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Novel properties of magnetic materials with strong spin-lattice coupling

Research Project

Project/Area Number 17510089
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionSaga University

Principal Investigator

ZHENG Xu-Guang  Saga University, Department of Physics, Professor, 理工学部, 教授 (40236063)

Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥3,800,000 (Direct Cost: ¥3,800,000)
Fiscal Year 2006: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2005: ¥3,200,000 (Direct Cost: ¥3,200,000)
KeywordsQuantumn fluctuation / geometric frustration / coexisting spin order and disorder / 幾何学的フラストレーション
Research Abstract

Main results:
1. We prepared nanoparticles of CuO and investigated the change in magnetism. We have found that the magnetic transition temperature in nanoparticle CuO is drastically reduced, demonstrating a dramatic finite-size effect. This is the first report of direct evidence of a drastic decrease of the magnetic transition temperature in antiferromagnetic system.
2. We have found a new magnetic material system of hydroxyhalides M_2(OH)_3X where M stands for magnetic ions and X for halogens. We found they are a new geometrically frustarated spin system with novel new quantumn spin properties. In special, we found the co-existence of spin fluctuation and magnetic order in structurally ordered magnets. This discovery uncovers a new route for the study of geometric frustration both in the material aspect as well as in the magnetism (of d-electron spins). As a material route, it provides a new system of M_2(OH)_3 X with a huge number where M is transition metal and X halogen.
These discoveries are partly reflected in 12 papers published in high-profile scientific magazines, two papers in Physical Review Letters and five papers in Physical Review B.

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (30 results)

All 2007 2006 2005 2004 2003 Other

All Journal Article (30 results)

  • [Journal Article] Co-existence of long range order and spin fluctuation in a new geometric frustration series M_2(OH)_3Cl2007

    • Author(s)
      X.G.Zheng, M.Hagihala, T.Toriyi
    • Journal Title

      J. Magn. Magn. Mater. 310

      Pages: 1288-1288

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Antiferromagnetism and geometric frustration in tetrahedral lattice hydroxyhalides M_2(OH)_3X2007

    • Author(s)
      M.Hagihara, X.G.Zheng, T.Toriyi, T.Kawae
    • Journal Title

      Journal of Physics, Condensed Matter. 19

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Synthesis and Application of Stable Copper Oxide Nanoparticle Suspensions for Nanoparticulate Film Fabrication2007

    • Author(s)
      Tetsuya Kida, Takanori Oka, Masamitsu Nagano, Yoichi Ishiwata, Xu-Guang Zheng
    • Journal Title

      Journal of the American Ceramic Society 90

      Pages: 107-110

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Co-existence of long range order and spin fluctuation in a new geometric frustration series M_2(OH)_3Cl2007

    • Author(s)
      X.G.Zheng, M.Hagihara,, T.Toriyi
    • Journal Title

      J. Magn. Magn. Mater. 310

      Pages: 1288-1288

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Geometric frustration in a new material system M_2X(OH)_32006

    • Author(s)
      X.G.Zheng, K.Nishiyama
    • Journal Title

      Physica B 374-375

      Pages: 156-159

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Effect of pressure on the magnetic phase transition in cupric oxide2006

    • Author(s)
      M.Ohashi, A.Tashiro, G.Oomi, E.Maeda, X.G.Zheng
    • Journal Title

      Physical Review B 73

      Pages: 134421-134421

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Coexisting ferromagnetic order and disorder in a uniform system of hydroxyhalide Co_2(OH)_3Cl2006

    • Author(s)
      X.G.Zheng, T.Kawae, H.Yamada, K.Nishiyama, C.N.Xu
    • Journal Title

      Physical Review Letters 97

      Pages: 247204-247204

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Unconventional magnetic transitions in the mineral clinoatacamite Cu_2Cl(OH)_32005

    • Author(s)
      X.G.Zheng, T.Kawae, Y.Kashitani, C.S.Li, H.Yamada, C.N.Xu, N.Tateiwa, K.Takeda, Ren Yang
    • Journal Title

      Physical Review B 71

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Coexistence of long-range order and spin fluctuation in geometrically frustrated clinoatacamite Cu_2Cl(OH)_32005

    • Author(s)
      X.G.Zheng, H.Kubozono, K.Nishiyama, W.Higemoto, T.Kawae, K.Koda, C.N.Xu
    • Journal Title

      Physical Review Letters 95

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Finite-size effect on Neel temperature in antiferromagnetic nanoparticles2005

    • Author(s)
      X.G.Zheng, C.N.Xu, K.Nishikubo, K.Nishiyama, W.Higemoto, W.J.Moon, E.Tanaka, E.S.Otabe
    • Journal Title

