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Gas Phase Synthesis of Non-Agglomerated Nanoparticles Using Coulombic Repulsive Force

Research Project

Project/Area Number 17560677
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionOsaka Prefecture University

Principal Investigator

ADACHI Motoaki  Osaka Prefecture University, Graduate School of Engineering, Professor (40100177)

Co-Investigator(Kenkyū-buntansha) TSUKUI Shigeki  Osaka Prefecture University, Graduate School of Engineering, Assistant Professor (40207353)
Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥240,000)
Fiscal Year 2007: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2006: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2005: ¥1,800,000 (Direct Cost: ¥1,800,000)
KeywordsNanoparticle / Gas phase synthesis / Ionization / Maenetic narticles / CVD
Research Abstract

Ionization CVD method has been developed to form fast nanparticle films which non-agglomerated particles are deposited widely and uniformly on a substrate with a high number density. SiO_2 and Co nanoparticles have been synthesized from tetraethylorthosilicate (TEOS) and cobalt tricarbonyl nitrosyl (CoTN), respectively, by the developed synthesis apparatus. Following results have been obtained.
(1) SiO_2 nanoparticles
(1) Non-agglomerated and negatively charged SiO2 particles with 10 nm diameter are deposited uniformly with particle number density of 10^<10> cm^<-2> on Si substrate of 14x14 mm^2 area in the deposition time of 40 s.
(2) Non-agglomerated SiO_2 particles with 20 nm diameter are deposited selectively on positively charged lines drew by the contact charging method. The length, wide, and number density of the nanoparticle lines are 10 mm, 500 nm and 4x10^<10> cm^<-2>.
(2)Co nanoparticles
(1) Non-agglomerated Co particles with 14 nm diameter are deposited uniformly with particle number density of 10^<11> cm^<-2> on Si substrate of 20x20 mm^2 area
(2) Co nanoparticles synthesized are ferromagnetic.
(3) Co nanoparticle films formed on a Si substrate coated with a thermal oxide film show a magnetic resistance.

Report

(4 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (50 results)

All 2008 2007 2006 2005

All Journal Article (26 results) (of which Peer Reviewed: 7 results) Presentation (20 results) Book (4 results)

  • [Journal Article] 帯電ナノ液滴の合成とその大腸菌殺菌効果2007

    • Author(s)
      溝田 樹容子、古田 雅一、足立 元明
    • Journal Title

      日本防菌防徽学会誌 35

      Pages: 639-645

    • NAID

      10019822221

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Generation of Charge Nanodroplets and Their Sterilization Effect on Escherichia coli2007

    • Author(s)
      K. Mizota, M. Furuta, M. Adachi
    • Journal Title

      Bokin Bobai 35, 10

      Pages: 639-645

    • NAID

      10019822221

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] 帯電ナノ液滴の合成とその大腸菌殺菌効果2007

    • Author(s)
      溝田 樹容子, 古田 雅一, 足立 元明
    • Journal Title

      日本防菌防徽学会誌 35

      Pages: 639-645

    • NAID

      10019822221

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 帯電ナノ液滴による大腸菌殺菌2007

    • Author(s)
      足立 元明
    • Journal Title

      月刊クリーンテクノロジー 17

      Pages: 55-58

    • Related Report
      2007 Annual Research Report
  • [Journal Article] Synthesis of the Bi-2222 Compounds of Bi-Sr-Ln(Zr)-Cu-O(Ln=Sm,Eu,Gd,and Dy),2007

    • Author(s)
      H.Sasakura, Y.Akagi, S.Tsukui, T.Oka, M.Adachi
    • Journal Title

      J, Superconduct 20

      Pages: 383-386

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of the Ru-1232 compounds in the RuSr_2(Nd_<1-x>DY_xCe_<1.8>Sr_<0.2>)Cu_2 O_2 system2007

    • Author(s)
      Y.Akagi, H.Sasakura, S.Tsukui, T.Oka, M.Adachi
    • Journal Title

      Physica C 463-465

      Pages: 190-193

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge Control by Ions and Electrons2006

