Chiral porphyrin complexes for sensing and asymmetric catalysis
| Project/Area Number |
17F17825
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 外国 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | National Institute for Materials Science |
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Principal Investigator |
HILL Jonathan 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主席研究員 (30421431)
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| Co-Investigator(Kenkyū-buntansha) |
PAYNE DANIEL 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
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| Project Period (FY) |
2017-11-10 – 2020-03-31
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| Project Status |
Completed (Fiscal Year 2019)
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| Budget Amount *help |
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2019: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2018: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2017: ¥500,000 (Direct Cost: ¥500,000)
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| Keywords | Porphyrin / Chirality / Dimer / Macrocycle / Self-assembly |
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| Outline of Annual Research Achievements |
Synthesis of chiral binaphthyl porphyrin dimers for guest binding was completed and the work has been published. The compounds were found to be multichannel sensors for enantiomeric excess of chiral compounds. Related work on resorcinarene macrocycles has been completed and published. Those compounds were found useful for sensing acidity and for generation of singlet oxygen. Further allied work on the novel catalytic properties of the compounds has been completed and published.
Other work is ongoing in collaboration with Dr. Payne.
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| Research Progress Status |
令和元年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
令和元年度が最終年度であるため、記入しない。
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Report
(3 results)
Research Products
(12 results)
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[Journal Article] Nanomolecular Singlet Oxygen Photosensitizers based on Hemiquinonoid-resorcinarenes, the Fuchsonarenes2020
Author(s)
Daniel T. Payne, Whitney A. Webre, Habtom Gobese, Yoshitaka Matsushita, Paul A. Karr, Mandeep K. Chahal, Jan Labuta, John S. Fossey, Katsuhiko Ariga, Francis D’Souza, Jonathan P. Hill
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Journal Title
Chemical Science
Volume: 11
Issue: 10
Pages: 2614-2620
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] Multimodal Switching of a Redox-active Macrocycle2019
Author(s)
Daniel T. Payne, Whitney A. Webre, Yoshitaka Matsushita, Nianyong Zhu, Zdenek Futera, Jan Labuta, Wipakorn Jevasuwan, Naoki Fukata, John S. Fossey, Francis D’Souza, Katsuhiko Ariga, Wolfgang Schmitt, Jonathan P. Hill
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Journal Title
Nature Communications
Volume: 10
Issue: 1
Pages: 1007-1007
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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