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DEVELOPMENT OF CO-TORELANT HYDROGEN FUEL CELL COMBINED WITH ACTVE PROX CATALYST FOR CO OXIDATION

Research Project

Project/Area Number 17550136
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionSAITAMA INSTITUTE OF TECHNOLOGY

Principal Investigator

TANAKA Ken-Ichi  SAITAMA INSTITUTE OF TECHNOLOGY, ADV.SCI.RES.LABO., PROFESSOR (00016718)

Co-Investigator(Kenkyū-buntansha) ITO Masatoki  KEIO UNIVERSITY, Faculty of Sci & Engn, PROFESSOR (80005438)
JU Dong-Ying  埼玉工業大学, SAITAMA INSTITUTE OF TECHNOLOGY, PROFESSOR (10255143)
Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2006: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2005: ¥2,300,000 (Direct Cost: ¥2,300,000)
KeywordsPROX REACTION / PT CATALYST / CARBON NANOTUBE / CO-TORELANT HYDROGEN FUEL CELL / FeOx / Pt / TiO2触媒 / Au / nanotube-C / PROX触媒反応 / CO選択酸化 / H2Oの触媒作用 / PROX反応機構 / CO酸化反応中間体 / 一酸化炭素選択酸化 / 水素燃料 / 新触媒 / TiO2
Research Abstract

One awkward problem of the hydrogen fuel cell (HFC) is the serious poisoning of the Pt-electrode by a trace amount of CO in H_2. To avoid it, CO in H_2 is desired to be lower than 10ppm, and the CO in H_2 is usually removed by performing a preferential oxidation (PROX) reaction of CO by using Rh-base catalyst at around 160℃. If we could develop a low temperature active catalyst (<80℃), we can operate HFC by H_2 containing CO without purification. We have developed three extremely active new catalysts, which are FeOx/Pt/TiO_2, FeOx/Au/TiO_2, Pt on carbon nano-tube. By using one of these catalyst, we operate a polymer electrolyte hydrogen fuel cell in H2 containing 1,000ppm CO for more than 6 hours without drop of the power.

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (32 results)

All 2006 2005

All Journal Article (28 results) (of which Peer Reviewed: 3 results) Presentation (4 results)

  • [Journal Article] FeOx/Au/TiO2触媒の活性化とCO酸化反応に対するH_2の促進効果2006

    • Author(s)
      庄将志、竹川裕幸、巨東英、萩原時男、田中虔一、
    • Journal Title

      触媒 48

      Pages: 98-100

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Activation of Pt/TiO_2 Catalysts by Structural Transformation of Pt-Sites2006

    • Author(s)
      Xiaoyan Shi, Changbin Zhang, Masashi Shou, Hong He, Shinichi Sugihara, Ken-ichi Tanaka
    • Journal Title

      Catalysis Letters 107

      Pages: 1-4

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Activation of Pt/TiO_2 Catalysts by Structural Transformation of Pt-Sites2006

    • Author(s)
      X.Shi, C.Zhang, M.i Shou, H.He, S.Sugihara, K.Tanaka
    • Journal Title

      Catal.Letters 107

      Pages: 1-4

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Site selective adsorption of C_2H_5OH and NO depending on the local structure or the local electron density of a Si(111)-7x7 surface2006

    • Author(s)
      H.Liu, Z.Xie, H.Watanabe, J.Qu, K.Tanaka
    • Journal Title

      Phys.Rev.B 73

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Activation of a Au/TiO_2 catalyst by loading a large amount of Fe-Oxide-Oxidation of CO enhanced by H_2 and H_2O-2006

    • Author(s)
      M.Shou, H.Takekawa, D-Y.Ju, T.Hagiwara, K.Tanaka
    • Journal Title

      Catal.Letters 108

      Pages: 119-123

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Significant Enhancement of the Oxidation of CO by H_2 nd/or H_2O on a FeO_x/Pt/TiO_2 Catalyst2006

