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Fabrication of Transparent Conductive Zinc Oxide Thin Film Using Inductively Coupled Plasma Assisted Sputtering

Research Project

Project/Area Number 17540472
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Plasma science
Research InstitutionNagasaki University

Principal Investigator

MATSUDA Yoshinobu  Nagasaki University, Faculty of Engineering, Associate Professor (60199817)

Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥3,370,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥270,000)
Fiscal Year 2007: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2006: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2005: ¥1,300,000 (Direct Cost: ¥1,300,000)
KeywordsInductively Coupled Plasma / Sputtering / Aluminum doped Zinc Oxide / Transparent Conductive Film / Planar Magnetron / Arcing / 透明誘電膜 / 酸化亜鉛
Research Abstract

Aluminum (Al) doped zinc oxide (ZnO) is a well known transparent conductive oxide and has a high technological impact due to its unique material properties such as low production cost and non-toxic nature. Thereby, the Al doped ZnO has been expected as one of the promising alternatives to indium tin oxide (ITO), which has long been widely used as transparent conductive electrodes of solar cells and flat panel displays but the use of costly and sparse indium (In) has recently been worried about. In order to put the Al doped ZnO to practical use in industry, however, both the understanding of its fundamental properties like electrical, optical, and micro-structural properties and the establishment of low cost and reproducible fabrication processes of Al doped ZnO thin films are essential.
To explore a high rate fabrication process of high quality Al doped ZnO thin films, we have employed inductively coupled plasma (ICP : 13.56MHz) to assist planar magnetron (PM) sputtering (3 inch, Al dop … More ed ZnO target). Obtained results are summarized as follows.
1) Superposition of high density ICP to the conventional planar magnetron makes it possible to decrease the target sputtering voltage while increasing target ion current at a fixed sputtering power ; in addition, target eroded area expands. Thus, film damage is decreased due to the decrease in average energy of particles impinging the substrate ; spatial uniformity of electrical and optical properties on the substrate is improved ; and the target usability is also improved.
2) Depending on the experimental condition, arcing frequently occurred on the Al doped ZnO target during the sputter-deposition process. The number of arcing event was found to decrease by the superposition of ICP.
3) Resistivity attained in this research is of the order of 10-3Ωcm, which is one order of magnitude higher than the top data ever reported. For the improvement of film quality, we need to pay more attention to the degradation of target, arcing generation, and impurity control. Less

Report

(4 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (29 results)

All 2008 2007 2006 2005

All Journal Article (23 results) (of which Peer Reviewed: 10 results) Presentation (6 results)

  • [Journal Article] Smoothing of resistivity distributions of sputtered AZO thin film by the assist of ICP2008

    • Author(s)
      Y. Matsuda
    • Journal Title

      Proc.of the 25th Symposium on Plasma Processing, Yamaguchi, Japan, January 23-25 2008

      Pages: 79-80

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Smoothing of resistivity distributions of sputtered AZO thin film by the assist of ICP2008

    • Author(s)
      Yoshinobu, Matsuda, Shibasaki, Takashi, Shinohara, Masanori
    • Journal Title

      Proc. of the 25th Symposium on Plasma Processing, Yamaguchi, Japan A5-01

      Pages: 79-80

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Smoothing of resistivity distributions of sputtered AZO thin film by the assist of ICP2008

    • Author(s)
      Yoshinobu Matsuda
    • Journal Title

      Proc.of the 25th Symposium on Plasma Processing, January 23-25, 2008, Yamaguchi, Japan

      Pages: 79-80

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deposition of AZO Thin Films by ICP Assisted Magnetron Sputtering2007

    • Author(s)
      Shiro Iwai
    • Journal Title

      Proc.of the 24th Symposium on Plasma Processing, Senri Life Science Center, Osaka, Japan, January 29-31 2007

      Pages: 27-28

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Sputter-deposition of aluminum-doped zinc oxide thin films assisted by inductively coupled plasma2007

    • Author(s)
      Shiro Iwai
    • Journal Title

      Abstracts and Full-Papers CD of ISPC-18, August 26-31 2007, Kyoto, Japan

      Pages: 396-396

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Influence of RF power on the film properties of aluminum doped zinc oxide deposited by inductively coupled plasma assisted sputtering2007

