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High quality InN grown by MOVPE and its electron transport properties

Research Project

Project/Area Number 17560278
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionUniversity of Fukui

Principal Investigator

YAMAMOTO Akio  University of Fukui, Graduate School ofEngineering, Professor (90210517)

Co-Investigator(Kenkyū-buntansha) HASHIMOTO Akihiro  University of Fukui, Graduate Schcol of Engineering, Associate Professor (10251985)
KUZUHARA Masaaki  University of Fukui, Graduate Schcol of Engineering, Professor (20377469)
Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥300,000)
Fiscal Year 2007: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2006: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 2005: ¥1,200,000 (Direct Cost: ¥1,200,000)
Keywordsindium nitride (InN) / MOVPE / two-dimensional electron gas / Si substrate / Mg doping / Mgドーピング / CP_2Mg / キャリア濃度 / 抵抗率 / 電子移動度 / tilt / twist / N面劣化 / 残留キャリア濃度 / V / III比
Research Abstract

Although indium nitride (InN) is still a less studied material than other III-nitride semiconductors, it is expected to have the smallest effective mass, 0.07m_0, and the highest electron drift velocity, 4.2 x 10^7 cm/s, in the III-nitrides. Therefore, InN is promising for a channel material in high-speed and high-frequency electron devices. In order to accomplish these applications, considerable improvements in electrical/optical and crystallographic improvements will be required for InN films. The characterization of electron transport property in InN is also needed to realize an InN-based high speed devices.
The research results obtained in this project are summarized as follows.
1. Theoretical estimation has been made of two-dimensional electron gas density in InN/InGaN (InAlN) heterostructures. An electron gas as high as 2 x 10^<14> cm^2 is expected when ALN is used as a bather.
2. To improve MOVPE InN quality, effects of growth temperature on the crystalline quality of InN has been studied. The grown InN is found to becomes mosaic structure when it is grown at a temperature higher than 600℃.
3. The residual carrier concentration in MOVPE InN is found to be markedly reduced by the annealing in O_2 ambient at around 300℃. Such an annealing brings no changes in electron mobility and crystallographic properties of InN.
4. The process for MOVPE growth of InN on Si substrate has been established by the use of cubic SiC interlayer formed by C^+-ion implantation into Si
5. Electron transport properties of Mg-doped InN have been studied. The resistivity shows a maximum for a CP_2Mg/TEG molar ratio at around 0.02-0.05, suggesting that a carrier compensation occurs.

Report

(4 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (45 results)

All 2008 2007 2006 2005 Other

All Journal Article (20 results) (of which Peer Reviewed: 9 results) Presentation (25 results)

  • [Journal Article] Marked improvements in electrical and optical properties for MOVPE InN annealed at a low temperature(300℃)in O_2 atmosphere2008

    • Author(s)
      K. Sugita
    • Journal Title

      physica status solidi(c) 5

      Pages: 1765-1767

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Two dimensional electron gas in InN-based heterostructures: Effects of spontaneous and piezoelectric polarization2008

    • Author(s)
      Md. Tanvir Hasan
    • Journal Title

      Solid-State Electronics 52

      Pages: 134-139

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Marked improvements in electrical and optical properties for MOVPE InN annealed at a low temperature (300℃) in O_2 atmosphere2008

    • Author(s)
      K. Sugita, Y. Nagai, D. Matsuoka, A. Hashimoto, H. Harima, A. Yamamoto
    • Journal Title

      physica status solidi (c) 5

      Pages: 1765-1767

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Two dimensional electron gas in InN-based heterostructures : Effects of spontaneous and piezoelectric polarization2008

    • Author(s)
      Md. Tanvir, Hasan, Ashraful, G. Bhuiyan, A. Yamamoto
    • Journal Title

      Solid-State Electronics 52

      Pages: 134-139

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Marked improvements in electrical and optical properties for MOVPE InN annealed at a low temperature(300℃)in O2 atmosphere2008

    • Author(s)
      Y. Nagai
    • Journal Title

      physica status solidi(c) (印刷中)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-resolution X-ray diffraction analysis of InN films grown by metalorganic vapor phase epitaxy2007

