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Fundamental study of design of small size DMFC by using Marangoni convection

Research Project

Project/Area Number 17360374
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionShizuoka University

Principal Investigator

OKANO Yasunori  Shizuoka University, Graduate School of Science & Technology, Professor (90204007)

Co-Investigator(Kenkyū-buntansha) SUDOH Masao  Shizuoka UniverAty, Faculty of Engineering, Professor (80154615)
Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥6,290,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥390,000)
Fiscal Year 2007: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2006: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 2005: ¥2,600,000 (Direct Cost: ¥2,600,000)
KeywordsFuel cell / Chemical engineering / Fluid dynamics / Environmental Technology / Numerical Simulation / Heat transfer / Mass transfer / Chemical Reaction
Research Abstract

A fuel cell is expected as a source of clean energy in the various fields. A PEMFC is developed in the field vehicle. On the other hand, a DMFC is suitable for small size product such as note PCs and cell phones. However, method of methanol supply is serious problem to be solved because 1/10 size of DMFC is required compare with the present situation. At present, small size of pump is used for it. In order to shrink the size very much, new type of supply method must be developed. For this purpose, fundamental study was carried out for development of new type of methanol supply by using Marangoni convection. The following results were obtained ;
(A) Effect of gas-liquid two-phase flow:
Numerical simulation was carried out for the effect of CO_2 bubbles which was induced by chemical reaction during FC running on the Marangoni convection. Simulation results showed the bubbles disturbed the interface and suppressed the Marangoni convection. Also, it was found that the bubbles suppressed the chemical reaction on the catalysis and decreased electrical current density. By using this simulation code, calculation of limit current density is available.
(B) Co-existence effect of thermal and solutal Marangoni convection:
Effect of co-existence effect of thermal and solutal Marangoni convection on fluid flow was numerically investigated. It was found that thermal Marangoni convection determine the flow structure in the liquid. However, it was also found that solutal Marangoni convection was important for local structure of flow. Especially, velocity induced by solutal Marangoni convection was relatively slow because the concentration gradient became gentle as flow developed.

Report

(4 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (12 results)

All 2007 2006 2005

All Journal Article (9 results) (of which Peer Reviewed: 4 results) Presentation (3 results)

  • [Journal Article] Performance of sputter-deposited platinum cathodes with Nafion and carbon loading for direct methanol fuel cells2007

    • Author(s)
      M. Sudoh
    • Journal Title

      J. Power Sources 166

      Pages: 30-34

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Surface modification of activated carbon with cold plasma treat-ment for high power capacitor2007

    • Author(s)
      M. Sudoh
    • Journal Title

      Electrochemistry 75

      Pages: 702-704

    • NAID

      130002150846

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Performance of sputter-deposited platinum cathodes with Nafion and carbon loading for direct methanol fuel cells2007

    • Author(s)
      M. Sudoh, et. al.
    • Journal Title

      J. Power Sources Vol.166

      Pages: 30-34

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Surface modification of activated carbon with cold plasma treatment for high power capacitor2007

    • Author(s)
      M. Sudoh, et. al.
    • Journal Title

      Electrochemistry Vol.75

      Pages: 702-704

    • NAID

      130002150846

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Performance of sputterdeposited platinum cathodes with Nafion and carbon loading for direct methanol fuel cells2007

    • Author(s)
      M.Sudoh
    • Journal Title

      J.Power Sources 166

      Pages: 30-34

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface modification of activated carbon with cold plasma treatment for high power capacitor2007

    • Author(s)
      M.Sudoh
    • Journal Title

      Electrochemistry 75

      Pages: 702-704

    • NAID

      130002150846

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the methanol crossover on the DMFC performance2006

    • Author(s)
      H.Minakuchi et al.
    • Journal Title

      Proc. 5th International Conference on Global Research and Education 1

      Pages: 211-221

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A three-dimensional numerical simulation study for the cathode side of a fuel cell2005

    • Author(s)
      H.Minakuchi
    • Journal Title

      Electrochemistry 73

      Pages: 182-188

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Intelligent structure design of membrane cathode assembly for direct methanol fuel cell2005

    • Author(s)
      K.Furukawa
    • Journal Title

      Int.J.Energy Res 29

      Pages: 1073-1082

    • Related Report
      2005 Annual Research Report
  • [Presentation] Numerical simulation of temperature distribution in DMFC stack2007

    • Author(s)
      Y. Fukami
    • Organizer
      6th International Conference on Global Rese-arch and Education(inter-academia 2007)
    • Place of Presentation
      浜松
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Numerical simulation of temperature distribution in DMFC stack2007

    • Author(s)
      Y. Fukami, et. al.
    • Organizer
      6th International Conference on Global Research and Education (inter-academia 2007)
    • Place of Presentation
      Hamamatsu
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Numerical simulation of temperature distribution in DMFC stack2007

    • Author(s)
      Y.Fukami
    • Organizer
      6th International Conference on Global Research and Education (inter-academia 2007)
    • Place of Presentation
      浜松
    • Related Report
      2007 Annual Research Report

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Published: 2005-04-01   Modified: 2016-04-21  

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