    • Author(s)
      K.Tanaka, M.Shou, Hong He, X, Shi
    • Journal Title

      Catal.Letters. 110

      Pages: 185-190

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Hydrogen Isotope Effect on the Oxidation of CO Enhanced by H_2 and H_2O on a FeO_x/Pt/TiO_2 Catalyst2006

    • Author(s)
      M.Shou, K.Tanaka
    • Journal Title

      Catal.Letters 111

      Pages: 115-118

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Catalytic Performance and mechanism of a Pt/TiO_2 catalyst for the oxidation of formaldehyde at room temperature2006

    • Author(s)
      Changbin Zhang, Hong He, Ken-ichi Tanaka
    • Journal Title

      Appl.Catal.B, Envir. 65

      Pages: 37-43

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Activation of Pt/TiO_2 Catalysts by Structural Transformation of Pt-Sites.2006

    • Author(s)
      Xiaoyan Shi, Changbin Zhang, Masashi Shou, Hong He, Shinichi Sugihara, Ken-ichi Tanaka
    • Journal Title

      Catalysis Letters 107

      Pages: 1-4

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Site selective adsorption of C_2H_5OH and NO depending on the local structure or the local electron density of a Si(111)-7x7 surface2006

    • Author(s)
      Hui-Juan Liu, Zhao-Xiong Xie, Hiroaki Watanabe, Jiuhui Qu, Ken-ichi Tanaka
    • Journal Title

      Physical Review,B 73

      Pages: 165421-7

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Activation of a Au/TiO_2 catalyst by loading a large amount of Fe-Oxide-Oxidation of CO enhanced by H_2 and H_2O-,2006

    • Author(s)
      Masashi Shou, Hiroyuki Takekawa, Dong-Ying Ju, Tokio Hagiwara, Ken-ichi Tanaka
    • Journal Title

      Catalysis Letters 108

      Pages: 119-123

    • Related Report
      2006 Annual Research Report
  • [Journal Article] FeOx/Au/TiO_2 触媒の活性化とCO酸化反応に対するH_2の促進効果2006

    • Author(s)
      庄将志, 竹川裕幸, 巨東英, 萩原時男, 田中虔一
    • Journal Title

      触媒 48

      Pages: 98-100

    • NAID

      10017309603

    • Related Report
      2006 Annual Research Report
  • [Journal Article] H_2が促進するCO酸化反応の中間体,FeOx/Pt/TiO_2触媒の反応中の赤外スペクトル,2006

    • Author(s)
      田中虔一, 庄将志, 石暁燕, 賀 泓
    • Journal Title

      触媒 48

      Pages: 442-444

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Significant Enhancement of the Oxidation of CO by H_2 and/or H_2O on a FeO_x/Pt/TiO_2Catalyst,2006

    • Author(s)
      Ken-ichi Tanaka, Masashi Shou, Hong He, Xiaoyan Shi
    • Journal Title

      Catalysis Letters 110

      Pages: 185-190

    • Related Report
      2006 Annual Research Report
  • [Journal Article] H_2 and H_2O on a FeO_x/Pt/TiO_2 Catalyst,2006

    • Author(s)
      M.Shou, K.Tanaka
    • Journal Title

      Catalysis Letters 111

      Pages: 115-118

    • Related Report
      2006 Annual Research Report
  • [Journal Article] FeOx/Au/TiO2触媒の活性化とCO酸化反応に対するH_2の促進効果2006

    • Author(s)
      庄将志, 竹川裕幸, 巨東英, 萩原時男, 田中虔一
    • Journal Title

      触媒 48・2

      Pages: 98-100

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Activation of Pt/TiO_2 Catalysts by Structural Transformation of Pt-Sites2006

    • Author(s)
      Xiaoyan Shi, Changbin Zhang, Masashi Shou, Hong He, Shinichi Sugihara, Ken-ich Tanaka
    • Journal Title

