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Theoretical study on explosion of energetic materials

Research Project

Project/Area Number 17H00844
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Social systems engineering/Safety system
Research InstitutionYokohama National University

Principal Investigator

Miyake Atsumi  横浜国立大学, 先端科学高等研究院, 教授 (60174140)

Co-Investigator(Kenkyū-buntansha) 井上 智博  九州大学, 工学研究院, 准教授 (70466788)
伊里 友一朗  横浜国立大学, 大学院環境情報研究院, 助教 (90794016)
塩田 謙人  横浜国立大学, 先端科学高等研究院, 特任教員(助教) (30827837)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥42,770,000 (Direct Cost: ¥32,900,000、Indirect Cost: ¥9,870,000)
Fiscal Year 2019: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2018: ¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2017: ¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Keywordsエネルギー物質 / 爆発 / 発火 / 爆轟 / 詳細反応モデリング / 安全工学
Outline of Final Research Achievements

The aim of this study is to establish methodology that analyze and organizes explosion chemistry associated with high energetic materials based on advanced measurements and ab initio calculations. We conducted various measurements such as high-speed camera combined with two-color temperature radiometry and thermal analysis combined with high-resolution time-of-flight mass spectrometer to investigate wide range of explosion chemistry such as decomposition, ignition, combustion, and detonation. We succeeded in constructing a detailed reaction model from the first principle by utilizing the quantum mechanics/continuous solvation model method.

Academic Significance and Societal Importance of the Research Achievements

化学産業界からは,凝縮相エネルギー物質を含む高反応性化学物質の取扱いに関連して,爆発学理に基づいた爆発影響評価ならびにより精度の高いリスク評価への展開が強く求められていた。当該研究で構築した爆発反応に関する計測および計算手法は,化学反応計測に基づいたプロセスデザイン支援,化学反応危険性予測に基づいたプロセス管理指標の設定,および災害発生シナリオの体系的抽出とそれに基づいた防災減災戦略の策定に活用可能であることから,化学産業ならびに航空宇宙産業の安全性向上と新規学術領域の構築に貢献した。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (35 results)

All 2019 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (24 results) (of which Int'l Joint Research: 24 results)

  • [Int'l Joint Research] University of Bologna(イタリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] University of Craiova(ルーマニア)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] A detailed kinetics model for the decomposition of aqueous hydroxylammonium nitrate2019

    • Author(s)
      Yu-ichiro Izato, Kento Shiota, Atsumi Miyake
    • Journal Title

      Science and Technology of Energetic Materials

      Volume: 80 Pages: 212-221

    • NAID

      40022107655

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reactivity analysis of ammonium dinitramide binary mixtures based on ab initio calculations and thermal analysis2019

    • Author(s)
      Shiota Kento, Izato Yu-ichiro, Habu Hiroto, Miyake Atsumi
    • Journal Title

      Journal of Thermal Analysis and Calorimetry

      Volume: 138 Issue: 4 Pages: 2615-2622

    • DOI

      10.1007/s10973-019-08557-2

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal and evolved gas analyses of decomposition of ammonium dinitramide-based ionic liquid propellant using TG-DSC-HRTOFMS2019

    • Author(s)
      Izato Yu-ichiro, Shiota Kento, Satoh Kenta, Satoh Takashi, Yahata Yukinori, Habu Hiroto, Miyake Atsumi
    • Journal Title

      Journal of Thermal Analysis and Calorimetry

      Volume: 138 Issue: 3 Pages: 1853-1861

    • DOI

      10.1007/s10973-019-08475-3

    • NAID

      120006786476

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Condensed-phase pyrolysis mechanism of ammonium nitrate based on detailed kinetic model2019

    • Author(s)
      Izato Yu-ichiro, Shiota Kento, Miyake Atsumi
    • Journal Title

      Journal of Analytical and Applied Pyrolysis

      Volume: 143 Pages: 104671-104671

    • DOI

      10.1016/j.jaap.2019.104671

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A simple heuristic approach to estimate the thermochemistry of condensed-phase molecules based on the polarizable continuum model2019