    • Author(s)
      M. Adachi, K.Okuyama
    • Journal Title

      Powder Technology Handbook 3rd Edition (ed. H.Masuda, K.Higashitani and Yoshida) 465-473

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Patterning of nanoparticles on substrate by cluster ion deposition method2006

    • Author(s)
      Shirai, H, M. Adachi
    • Journal Title

      Proc. of 2006 International Aerosol Conference

      Pages: 166-166

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Size control of nanoparticles in pulsed laser deposition2006

    • Author(s)
      Kiaihara, S., S.Tsukui, T.Oka, M.Adachi
    • Journal Title

      Proc. of 2006 International Aerosol Conference

      Pages: 650-650

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Generation of nanodroplets and its effect of inactivating E. coli2006

    • Author(s)
      Mizota, K., M.Adachi, M.Furuta
    • Journal Title

      Proc. of 2006 International Aerosol Conference

      Pages: 941-941

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Ion mobility changes in differential mobility analyzer at various humidity2006

    • Author(s)
      Yokoyama, N., M. Adachi
    • Journal Title

      Proc. of 2006 International Aerosol Conference

      Pages: 1617-1617

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 交流電圧による静電噴霧を用いたZnSナノ粒子合成装置の開発2006

    • Author(s)
      横山奈津子, 金丸真広, 足立元明
    • Journal Title

      粉体工学会誌 43・3

      Pages: 181-181

    • NAID

      10017330601

    • Related Report
      2006 Annual Research Report
  • [Journal Article] 交流高電圧を用いた新しい静電噴霧法2006

    • Author(s)
      金丸真広, 横山奈津子, 足立元明
    • Journal Title

      エアロゾル研究 21・3

      Pages: 233-233

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Patterning of nanoparticles on substrate by cluster ion deposition method2006

    • Author(s)
      Shirai, H, M.Adachi
    • Journal Title

      Proc. of 2006 International Aerosol Conference (accepted)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Size control of nanoparticles in pulsed laser deposition2006

    • Author(s)
      Kiaihara, S., S.Tsukui, T.Oka, M.Adachi
    • Journal Title

      Proc. of 2006 International Aerosol Conference (accepted)

    • Related Report
      2005 Annual Research Report
  • [Journal Article] 交流電圧による静電噴霧を用いたZnSナノ粒子合成装置の開発2006

    • Author(s)
      横山奈津子, 金丸真広, 足立元明
    • Journal Title

      粉体工学会誌 (掲載決定)

    • NAID

      10017330601

    • Related Report
      2005 Annual Research Report
  • [Journal Article] イオンを利用したナノ粒子の合成2005

    • Author(s)
      足立 元明
    • Journal Title

      静電気学会誌 29

      Pages: 194-199

    • NAID

      10016682842

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Generation of nanoparticles and nanodroplets by ion-induced nucleation2005

    • Author(s)
      Adachi, M., M.:Kusumi, M.Furuta and S.Tsukui
    • Journal Title

      Advanced Powder Technology 16

      Pages: 549-559

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] An experimental study of ion-induced nucleation using a drift tube ion mobility spectrometer/mass spectrometer and acluster-differelltial mobihty analyzer/faraday cup electrometer2005

    • Author(s)
      Nagato, K., C.S.Kim, M.Adachi, K.Okuyama
    • Journal Title

      J.Aerosol Science 36

      Pages: 1036-1049

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Nanoparticle Synthesis Using Ions2005

    • Author(s)
      M. Adachi
    • Journal Title

      J. the Institute of Electrostatics Japan 29, 4

      Pages: 194-199

    • NAID

      10016682842

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Gegenation of nanoparticles and nanodroplets by ion-induced nucleation2005

    • Author(s)
      M. Adachi, M. Kusumi, M. Furuta, S. Tsukui
    • Journal Title

      Advanced Powder Technology 16, 5

      Pages: 549-559

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] An experimental study of ion-induced nucleation using a drift tube ion mobility spectrometer/mass spectrometer and a cluster-differential mobility analyzer/faraday cup electrometer2005