      Catalysis Letters, 107

      Pages: 1-4

    • Related Report
      2005 Annual Research Report
  • [Journal Article] CO酸化反応に対するH_2とH_2Oの促進効果-Pt/TiO_2とFeOx/Pt/TiO_2触媒-2005

    • Author(s)
      田中虔一、庄将志
    • Journal Title

      触媒 47

      Pages: 418-420

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] 電位制御によるAuの多重双晶粒子の生成とAu表面の再構成2005

    • Author(s)
      田中虔一、魯大凌
    • Journal Title

      表面科学 26

      Pages: 585-592

    • NAID

      130004784524

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] H_2中のCOを選択酸化する新触媒の活性化機構2005

    • Author(s)
      田中虔一、庄将志、石暁燕、張長斌、賀泓
    • Journal Title

      触媒 17

      Pages: 69-71

    • NAID

      80017264394

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Perfect catalytic oxidation of formaldehyde over a Pt/TiO_2 catalyst at room temperature2005

    • Author(s)
      Changbin Zhang, Hong He, Ken-ichi Tanaka.
    • Journal Title

      Catalysis Communication 6

      Pages: 211-214

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Adsorption kinetics and patterning of a Si(111)-7x7 surface by dissociation of methanol2005

    • Author(s)
      K.Tanaka, Z-X.Xie
    • Journal Title

      J.Chem.Phys. 122

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Perfect catalytic oxidation of formaldehyde over a Pt/TiO_2 catalyst at room temperature2005

    • Author(s)
      C.Zhang, Hong He, K.Tanaka
    • Journal Title

      Catalysis Comm. 6

      Pages: 211-214

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] The Growth of Zn on a Si(100)-2x1 Surface2005

    • Author(s)
      Z.Xie, K.Tanaka
    • Journal Title

      Ultramicroscopy 105

      Pages: 6-11

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] CO酸化反応に対するH_2とH_2Oの促進効果-Pt/TiO_2とFeOx/Pt/TiO_2触媒-2005

    • Author(s)
      田中虔一, 庄将志
    • Journal Title

      触媒 47

      Pages: 418-420

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 電位制御によるAuの多重双晶粒子の生成とAu表面の再構成2005

    • Author(s)
      田中虔一, 魯大凌
    • Journal Title

      表面科学 26

      Pages: 585-592

    • NAID

      130004784524

    • Related Report
      2005 Annual Research Report
  • [Journal Article] H_2中のCOを選択酸化する新触媒の活性化機構、2005

    • Author(s)
      田中虔一, 庄将志, 石暁燕, 張長斌, 賀 泓
    • Journal Title

      触媒 17

      Pages: 69-71

    • NAID

      80017264394

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Perfect catalytic oxidation of formaldehyde over a Pt/TiO_2 catalyst at room temperature,2005

    • Author(s)
      Changbin Zhang, Hong He, Ken-ichi Tanaka
    • Journal Title

      Catalysis Communications, 6

      Pages: 211-214

    • Related Report
      2005 Annual Research Report
  • [Presentation] FeO_x/Au/TiO_2触媒の活性化とCO酸化反応に対するH_2の促進効果2006

    • Author(s)
      庄将志、竹川裕幸、巨東英、萩原時男、田中虔一
    • Organizer
      触媒
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] H_2が促進するCO酸化反応の中間体, FeO_x/Pt/TiO_2触媒の反応中の赤外スペクトル2006

    • Author(s)
      田中虔一、庄将志、石暁燕、賀泓
    • Organizer
      触媒
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] H_2中のCOを選択酸化する新触媒の活性化機構2005

    • Author(s)
      田中虔一、庄将志、石暁燕、張長斌、賀泓
    • Organizer
      触媒
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] CO酸化反応に対するH_2とH_2Oの促進効果-Pt/TiO_2とFeO_x/Pt/TiO_2触媒-2005

    • Author(s)
      田中虔一、庄将志
    • Organizer
      触媒
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary

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Published: 2005-04-01   Modified: 2016-04-21  

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