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SUPLAMOLECULAR ASSEBLIES OF 4-AMINO-6-OXOPYRIMIDINE DERIVATIVES CONTAINING A SIMPLE MEROCYANIE SKELETONE : THEIR PHOTOPHYSICAL PROPERTIES AND STRUCTURES

Research Project

Project/Area Number 17510087
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionKyushu University

Principal Investigator

GOTO Kenta  Kyushu University, INSTITUTE FOR MATERIALS CHEMISTRY AND ENGINEERING, ASSISTANT PROFESSOR (30380538)

Co-Investigator(Kenkyū-buntansha) SHINMYOZU Teruo  KYUSHU UNIVERSITY, INSTITUTE FOR MATERIALS CHEMISTRY AND ENGINEERING, PROFESSOR (90037292)
Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 2006: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 2005: ¥2,900,000 (Direct Cost: ¥2,900,000)
KeywordsMEROCYANINE / HYDROGEN BOND / EXCITON INTERACTION / CLUSTER / 自己組織化 / プロトン移動
Research Abstract

The absorption and fluorescence spectral properties of 4-amino-6-oxopyrimidine 1, which has a simple streptopolymethine merocyanine skeleton, clearly showed that the molecule 1 formed the aggregate In, and showed an exciton band, appearing at an absorption of 350 nm due to the red-shifted HOMO-LUMO transition. Upon light irradiation of the exciton band, a fluorescence band at 398 nm (ΦFL = 0.10) was observed, and its decay life-times were determined. Based on these spectral features, the aggregated In was found to be formed by J-type aggregation. The molecular orientation 1 in the crystal was revealed as being both parallel π-π stacking and hydrogen bonding chains [1]. Since the molecule orientation the parent molecule is closely related to an excitonic interaction, we therefore focused on molecular assembly of its derivatives. Crystals of 4-methylamino-6-oxopyrimidine 2 grown from aqueous alcohol were found to contain 2D water layers consisting of hexameric water clusters with alternating quasi-planar and chair conformations, which are apparently regulated by interactions with the supramolecular aggregate of 2n through hydrogen bonds [2].

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (4 results)

All 2008 2007

All Journal Article (4 results) (of which Peer Reviewed: 1 results)

  • [Journal Article] J-type aggregation of a simple merocyanine skeleton:Spectral features and structure of 4-amino-6-oxopyrimidine2008

    • Author(s)
      Kenta Goto, Rieko Omae, Minoru Yamaji, Teruo Shinmyozu
    • Journal Title

      Journal of Photochemistry and Photobiology A:Chemistry P94

      Pages: 92-96

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] J-type aggregation of a simple merocyanine skeleton : Spectral features and structure of 4-amino-6-oxopyrimidine2008

    • Author(s)
      K. Goto, R. Omae, M. Yamaji, T. Shinmyozu
    • Journal Title

      Journal of Photochemistry and Photobiology A : Chemistry 194

      Pages: 92-98

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Regulated Formation of 2D Water Layers with Alternating SiX-membered Quasi-planar and Chair Cluster Units by 1D Supramolecular Chain2007

    • Author(s)
      Kenta Goto and Teruo Shinmyozu
    • Journal Title

      Chemistry Letters 36

      Pages: 1100-1101

    • NAID

      10019845434

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Regulated Formation of 2D Water Layers with Alternating Six-membered Quasi-planar and Chair Cluster Units by 1D Supramolecular Chain2007

    • Author(s)
      K. Goto, T. Shinmyozu
    • Journal Title

      Chemistry Letters 36

      Pages: 1100-1101

    • NAID

      10019845434

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary

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Published: 2005-04-01   Modified: 2016-04-21  

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