Synthesis and photo-catalytic carbon dioxide reduction property of dinuclear rhenium (I) complexes
| Project/Area Number |
17550051
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Hirosaki University |
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Principal Investigator |
KITA Shouichi Hirosaki University, Hirosaki University, Graduate School of Science and Technology, Associate Professor (80142834)
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| Co-Investigator(Kenkyū-buntansha) |
MIYAMOTO Ryo Hirosaki University, Graduate School of Science and Technology, Assistant Professor (20250590)
須藤 進 弘前大学, 理工学部, 教授 (60003513)
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| Project Period (FY) |
2005 – 2007
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| Project Status |
Completed (Fiscal Year 2007)
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| Budget Amount *help |
¥3,850,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥150,000)
Fiscal Year 2007: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2006: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2005: ¥2,000,000 (Direct Cost: ¥2,000,000)
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| Keywords | Photoreduction of Carbon Dioxide / Photocatalyst / Polynuclear Complex / Reaction Intermediate / DFT calculations / レニウム(I)トリカルボニル / 複核錯体 / 国際情報交換 / アメリカ合衆国 |
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| Research Abstract |
It is known that rhenium (I) tricarbonyl di-imine complexes works as the photocatalyst which selectively reduces the carbon dioxide to carbon monoxide under the existence of weak reducing agent. The polynuclear metal complexes have attracted interest as two electrons reduction catalyst of such reaction.
1. Two novel ligand, bdpbiaH_2=1,8-bis(dipyrido-[2,3-e:2',3'-g]-1H-benzoimidazole)anthracene and bdpbibH_2=1,8-bis(dipyrido-[2,3-e:2'',3''-g]-1H-benzoimidazole)benzene which could closely combine two metal core to each other, was designed, and rhenium (I) or ruthenium (II) binuclear complex were synthesized using these bridging ligand. These complexes may be able to activate the small molecule like carbon dioxide in two metal core. The ligands and complexes were identified by elemental analysis and MALDI-TOF mass spectrometric analysis.
2. Both ligands showed the intense fluorescence in fluid solution at ambient temperature. BdpbibH2 ligand showed the broad emission which seemed to be the intramolecular excimer emission at room temperature in the long wavelength region. The UV-visible absorption and the emission spectra, and the electrochemistry measurement of binuclear metal complexes show that the only weak interactions work between two metal centers.
3. The geometry optimization calculations by the density functional theory (DFT) show that the distances between two metal.cores (7~11A) are sufficient in order to insert molecules such as the carbon dioxide. But the synergic effect of the photo catalytic reduction abilities of carbon dioxide could not be observed.
The part of the result was reported in 20th Conference on Photochemistry and Photophysics of Coordination Compound, and 57th Annual Meetings of Japan Society of Coordination Chemistry.
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Report
(4 results)
Research Products
(6 results)
