• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Research and development of fuel cells using high temperature proton conductors

Research Project

Project/Area Number 17360466
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionKyushu University

Principal Investigator

MATSUMOTO Hiroshige  Kyushu University, INAMORI Frontier Center, Research Professor (70283413)

Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥16,390,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2007: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2006: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 2005: ¥7,600,000 (Direct Cost: ¥7,600,000)
Keywordsproton conductor / fuel cell / prerovskite / zirconate / thin film / slurry coating / oxide electrode / ペロブスカイト型酸化物 / 薄膜電解質 / プロトン導電体 / アノード支持 / PLD / 混合ペロブスカイト / ルテニウム / 化学的安定性 / ドーパント / イオン半径
Research Abstract

Thin-film electrolyte fuel cells are fabricated using strontium-zirconate-cerate solid solution whic h has both chemical stability and fairly high proton conductivity. When the film was prepared by pul sed-laser deposition method, the fuel cells thus fabricated showed high performance in the operation al temperature range of 500-700 degree C. Samarium-strontium cobaltate that have shown high cathode performance with barium cerate electrolyte was found to work well for the solid solution electrolyte.
Slurry coating was tested for fabrication of thin film electrolyte, intending the use for industria 1 process. Cobalt was found to work as a sintering aid, where as the resulting electrolyte shoed ten times lower conductivity than the undoped material. On the other hand, the mixture of starting mate rial (i. e., carbonates and oxides) can become well-sintered thin film when it backed without taking the course of calcinations. Thin film thus fabricated was confirmed to work for fuel cells.
In the investigation in this project, fabrication route of proton conductor fuel cells can be establ ished.

Report

(4 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (22 results)

All 2009 2008 2007 2006 2005 Other

All Journal Article (16 results) (of which Peer Reviewed: 4 results) Presentation (3 results) Book (3 results)

  • [Journal Article] Proton conduction and chemical stability of (La0.5Sr0.5) (Mg0.5+yNb0.5-y)O3-δ2009

    • Author(s)
      Y. Kawasaki, S. Okada, N. Ito, H. Matsumoto, T. Ishihara
    • Journal Title

      Materials Research Bulletin 44

      Pages: 457-461

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Proton conduction and chemical stability of (La0.5Sr0.5)(Mg0.5+yNb0.5-y)O3-82009

    • Author(s)
      Y. Kawasaki, S. Okada, N. Ito, H. Matsumoto, T. Ishihara
    • Journal Title

      Materials Research Bulletin 44

      Pages: 457-461

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Proton conduction and chemical stability of (La0. 5Sr0. 5)(Mg0. 5+yNb0. 5-y)O3-δ2009

    • Author(s)
      Y. Kawasaki, S. Okada, N. Ito, H. Matsumoto, T. Ishihara
    • Journal Title

      Materials Research Bulletin 44

      Pages: 457-461

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ntermediate-temperature solid oxide fuel cells using perovskite-type oxide based on barium cerate2008

    • Author(s)
      H. Matsumoto, I. Nomura, S. Okada, T. Ishihara
    • Journal Title

      Solid State Ionics 179

      Pages: 1486-1489

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Intermediate-temperature solid oxide fuel cells using perovskite-type oxide based on barium cerate2008

    • Author(s)
      H. Matsumoto, I. Nomura, S. Okada, T. Ishihara
    • Journal Title

      Solid State Ionics 179

      Pages: 1486-1489

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Proton-conducting ceria-related materials (in Japanese)2008

    • Author(s)
      H. Matsumoto
    • Journal Title

      In the book let of Hand book of rare-earth materials and technologies, NTS Co. Ltd.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] セリア系プロトン伝導性材料2008

    • Author(s)
      松本広重、石原達己
    • Journal Title

      セラミックス 42

      Pages: 877-882

    • NAID

      10019786573

    • Related Report
      2007 Annual Research Report
  • [Journal Article] Intermediate-temperature solid oxide fuek cell using perovskite-type oxid e based on barium cerate2008