    • Author(s)
      Nagato, K. C.S. Kim, M. Adachi, K. Okuyama
    • Journal Title

      J. Aerosol Science 36

      Pages: 1036-1049

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Pulse Charging", "Charging", "Electrical Mobility Analyzer2005

    • Author(s)
      M. Adachi
    • Journal Title

      Kagaku Kogaku Giten 87-88, 334

      Pages: 392-393

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Gegenation of nanoparticles and nanodroplets by ion-induced nucleation2005

    • Author(s)
      Adachi, M., M.Kusumi, M.Furuta, S.Tsukui
    • Journal Title

      Advanced Powder Technol. 16

      Pages: 549-559

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Arrangement of nanoparticles on substrate by cluster ion deposition method2005

    • Author(s)
      Adachi, M., Y.Ikari
    • Journal Title

      Proc. of 2^<nd> Int. Sym. Nanotechnology and Occupational Health

      Pages: 41-41

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Desing of nanoparticle charger2005

    • Author(s)
      Kanamarru, M., M.Adachi
    • Journal Title

      Proc. of European Aerosol Conference 2005

      Pages: 151-151

    • Related Report
      2005 Annual Research Report
  • [Presentation] オン化CVD法によるCoナノ粒子の合成と配列2008

    • Author(s)
      畑本 章雄、白井 浩之、木下 卓也、足立 元明
    • Organizer
      化学工学会第73年会
    • Place of Presentation
      浜松
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Synthesis and Arrangement of Cobalt nanoparticles by Ionization CVD Method2008

    • Author(s)
      A. Hatamoto, H. Shirai, T. Kinosita, M. Adachi
    • Organizer
      Annual meeting of the Society of Chemical Engineering Japan
    • Place of Presentation
      Hamamatu
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Fabrication of Thin Film Electrodes and Electrolytes of SOFC2007

    • Author(s)
      S. Tsukui, M. Otani, K. Yoshida, K. Sagara, T. Oka, and M. Adachi
    • Organizer
      International Symposium on Innovative Materials for Process in Energy Systems
    • Place of Presentation
      Kyoto,Japan
    • Year and Date
      2007-10-10
    • Related Report
      2007 Annual Research Report
  • [Presentation] Numerical Model for Particle Formation in Laser Ablation Plasma2007

    • Author(s)
      S. Kaihara, M. Adachi and S. Tsukui
    • Organizer
      The 5th Asian Aerosol Confbrence
    • Place of Presentation
      Kaohsiung,Taiwan
    • Year and Date
      2007-08-29
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Cobalt nanoparticles and Patteming on Substrate by Ionization CVD Method.2007

    • Author(s)
      Shirai, H and M. Adachi
    • Organizer
      The 5th Asian Aerosol Conference
    • Place of Presentation
      Kaohsiung,Taiwan
    • Year and Date
      2007-08-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] Theoretical Estimation of Mixing type Bipolar Charger2007

    • Author(s)
      K. Mizota, M. Adachi, S. Kimoto, H. Okuda and D. Okuda
    • Organizer
      The 5th Asian Aerosol Conference
    • Place of Presentation
      Kaohsiung,Taiwan
    • Year and Date
      2007-08-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] Real Time Measurement of Diesel Exhaust particle by Transient-DMA Using High-Concentration Bipolar Charger2007

    • Author(s)
      S. Kimoto, H. Okuda, T. Kawai, D. Kawano, H. Yamada, M. Adachi and D. Okuda
    • Organizer
      The 5th Asian Aerosol Conference
    • Place of Presentation
      Kaohsiung,Taiwan
    • Year and Date
      2007-08-27
    • Related Report
      2007 Annual Research Report
  • [Presentation] Synthesis of Cobalt nanoparticles and Patterning on Substrate by Ionization CVD Method2007

    • Author(s)
      Shirai, H., and M.Adachi
    • Organizer
      5th Asian Aerosol Conference
    • Place of Presentation
      Kaohsiung
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] クラスターイオン沈着法による基板へのナノ粒子配列2006

