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Dynamically structural control and development of energy-storing type fuel cells based on ionic electronic transport

Research Project

Project/Area Number 17H00801
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Design and evaluation of sustainable and environmental conscious system
Research InstitutionTokyo Institute of Technology (2020)
The University of Tokyo (2017-2019)

Principal Investigator

Otomo Junichiro  東京工業大学, 環境・社会理工学院, 教授 (90322065)

Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥36,270,000 (Direct Cost: ¥27,900,000、Indirect Cost: ¥8,370,000)
Fiscal Year 2020: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2019: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2018: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Fiscal Year 2017: ¥13,260,000 (Direct Cost: ¥10,200,000、Indirect Cost: ¥3,060,000)
Keywords低炭素社会 / 燃料電池 / イオン伝導体 / 酸化還元反応
Outline of Final Research Achievements

In this study, material design was conducted in combination with ionic-electronic transport and dynamic changes in reaction / transport / morphology in redox cycles between charge and discharge, and a new electrochemical system with functions of energy storage and power generation was proposed based on high-performance fuel cell technology. We investigated active materials which enable fast hydrogen generation reaction with ionic and electron transport properties, and developed carrier particles realizing high redox reaction rates and stability. In addition, an extremely efficient proton-conducting ceramic fuel cells (PCFC) was designed, and a prototype cell was developed. Finally, we designed an energy storage fuel cell system consisting of the developed carrier particles and PCFC, and proposed the high-performance and economical system.

Academic Significance and Societal Importance of the Research Achievements

本研究の成果の学術的意義は、イオン、電子輸送物性を制御し、長寿命の酸化還元反応を実現するエネルギー貯蔵型燃料電池システムを設計・提案する点にある。この研究を通じて、金属酸化物の酸化還元反応速度の情報によるシステム全体への影響について明らかにすることができた。さらに、将来の大規模な再生可能エネルギーの導入のよる電力の平準化や、高密度エネルギー貯蔵と高効率なエネルギー変換を同時に満たす新しい技術が必要であり、本研究は、将来のシステム開発に貢献できる内容である。エネルギー密度についても、金属酸化物を用いることで、リチウムイオン電池等の従来技術を大きく上回るシステムを構築することができた。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (58 results)

All 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (47 results) (of which Int'l Joint Research: 12 results,  Invited: 5 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] Imperial College London(英国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Imperial College London(英国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Effect of lanthanum tungstate hole-blocking layer for improvement of energy efficiency in anode-supported protonic ceramic fuel cells2021

    • Author(s)
      Matsuo Hiroki、Nakane Kenta、Matsuzaki Yoshio、Otomo Junichiro
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 129 Issue: 3 Pages: 147-153

    • DOI

      10.2109/jcersj2.20204

    • NAID

      130007993747

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2021-03-01
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] CO production from CO2 and H2 via the rWGS reaction by thermochemical redox cycling in interconnected fluidized beds2020

    • Author(s)
      Keller Martin、Otomo Junichiro
    • Journal Title

      Journal of CO2 Utilization

      Volume: 40 Pages: 101191-101191

    • DOI

      10.1016/j.jcou.2020.101191

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and electrochemical performance of anode-supported solid oxide fuel cells based on proton-conducting lanthanum tungstate thin electrolyte2019

    • Author(s)
      Kojo Gen、Wei Xiaochu、Matsuzaki Yoshio、Matsuo Hiroki、Hellgardt Klaus、Otomo Junichiro
    • Journal Title

      Solid State Ionics

      Volume: 337 Pages: 132-139

    • DOI

      10.1016/j.ssi.2019.04.015

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Performance of Anode-Supported Proton-Conducting Solid Oxide Fuel Cells with Lanthanum-Based Thin Bilayer Electrolyte2019

    • Author(s)
      Matsuo Hiroki、Kojo Gen、Sakata Kazuma、Matsuzaki Yoshio、Otomo Junichiro
    • Journal Title

      ECS Transactions (国際会議紀要)

      Volume: 91 Issue: 1 Pages: 1019-1028

    • DOI

      10.1149/09101.1019ecst

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Evaluation of Microstructural Changes and Performance Degradation in Iron-Based Oxygen Carriers During Redox Cycling for Chemical Looping Systems with Image Analysis2018

    • Author(s)
      Yuya Saito, Fumihiko Kosaka, Noriaki Kikuchi, Hiroyuki Hatano, Junichiro Otomo
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 57 Issue: 16 Pages: 5529-5538