    • Author(s)
      W. J. Wang
    • Journal Title

      Powder Diffraction 22

      Pages: 219-222

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Characterization of MOVPE InN films grown on 3c-SiC/Si(111)templates2007

    • Author(s)
      M. S. Cho
    • Journal Title

      physica status solidi(c) 4

      Pages: 2441-2444

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Electrical and optical properties of MOVPE InN doped with Mg using CP_2Mg2007

    • Author(s)
      A. Yamamoto
    • Journal Title

      Journal of Crystal Growth 298

      Pages: 399-402

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] High-resolution X-ray diffraction analysis of InN films grown by metalorganic vapor phase epitaxy2007

    • Author(s)
      W. J. Wang, K. Sugita, Y. Nagai, Y. Houchin, A. Hashimoto, A. Yamamoto
    • Journal Title

      Powder Diffraction 22

      Pages: 219-222

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Characterization of MOVPE InN films grown on 3_c-SiC/Si(LLL) templates2007

    • Author(s)
      M. S. Cho, N. Sawazaki, K. Sugita, A. Hashimoto, A. Yamamoto, Y. Ito
    • Journal Title

      physica status solidi (c) 4

      Pages: 2441-2444

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Electrical and optical properties of MOVPE InN doped with Mg using CP_2Mg2007

    • Author(s)
      A. Yamamoto, Y. Nagai, H. Niwa, H. Miwa, A. Hashimoto
    • Journal Title

      Journal of Crystal Growth 298

      Pages: 399-402

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Adduct formation of CP_2Mg with NH_3 in MOVPE growth2007

    • Author(s)
      Y. Nagai
    • Journal Title

      physica status solidi(c) 4

      Pages: 2457-2460

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of MOVPE InN films grown on 3c-SiC/Si(111) templates2007

    • Author(s)
      M.S.Cho
    • Journal Title

      physica status solidi (c) (印刷中)

    • Related Report
      2006 Annual Research Report
  • [Journal Article] A comparative study on MOVPE InN films grown on 3c-SiC/Si(111)and sapphire2006

    • Author(s)
      T. Kobayashi
    • Journal Title

      physica status solidi(a) 203

      Pages: 127-130

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] A comparative study on MOVPE InN films grown on 3_c-SiC/Si(LLL) and sapphire2006

    • Author(s)
      T. Kobayashi, M. S. Cho, N. Sawazaki, A. Hashimoto, A. Yamamoto, Y. Ito
    • Journal Title

      physica status solidi (a) 203

      Pages: 127-130

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] A comparative study on MOVPE InN films grown on 3c-SiG/Si(111) and sapphire2006

    • Author(s)
      T.Kobayashi
    • Journal Title

      physica status solidi (a) 203

      Pages: 127-127

    • Related Report
      2006 Annual Research Report
  • [Journal Article] The most possible donor in InN grown by metalorganic vapor-phase epitaxy2006

    • Author(s)
      A.Yamamoto ほか3名
    • Journal Title

      Thin Solid Films 464

      Pages: 74-78

    • Related Report
      2005 Annual Research Report
  • [Journal Article] MOVPE InN on a 3c-SiC/Si(111)template formed by C^+-ion implantation into Si(111)2005

    • Author(s)
      A. Yamamoto
    • Journal Title

      physica status solidi(c) 2

      Pages: 2281-2284

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] MOVPE InN on a 3_c-SiC/Si(LLL) template formed by C^+-ion implantation into Si(LLL)2005

    • Author(s)
      A. Yamamoto, T. Kobayashi, T. Yamauchi, M. Sasase, A. Hashimoto, Y. Ito
    • Journal Title

      physica status solidi (c) 2

      Pages: 2281-2284

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Deterioration of MOVPE InN films on sapphire during growth and post-growth annealing

    • Author(s)
      H.Miwa ほか2名
    • Journal Title

      Physica Status Solidi (印刷中)

    • Related Report
      2005 Annual Research Report
  • [Presentation] Status and substrate-related issues for MOVPE InN2007