    • Author(s)
      足立 元明、白井 浩之
    • Organizer
      2006年静電気学会
    • Place of Presentation
      堺
    • Year and Date
      2006-08-09
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Generation of Nanodroplets and Its Effect of Inactivating E.coli2006

    • Author(s)
      Mizota, K., M.Adachi and M.Furuta
    • Organizer
      7th International Aerosol Conference
    • Place of Presentation
      Minneapolis
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Patterning of Nanoparticles on Substrate by Cluster Ion Deposition Method2006

    • Author(s)
      Shirai, H., and M.Adachi
    • Organizer
      7th International Aerosol Conference
    • Place of Presentation
      Minneapolis
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Ion Mobihty Changes in Differential Mobility Analyzer at Various Humiduty2006

    • Author(s)
      Yokoyama, N.and M.Adachi
    • Organizer
      7th International Aerosol Conference
    • Place of Presentation
      Minneapolis
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] クラスターイオン沈着法による基板へのナノ粒子配列2006

    • Author(s)
      足立 元明、白井 浩之
    • Organizer
      第23回エアロゾル化学・技術研究討論会
    • Place of Presentation
      福岡
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Patterning of Nanoparticles on Substarte by Cluster Ion Deposition Method2006

    • Author(s)
      M. Adachi, H. Shirai
    • Organizer
      2006 Annual Meeting of the Institute of Electrostatic Japan
    • Place of Presentation
      Sakai
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Ion Mobility Changes in Differential Mobility Analyzer at Various Humiduty2006

    • Author(s)
      Yokoyama, N. M. Adachi
    • Organizer
      7th International Aerosol Conference
    • Place of Presentation
      Minneapolis
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Arrangement of Nanoparticles on Substarte by Cluster Ion Deposition Method2006

    • Author(s)
      M. Adachi, H. Shirai
    • Organizer
      The 23rd Symposium on Aerosol Science & Tchnology
    • Place of Presentation
      Fukuoka
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Novel measurement method for ion-induced nucleation2005

    • Author(s)
      Adachi, M.and N.Yokoyama
    • Organizer
      4th Asian Aerosol Conference
    • Place of Presentation
      Mumbai
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Arrangement of nanoparticles on substrate by cluster ion deposition method2005

    • Author(s)
      Adachi, M., Y.Ikari
    • Organizer
      2nd Int.Sym.Nanotechnology and Occupa-tional Health
    • Place of Presentation
      Minneapolis
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Novel Measurement Method for Ion-Induced Nucleation2005

    • Author(s)
      Adachi, M. N.Yokoyama
    • Organizer
      4th Asian Aerosol Conference
    • Place of Presentation
      Mumbai
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Arrangement of Nanoparticles on Substrate by Cluster Ion Deposition Method2005

    • Author(s)
      Adachi, M. Y. Ikari
    • Organizer
      2nd International Symposium on Nanotechnology and Occupational Health
    • Place of Presentation
      Minneapolis
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] エアロゾルの大気環境影響(笠原三紀夫・東野達編)2007

    • Author(s)
      足立 元明
    • Publisher
      京都大学出版会
    • Related Report
      2007 Annual Research Report
  • [Book] Powder Technology Handbook 3rd Edition (ed.H.Masuda, K.Higashitani and Yoshida)2006

    • Author(s)
      M.Adachi and K.Okuyama
    • Total Pages
      889
    • Publisher
      Marcel Dekker,lnc.
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Book] Powder Technology Handbook 3^<rd> Edition2006

    • Author(s)
      M.Adachi, K.Okuyama
    • Total Pages
      889
    • Publisher
      Marcel Dekker, Inc.
    • Related Report
      2005 Annual Research Report
  • [Book] 化学工学辞典(化学工学辞典編集委員会)2005

    • Author(s)
      足立 元明
    • Total Pages
      606
    • Publisher
      丸善
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary

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Published: 2005-04-01   Modified: 2025-11-20  

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