    • Author(s)
      Y. Matsuda
    • Journal Title

      Proc.29th Int.Sympo.on Dry Process, Nov.13-14 2007, Tokyo, Japan

      Pages: 161-162

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Deposition of AZO Thin Films by ICP Assisted Magnetron Sputtering2007

    • Author(s)
      Shiro, Iwai, Yoshinobu, Matsuda, Masanori, Shinohara, Hiroshi, Fujiyama
    • Journal Title

      Proc. of the 24th Symposium on Plasma Processing, Senri Life Science Center, Osaka, Japan B2-01

      Pages: 27-28

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Sputter-deposition of aluminum-doped zinc oxide thin films assisted by inductively coupled plasma2007

    • Author(s)
      Shiro, Iwai, Yoshinobu, Matsuda, Masanori, Shinohara, Hiroshi, Fujiyama
    • Journal Title

      Abstracts and Full-Papers CD of ISPC-18, Kyoto, Japan 27P-28

      Pages: 369-369

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Influence of RF power on the film properties of aluminum doped zinc oxide deposited by inductively coupled plasma assisted sputtering2007

    • Author(s)
      Y., Matsuda, T., Shinbasaki, S., Iwai, M., Shinohara
    • Journal Title

      Proc. 29th Int. Sympo. on Dry Process, Tokyo, Japan 13-14, P2-02

      Pages: 161-162

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Sputter-deposition of aluminum-doped zinc oxide thin films assisted by inductively coupled plasma2007

    • Author(s)
      Shiro Iwai
    • Journal Title

      Abstracts and Full-Papers CD of ISPC-18, August 26-31, 2007, Kyoto, Japan

      Pages: 396-396

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sputter-Deposition of Aluminum-Doped Zinc Oxide Thin Films by Inductively Coupled Plasma Assisted Magnetron Sputtering2007

    • Author(s)
      Yoshinobu Matsuda
    • Journal Title

      Proc.29th Int.Sympo.on Dry Process, Nov.13-14 2007, Tokyo, Japan

      Pages: 161-162

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deposition of AZO Thin Films by ICP Assisted Magnetron Sputtering2007

    • Author(s)
      S.Iwai
    • Journal Title

      Proc. of the 24th Symposium on Plasma Processing (SPP-24), January 29-31 2007, Osaka

      Pages: 27-28

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Deposition of Aluminum Doped Zinc Oxide Films by Inductively Coupled Plasma Assisted Sputtering2006

    • Author(s)
      Y. Matsuda
    • Journal Title

      Proc.of the 6th International Conference on Reactive Plasmas and 23rd Symposium on Plasma Processing(ICRP-6/SPP-23), Matsushima/Sendai, January 24-27 2006

      Pages: 433-434

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Reactive Deposition of Aluminum Doped Zinc Oxide Films by Inductively Coupled Plasma Assisted Sputtering2006

    • Author(s)
      Y., Matsuda, Y., Nagano, S., Iwai, M., Shinohara, H. Fujiyama
    • Journal Title

      Proc. of the 6th Int. Conf. on Plasmas and 23rd Symposium on Plasma Processing ICRP-6/SPP-23 Matsushima/Sendai P-2A-21

      Pages: 433-434

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Deposition of transparent conducting thin films using inductively-coupled-plasma assisted dc magnetron sputtering of aluminum-doped zinc oxide target2006

    • Author(s)
      Y.Matsuda
    • Journal Title

      Abstract book of 8th Asia-Pacific Conference on plasma Science and 19th Symposium on Plasma Science for Materials, 2-5th July 2006, Cairns, Australia

      Pages: 107-107

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Discharge characteristics of inductively-coupled-plasma assisted dc planar magnetron for the deposition of aluminum-doped zinc oxide thin films2006

    • Author(s)
      Y.Matsuda
    • Journal Title

      Abstract book of 8th Asia-Pacific Conference on Plasma Science and Technology and 19th Symposium on Plasma Science for Materials, 2-5th July 2006, Cairns, Australia

      Pages: 108-108

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Deposition of aluminum doped zinc oxide films by inductively coupled plasma assisted sputtering2006

    • Author(s)
      Y.Matsuda
    • Journal Title

      Proc. of the 6th Int. Conf. on Reactive Plasmas and 23rd Symposium on Plasma Processing, Matsushima/Sendai, Japan, January 24-27, 2006, P-2A-21

