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繊維充填型ショートメタルキャピラリーカラムを応用した高温ガスクロマトグラフィー

Research Project

Project/Area Number 17550078
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Analytical chemistry
Research InstitutionToyohashi University of Technology

Principal Investigator

齊戸 美弘  豊橋技術科学大学, 工学部, 助手 (00303701)

Co-Investigator(Kenkyū-buntansha) 神野 清勝  豊橋技術科学大学, 工学部, 教授 (60124731)
Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 2006: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 2005: ¥2,200,000 (Direct Cost: ¥2,200,000)
Keywords耐熱性繊維 / 充填キャピラリーカラム / メタルキャピラリー / 液相被覆 / 不活性化処理 / 高速分離 / マイクロ化 / 高温分離
Research Abstract

本研究では、耐熱性細繊維を充填した、全く新しい形態の繊維充填型ショートメタルキャピラリーカラムの開発を行った。以下に研究成果の概要を示す。
1.各種繊維の比較検討
(1)各種合成繊維の耐熱性評価
GC装置を用いて、各種繊維の耐熱性について評価し、高温分離に最適な耐熱性繊維を決定した。
(2)選択性の比較・耐久性の比較
繊維状充填剤と従来カラムとの性能比較、繊維の化学構造とその対象化合物に対する選択性の関係についても系統的に検討した。
(3)金属内面不活性化の検討
金属キャピラリーの内面不活性化について検討し、高温GCカラムに適した不活性化法を採用した。
2.耐熱性液相被覆による高性能化
(1)耐熱性高分子による液相被覆の検討
ポリジメチルシロキサンを基本化学構造とする液相を用いて、繊維表面の液相被覆処理を行い、高性能化を達成した。
(2)高温分離条件の検討
高温分離条件について検討するとともに、カラムの小型化に成功した。
3.高性能繊維充填カラムの開発
(1)繊維表面誘導体化の検討
繊維表面への各種化学官能基の導入について系統的に研究し、新規カラムを開発した。
(2)各種高温GC分離への応用
検討の結果、従来のGCでは一般に分離困難であった、低揮発性の高分子試料への応用も可能であることが明らかとなった。
4.周辺技術への応用
(1)他のクロマトグラフィー手法への応用
本研究で開発したキャピラリーカラムを、液体クロマトグラフィーなどの分離カラムとして応用する可能性についても幅広く検討した。
(2)マイクロスケール試料前処理法への応用
環境試料あるいは生体試料に代表される複雑系試料の前処理媒体としての応用についても基本的な検討を行った。
なお、上記の研究成果は、以下に示す論文にて発表するとともに、国内外の国際学術会議等でも広く発表している。

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (28 results)

All 2007 2006 2005

All Journal Article (28 results)

  • [Journal Article] Miniaturized Sample Preparation Using a Fiber-Packed Capillary as the Medium2007

    • Author(s)
      K.Jinno
    • Journal Title

      Trends in Analytical Chemistry 26

      Pages: 27-35

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Micro Sample Preparation and Separation : Fiber-Packed Capillary and Needle for Miniaturization2007

    • Author(s)
      Y.Saito
    • Journal Title

      G.I.T. Laboratory Journal (未定)(掲載決定)(印刷中)

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Removal of Phosphate Ions with Chemically Modified Chitosan-Metal Ion Complex2007

    • Author(s)
      Y.Shimizu
    • Journal Title

      Journal of Applied Polymer Science (未定)(掲載決定)(印刷中)

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] A Spot Test for Ammonium Ion by the Color Band Formation Method2007

    • Author(s)
      S.Asaoka
    • Journal Title

      Talanta (未定)(掲載決定)(印刷中)

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Effect of Counter-Anions on the Retention of Zwitterionic Quinolones in Reversed-Phase Liquid Chromatography2007

    • Author(s)
      N.S.Quiming
    • Journal Title

      Journal of Liquid Chromatography and Related Technologies (未定)(掲載決定)(印刷中)

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Miniaturized Sample Preparation Needle : A Versatile Design for the Rapid Analysis of Smoking-Related Compounds in Hair and Air Samples2007

    • Author(s)
      Y.Saito
    • Journal Title

      Journal of Pharmaceutical and Biomedical Analysis (未定)(掲載決定)(印刷中)

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Fiber-Packed Needle for Dynamic Extraction of Aromatic Compounds2007

    • Author(s)
      M.Ogawa
    • Journal Title

      Analytical and Bioanalytical Chemistry (未定)(掲載決定)(印刷中)

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Simultaneous LC Determination of Ginsenosides Using a Modified Extraction Procedure and an Improved Step Gradient Program2006

    • Author(s)
      D.-W.Lou
    • Journal Title

      Chromatographia 63

      Pages: 31-37

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] In-Needle Extraction Device Designed for Gas Chromatographic Analysis of Volatile Organic Compounds2006

    • Author(s)
      Y.Saito
    • Journal Title

      Journal of Chromatography A 1106

      Pages: 190-195

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Crosslinking of Chitosan with a Trifunctional Crosslinker and the Adsorption of Acid Dyes and Metal Ions onto the Resulting Polymer2006

