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Chiral porphyrin complexes for sensing and asymmetric catalysis

Research Project

Project/Area Number 17F17825
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section外国
Research Field Functional solid state chemistry
Research InstitutionNational Institute for Materials Science

Principal Investigator

HILL Jonathan  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主席研究員 (30421431)

Co-Investigator(Kenkyū-buntansha) PAYNE DANIEL  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
Project Period (FY) 2017-11-10 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2019: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2018: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2017: ¥500,000 (Direct Cost: ¥500,000)
KeywordsPorphyrin / Chirality / Dimer / Macrocycle / Self-assembly
Outline of Annual Research Achievements

Synthesis of chiral binaphthyl porphyrin dimers for guest binding was completed and the work has been published. The compounds were found to be multichannel sensors for enantiomeric excess of chiral compounds. Related work on resorcinarene macrocycles has been completed and published. Those compounds were found useful for sensing acidity and for generation of singlet oxygen. Further allied work on the novel catalytic properties of the compounds has been completed and published.
Other work is ongoing in collaboration with Dr. Payne.

Research Progress Status

令和元年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和元年度が最終年度であるため、記入しない。

Report

(3 results)
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (12 results)

All 2020 2019 2018 Other

All Journal Article (6 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 6 results,  Open Access: 2 results) Presentation (5 results) (of which Int'l Joint Research: 3 results) Remarks (1 results)

  • [Journal Article] Diporphyrin tweezer for multichannel spectroscopic analysis of enantiomeric excess2020

    • Author(s)
      Daniel T. Payne, Mandeep K. Chahal, Vaclav Brezina, Whitney A. Webre, Katsuhiko Ariga, Francis D’Souza, Jan Labuta, Jonathan P. Hill
    • Journal Title

      Front. Chem. Sci. Eng.

      Volume: 14 Issue: 1 Pages: 28-40

    • DOI

      10.1007/s11705-019-1869-1

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nanomolecular Singlet Oxygen Photosensitizers based on Hemiquinonoid-resorcinarenes, the Fuchsonarenes2020

    • Author(s)
      Daniel T. Payne, Whitney A. Webre, Habtom Gobese, Yoshitaka Matsushita, Paul A. Karr, Mandeep K. Chahal, Jan Labuta, John S. Fossey, Katsuhiko Ariga, Francis D’Souza, Jonathan P. Hill
    • Journal Title

      Chemical Science

      Volume: 11 Issue: 10 Pages: 2614-2620

    • DOI

      10.1039/d0sc00651c

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Supramolecular Ultrafast Energy and Electron Transfer in a Directly Linked BODIPY-oxoporphyrinogen Dyad upon Fluoride Ion Binding2020

    • Author(s)
      Mandeep K. Chahal, Anuradha Liyanage, Habtom B. Gobeze, Daniel T. Payne, Katsuhiko Ariga, Jonathan P. Hill, Francis D’Souza
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 27 Pages: 3855-3858

    • DOI

      10.1039/d0cc00633e

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Molecular Engineering of β-Substituted Oxoporphyrinogens for Hydrogen-Bond Donor Catalysis2020

    • Author(s)
      Mandeep K. Chahal, Daniel T. Payne, Yoshitaka Matsushita, Jan Labuta, Katsuhiko Ariga, Jonathan P. Hill
    • Journal Title

      Eur. J. Org. Chem.

      Volume: - Issue: 1 Pages: 82-90

    • DOI

      10.1002/ejoc.201901706

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Knock-on synthesis of tritopic calix[4]pyrrole host for enhanced anion interactions2019

    • Author(s)
      Mandeep K. Chahal, Jan Labuta, Vaclav Brezina, Paul A. Karr, Yoshitaka Matsushita, Whitney A. Webre, Daniel T. Payne, Katsuhiko Ariga, Francis D’Souza, Jonathan P. Hill
    • Journal Title

      Dalton Trans.

      Volume: 48 Issue: 41 Pages: 15583-15596

    • DOI

      10.1039/c9dt02365h

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Multimodal Switching of a Redox-active Macrocycle2019

    • Author(s)
      Daniel T. Payne, Whitney A. Webre, Yoshitaka Matsushita, Nianyong Zhu, Zdenek Futera, Jan Labuta, Wipakorn Jevasuwan, Naoki Fukata, John S. Fossey, Francis D’Souza, Katsuhiko Ariga, Wolfgang Schmitt, Jonathan P. Hill
    • Journal Title

      Nature Communications

      Volume: 10 Issue: 1 Pages: 1007-1007

    • DOI

      10.1038/s41467-019-08978-5

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Resorcinarenes as Molecular Switches2019

    • Author(s)
      Daniel T. Payne
    • Organizer
      14th International Symposium on Macrocyclic and Supramolecular Chemistry
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Non-Planar beta-Substituted Porphyrinoids as Hydrogen-Bond Donor Catalysts2019

    • Author(s)
      Daniel T. Payne
    • Organizer
      8th Asian Conference on Colloids and Interface Science
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Oxidation-Induced Isomerisation and hemiquinhydrone complex formation of an Anti-Oxidant-Substituted Resorcinarenes2019

    • Author(s)
      Daniel T. Payne
    • Organizer
      MANA Symposium 2019
    • Related Report
      2018 Annual Research Report
  • [Presentation] Oxidation-Induced Isomerisation and hemiquinhydrone complex formation of an Anti-Oxidant-Substituted Resorcinarenes2018

    • Author(s)
      Daniel T. Payne
    • Organizer
      7th EuChems Chemistry Congress
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Oxidation- Induced Isomerisation of an Anti Oxidant-Substituted Resorcinarene2018

    • Author(s)
      Daniel T. Payne, Katsuhiko Ariga, Jonathan P. Hill
    • Organizer
      MANA International Symposium 2018, Tsukuba International Congress Center
    • Related Report
      2017 Annual Research Report
  • [Remarks] Multimodal Switching of a Redox-active Macrocycle

    • URL

      https://chemistrycommunity.nature.com/users/210279-jonathan-hill/posts/45447-multimodal-switching-of-a-redox-active-macrocycle

    • Related Report
      2018 Annual Research Report

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Published: 2017-11-13   Modified: 2024-03-26  

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