    • Author(s)
      A. Yamamoto
    • Organizer
      European Materials Research Society 2007 Spring Meeting
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2007-05-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] MOVPE成長夏InNの低温熱処理効果:フォトルミネッセンス特性の改善2007

    • Author(s)
      永井泰彦
    • Organizer
      第54回応用物理学関係連合講演会
    • Place of Presentation
      相模原市,神奈川県
    • Year and Date
      2007-03-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Low-temperature annealing effects of MOVPE InN : Improvement of photoluminescence properties (in Japanese)2007

    • Author(s)
      Y. Nagai, K. Sugita, A. Hashimoto, A. Yamamoto
    • Organizer
      The 54th Spring Meeting of the Japan Society of Applied Physics and Related Societies
    • Place of Presentation
      Kanagawa, Japan
    • Year and Date
      2007-03-27
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Marked improvements in electrical and optical properties for MOVPE InN annealed at a low temperature(-300℃)in O2 atmosphere2007

    • Author(s)
      Y. Nagai
    • Organizer
      7th International Conference of Nitride Semicond uctors(ICNS-7)
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2007 Annual Research Report
  • [Presentation] Characterization of MOVPE InN Films Grown on 3c-SiC/Si(111)Templates2006

    • Author(s)
      M. S. Cho
    • Organizer
      International Workshop on Nitride Semiconductors 2006
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2006-10-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Adduct Formation of CP_2Mg with NH_3 in MOVPE Growth of Mg-doped InN2006

    • Author(s)
      Y. Nagai
    • Organizer
      Intematioal Workshop on Nitride Semiconductors 2006
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2006-10-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Characterization of MOVPE InN films grown on 3_c-SiC/Si(LLL) templates2006

    • Author(s)
      M. S. Cho, N. Sawazaki, K. Sugita, A. Hashimoto, A. Yamamoto, Y. Ito
    • Organizer
      International Workshop on Nitride Semiconductors 2006
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2006-10-22
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Adduct Formation of CP_2Mg with NH_3 in MOVPE Growth of Mg-doped InN2006

    • Author(s)
      Y. Nagai, H. Miwa, A. Hashimoto, A. Yamamoto
    • Organizer
      International Workshop on Nitride Semiconductors 2006
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2006-10-22
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 3c-SiC/Si(111)基板上MOVPE成長InN膜の結晶性評価2006

    • Author(s)
      趙 明秀
    • Organizer
      第67回応用物理学会学術講演会
    • Place of Presentation
      草津市,滋賀県
    • Year and Date
      2006-08-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Crystalline quality of MOVPE InN grown on 3_c-SiC/Si(LLL) substrates(in Japanese)2006

    • Author(s)
      M.S. Cho, N. Sawazaki, K. Sugita, A. Hashimoto, A. Yamamoto, Y. Ito
    • Organizer
      The 67th Fall Meeting of the Japan Society of Applied Physics
    • Place of Presentation
      Kusatsu, Japan
    • Year and Date
      2006-08-29
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Electrical and optical properties of MOVPE InN doped with Mg using CP_2Mg2006

    • Author(s)
      A. Yamamoto
    • Organizer
      13th International Conference on Metal Organic Vapor Phase Epitaxy
    • Place of Presentation
      Miyazaki, Japan
    • Year and Date
      2006-05-26
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] CP_2Mgを用いたMOVPE成長InN膜へのMgドーピングの検討(II)2006

    • Author(s)
      永井泰彦
    • Organizer
      第53回応用物理学関係連合講演会
    • Place of Presentation
      世田谷区,東京都
    • Year and Date
      2006-03-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] CP_2Mgを用いたMOVPE成長InN膜へのMgドーピングの検討(I)2006

    • Author(s)
      永井泰彦
    • Organizer
      第53回応用物理学関係連合講演会
    • Place of Presentation
      世田谷区,東京都
    • Year and Date
      2006-03-22
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Mg-doping of MOVPE InN using CP_2Mg (LL) (in Japanese)2006