    • DOI

      10.1021/acs.iecr.7b04966

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] プロトン伝導性酸化物混合電解質膜の輸送特性評価2021

    • Author(s)
      田島 星也、松尾 拓紀、大友 順一郎
    • Organizer
      化学工学会第86年会(オンライン)
    • Related Report
      2020 Annual Research Report
  • [Presentation] プロトン伝導性電解質薄膜の低温合成と電解質積層型燃料電池への適用2021

    • Author(s)
      戸田 亮輔、松尾 拓紀、松崎 良雄、大友 順一郎
    • Organizer
      化学工学会第86年会(オンライン)
    • Related Report
      2020 Annual Research Report
  • [Presentation] バッチ式流動層型蓄エネルギーシステムにおける鉄・マンガン系キャリア材料開発と反応モデル解析2021

    • Author(s)
      山村 泰平、大友 順一郎
    • Organizer
      化学工学会第86年会(オンライン)
    • Related Report
      2020 Annual Research Report
  • [Presentation] プロトン伝導性固体酸化物形燃料電池の高効率化に向けた積層型電解質の設計2021

    • Author(s)
      松尾 拓紀、中根 健太、松崎 良雄、大友 順一郎
    • Organizer
      2021年電気化学会第88回大会(オンライン)
    • Related Report
      2020 Annual Research Report
  • [Presentation] BaZr0.8Y0.2O3-δおよびBaZr0.1Ce0.7Y0.1Yb0.1O3-δ電解質を用いたプロトン伝導性固体酸化物形燃料電池における電解質積層効果2020

    • Author(s)
      松尾 拓紀、中根 健太、松崎 良雄、大友 順一郎
    • Organizer
      化学工学会第51回秋季大会(オンライン)
    • Related Report
      2020 Annual Research Report
  • [Presentation] プロトン伝導性ランタン系酸化物混合電解質膜の水素透過測定2020

    • Author(s)
      田島星也、松尾拓紀、大友順一郎
    • Organizer
      化学工学会第51回秋季大会(オンライン)
    • Related Report
      2020 Annual Research Report
  • [Presentation] Improvement of Energy Efficiency in Anode-Supported Proton Ceramic Fuel Cells by Lanthanum Tungstate Hole Blocking Layer2020

    • Author(s)
      Matsuo Hiroki , Nakane Kenta, Matsuzaki Yoshio, Otomo Junichiro
    • Organizer
      PRiME 2020(Digital platform)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Design and Performance of a Proton-Conducting Solid Oxide Reversible Cell2020

    • Author(s)
      Ortiz-Corrales Julian, Matsuo Hiroki, Otomo Junichiro
    • Organizer
      PRiME 2020(Digital platform)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体酸化物形燃料電池の技術および経済性評価 -プロトン伝導性セラミックス燃料電池の実用化に向けた評価の取り組み-2020

    • Author(s)
      大友 順一郎、松尾 拓紀、Ortiz Corrales Julian Andres、山手 駿
    • Organizer
      第29回SOFC研究発表会(オンライン)
    • Related Report
      2020 Annual Research Report
  • [Presentation] Progress and outlook of proton-conducting ceramic fuel cells for highly efficient energy conversion, electrolysis, and energy carrier2020

    • Author(s)
      Junichiro Otomo
    • Organizer
      化学工学会第85年会 国際シンポジウム(要旨公開)
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 電解質積層構造を有する固体酸化物形燃料電池の高効率化2020

    • Author(s)
      松尾拓紀、阪田一真、松崎良雄、大友順一郎
    • Organizer
      化学工学会第85年会(要旨公開)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 酸化物イオン・電子混合伝導体の異相界面における電気化学的特性評価2020

    • Author(s)
      那須雄太、松尾拓紀、大友順一郎
    • Organizer
      化学工学会第85年会(要旨公開)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 金属酸化物を用いた水素エネルギー貯蔵システムの設計と評価2020

    • Author(s)
      中西 泰介、大友順一郎
    • Organizer
      化学工学会第85年会(要旨公開)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 固体酸化物燃料電池の高効率化に向けた電解質積層効果の検証2020

    • Author(s)
      松尾 拓紀、松崎 良雄、大友 順一郎
    • Organizer
      電気化学会第87回大会(要旨公開)
    • Related Report
      2019 Annual Research Report
  • [Presentation] プロトン伝導性固体酸化物形燃料電池の電解質多層化による輸送特性制御2020