    • Author(s)
      Y.Shimizu
    • Journal Title

      Adsorption Science and Technology 24

      Pages: 29-39

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Isocratic Separation of Ginsenosides by High-Performance Liquid Chromatography on a Diol Column at Subambient Temperatures2006

    • Author(s)
      D.-W.Lou
    • Journal Title

      Analytical and Bioanalytical Chemistry 385

      Pages: 96-104

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Longitudinal Miniaturization of Fiber-Packed Capillary Column in High Temperature Gas Chromatography2006

    • Author(s)
      M.Ogawa
    • Journal Title

      Chromatographia 63

      Pages: 459-463

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Optimization of Capillary Electrophoretic Enantioseparation for Basic Drugs with Native β-CD as a Chiral Selector2006

    • Author(s)
      N.L.Denola
    • Journal Title

      Electrophoresis 27

      Pages: 2367-2375

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Simultaneous Derivatization/Preconcentration of Volatile Aldehydes with a Miniaturized Fiber-Packed Sample Preparation Device Designed for Gas Chromatographic Analysis2006

    • Author(s)
      Y.Saito
    • Journal Title

      Analytical and Bioanalytical Chemistry 386

      Pages: 725-732

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Visual Determination of Nitrite and Nitrate in Waters by Color Band Formation Method2006

    • Author(s)
      Y.Kiso
    • Journal Title

      Chemosphere 26

      Pages: 1949-1954

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Chromatographic Behavior of C_<60> and C_<70> Fullerenes at Subambient Temperature with n-Alkanes Mobile Phases2006

    • Author(s)
      P.K.Zarzycki
    • Journal Title

      Chromatographia 64

      Pages: 79-82

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] 細繊維を応用したマイクロ試料前処理およびクロマトグラフィー分離2006

    • Author(s)
      齊戸美弘
    • Journal Title

      化学工業 57

      Pages: 352-359

    • Related Report
      2006 Annual Research Report 2006 Final Research Report Summary
  • [Journal Article] Crosslinking of Chitosan with a Trifunctional Crosslinker and the Adsorption of Acid Dyes and Metal Ions onto the Resulting Polymer2006

    • Author(s)
      Y.Shimizu
    • Journal Title

      Adsorption Science and Technology (未定)(掲載決定)(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Isocratic Separation of Ginsenosides by High-Performance Liquid Chromatography on a Diol Column at Subambient Temperatures2006

    • Author(s)
      D.-W.Lou
    • Journal Title

      Analytical and Bioanalytical Chemistry (未定)(掲載決定)(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Longitudinal Miniaturization of Fiber-Packed Capillary Column in High Temperature Gas Chromatography2006

    • Author(s)
      M.Ogawa
    • Journal Title

      Chromatographia (未定)(掲載決定)(印刷中)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] High-Temperature Separation with Polymer-Coated Fiber in Packed Capillary Gas Chromatography2005

    • Author(s)
      Y.Saito
    • Journal Title

      Analytical and Bioanalytical Chemistry 382

      Pages: 825-829

    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Molecular-Dynamics Simulation for the Characterization of Liquid Chromatographic Stationary Phase-Effect of Temperature-2005

    • Author(s)
      K.Ban
    • Journal Title

      Analytical Sciences 21

      Pages: 397-402

    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Synthesis of Chemically Modified Chitosans with a Higher Fatty Acid Glycidyl and Their Adsorption Abilities for Anionic and Cationic Dyes2005

    • Author(s)
      Y.Shimizu
    • Journal Title

      Journal of Applied Polymer Science 96

      Pages: 2423-2428

    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Short Metal Capillary Columns Packed with Polymer-Coated Fibrous Materials in High Temperature Gas Chromatography2005

    • Author(s)
      Y.Saito
    • Journal Title

      Journal of Chromatographic Science 43

      Pages: 536-541

    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Surface Derivatization of Poly(p-phenylene terephthalamide) Fiber Designed for Novel Separation and Extraction Media2005

    • Author(s)
      A.Abe
    • Journal Title

      Journal of Separation Science 28

      Pages: 2413-2418

    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Solid-Phase Extraction and High-Performance Liquid Chromatography for Simultaneous Determination of Important Bioactive Ginsenosides in Pharmaceutical Preparation2005

    • Author(s)
      D.-W.Lou
    • Journal Title

      Chromatographia 62

      Pages: 349-354

    • Related Report
      2006 Final Research Report Summary 2005 Annual Research Report
  • [Journal Article] Molecular-Dynamics Simulation for the Characterization of Liquid Chromatographic Stationary Phase --Effect of Temperature--2005

    • Author(s)
      K.Ban
    • Journal Title

      Analytical Sciences 21

      Pages: 397-402

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Surface Derivatization of Poly( p-phenylene terephthalamide) Fiber Designed for Novel Separation and Extraction Media2005

    • Author(s)
      A.Abe
    • Journal Title

      Journal of Separation Science 28

      Pages: 2413-2428

    • Related Report
      2005 Annual Research Report

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Published: 2005-04-01   Modified: 2016-04-21  

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