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Construction of Phthalocyanine-Based Solid Phase Tags and Their Utility for Synthetic Organic Chemistry

Research Project

Project/Area Number 17590018
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Chemical pharmacy
Research InstitutionMeiji Pharmaceutical University

Principal Investigator

TAKANAMI Toshikatsu  Meiji Pharmaceutical University, Faculty of Pharmaceutical Sciences, Associate Professor (40241111)

Co-Investigator(Kenkyū-buntansha) SUDA Kohji  Meiji Pharmaceutical University, Faculty of Pharmaceutical Sciences, Professor (00087785)
Project Period (FY) 2005 – 2007
Project Status Completed (Fiscal Year 2007)
Budget Amount *help
¥3,810,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥210,000)
Fiscal Year 2007: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2006: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2005: ¥1,700,000 (Direct Cost: ¥1,700,000)
Keywordsphthalocyanine / recycling and reuse / epoxide / aldehyde / Claisen rearrangement / cyanoporphyrin / zinc porphyrin dimer / rearrangement / π拡張ポルフィリン / リサイクル / 機能性固相担体 / NHK反応 / ホルミル化 / シリルメチルリチウム / 根岸クロスカップリング / 金属フタロシアニン / 金属ポルフィリン / [3,3]シグマトロピー転位 / 三置換エポキシド
Research Abstract

A broad range of topics of porphyrin and phthalocyanine chemistry including construction of phthalocyanine-based solid phase tags were studied. The results obtained are summarized as follows.
1. A metallophthalocyanine complex, Cr(TBPC) OTf works as an efficient Lewis acid catalyst that can promote the regio- and stereoselective rearrangement of epoxides to aldehydes. It shows not only high efficiencies in yields and selectivities, but also excellent reusability, in the catalysis, which enables practical synthesis of enantio-enriched aldehydes bearing a stereogenic quatemary carbon center from optically active tri-substituted epoxides.
2 The catalytic Z-selective Claisen rearrangement of simple aliphatic allyl vinyl ethers can be realized using a chromium(III) porphyrin complex, Cr(IPP) C1, as a catalyst Cr(TPP) Cl significantly enhances reversal of E/Z selectivity in the thermal Claisen rearrangement of allyl vinyl ethers at low catalyst loading
3. We have developed the first method that … More achieves catalytic mono-and dicyanation of porphyrins. These palladium-catalyzed cyanation reactions utilizing cyanoethyl zinc bromide as an efficient cyanide ion source are compatible with an array of porphyrins.
4. A simple one-pot procedure that converts 5, 15-substituted porphyrins into the corresponding meso formylated porphyrins has been developed. The method, based on a new synthetic concept for functionalized porphyrins utilizing the(2-pyridyl-dimethylsilyl) methyl group as a latent formyl functionality, affords desired product in good yield.
5. A series of mono-and bis-functionalized meso-substituted porphyrins bearing chemically reactive functional groups in the alkyl substituents at the meso positions were efficiently synthesized by the reactions of meso-brominated precursors with alkylzinc reagents via palladium-catalyzed Negishi cross-coupling.
6. A new supramolecular chirogenic system on the basis of zinc porphyrin dimers and various enantiopure organic molecules, which was specifically designed for investigation of the chirogenic phenomenon upon extremely weak interaction modes and marginal chiroptical responses, is studied. Less

Report

(4 results)
  • 2007 Annual Research Report   Final Research Report Summary
  • 2006 Annual Research Report
  • 2005 Annual Research Report
  • Research Products

    (49 results)

All 2008 2007 2006 2005 Other

All Journal Article (17 results) (of which Peer Reviewed: 8 results) Presentation (30 results) Remarks (2 results)

  • [Journal Article] One-Pot Synthesis of meso-Formylporphyrins by S_NAr Reaction of 5,15-Disubstituted2008

    • Author(s)
      Takanami, T.;Wakita, A.;Sawaizumi, A.;Iso, K.;Onodera, H.;Suda, K.
    • Journal Title

      Org. Lett. 10

      Pages: 685-687

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] A Facile and Efficient Synthesis of Mono- and Bis-Functionalized meso-Substituted Porphyrins via Palladium-Catalyzed Negishi Cross-Coupling2008

    • Author(s)
      Takanami, T.;Yotsukura, M.;Inoue, W.;Inoue, N.;Hino, F.;Suda, K.
    • Journal Title