    • Author(s)
      阪田 一真、松尾 拓紀、松崎 良雄、大友 順一郎
    • Organizer
      電気化学会第87回大会(要旨公開)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Design and performance of a proton-conducting solid oxide electrolysis cell using lanthanum tungstate as electrolyte2020

    • Author(s)
      Julian Andres Ortiz Corrales,Hiroki Matsuo,Junichiro Otomo
    • Organizer
      電気化学会第87回大会(要旨公開)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 水素製造技術における燃料電池の役割と課題2019

    • Author(s)
      大友順一郎
    • Organizer
      第114回SOFC研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Cell Design and Performance of Proton-conducting Ceramic Fuel Cells by Controlling Transport Properties of Solid Electrolyte Membranes2019

    • Author(s)
      Junichiro Otomo, Gen Kojo, Hiroki Matsuo, Yoshio Matsuzaki
    • Organizer
      World Hydrogen Technologies Convention 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イオンー電子混合伝導体の異相界面を利用した固体酸化物形燃料電池の作製と電気化学特性評価2019

    • Author(s)
      福田 一峻、甚野 幸一、松尾 拓紀、大友 順一郎
    • Organizer
      化学工学会横浜大会2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] Performance of anode-supported proton-conducting solid oxide fuel cells with lanthanum-based thin bilayer electrolyte2019

    • Author(s)
      Hiroki Matsuo, Gen Kojo, Kazuma Sakata, Yoshio Matsuzaki, Junichiro Otomo
    • Organizer
      16th International Symposium on Solid Oxide Fuel Cells
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of thin bilayer electrolytes on performance of anode-supported proton-conducting solid oxide fuel cells2019

    • Author(s)
      Hiroki Matsuo, Junichiro Otomo
    • Organizer
      Asian Pacific Confederation of Chemical Engineering (APCChE) congress
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Performance of anode-supported proton-conducting solid oxide fuel cells with stacked electrolyte layers2019

    • Author(s)
      Hiroki Matsuo, Gen Kojo, Yoshio Matsuzaki, Junichiro Otomo
    • Organizer
      The Fifth International Symposium on Innovative Materials and Processes in Energy Systems (IMPRES2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Design of highly efficient proton-conducting solid oxide fuel cells with multi-layered electrolyte membranes2019

    • Author(s)
      Junichiro Otomo, Gen Kojo, Kazuma Sakata, Hiroki Matsuo, Yoshio Matsuzaki
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of anode-supported proton-conducting solid oxide fuel cells with bilayer electrolyte membranes2019

    • Author(s)
      Kazuma Sakata, Hiroki Matsuo, Gen Kojo, Yoshio Matsuzaki, Junichiro Otomo
    • Organizer
      The 13th Pacific Rim Conference of Ceramic Societies (PACRIM13)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Material and Cell Design of Highly Efficient Proton-conducting Ceramic Fuel Cells2019

    • Author(s)
      Junichiro Otomo, Gen Kojo, Hiroki Matsuo, Yoshio Matsuzaki
    • Organizer
      5th Annual World Congress of Smart Materials
    • Related Report
      2018 Annual Research Report
  • [Presentation] CO2 activation via rWGS redox cycling -exploiting phase changes or oxygen nonstoichiometry?2019

    • Author(s)
      ケラーマーチン、大友 順一郎
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電解質多層化によるプロトン伝導性固体酸化物形燃料電池の高効率化の検討2019

    • Author(s)
      小城元、松尾拓紀、松崎良雄、大友順一郎
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 固体酸化物形燃料電池の金属-プロトン伝導体界面における水素拡散機構の検討2019

    • Author(s)
      田所 洸、松尾拓紀、大友順一郎
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 三塔式ケミカルループ燃焼システムにおけるCa改質型イルメナイト系酸素キャリア粒子の構造と反応速度の評価及びシステム設計2019

    • Author(s)
      松原 一起、ケラーマーチン、大友 順一郎
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] プロトン伝導性固体酸化物形燃料電池の電解質多層化による輸送特性制御2019

    • Author(s)
      小城 元、松尾 拓紀、松崎 良雄、大友 順一郎
    • Organizer
      2019年電気化学会第86回大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Evaluation of Anode-Supported Solid Oxide Fuel Cells using Lanthanum Tungstate as a Proton-Conducting Solid Electrolyte Membrane2018

    • Author(s)
      Gen Kojo, Hiroshi Tadokoro, Yoshio Matsuzaki, Junichiro Otomo
    • Organizer
      22nd Topical Meeting of the International Society of Electrochemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication and evaluation of electrode-supported type fuel cells with proton-conducting lanthanum tungstate2018