    • Author(s)
      Izato Yu-ichiro, Matsugi Akira, Koshi Mitsuo, Miyake Atsumi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 21 Issue: 35 Pages: 18920-18929

    • DOI

      10.1039/c9cp03226f

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Detailed kinetic model for ammonium dinitramide decomposition2018

    • Author(s)
      Izato Yu-ichiro, Miyake Atsumi
    • Journal Title

      Combustion and Flame

      Volume: 198 Pages: 222-229

    • DOI

      10.1016/j.combustflame.2018.09.013

    • NAID

      120006551705

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic analysis of the thermal decomposition of liquid ammonium nitrate based on thermal analysis and detailed reaction simulations2018

    • Author(s)
      Izato Yu-ichiro, Miyake Atsumi
    • Journal Title

      Journal of Thermal Analysis and Calorimetry

      Volume: 134 Issue: 1 Pages: 813-823

    • DOI

      10.1007/s10973-018-7322-8

    • NAID

      120006551706

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A detailed chemical kinetics model for the combustion of gas-phase guanidine nitrate2018

    • Author(s)
      Izato Yu-ichiro, Miyake Atsumi
    • Journal Title

      Science and Technology of Energetic Materials

      Volume: 79 Pages: 166-174

    • NAID

      40021763931

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The decomposition pathways of ammonium dinitramide on the basis of ab initio calculations2017

    • Author(s)
      Izato Yu-ichiro、Miyake Atsumi
    • Journal Title

      Journal of Energetic Materials

      Volume: 36 Issue: 3 Pages: 302-315

    • DOI

      10.1080/07370652.2017.1405099

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Study on high energetic ionic liquids for propellant2018

    • Author(s)
      H. Matsunaga, N. Itouyama, K. Shiota, Y. Izato, T. Katsumi, H. Habu, M. Noda, A. Miyake
    • Organizer
      3rd New Energetics Workshop, Stockholm, Sweden
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal behaviour of ammonium dinitramide-based high energetic ionic liquid under reduced pressure2018

    • Author(s)
      H. Matsunaga, K. Katoh, H. Habu, M. Noda, A. Miyake
    • Organizer
      12th European Symposium on Thermal Analysis and Calorimetry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal analysis and detailed chemical reaction simulation of ammonium dinitramide decomposition2018

    • Author(s)
      Y. Izato, A. Miyake
    • Organizer
      12th European Symposium on Thermal Analysis and Calorimetry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reactivity analysis on ammonium dinitramide binary mixtures in condensed phase2018

    • Author(s)
      K. Shiota, Y. Izato, A. Miyake
    • Organizer
      12th European Symposium on Thermal Analysis and Calorimetry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-speed visualization measurement of Senko-Hanabi2017

    • Author(s)
      C. Inoue, Y. Izato, A. Miyake M. Koshi
    • Organizer
      16th International Symposium on Fireworks
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Scaling law of Senko-Hanabi2017

    • Author(s)
      C. Inoue, Y. Izato, A. Miyake M. Koshi
    • Organizer
      16th International Symposium on Fireworks
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal analysis for chemical reactions of Senko-Hanabi2017

    • Author(s)
      Y. Izato, C. Inoue, A. Miyake, M. Koshi
    • Organizer
      16th International Symposium on Fireworks
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Influences of chemical dyes on laser ignitionability and thermal stability of ammonium dinitramide-based energetic ionic liquid2017

    • Author(s)
      M. Hayata, K. Shiota, Y. Izato, H. Matsunaga, H. Habu, A. Miyake
    • Organizer
      16th International Symposium on Fireworks
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal study of ammonium dinitramide and acetamide binary mixture and their agarose mixture2017

    • Author(s)
      K. Shiota, Y. Izato, H. Matsunaga, H. Habu, A. Miyake
    • Organizer
      16th International Symposium on Fireworks
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation and thermal decomposition behavior of high energetic ionic liquids based on ammonium dinitramide and amine nitrates2017

    • Author(s)
      H. Matsunaga, K. Katoh, H. Habu, M. Noda, A. Miyake
    • Organizer
      31st International Symposium on Space Technology and Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal properties of ADN based ionic liquid gel propellants2017

    • Author(s)
      K. Shiota, Y. Izato, H. Matsunaga, H. Habu, and A. Miyake
    • Organizer
      31st International Symposium on Space Technology and Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Laster ignition and thermal property of ammonium dinitramide based energetic ionic liquid propellants by including chemical dyes2017

    • Author(s)
      M. Hayata, K. Shiota, Y. Izato, H. Matsunaga, H. Habu, A. Miyake
    • Organizer
      31st International Symposium on Space Technology and Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Kinetic Model for combustion of hydroxylammonium nitrate (HAN)-based propellants2017

    • Author(s)
      Y. Izato, M. Koshi, A. Miyake
    • Organizer
      31st International Symposium on Space Technology and Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetic analysis and detailed chemical reaction simulation for ammonium nitrate decomposition2017

    • Author(s)
      Y. Izato, A. Miyake
    • Organizer
      4th Central and Eastern European Conference on Thermal Analysis and Calorimetry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evolved gas analysis of thermal decomposition and combustion of high energetic ionic liquid based on ammonium dinitramide2017

    • Author(s)
      H. Matsunaga, K. Katoh, H. Habu, M. Noda, A. Miyake
    • Organizer
      4th Central and Eastern European Conference on Thermal Analysis and Calorimetry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal study on complex formation of ADN mixtures2017

    • Author(s)
      K. Shiota, Y. Izato, H. Matsunaga, H. Habu, A. Miyake
    • Organizer
      4th Central and Eastern European Conference on Thermal Analysis and Calorimetry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal and structure analysis of ammonium dinitramide and nitrate salt eutectic mixtures2017

    • Author(s)
      K. Shiota, Y. Izato, H. Matsunaga, H. Habu, A. Miyake
    • Organizer
      4th Central and Eastern European Conference on Thermal Analysis and Calorimetry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Validation for a condensed phase reaction model of hydroxylammonium nitrate aqueous based on kinetic analysis2017

    • Author(s)
      K. Kuroki, Y. Izato, A. Miyake
    • Organizer
      The 6th International Symposium on Energetic Materials and Their Applications
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Detailed reaction simulation for thermal decomposition of ammonium dinitramide (ADN)2017

    • Author(s)
      Y. Izato, A. Miyake
    • Organizer
      The 6th International Symposium on Energetic Materials and Their Applications
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal decomposition and combustion behavior of high energy ionic liquid based on ammonium dinitramide2017

    • Author(s)
      H. Matsunaga, K. Katoh, H. Habu, M. Noda, A. Miyake
    • Organizer
      The 6th International Symposium on Energetic Materials and Their Applications
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modeling for decomposition reactions of aqueous hydroxylammonium nitrate solution2017

    • Author(s)
      Y. Izato, A. Miyake
    • Organizer
      The 6th International Symposium on Energetic Materials and Their Applications
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Vapor Pressure measurement of ammonium dinitramide binary mixtures using thermogravimetric analysis2017

    • Author(s)
      K.Shiota, Y. Izato, H. Matsunaga, H. Habu, A. Miyake
    • Organizer
      The 6th International Symposium on Energetic Materials and Their Applications
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Gasification behavior of ammonium dinitramide based ionic liquid propellants under low pressure condition2017

    • Author(s)
      M. Hayata, K. Shiota, Y. Izato, H. Matsunaga, H. Habu, A. Miyake
    • Organizer
      The 6th International Symposium on Energetic Materials and Their Applications
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Combustion behavior of guanidine nitrate/basic copper nitrate2017

    • Author(s)
      M. Nakashima, Y. Izato, H. Matsunaga, E. Higashi, S. Takagi, A. Miyake, K. Katoh
    • Organizer
      The 6th International Symposium on Energetic Materials and Their Applications
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research

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Published: 2017-04-28   Modified: 2021-02-19  

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