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The preparation of semiconductor nanoparticles by PLA in water and the their evaluation as functional materials

Research Project

Project/Area Number 17560592
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionThe University of Electro-Communications

Principal Investigator

TANAKA Katsumi  The University of Electro-Communications, Department of Electronic Engineering, Professor (30155121)

Project Period (FY) 2005 – 2006
Project Status Completed (Fiscal Year 2006)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2006: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2005: ¥2,500,000 (Direct Cost: ¥2,500,000)
KeywordsTitania nanoparticles / Pulsed Laser Ablation / PLA in Water / ICP-Mass / Visible Light Response / Environmental Cleaning / Quantum Size Effect / Thin Film / パルスレーザーアプレーション / 微粒子半導体 / 酸化チタン / シリコン微粒子 / 光触媒 / 半導体微粒子 / 可視光応答触媒
Research Abstract

The amount of titanium formed by TiO2 single crystal PLA in water was measured by ICP-mass spectrometry. The PLA yield was evaluated as a function of laser fluence, water thickness, pH and temperature in solution, and acid kind. The yield was mainly controlled by the former two factors and was shown by two equations. The size and behavior of titania particles on the substrate were studied with STM. The size of the particles as small as 4nm was detected and they easily moved on the substrate surface by biased voltage between tip and nano-particles. The bandgap of the thin films was measured to be 3.87 to 4.13eV with diffused reflectance spectroscopy. Such clear bandgap enlargement due to quantum-size effect is quite unique only on these nano-particles. Such blue shift is disadvantage for the photo-catalytic reaction on TiO2. However, the thin films were photo-active to methylene blue degradation not only with ultraviolet but also with >400nm visible light. The fact was interpreted by the impurity levels formed in between the enlarged bandgap such as nitrogen involved by PTA in water. Probably high concentration of impurity in nanoparticles play significant role on producing much holes active for photo-oxidation with visible light.

Report

(3 results)
  • 2006 Annual Research Report   Final Research Report Summary
  • 2005 Annual Research Report
  • Research Products

    (9 results)

All 2007 2006 2005

All Journal Article (5 results) (of which Peer Reviewed: 2 results) Presentation (2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Deposition of Pottasium-oxygen on Silicon Surfaces by Pulsed Laser Ablation of Pottasium Superoxide : Study of Work Function Changes2006

    • Author(s)
      C.K.Choo, D.Suzawa, K.Tanaka
    • Journal Title

      Surface Science 600

      Pages: 1518-1525

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Deposition of Pottasium-oxygen on Silicon Surfaces by Pulsed Laser Ablation of Pottasium Superoxide : Study of Work Function Changes2006

    • Author(s)
      C-K.Choo, D.Suzawa, K.Tanaka
    • Journal Title

      Surface Science 600

      Pages: 1518-1525

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Journal Article] Deposition of Potassium-oxygen on Silicon Surfaces by Pulsed Laser Ablation of Potassium Superoxide : Study of Work Function Changes2006

    • Author(s)
      C.-K.Choo, D.Suzawa, K.Tanaka
    • Journal Title

      Surface Science Vol 600

      Pages: 1518-1525

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Time-resolved Photoluminescence Spectra of Si Species Encapsulated in Zeolite Supercages2005

    • Author(s)
      K.Tanaka, Y.Komatsu, C-K.Choo
    • Journal Title

      Journal of Physical Chemistry B 109

      Pages: 736-742

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Time-resolved Photoluminescence Spectra of Si Species Encapsulated in Zeolite Supercages2005

    • Author(s)
      K.Tanaka, Y.Komatsu, C-K.Choo
    • Journal Title

      Journal of Physical Chemistry B109

      Pages: 736-742

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] 水中レーザアブレーション法で作製したチタニア微粒子によるメチレンブルー光分解反応2005

    • Author(s)
      高尾誠、チュウチャオキョン、田中勝己
    • Organizer
      第25回日本表面科学講演大会
    • Place of Presentation
      大宮市
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Presentation] Methylene Blue Photodecomposition Reaction by Titania particles Prepared with Pulsed Laser Ablation in Water2005

    • Author(s)
      Makoto Takao, Cheow-Keong Choo, Katsumi Tanaka
    • Organizer
      25th Meeting of The Surface Scienece Society of Japan
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] 酸化チタン薄膜の製造方法及び酸化チタン薄膜を有する樹脂製品2007

    • Inventor(s)
      又賀純一郎, チュウチャオキョン, 田中勝己, 松田則夫
    • Industrial Property Rights Holder
      国立大学法人 電気通信大学
    • Industrial Property Number
      2007-106277
    • Filing Date
      2007-04-13
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary
  • [Patent(Industrial Property Rights)] アナターゼ型酸化チタン微粒子及びアナターゼ型酸化チタン微粒子の製造方法2007

    • Inventor(s)
      チュウ チャオキョン, 田中勝己
    • Industrial Property Rights Holder
      国立大学法人 電気通信大学
    • Industrial Property Number
      2007-210787
    • Filing Date
      2007-08-13
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2006 Final Research Report Summary

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Published: 2005-04-01   Modified: 2016-04-21  

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