      Physical Review B 72

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Antiferromagnetic transitions in polymorphic minerals of the natural cuprates atacamite and botallackite Cu_2Cl(OH)_32005

    • Author(s)
      X.G.Zheng, T.Mori, K.Nishiyama, W.Higemoto, H.Yamada, K.Nishikubo, C.N.Xu
    • Journal Title

      Physical Review B 71

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Ordered magnetic state in PrFe_4Sb_<12> single crystals2005

    • Author(s)
      N.P.Butch, W.M.Yuhasz, P.-C.Ho, J.R.Jeffries, N.A.Frederick, T.A.Sayles, X.G.Zheng, M.B.Maple, J.B.Betts, A.H.Lacerda, F.M.Woodward, J.M.Lynn, P.Rpgl, G.Giester
    • Journal Title

      Physical Review B 71

      Pages: 214417-214417

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Electro-Mechano-Optical Conversions in Pr^<3+>-Doped BaTiO_3-CaTiO_3 Ceramics2005

    • Author(s)
      X.S.Wang, C.N.Xu, H.Yamada, X.G.Zheng
    • Journal Title

      Advanced Materials 17

      Pages: 1254-1258

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Coexistence of long-range order and spin fluctuation in geometrically frustrated clinoatacamite Cu_2CI(OH)_3 Physical2005

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Review Letters (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Unconventional magnetic transitions in the mineral clinoatacamite2005

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Physical Review B 71

      Pages: 52409-52409

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Anti ferromagnetic transitions in polymorphous minerals of natural cuprates atacamite and botallackite Cu_2CI(OH)_32005

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Physical Review B 71

      Pages: 174404-174404

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Antiferromagnetic transinons in polymorphic minerals of the natural cuprates atacamite and botallackite Cu_2Cl(OH)_32005

    • Author(s)
      X.G.Zheng, T.Mori, K.Nishiyama, W.Higemoto, H.Yamada, K.Nishikubo, C.N.Xu
    • Journal Title

      Physical Review B 71

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Ordered magnetic state in PrFe_4Sb_<12> single crystals2005

    • Author(s)
      N.P.Butch, W.M.Yuhasz, P.-C.Ho, J.R.Jeffries, N.A.Frederick, T.A.Sayles, X.G.Zheng, M.B.Maple, J.B.Betts, A.H.Lacerda, F.M.Woodward, J.M.Lynn, P.Rpgl, G.Gester
    • Journal Title

      Physical Review B 71

      Pages: 214417-214417

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Dramatic suppression of antiferromagnetic coupling in nanoparticle CuO2004

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Solid State Commun. 132

      Pages: 493-496

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Antiferromagnetic transition in botallackite Cu_2CI(OH)_32004

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Solid State Communications 131

      Pages: 509-511

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Antiferromagnetic transition in atacamite Cu_2CI(OH)_32004

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Solid State Communications 130

      Pages: 107-109

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Fast suppression of anti ferromagnetism in Cu_<1-x>Li_xO2004

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Physical Review B 69

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Lattice distortion and magnetolattice coupling in CuO2004

    • Author(s)
      H.Yamada, X.G.Zheng et al.
    • Journal Title

      Physical Review B 69

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Room temperature sensing of ozone by transparent p-type semiconductor CuAlO_22004

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Appl. Phys. Lett. 85

      Pages: 1728-1728

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Strong elasticoluminescence from monoclinic-structure SrAl_2O_42004

    • Author(s)
      C.N.Xu et al., X.G.Zheng
    • Journal Title

      Appl. Phys. Lett. 84

      Pages: 3040-3040

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Effect of hole-doping in Li_xCu_<1-x>O2003

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Physical Review B 67

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Phase diagram of lithium-doped copper oxide Cu_<1-x>Li_xO2003

    • Author(s)
      K.Saito, X.G.Zheng et al.
    • Journal Title

      Solid State Communications 125

      Pages: 23-26

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Finite-size effect in antiferromagnetic nanoparticles,

    • Author(s)
      X.G.Zheng et al.
    • Journal Title

      Physical Review B (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Ordered magnetic state in PrFe_4Sb_<12> single crystals

    • Author(s)
      N.P.Butch et al., X.G.Zheng
    • Journal Title

      Physical Review B (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Electro-Mechano-Optical Conversions in Pr^<3+>-Doped BaTiO_3-CaTiO_3 Ceramics

    • Author(s)
      X.S.Wang et al., X.G.Zheng
    • Journal Title

      Advanced Materials (in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary

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Published: 2005-04-01   Modified: 2016-04-21  

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