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Study of Electrochemical Hydrogen Separation Pump using Polymer Electrolyte Membrane

Research Project

Project/Area Number 17360125
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 電力工学・電気機器工学
Research InstitutionToyohashi University of Technology

Principal Investigator

ONDA Kazuo  Toyohashi Univ.Tech., Faculty of Eng., Professor, 大学院工学研究科, 教授 (50281077)

Co-Investigator(Kenkyū-buntansha) 荒木 拓人  豊橋技術科学大学, 大学院工学研究科, 助手 (90378258)
Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥10,800,000 (Direct Cost: ¥10,800,000)
Fiscal Year 2006: ¥5,000,000 (Direct Cost: ¥5,000,000)
Fiscal Year 2005: ¥5,800,000 (Direct Cost: ¥5,800,000)
KeywordsHydrogen pump / Polymer electrolyte membrane / isothermal compression / Hydrogen separation and recirculation / 水素分離 / 水素圧縮 / 濃淡電池 / 水素分離・圧縮の特性解析
Research Abstract

The basic separation and compression characteristics were measured for an electrochemical hydrogen pump that can selectively separate and compress hydrogen. The current distribution along the flow direction calculated by our simulation code of hydrogen pump agreed well to the measured current distribution by a segmented electrode cell, except when H_2 concentration is low and H_2 transport rate is high. We could thus confirm the basic operation of hydrogen pump. In the separation pump operated under atmospheric pressure down to H_2 concentration of 1% and the compression pump up to cathode pressure of 1 MPa, the open-circuit voltage agreed well with the Nernst potential. almost 100% of supplied H2 could be separated and compressed with a cell voltage of 0.06-0.15 V and current efficiency near 100%. Moreover, the anode exhausted gas contains no more than 50ppm of Hydrogen. In the H_2 compression test with the pressure ratio of 10 and the current density of 0.1A cm^<-2>, the compressor power considering overpotential loss was equal to an adiabatic compression power with 100% adiabatic efficiency. In the future we would like to clarify further the characteristics of electrochemical hydrogen pumps for low H_2 concentration and high H2 transport rate.

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (13 results)

All 2007 2006 2005 Other

All Journal Article (13 results)

  • [Journal Article] Separation and Compression Characteristics of Hydrogen by Use of Proton Exchange Membrane2007

    • Author(s)
      Kazuo Onda, Keiji Ichihara, Mitsuyuki Nagahama, Yasuo Minamoto, Takuto Araki
    • Journal Title

      Journal of Power Sources 164-1

      Pages: 1-8

    • NAID

      110006342852

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Separation and Compression Characteristics of Hydrogen by Use of Proton Exchange Membrane2007

    • Author(s)
      Kazuo Onda, Keiji Ichihara, Mitsuyuki Nagahama, Yasuo Minamoto, Takuto Araki
    • Journal Title

      Journal of Power Sources Vol 164, No.1

      Pages: 1-8

    • NAID

      110006342852

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 固体高分子膜による水素の分離・圧縮特性に関する基礎研究2006

    • Author(s)
      池田孝伸, 市原敬士, 砂川大輔, 服部紀公士, 荒木拓人, 恩田和夫, 五十嵐基仁, 本吉智行
    • Journal Title

      電気学会論文誌B 126

      Pages: 926-932

    • NAID

      10019289842

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Basic Study on Hydrogen separation and Compression Characteristics by Polymer electrolyte Membrane2006

    • Author(s)
      T.Ikeda, K.Ichihara, D.Sunakawa, K.Hattori, T.Araki, K.Onda, M.Igarashi, T.Motoyoshi
    • Journal Title

      IEEJ Transactions on Power and Energy Vol.126, No.9

    • NAID

      10019289842

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 固体高分子膜による低濃度水素の分離特性の研究2006

    • Author(s)
      池田, 砂川, 市原, 大山, 荒木, 恩田
    • Journal Title

      平成18年度電気学会全国大会 (発表予定)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 固体高分子膜による水素ポンプの昇圧特性2006

    • Author(s)
      市原, 池田, 荒木, 恩田
    • Journal Title

      平成18年度電気学会全国大会 (発表予定)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 固体高分子膜による水素の分離・圧縮特性に関する基礎試験2006

    • Author(s)
      池田, 市原, 砂川, 服部, 荒木, 恩田, 五十嵐, 本吉
    • Journal Title

      電気学会論文誌B編 (掲載予定)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 燃料電池排出水素処理に関する研究2005

    • Author(s)
      池田, 服部, 市原, 砂川, 荒木, 恩田, 五十嵐, 本吉
    • Journal Title

      平成17年度電気学会電力・エネルギー部門大会講演集

      Pages: 42-23

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Polymer Electrolyte Separation Pump of Exhausted Hydrogen from PEMFC2005

    • Author(s)
      Onda, Hattori, Ikeda, Ichihara, Araki, Terai, Igarashi, Kusada, Motoyoshi
    • Journal Title

      2005 Fuel Cell Seminar

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 燃料電池排出水素処理に関する研究2005

    • Author(s)
      池田, 市原, 大山, 荒木, 恩田, 五十嵐, 本吉
    • Journal Title

      第46回電池討論会講演集

      Pages: 518-518

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 固体高分子膜を使った水素の分離・圧縮特性

    • Author(s)
      市原敬士, 長濱光幸, 源 保男, 荒木拓人, 恩田和夫
    • Journal Title

      機械学会論文集B編 (印刷中)

    • NAID

      110006342852

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Separation and Compression Characteristics of Hydrogen by Use of Proton Exchange Membrane

    • Author(s)
      Keiji ICHIHARA, Mitsuyuki NAGAHAMA, Yasuo MINAMOTO Takuto ARAKI, Kazuo ONDA
    • Journal Title

      Trans.JSME B (in printing)

    • NAID

      110006342852

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 固体高分子膜を使った水素の分離・圧縮特性

    • Author(s)
      市原敬士, 長濱光幸, 源 保男, 荒木拓人, 恩田和夫
    • Journal Title

      機械学会論文集B編 (印刷中)

    • NAID

      110006342852

    • Related Report
      2006 Annual Research Report

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Published: 2005-04-01   Modified: 2016-04-21  

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