      Heterocycles 76

    • NAID

      40016208584

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] One-Pot Synthesis of meso-Formylporphyrins by SNAr Reaction of 5, 15-Disubstituted Porphyrins with(2-Pyridyldimethylsilyl) methyPlithium2008

    • Author(s)
      Takanami, T.; Wakita, A.; Sawaizumi, A.; Iso, K.; Onodera, H.; Suda, K.
    • Journal Title

      Org. Lett. 10

      Pages: 685-687

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] One-Pot Synthesis of meso-Formylporphyrins by SNAr Reaction of 5,15-Disubstituted Porphyrins with (2-Pyridyldimethylsnyl)methyllithium2008

    • Author(s)
      T.Takanami, A.Wakita, A.Sawaizumi, K.Iso, H.Onodera, K.Suda
    • Journal Title

      Org.Lett 10

      Pages: 685-687

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Facile and Efficient Synthesis of Mono-and Bis-Functiollalized meso-Substituted Porphyrins via Palladium-Catalyzed Negishi Cross-Coupling2008

    • Author(s)
      T.Takanami, M.Yotsukura, W.Inoue, N.Inoue, F.Hino, K.Suda
    • Journal Title

      HETEROCYCLES 76

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 対面型不斉ダブルデッカーポルフィリン触媒の開発とその合成化学的応用に関する研究2007

    • Author(s)
      高波 利克
    • Journal Title

      明治薬科大学研究紀要 36

      Pages: 83-85

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Development of facing-type double-decker porphyrin catalysts and their applications in synthetic chemistry2007

    • Author(s)
      Takanami, T.
    • Journal Title

      Meiji Yakka Daigaku Kenkyu Kiyo 36

      Pages: 83-85

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Highly Regioselective [3,3] Rearrangement of Aliphatic Allyl Vinylethers Catalyzed by a Metalloporphyrin Complex, Cr(TPP)Cl2006

    • Author(s)
      Takanami, T.;Hayashi, M.;Iso, K.;Nakamoto, H.;Suda, K.
    • Journal Title

      Tetrahedron 62

      Pages: 9467-9474

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Highly Regioselective [3,31 Rearrangement of Aliphatic Allyl Vinylethers Catalyzed by a Metalloporphyrin Complex, Cr(TPP) Cl2006

    • Author(s)
      Takanami, T.; Hayashi, M.; Iso, K.; Nakamoto, H.; Suda, K.
    • Journal Title

      Tetrahedron 62

      Pages: 9467-9474

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Highly Regioselective [3,3] Rearrangement of Aliphatic Allyl Vinylethers Catalyzed by a Metalloporphyrin Complex,Cr(TPP)Cl2006

    • Author(s)
      T.Takanami, M.Hayashi, K.Iso, H.Nakamoto, K.Suda
    • Journal Title

      Tetrahedron 62

      Pages: 9467-9474

    • Related Report
      2006 Annual Research Report
  • [Journal Article] Metalloporphyrin Cr(TPP)Cl-Catalyzed Claisen Rearrangement of Simple Aliphatic Allyl Vinyl Ethers and Its Unique Stereoselectivity2005

    • Author(s)
      Takanami, T.;Hayashi, M.;Suda K.
    • Journal Title

      Tetrahedron Lett. 46

      Pages: 2893-2896

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Cyanation of Porphyrins Utilizing Cyanoethylzinc Bromide as an Efficient Cyanide Ion Source2005

    • Author(s)
      Takanami, T.;Hayashi, M.;Chijimatsu, H.;Inoue, W.;Suda, K.
    • Journal Title

      Org. Lett. 7

      Pages: 3937-3940

    • NAID

      130006996507

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
    • Peer Reviewed
  • [Journal Article] Metalloporphyrin Cr(TPP) C1-Catalyzed Claisen Rearrangement of Simple Aliphatic Allyl Vinyl Ethers and Its Unique Stereoselectivity2005

    • Author(s)
      Takanami, T.; Hayashi, M.; Suda K.
    • Journal Title

      Tetrahedron Lett. 46

      Pages: 2893-2896

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Palladium-Catalyzed Cyanation of Porphyrins Utilizing Cyanoethylzinc Bromide as an Efficient Cyanide Ion Source2005

    • Author(s)
      Takanami, T.; Hayashi, M.; Chijimatsu, H.; Inoue, W.; Suda, K.
    • Journal Title

      Org. Lett. 7

      Pages: 3937-3940

    • NAID

      130006996507

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Journal Article] Metalloporphyrin Cr (TPP) Cl-catalyzed Claisen Rearrangement of Simple Aliphatic Allyl Vinyl Ethers and Its Unique Stereoselectivity2005