    • Author(s)
      Hiroki Matsuo, Gen Kojo, Yoshio Matsuzaki, Junichiro Otomo
    • Organizer
      The 19th International Conference on Solid State Protonic Conductors (SSPC-19)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プロトン伝導性タングステン酸ランタンを用いた燃料電池 セル作製と輸送特性の影響2018

    • Author(s)
      小城元、松崎良雄、松尾拓紀、大友順一郎
    • Organizer
      化学工学会第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] “Reaction Kinetics and Stability of Calcium-Modified Ilmenite Redox Cycles of Chemical Looping Systems2018

    • Author(s)
      Junichiro Otomo, Martin Keller, Hikaru Oka, Kazuki Matsubara, Takeshi Hatanaka
    • Organizer
      5th International Conference on Chemical Looping
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プロトン伝導性中温作動燃料電池における輸送特性が発電効率に与える影響2018

    • Author(s)
      小城元、松崎良雄、松尾拓紀、大友順一郎
    • Organizer
      2018年電気化学会秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高効率燃料電池システム実現に向けた取り組みと将来の役割2018

    • Author(s)
      大友順一郎
    • Organizer
      水素エネルギー協会(HESS)第157回定例研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] タングステン酸ランタンを用いたプロトン伝導性電極支持型燃料電池の中間層が発電性能に与える影響2018

    • Author(s)
      小城元、松崎良雄、松尾拓紀、大友順一郎
    • Organizer
      第27回SOFC研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Recent advances in highly efficient fuel cell systems with proton-conducting solid electrolytes and their applications2018

    • Author(s)
      Junichiro Otomo
    • Organizer
      2018 Global Research Efforts on Energy and Nanomaterials (GREEN 2018)
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] プロトン伝導性固体酸化物形燃料電池における輸送特性と発電効率の相関2018

    • Author(s)
      小城 元、田所 洸、松崎 良雄、大友 順一郎
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] プロトン伝導性固体酸化物形電解セルのイオン・電子輸送特性と水蒸気電解への影響2018

    • Author(s)
      橋本 隼輔、大友 順一郎
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 固体酸化物形燃料電池の技術的可能性と将来の役割2018

    • Author(s)
      大友 順一郎
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 電解質の輸送特性に基づくプロトン伝導性固体酸化物形燃料電池の高効率化の検討2018

    • Author(s)
      小城 元、 田所 洸、 橋本 隼輔、松崎 良雄、大友 順一郎
    • Organizer
      電気化学会第85回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Material and cell design for proton-conducting solid oxide fuel cells using lanthanum tungstate with high La/W ratio2017

    • Author(s)
      Gen Kojo, Reina Reinga Tsukimura, Yoshio Matsuzaki, Junichiro Otomo
    • Organizer
      21th International Conference on Solid State Ionics (SSI-21)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] タングステン酸ランタンの物性評価及び燃料電池セル化の検討2017

    • Author(s)
      小城 元、月村 玲菜、松崎 良雄、大友 順一郎
    • Organizer
      化学工学会東京大会2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] ケミカルループ法における鉄ドープチタン酸カルシウム担体による水素生成反応の促進効果2017

    • Author(s)
      有賀 耀介、高坂 文彦、大友 順一郎
    • Organizer
      化学工学会東京大会2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] タングステン酸ランタンを用いた中温作動燃料電池セル化の検討2017

    • Author(s)
      小城 元、月村 玲菜、松崎 良雄、大友 順一郎
    • Organizer
      2017年電気化学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] プロトン伝導型中温作動燃料電池の作製と電極反応特性2017

    • Author(s)
      小城 元、松崎 良雄、大友 順一郎
    • Organizer
      第26回SOFC研究発表会
    • Related Report
      2017 Annual Research Report
  • [Remarks] 大友研究室ホームページ(東京大学)

    • URL

      http://www.otomolab.k.u-tokyo.ac.jp/index.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 大友研究室ホームページ(東京工業大学)

    • URL

      http://www.tse.ens.titech.ac.jp/~otomolab/index.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 大友研究室ホームページ

    • URL

      http://www.otomolab.k.u-tokyo.ac.jp/index.html

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report 2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 混合伝導体層を有する固体酸化物燃料電池2018

    • Inventor(s)
      大友 順一郎、松尾 拓紀、松崎 良雄
    • Industrial Property Rights Holder
      国立大学法人東京大学、東京瓦斯株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-226798
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2017-04-28   Modified: 2022-01-27  

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