| Project/Area Number |
17550056
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Aichi University of Education |
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Principal Investigator |
NAKAJIMA kiyohiko Aichi University of Education, Department of Chemistry, Professor (50198082)
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| Project Period (FY) |
2005 – 2007
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| Project Status |
Completed (Fiscal Year 2007)
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| Budget Amount *help |
¥3,340,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥240,000)
Fiscal Year 2007: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2006: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2005: ¥1,500,000 (Direct Cost: ¥1,500,000)
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| Keywords | Platinum(II) complex / Hydrazone / Emission / Protonation and deprotonation / Photoreaction / Structure / Synthesis / 分子構造 / プロトン濃度 / 白金(II)錯体 / ヒドラゾン配位子 / 構造 |
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| Research Abstract |
We prepared hydrazone ligands derived from 2-hydrazinopyridine, 2-hydrazinoquinoline, benzoylhydrazine, picolinic hydrazide and 2-(alkylthio)benzaldehyde (R = Me, Bu, 4-chlorophenyl)or 2-(diphenylphosphino)benzaldehyde. The NH hydrogen atoms of the coordinated hydrazone ligands on the metal complexes(M = Pd(Il), Pt(11), and Ru(Il)) were easily protonated or deprotonated by the action of acids and bases. The reaction was followed spectrnphotometrically, and the isosbestic points were observed for Pd(II) and Pt(11) complexes. The Ru(II) complexes were oxidized by air after deprotonation to yield Ru complexes. The uncoordinated hydrazone ligands and their Pd(II) and Rua() complexes was not emissive, however, the Pt(11) complexes showed strong emission peaks in the visible region. Reversible large sifts of the emission peaks were observed by the action of acids and bases
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