    • Author(s)
      T.Takanami, M.Hayashi, K.Suda
    • Journal Title

      Tetrahedron Lett. 46

      Pages: 2893-2896

    • Related Report
      2005 Annual Research Report
  • [Journal Article] Palladium-Catalyzed Cyanation of Porphyrins Utilizing Cyanoethylzinc Bromide as an Efficient Cyanide Ion Source2005

    • Author(s)
      T.Takanami, M.Hayashi, H.Chijimatsu, W.Inoue, K.Suda
    • Journal Title

      Org.Lett. 7

      Pages: 3937-3940

    • NAID

      130006996507

    • Related Report
      2005 Annual Research Report
  • [Journal Article] A Facile and Efficient Synthesis of Mono-and Bis-Functionalized meso-Substituted Porphyrins via Palladium-Catalyzed Negishi Cross-Coupling

    • Author(s)
      Takanaqii, T.; Yotsukura, M.; Inoue, w.; Innue, N.; Hino, K; Suda, K.
    • Journal Title

      Heterocycles (COM-08-S(N) 25)(in press)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] ポルフィリンとシリルメチルリチウムとの反応:反応性の異なる二つのカルボニル基を持つ非対称ポルフィリンのone-pot合成2008

    • Author(s)
      高波 利克、脇田 篤、磯和 宏、日野 文男、須田 晃治
    • Organizer
      日本薬学会第128年会
    • Place of Presentation
      横浜
    • Year and Date
      2008-03-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Annual Research Report 2007 Final Research Report Summary
  • [Presentation] (2-Pyridyldimethylsilyl)methyl LithiumとのSNAr型反応を用いるmeso-ホルミル及びmesaヒドロキシメチルポルフィリンの合成2007

    • Author(s)
      高波 利克、脇田 篤、澤泉 青代、磯 和宏、小野寺 秀俊、須田 晃治
    • Organizer
      第33回反応と合成のシンポシンポジウム
    • Place of Presentation
      長崎
    • Year and Date
      2007-11-15
    • Related Report
      2007 Annual Research Report
  • [Presentation] (2-Pyridyldimethylsily)methyl Lithium とのS_NAr型反応を用いるmeso-ホルミル及びmeso-ヒドロキシメチルポルフィリンの合成2007

    • Author(s)
      高波 利克、脇田 篤、澤泉 青代、磯和 宏、小野寺 秀俊、須田 晃治
    • Organizer
      第33回反応と合成の進歩シンポジウム
    • Place of Presentation
      長崎
    • Year and Date
      2007-11-05
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] One-pot Synthesis of meso-Formyl-Substituted Free Base Porphyrins via S_NAr Aliphatic Reactions with (Trialkylsilyl)methyllithium Reagents2007

    • Author(s)
      Takanami, T.;Iso, K.;Sawaizumi, A.;Hayashi, M.;Suda, K.
    • Organizer
      21st International Congress of Heterocyclic Chemistry
    • Place of Presentation
      Sydney,Australia
    • Year and Date
      2007-07-17
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] One' pot Synthesis of meso-Formyl-Substituted Free Base Porphyrins via SNAr Aliphatic Reactions with(Trialkylsilyl) -methyllithium Reagents2007

    • Author(s)
      Takanami, T.; Iso, K.; Sawaizumi, A.; Hayashi, M.; Suda, K.
    • Organizer
      21st International Congress of Heterocyclic Chemistry
    • Place of Presentation
      Sydney, Austrralia
    • Year and Date
      2007-07-17
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] One-pot Synthesis of meso-Formyl-Substituted Free Base Porphyrins via SNAr Reactions with(Trialkylsilyl)methyllithium Reagents2007

    • Author(s)
      T.Takanami, KIso, A.Sawaizumi, M.Hayashi, K.Suda
    • Organizer
      21ST INTERNATIONAL CONGRESS FOR HETEROCYCHC CHEMISTRY
    • Place of Presentation
      Sydney,AUSTRALIA
    • Year and Date
      2007-07-17
    • Related Report
      2007 Annual Research Report
  • [Presentation] 対面型ポルフィリン二量体の構築とその不斉認識能2007

    • Author(s)
      高波 利克, 四倉 未来, 井上 わか葉, 小林 茂, 須田 晃治
    • Organizer
      日本薬学会第127年会
    • Place of Presentation
      富山
    • Year and Date
      2007-03-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 反応性の異なる二つのカルボニル基を持つ非対称ポルフィリンのone-pot合成2007