    • Author(s)
      H. Matsumoto, I. Nomura, S. Okada, T. Ishihara
    • Journal Title

      Solid State Ionics 179

      Pages: 1486-1489

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] セリア系プロトン伝導性材料2007

    • Author(s)
      松本広重, 石原達己
    • Journal Title

      セラミックス 42

      Pages: 877-882

    • NAID

      10019786573

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Cerate-based proton conductors (in Japanese)2007

    • Author(s)
      H. Matsumoto, T. Ishihara
    • Journal Title

      Ceramics 42

      Pages: 877-882

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Reaction between Electrical Conductivity and Chemical Stability of BaCeO3-Based Proton Conductors with Different Trivalent Dopants2007

    • Author(s)
      H.Matsumoto, Y.Kawasaki, N.Ito, M.Enoki, T.Ishihara
    • Journal Title

      Electrochem. Solid-State Lett. 10

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Application of Protonic Conduction in Perovskite-Type Oxides : Mixed Proton-Electron-Conducting Membrane for Hydrogen Separation2006

    • Author(s)
      H.Matsumoto
    • Journal Title

      Advances in Science and Technology 45

      Pages: 2024-2032

    • Related Report
      2006 Annual Research Report
  • [Journal Article] EFFECT OF TRIVALENT DOPANTS ON THE ELECTRICAL CONDUCTIVITY AND CHEMICAL STABILITY OF BaCeO3-BASED PROTON CONDUCTORS2006

    • Author(s)
      Y.Kawasaki, H.Matsumoto, T.Ishihara
    • Journal Title

      Proc. 16th IKETANI Conference 2006 Electrochemistry and Thermodynamics on Materials Processing for sustainable Production

      Pages: 863-869

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 単純ペロブスカイト型のプロトン導電体2005

    • Author(s)
      松本広重
    • Journal Title

      マテリアルズインテグレーション 18巻・7号

      Pages: 5-9

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Hydrogen separation using proton-conducting perovskites2005

    • Author(s)
      H.Matsumoto, 他7名
    • Journal Title

      J.Alloys & Compounds 408-412巻

      Pages: 456-462

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Hydrogen separation from syngas using high-temperature proton conductors

    • Author(s)
      H.Matsumoto, 他6名
    • Journal Title

      Ionics (印刷中)

    • Related Report
      2006 Annual Research Report
  • [Presentation] トロンチウムジルコネート系プロトン伝導体を用いた燃料電池の電極材の検討2008

    • Author(s)
      佐藤恭彦, 松本広重, 野村育代, 岡田祥夫, 石原達己
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      山梨大学
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Investigation of electrode materials for strontium-zirconate fuel cells2008

    • Author(s)
      Y. Sato, H. Matsumoto, I. Nomura, T. Ishihara
    • Organizer
      75 Meeting of Electrochemical Society
    • Place of Presentation
      Yamanashi University
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] トロンチウムジルコネート系プロトン伝導体を用いた燃料電池の電極材の検討2008

    • Author(s)
      佐藤恭彦、松本広重、野村育代、岡田祥夫、石原達己
    • Organizer
      電気化学会第75回大会
    • Place of Presentation
      電気化学会第75回大会
    • Related Report
      2007 Annual Research Report
  • [Book] 希土類の材料技術ハンドブック第4章 第2節 プロトン伝導体セリア系ペロズスカイト2008

    • Author(s)
      松本広重
    • Total Pages
      1050
    • Publisher
      株式会社エヌ・ティー・エス
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] 希土類の杉料技術ハンドブック第4章 第2節 プロトン伝導体セリア系ペロブスカイト2008

    • Author(s)
      松本広重
    • Total Pages
      1050
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2007 Annual Research Report
  • [Book] 環境調和型材料シリーズ 燃料電池材料 4.6ブロトン伝導性酸化物電解質(II) 中・低温2007

    • Author(s)
      (社)日本セラミックス協会
    • Publisher
      日刊工業新聞社
    • Related Report
      2006 Annual Research Report

URL: 

Published: 2005-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi