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Catalytic conversion of all components of biomass into valuable chemicals

Research Project

Project/Area Number 17H00803
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Design and evaluation of sustainable and environmental conscious system
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

YAMAGUCHI Aritomo  国立研究開発法人産業技術総合研究所, 材料・化学領域, 研究グループ長 (90339119)

Co-Investigator(Kenkyū-buntansha) 佐藤 修  国立研究開発法人産業技術総合研究所, 材料・化学領域, 主任研究員 (20357148)
三村 直樹  国立研究開発法人産業技術総合研究所, 材料・化学領域, 主任研究員 (50358115)
Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥33,930,000 (Direct Cost: ¥26,100,000、Indirect Cost: ¥7,830,000)
Fiscal Year 2020: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2019: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Fiscal Year 2018: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
Fiscal Year 2017: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Keywordsバイオマス利活用
Outline of Final Research Achievements

Efficient utilization of all three components of lignocellulose-cellulose, hemicellulose, and lignin-impels efficient utilization of carbon dioxide and photosynthetically active radiation via production of plant biomass. Conversion of all three of these polymeric components of lignocellulosic biomass into the corresponding monomeric chemicals was investigated using reusable solid catalysts in water without organic solvents, acids, or bases. Cellulose and hemicellulose were first converted into sugar alcohols such as sorbitol and xylitol using a carbon-supported platinum catalyst (Pt/C), H2, and bagasse as a reactant at 463 K for 16 h. The solid residue from this process, which was mainly lignin and Pt/C, was recovered by simple filtration. Lignin in the solid residue was then converted into aromatic products at 673 K. After this process, only Pt/C catalyst was recovered as a solid residue, and it retained its activity.

Academic Significance and Societal Importance of the Research Achievements

循環型社会構築のために、枯渇性資源ではなく再生可能な資源を化学品原料として利用する必要がある。木質バイオマスは、セルロース・ヘミセルロース・リグニンから成り立ち、それぞれを変性させずに分離することは困難であり、木質バイオマスを反応物としてそのセルロース・ヘミセルロース・リグニンをすべて使用する研究は、あまり進められていない。本研究では、木質バイオマスを反応物としてそのセルロース・ヘミセルロース・リグニンをすべて有用化学物質へと変換する技術を確立した。学術的なインパクトのみならず、社会的にも非常に意義のある研究である。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (32 results)

All 2021 2020 2019 2018 2017

All Journal Article (10 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 10 results,  Open Access: 4 results) Presentation (21 results) (of which Int'l Joint Research: 8 results,  Invited: 5 results) Book (1 results)

  • [Journal Article] Magnesium Oxide‐Catalyzed Conversion of Chitin to Lactic Acid2021

    • Author(s)
      Kun‐asa Kodchakon、Reubroycharoen Prasert、Yamazaki Kiyoyuki、Mimura Naoki、Sato Osamu、Yamaguchi Aritomo
    • Journal Title

      ChemistryOpen

      Volume: 10 Issue: 3 Pages: 308-315

    • DOI

      10.1002/open.202000303

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of Catalyst Support on Aromatic Monomer Production from Lignocellulosic Biomass Over Pt-Based Catalysts2021

    • Author(s)
      Yamazaki Kiyoyuki、Sasaki Ryuto、Watanabe Tatsuya、Kuwano Satoko、Murakami Yuka、Mimura Naoki、Sato Osamu、Yamaguchi Aritomo
    • Journal Title

      Waste and Biomass Valorization

      Volume: in press. Issue: 11 Pages: 6081-6089

    • DOI

      10.1007/s12649-021-01423-z

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lignin Depolymerization into Aromatic Monomers Using Supported Metal Catalysts in Supercritical Water2020

    • Author(s)
      YAMAGUCHI Aritomo、MIMURA Naoki、SEGAWA Atsushi、MAZAKI Hitoshi、SATO Osamu
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 63 Issue: 4 Pages: 221-227

    • DOI

      10.1627/jpi.63.221

    • NAID

      130007868026

    • ISSN
      1346-8804, 1349-273X
    • Year and Date
      2020-07-01
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of Metal Catalysts on Bond Cleavage Reactions of Lignin Model Compounds in Supercritical Water2020

    • Author(s)
      Aritomo Yamaguchi, Naoki Mimura, Masayuki Shirai, and Osamu Sato
    • Journal Title

      Waste and Biomass Valorization

      Volume: 11 Issue: 2 Pages: 669-674

    • DOI

      10.1007/s12649-019-00647-4

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic analyses of intramolecular dehydration of hexitols in high-temperature water2020

    • Author(s)
      Yamaguchi Aritomo、Mimura Naoki、Shirai Masayuki、Sato Osamu
    • Journal Title

      Carbohydrate Research

      Volume: 487 Pages: 107880-107880

    • DOI

      10.1016/j.carres.2019.107880

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lignin depolymerization into aromatic monomers using supported metal catalysts in water2020

    • Author(s)
      Yamaguchi Aritomo、Mimura Naoki、Segawa Atsushi、Mazaki Hitoshi、Sato Osamu
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: in press.

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aromatic Monomer Production from Lignin Depolymerization Predicted from Bond Cleavage Data for Lignin Model Compounds2019

    • Author(s)
      YAMAGUCHI Aritomo、MIMURA Naoki、SHIRAI Masayuki、SATO Osamu
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 62 Issue: 5 Pages: 228-233

    • DOI

      10.1627/jpi.62.228

    • NAID

      130007700311

    • ISSN
      1346-8804, 1349-273X
    • Year and Date
      2019-09-01
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Cascade Utilization of Biomass: Strategy for Conversion of Cellulose, Hemicellulose, and Lignin into Useful Chemicals2019

    • Author(s)
      Yamaguchi Aritomo、Mimura Naoki、Shirai Masayuki、Sato Osamu
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 7 Issue: 12 Pages: 10445-10451

    • DOI

      10.1021/acssuschemeng.9b00786

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct conversion of lignocellulosic biomass into aromatic monomers over supported metal catalysts in supercritical water2019

    • Author(s)
      Yamaguchi Aritomo、Watanabe Tatsuya、Saito Kyota、Kuwano Satoko、Murakami Yuka、Mimura Naoki、Sato Osamu
    • Journal Title

      Molecular Catalysis

      Volume: 477 Pages: 110557-110557

    • DOI

      10.1016/j.mcat.2019.110557

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conversion of Cellulose to Lactic Acid by Using ZrO2?Al2O3 Catalysts2017

    • Author(s)
      Wattanapaphawong Panya、Sato Osamu、Sato Koichi、Mimura Naoki、Reubroycharoen Prasert、Yamaguchi Aritomo
    • Journal Title

      Catalysts

      Volume: 7 Issue: 7 Pages: 221-221

    • DOI

      10.3390/catal7070221

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 担持金属触媒を用いた水溶媒中での木質バイオマスから芳香族化合物への変換技術2020

    • Author(s)
      山口有朋、佐々木隆仁、渡邉竜也、桑野聡子、山崎清行、三村直樹、佐藤 修
    • Organizer
      第126回触媒討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 触媒を用いたキチンから有用化学物質製造2020

    • Author(s)
      Kun-asa Kodchakon、山崎清行、三村直樹、佐藤 修、Reubroycharoen Prasert、山口有朋
    • Organizer
      化学工学会 第51回秋季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 固体触媒によるキチンから乳酸への変換技術2020

    • Author(s)
      山口有朋、K. Kun-asa、P. Reubroycharoen、山崎清行、三村直樹、佐藤 修
    • Organizer
      第50回石油・石油化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 木質バイオマスから芳香族化合物を製造する担持金属触媒2020

    • Author(s)
      山口有朋、佐々木隆仁、渡邉竜也、三村直樹、佐藤 修、桑野聡子
    • Organizer
      令和元年度日本表面真空学会東北・北海道支部講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] リグノセルロース系バイオマスから芳香族化合物への直接変換2019

    • Author(s)
      山口有朋、渡邉竜也、齋藤杏汰、桑野聡子、佐藤 修、三村直樹
    • Organizer
      石油学会第68回研究発表会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Cascade Utilization of Biomass: Conversion of Cellulose, Hemicellulose, and Lignin into Chemicals2019

    • Author(s)
      A. Yamaguchi, N. Mimura, M. Shirai and O. Sato
    • Organizer
      26th meeting of the North American Catalysis Society (NAM26)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Conversion of lignin into aromatic compounds using supported metal catalysts2019

    • Author(s)
      A. Yamaguchi
    • Organizer
      8th Asia-Pacific Congress in Catalysis (APCAT-8)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] リグニン解重合反応による芳香族モノマー製造2019

    • Author(s)
      山口有朋、三村直樹、佐藤 修
    • Organizer
      第124回触媒討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Effect of supporteted metal catalysts on lignin deporimarization into aromatic monomer in supercritical water2019

    • Author(s)
      A. Yamaguchi, N. Mimura and O. Sato
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] バイオマスに含まれるリグニンの有用化学物質への変換2019

    • Author(s)
      山口有朋、三村直樹、白井誠之、佐藤 修
    • Organizer
      第49回石油・石油化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] バイオマスに含まれるリグニンの有用化学物質への変換2018

    • Author(s)
      山口有朋、三村直樹、白井誠之、瀬川敦司、佐藤 修
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Valorisation of cellulose, hemicellulose, and lignin using supported metal catalysts2018

    • Author(s)
      A. Yamaguchi, N. Mimura, M. Shirai and O. Sato
    • Organizer
      7th International Conference on Engineering for Waste and Biomass Valorisation (WasteEng2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalytic conversion of biomass to valuable chemicals using supported metal catalysts in high-temperature water2018

    • Author(s)
      A. Yamaguchi, N. Mimura, M. Shirai and O. Sato
    • Organizer
      8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalytic conversion of lignocellulosic biomass into valuable chemicals using supported metal catalysts2018

    • Author(s)
      A. Yamaguchi, N. Mimura and O. Sato
    • Organizer
      8th International IUPAC Conference on Green Chemistry (ICGC-8)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 木質バイオマスから化学品原料への直接変換2018

    • Author(s)
      山口有朋、齋藤杏汰、渡邉竜也、桑野聡子、三村直樹、佐藤 修
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] リグニンの有効利用を指向したモデル化合物の分解挙動の解明2018

    • Author(s)
      山口有朋、三村直樹、白井誠之、佐藤 修
    • Organizer
      第48回石油・石油化学討論会(創立60周年記念東京大会)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Recyclable solid catalysts for conversion of lignocellulosic biomass into valuable chemicals2018

    • Author(s)
      A. Yamaguchi
    • Organizer
      3rd International Conference on Emerging Advanced Materials (ICEAN2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Production of valuable chemicals from lignocellulosic biomass using supported metal catalysts2018

    • Author(s)
      Aritomo Yamaguchi
    • Organizer
      Indo-Japan Conference on New Insights into Multifunctional Catalysis for Biomass Transformation
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] バイオマスのセルロース・ヘミセルロース・リグニンすべてを化学原料に変換する2018

    • Author(s)
      山口有朋
    • Organizer
      石油学会東北支部講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] バイオマスに含まれるセルロース・ヘミセルロース・リグニンの化成品原料への変換2018

    • Author(s)
      山口有朋、三村直樹、白井誠之、佐藤 修
    • Organizer
      第118回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 固体触媒を用いた植物バイオマスの有用化学物質への変換技術2017

    • Author(s)
      山口有朋
    • Organizer
      第9回岩澤コンファレンス-サステイナブル社会のための最先端触媒化学・表面科学-
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Book] 海洋プラスチック汚染問題の解決を目指す生分解性プラスチックの素材・技術最前線2019

    • Author(s)
      山口有朋
    • Total Pages
      343
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2019 Annual Research Report

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Published: 2017-04-28   Modified: 2022-01-27  

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