      Pages: 433-434

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Optical emission studies of atomic and ionic species in the ionized sputter-deposition process of magnesium oxide thin films2005

    • Author(s)
      Y. Matsuda
    • Journal Title

      Thin Solid Films 475/1-2

      Pages: 113-117

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Aluminum Doped Zinc Oxide Films Deposition Using Inductively Coupled Plasma Assisted Magnetron Sputtering2005

    • Author(s)
      Y. Nagano
    • Journal Title

      Proc.International Symposium on Dry Process, Juju Korea, November 28-30 2005

      Pages: 141-142

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Optical emission studies of atomic and ionic species in the ionized sputter-deposition process of magnesium oxide thin films2005

    • Author(s)
      Y., Matsuda, Y., Koyama, M., Iwaya, M., Shinohara, H., Fujiyama
    • Journal Title

      Thin Solid Films vol.475/1-2

      Pages: 113-117

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Aluminum Doped Zinc Oxide Films Deposition Using Inductively Coupled Plasma Assisted Magnetron Sputtering2005

    • Author(s)
      Y., Nagano, S., Iwai, M., Shinohara, Y., Matsuda, H., Fujiyama
    • Journal Title

      Proc. International Symposium on Dry Process, Juju Korea 28-30

      Pages: 141-142

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Aluminium Doped Zinc Oxide Films Deposition Using Inductively Coupled Plasma Assisted Magnetron Sputtering2005

    • Author(s)
      Y.Nagano
    • Journal Title

      Porc. OF Int. Symp. on Dry Process, Ramada Plaza Juju Hotel, Jeju, Korea November 28-30, 2005, 5-57

      Pages: 141-142

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Inductively Coupled Plasma Assisted Sputter-Deposition of Aluminum-Doped Zinc Oxide Thin Films2005

    • Author(s)
      Y.Nagano
    • Journal Title

      Program and abstracts of the 16th Symposium of the Materials Research Society of Japan, Dec. 9-Dec. 11, 2005, [H1-P06]

      Pages: 178-178

    • Related Report
      2005 Annual Research Report
  • [Presentation] Sputter-Deposition of Aluminum-Doped Zinc Oxide Thin Films by Inductively Coupled Plasma Assisted Magnetron Sputtering2007

    • Author(s)
      Y. Matsuda
    • Organizer
      6th Asian-European Int.Conf.on Plasma Surface Engineering
    • Place of Presentation
      Nagasaki
    • Year and Date
      2007-09-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 誘導結合プラズマ支援によるAl添加ZnOスパッタ薄膜の導電性向上2007

    • Author(s)
      松田 良信
    • Organizer
      2007年秋季第68回応用物理学会学術講演会
    • Place of Presentation
      北海道工業大学(札幌)
    • Year and Date
      2007-09-05
    • Related Report
      2007 Annual Research Report
  • [Presentation] Influence of RF power on the film properties of aluminum doped zinc oxide deposited by inductively coupled plasma assisted sputtering2007

    • Author(s)
      Y., Matsuda, T., Shinbasaki, S., Iwai, M., Shinohara
    • Organizer
      29th Int. Symposium on Dry Process
    • Place of Presentation
      Tokyo Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Discharge characteristics of inductively-coupled-plasma assisted dc planar magnetron for the deposition of aluminum-doped zinc oxide thin films2006

    • Author(s)
      Y., Matsuda, Y., Nagano, S., Iwai, M., Shinohara, H., Fujiyama
    • Organizer
      8th APCPST&SPSM19
    • Place of Presentation
      Cairns Australia
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Influence of Rf Power and Substrate Bias Voltage on The Properties of Magneisium Oxide Thin Films Produced by ICP-Assisted Reactive Sputtering2005

    • Author(s)
      Y., Matsuda, M., Iwaya, M., Shinohara, H., Fujiyama
    • Organizer
      Asian and Europe international Conference on Plasma Surface Engineering
    • Place of Presentation
      Qingdao China
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Aluminum Doped Zinc Oxide Films Deposition Using Inductively Coupled Plasma Assisted Magnetron Sputtering2005

    • Author(s)
      Y., Nagano, S., Iwai, M., Shinohara, Y., Matsuda, H., Fujiyama
    • Organizer
      International Symposium on Dry Process
    • Place of Presentation
      Juju Korea
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2005-04-01   Modified: 2016-04-21  

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