-F and H-D substitutions on Jahn-Teller effects and charge transfer in the monocations of B, N-substituted acenes2005

    • Author(s)
      T.Kato, T.amabe
    • Journal Title

      Chem.Phys. 315

      Pages: 109-120

    • Related Report
      2005 Annual Research Report
  • [Book] Photochemistry and its Nanoelectronics Applications2006

    • Author(s)
      T.Kato (ed.)
    • Publisher
      Transwork Research Network, Kerada, India
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] Photochemistry and its Nanoelectronics Applications2006

    • Author(s)
      T.Kato(ed.)
    • Total Pages
      139
    • Publisher
      Transwork Research Network, Kerada, India
    • Related Report
      2006 Annual Research Report
  • [Book] Photochemistry and Photobiology 第1章Vibronic interactions in the photoinduced excited electronic states in a molecule : Application to the investigation of photoelectron spectroscopy(edited by Takashi Kato)

    • Author(s)
      T.Kato, T.Yamabe
    • Total Pages
      40
    • Publisher
      TRANSWORLD RESEARCH NETWORK, Kerala(印刷中)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] Photochemistry and Photobiology 第2章Vibronic interactions in the photoinduced excited electronic states in a molecule : Application to the investigation of absorption spectroscopy(edited by Takashi Kato)

    • Author(s)
      T.Kato, T.Yamabe
    • Total Pages
      20
    • Publisher
      TRANSWORLD RESEARCH NETWORK, Kerala(印刷中)
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Book] Photochemistry and Photobiology(edited by Takashi Kato)第1章Vibronic interactions in the photoinduced excited electronic states in a molecule : Application to the investigation of photoelectron spectroscopy

    • Author(s)
      T.Kato, T.Yamabe
    • Total Pages
      40
    • Publisher
      TRANSWORLD RESEARCH NETWORK, Kerala(印刷中)
    • Related Report
      2005 Annual Research Report
  • [Book] Photochemistry and Photobiology(edited by Takashi Kato)第2章Vibronic interactions in the photoinduced excited electronic states in a molecule : Application to the investigation of absorption spectroscopy

    • Author(s)
      T.Kato, T.Yamabe
    • Total Pages
      20
    • Publisher
      TRANSWORLD RESEARCH NETWORK, Kerala(印刷中)
    • Related Report
      2005 Annual Research Report
  • [Patent(Industrial Property Rights)] 電池構成材料2006

    • Inventor(s)
      藤井, 杉田, 山邊
    • Industrial Property Rights Holder
      長崎総合科学大学
    • Industrial Property Number
      2006-274478
    • Filing Date
      2006-09-08
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 燃料電池用触媒電極および燃料電池用触媒電極の製造方法2005

    • Inventor(s)
      奥村典男, 阿南悠太, 杉田勝, 山邊時雄
    • Industrial Property Rights Holder
      奥村典男
    • Filing Date
      2005-06-13
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 燃料電池用触媒担持方法および燃料電池2005

    • Inventor(s)
      奥村典男, 阿南悠太, 杉田勝, 山邊時雄
    • Industrial Property Rights Holder
      奥村典男
    • Filing Date
      2005-12-02
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 燃料電池用触媒電極および燃料電池用触媒電極の製造方法2005

    • Inventor(s)
      奥村 典男, 阿南 悠太, 杉田 勝, 山邊 時雄
    • Industrial Property Rights Holder
      奥村 典男
    • Filing Date
      2005-06-13
    • Related Report
      2005 Annual Research Report
  • [Patent(Industrial Property Rights)] 燃料電池用触媒担持方法および燃料電池2005

    • Inventor(s)
      奥村 典男, 阿南 悠太, 杉田 勝, 山邊 時雄
    • Industrial Property Rights Holder
      奥村 典男
    • Filing Date
      2005-12-02
    • Related Report
      2005 Annual Research Report

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Published: 2005-04-01   Modified: 2016-04-21  

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