    • Author(s)
      Y. Nagai, K. Niwa, H. Miwa, A. Hashimoto, A. Yamamoto
    • Organizer
      The 53th Spring Meeting of the Japan Society of Applied Physics and Related Societies
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2006-03-22
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Mg-doping of MOVPE InN using CP_2Mg (L)"(in Japanese)2006

    • Author(s)
      Y. Nagai, K. Niwa, H. Miwa, A. Hashimoto, A. Yamamoto
    • Organizer
      The 53th Spring Meeting of the Japan Society of Applied Physics and Related Societies
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2006-03-22
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] MOVPE growth of high quality InN on 3_c-SiC/Si(LLL) substrates(in Japanese)2005

    • Author(s)
      M.S. Cho, N. Sawazaki, K. Sugita, A. Hashimoto, A. Yamamoto, Y. Ito
    • Organizer
      Technical Reports of the Institute of Electronics, Information and CommunicationEngineers
    • Place of Presentation
      Fukui, Japan
    • Year and Date
      2005-11-13
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] "Mg-doping effects of MOVPE InN using CP_2Mg" (in Japanese)2005

    • Author(s)
      Y. Nagai, K. Niwa, H. Miwa, A. Hashimoto, A. Yamamoto
    • Organizer
      Technical Reports of the Institute of Electronics, Information and Communication Engineers
    • Place of Presentation
      Fukui, Japan
    • Year and Date
      2005-11-13
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 3c-SiC/Si(111)構造基板上への高品質InN膜のMOVPE成長2005

    • Author(s)
      趙 明秀
    • Organizer
      電子情報通信学会技術研究報告
    • Place of Presentation
      福井市,福井県
    • Year and Date
      2005-11-12
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] CP_2Mgを用いたMOVPE成長InN膜へのMgドーピング効果2005

    • Author(s)
      永井泰彦
    • Organizer
      電子情報通信学会技術研究報告
    • Place of Presentation
      草津市,滋賀県
    • Year and Date
      2005-10-13
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] "MOVPE growth of high quality InN on Si(LLL) substrates" (in Japanese)2005

    • Author(s)
      M.S. Cho, N. Sawazaki, K. Sugita, A. Hashimoto, A. Yamamoto, Y, Ito
    • Organizer
      The 67th Fall Meeting of the Japan Society of Applied Physics
    • Place of Presentation
      Tokushima, Japan
    • Year and Date
      2005-09-09
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Si(111)基板上への高品質InN膜のMOVPE成長2005

    • Author(s)
      趙 明秀
    • Organizer
      第67回応用物理学会学術講演会
    • Place of Presentation
      徳島市,徳島県
    • Year and Date
      2005-09-07
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] A comparative study on MOVPE InN films grow on 3c-SiC/Si(111)and sapphire substrates2005

    • Author(s)
      T. Kobayashi
    • Organizer
      European Materials Research Society 2005 Fall Meeting
    • Place of Presentation
      Warsaw, Poland
    • Year and Date
      2005-09-05
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] A comparative study on MOVPE InN films grow on 3c-SiC/Si(LLL) and sapphire substrates2005

    • Author(s)
      T. Kobayashi, M. S. Cho, N. Sawazaki, A. Hashimoto, A. Yamamoto, Y. Ito
    • Organizer
      European Materials Research Society 2005 FALL MEETING
    • Place of Presentation
      Warsaw, Poland
    • Year and Date
      2005-09-05
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metalorganic vapor phase epitaxial(MOVPE)growth of InN2005

    • Author(s)
      A. Yamamoto
    • Organizer
      INTERNATIONAL CONFERENCE ON METALLURGICAL COATINGS AND THIN FILMS 2005
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2005-05-30
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metalorganic vapor phase epitaxial (MOVPE) growth of InN2005

    • Author(s)
      A. Yamamoto, H. Miwa, A. Hashimoto
    • Organizer
      INTERNATIONAL CONFERENCE ON METALLURGICAL COATINGS AND THIN FILMS 2005
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2005-05-30
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2005-04-01   Modified: 2016-04-21  

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