    • Author(s)
      高波 利克、脇田 篤、磯和 宏、須田 晃治
    • Organizer
      日本薬学会第127年会
    • Place of Presentation
      富山
    • Year and Date
      2007-03-29
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シアノエチルZnBrをシアノ源として用いるポルフィリン環への新規シアノ基導入反応2006

    • Author(s)
      高波 利克, 林美 樹子, 岩田 康寛, 千々松 洋志, 井上 わか葉, 須田 晃治
    • Organizer
      第32回反応と合成の進歩シンポジウム
    • Place of Presentation
      広島
    • Year and Date
      2006-12-05
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] meso位を鎖状構造で連結した対面型ポルフィリン二量体の構築とその分子認識能2006

    • Author(s)
      高波 利克、四倉 未来、井上 わか葉、小林 茂、須田 晃治
    • Organizer
      第36回複素環化学討論会
    • Place of Presentation
      長崎
    • Year and Date
      2006-11-23
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metalloporphyrin Cr(TPP)Cl-Catalyzed Claisen Rearrangement of Simple Aliphatic Allyl Vinyl Ethers2006

    • Author(s)
      Suda, K.;Hayashi, M.;Takanami, T.
    • Organizer
      The 10th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-10)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2006-11-16
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シリルメチルリチウム反応剤を用いるポルフィリンのone-pot非対称官能基化反応2006

    • Author(s)
      高波 利克、脇田 篤、磯和 宏、須田 晃治
    • Organizer
      第50回日本薬学会関東支部大会
    • Place of Presentation
      新潟
    • Year and Date
      2006-10-15
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Pd触媒を用いた無金属ポルフィリンの一級アミノ化2006

    • Author(s)
      林美 樹子、仲本 広世、日野 文男、高波 利克、須田 晃治
    • Organizer
      日本薬学会第126年会
    • Place of Presentation
      仙台
    • Year and Date
      2006-03-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シリルメチルリチウム反応剤及びエノン類によるポルフィリンのone-pot非対称官能基化反応2006

    • Author(s)
      高波 利克、磯和 宏、林美 樹子、須田 晃治
    • Organizer
      日本薬学会第126年会
    • Place of Presentation
      仙台
    • Year and Date
      2006-03-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 官能基化されたポルフィリンの非対称二量化反応2006

    • Author(s)
      高波 利克、四倉 未来、小林 茂、井上 わか葉、須田 晃治
    • Organizer
      日本薬学会第126年会
    • Place of Presentation
      仙台
    • Year and Date
      2006-03-28
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 単純な鎖状リンカーで連結された対面型ポルフィリン二量体の構築とその超分子CD励起子キラリティー法への応用2005

    • Author(s)
      高波 利克、井上 わか葉、小林 茂、林美 樹子、中島 伸一郎、須田 晃治
    • Organizer
      第31回反応と合成の進歩シンポジウム
    • Place of Presentation
      神戸
    • Year and Date
      2005-11-07
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Construction of Bis(zinc porphyrin) and Its Application for the Direct Determination of Absolute Configuration of Monoalcohols2005

    • Author(s)
      Takanami, T.; Inoue, W.; Kobayashi, S.; Hayashi, M.; Nakajima, S.; Suda, K.
    • Organizer
      31st Symposium on Progress in Organic Reactions and Syntheses
    • Place of Presentation
      Kobe
    • Year and Date
      2005-11-07
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 金属フタロシアニン錯体 Cr(PC)OTfをルイス酸触媒として用いるエポキシドのアルデヒドへの位置・立体選択的転位反応2005

    • Author(s)
      高波 利克、佐藤 弥随臨、中島 伸一郎、須田 晃治
    • Organizer
      第35回複素環化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2005-10-27
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Highly Regio- and Stereoselective Rearrangement of Epoxides to Aldehydes Catalyzed by Phthalocyanine Complex, Cr(tpp) Otf2005

    • Author(s)
      Takanami, T.; Nakajima, S.; Sato, Y.; Suda, K.
    • Organizer
      35th Congress of Heterocyclic Chemistry
    • Place of Presentation
      Osaka
    • Year and Date
      2005-10-27
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Pd触媒を用いたmeso-アミノポルフィリンPor-NH_2の合成2005

    • Author(s)
      林美 樹子、仲本 広世、日野 文男、高波 利克、須田 晃治
    • Organizer
      第49回日本薬学会関東支部大会
    • Place of Presentation
      東京
    • Year and Date
      2005-10-08
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 対面型ポルフィリン二量体の構築とその不斉認識能2005

