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The development of new dendritic fluorescent chemosensors as analytical reagents.

Research Project

Project/Area Number 17550070
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionHirosaki University

Principal Investigator

KAWAKAMI Jun  Hirosaki University, Faculty of Science and Technology, Instructor, 理工学部, 助手 (60261426)

Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2006: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2005: ¥2,400,000 (Direct Cost: ¥2,400,000)
KeywordsDendrimer / Metal Ions / Fluorescence / Chemosensors / Naphthalene / Excimer / Exciplex / Intramolecular Interaction
Research Abstract

1.A poly(amine ester) dendrimer with naphthyl units (NG1) has been synthesized as a fluorescent chemosensor for metal ions. We investigated the metal ion recognition of NG1 by adding each Ag^+, Al^<3+>,Ba^<2+>,Ca^<2+>,Cd^<2+>,Co^<2+>,Cu^<2+>,Fe^<3+>,Mg^<2+>,Ni^<2+>, and Zn^<2+> in acetonitrile solution. Large changes were observed in the fluorescence spectra of NG1 on addition of Al^<3+>,Cu^<2+>, and Zn^<2+>.
2.Poly(amide amine) dendrimer with naphthyl units (N8) as a fluorescent chemosensor for metal ions was synthesized. We investigated the metal ion recognition of N8. Large changes in the fluorescence spectra of N8 were observed upon the addition of Al^<3+>,Zn^<2+>,Cd^<2+> and Ni^<2+>.

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (2 results)

All 2006

All Journal Article (2 results)

  • [Journal Article] Poly(amine ester) Dendrimer with Naphthyl Units as a Fluorescent Chemosensor for Al(III), Cu(II), and Zn(II)2006

    • Author(s)
      J.Kawakami, T.Mizuguchi, S.Ito
    • Journal Title

      Analytical Sciences 22

      Pages: 1383-1384

    • NAID

      10020140498

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Poly (amine ester) Dendrimer with Naphthyl Units as a Fluorescent Chemosensor for Al(III), Cu(II), and Zn(II)2006

    • Author(s)
      J.Kawakami, T.Mizuguchi, S.Ito
    • Journal Title

      Analytical Sciences 22

      Pages: 1383-1384

    • NAID

      10020140498

    • Related Report
      2006 Annual Research Report

URL: 

Published: 2005-04-01   Modified: 2016-04-21  

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