    • Author(s)
      高波 利克、四倉 未来、井上 わか葉、小林 茂、中島 伸一郎、須田 晃治
    • Organizer
      第49回日本薬学会関東支部大会
    • Place of Presentation
      東京
    • Year and Date
      2005-10-08
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] シリルメチルリチウム反応剤を用いたポルフィリン環への新規ホルミル基導入反応2005

    • Author(s)
      高波 利克、磯和 宏、澤泉 青代、林美 樹子、須田 晃治
    • Organizer
      第49回日本薬学会関東支部大会
    • Place of Presentation
      東京
    • Year and Date
      2005-10-08
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Synthesis of meso-Aminporphyrins via Pd(0) catalysis2005

    • Author(s)
      Hayashi, M.; Nakamoto, H.; Hino, F.; Takanami, T.; Suda, K.
    • Organizer
      The 49th Kanto Branch Meeting of the Pharmaceutical Society of Japan
    • Place of Presentation
      Tokyo
    • Year and Date
      2005-10-08
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metalloporphyrin Complex Cr(TPP)OTf-Catalyzed Regio- and Stereo-selective Rearrangement of Epoxides to Aldehydes2005

    • Author(s)
      Suda, K.;Kikkawa, T.;Nakajima, S.;Takanami, T.
    • Organizer
      20th International Congress of Heterocyclic Chemistry
    • Place of Presentation
      Palermo,Italy
    • Year and Date
      2005-08-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metalloporphyrin Cr(TPP)Cl Catalyzed Claisen Rearrangement of Simple Aliphatic Allyl Vinyl Ethers and Its Unique Stereoselectivity2005

    • Author(s)
      Takanami, T.;Hayashi, M.;Suda, K.
    • Organizer
      20th International Congress of Heterocyclic Chemistry
    • Place of Presentation
      Palermo,Italy
    • Year and Date
      2005-08-01
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metalloporphyrin Complex Cr(TPP) Otf-Catalyzed Regio-and Stereoselective Rearrangement of Epoxides to Aldehydes2005

    • Author(s)
      Suda, K.; Kikkawa, T.; Nakajima, S.; Takanami, T.
    • Organizer
      20th International Congress of Heterocyclic Chemistry
    • Place of Presentation
      Palermo, Italy
    • Year and Date
      2005-08-01
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metalloporphyrin Cr(TPP) Cl Catalyzed Claisen Rearrangement of Simple Aliphatic Allyl Cinyl Ethers and Its Unique Stereoselectivity2005

    • Author(s)
      Takanami, T.; Hayashi, M.; Suda, K.
    • Organizer
      20th International Congress of Heterocyclic Chemistry
    • Place of Presentation
      Palermo, Italy
    • Year and Date
      2005-08-01
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] 金属ポルフィリン及びフタロシアニン錯体をルイス酸触媒として用いるエポキシドのカルボニル化合物への位置・立体選択的転位反応2005

    • Author(s)
      高波 利克、中島 伸一郎、吉川 武年、佐藤 弥瑞臨、須田 晃治
    • Organizer
      第3回次世代を担う有機化学シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2005-05-21
    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metallophthalocyanine Complex, Cr(TBPC) Otf. An Efficient, Recyclable Lewis Acid Catalyst in the Regio- and Stereoselective Rearrangement of Epoxides to Aldehydes2005

    • Author(s)
      Takanami, T.; Nakajima, S.; Kikkawa, T.; Sato, Y.; Suda, K.
    • Organizer
      3rd Symposium on Organic Chemistry-the ext Generation
    • Place of Presentation
      Tokyo
    • Year and Date
      2005-05-21
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Presentation] Metalloporphyrin Cr(TPP) Cl Catalyzed Claisen Rearrangement of Simple Aliphatic Allyl Vinyl Ethers

    • Author(s)
      Suda, K.; Hayashi, M.; Takanami, T.
    • Organizer
      The 10th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC-10) .
    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2007 Final Research Report Summary
  • [Remarks] 「研究成果報告書概要(和文)」より

    • URL

      http://www.my-pharm.ac.jp/~physchem/

    • Related Report
      2007 Final Research Report Summary
  • [Remarks]

    • URL

      http://www.my-pharm.ac.jp/~physchem/

    • Related Report
      2007 Annual Research Report

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Published: 2005-04-01   Modified: 2016-04-21  

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