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Targeted synthesis and development of functions of superatoms and superatomic molecules

Research Project

Project/Area Number 17H01182
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

Tsukuda Tatsuya  東京大学, 大学院理学系研究科(理学部), 教授 (90262104)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥43,940,000 (Direct Cost: ¥33,800,000、Indirect Cost: ¥10,140,000)
Fiscal Year 2019: ¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
Fiscal Year 2018: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
Fiscal Year 2017: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Keywords超原子 / 超原子分子 / 金属クラスター / 金超原子 / 金鳥原子分子
Outline of Final Research Achievements

We have synthesized and characterized superatoms and superatomic molecules while precisely controlling their size, composition, charge state, and surface passivation. We have not only obtained novel suparatoms with open electronic shell and those containing hydrogen, but also developed new superatoms and superatomic molecules showing superior stability, optical properties, and catalysis. The hydride-mediated transformations of superatoms will be a promising bottom-up method for the targeted and large-scale synthesis of designed superatoms and superatomic molecules.

Academic Significance and Societal Importance of the Research Achievements

本研究の成果を通して、新たな超原子や超原子分子が創出されただけではなく、それらの構造因子と物性の相関に関する理解を深めることでナノスケールの物質科学の基礎学理を深化させることができた。また、超安定な超原子や超原子分子を大量に合成するための合成技術の端緒を切り開いたことで、学理に裏打ちされた設計指針に基づいてこれらの特異な個性を最大限に生かした機能性物質の開発が加速されるものと期待される。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (96 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (14 results) Journal Article (49 results) (of which Int'l Joint Research: 11 results,  Peer Reviewed: 48 results,  Open Access: 11 results) Presentation (30 results) (of which Int'l Joint Research: 21 results,  Invited: 29 results) Book (2 results) Remarks (1 results)

  • [Int'l Joint Research] Queen's University(カナダ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] University of Jyvaskyla(フィンランド)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Pontificia Universidad Catolica de Chile(チリ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Carnegie Mellon University(米国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Indian Institute of Technology, Madras(インド)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Queen's University(カナダ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] University of Jyvaskyla(フィンランド)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Xiangtan University(中国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Stanford University School of Medicine(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Queen's University(Canada)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] University of Liverpool(United Kingdom)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Fudan Univeristy(China)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] University of Jyvaskyla(Finland)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research]

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Base Catalytic Activity of [Nb10O28]6-: Effect of Countercations2020

    • Author(s)
      Hayashi Shun、Yamazoe Seiji、Tsukuda Tatsuya
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 124 Issue: 20 Pages: 10975-10980

    • DOI

      10.1021/acs.jpcc.0c01488

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron Binding in a Superatom with a Repulsive Coulomb Barrier: The Case of [Ag44(SC6H3F2)30]4- in the Gas Phase2020

    • Author(s)
      Tasaka Yuriko、Nakamura Katsunosuke、Malola Sami、Hirata Keisuke、Kim Kuenhee、Koyasu Kiichirou、Hakkinen Hannu、Tsukuda Tatsuya
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 11 Issue: 8 Pages: 3069-3074

    • DOI

      10.1021/acs.jpclett.0c00786

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electron Microscopic Observation of an Icosahedral Au13 Core in Au25(SePh)18 and Reversible Isomerization between Icosahedral and Face-Centered Cubic Cores in Au144(SC2H4Ph)602020

    • Author(s)
      Takahata Ryo、Yamazoe Seiji、Maehara Yosuke、Yamazaki Kenji、Takano Shinjiro、Kurashige Wataru、Negishi Yuichi、Gohara Kazutoshi、Tsukuda Tatsuya
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 124 Issue: 12 Pages: 6907-6912

    • DOI

      10.1021/acs.jpcc.9b11412

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] CdTe quantum dots modified electrodes ITO-(Polycation/QDs) for carbon dioxide reduction to methanol2020

    • Author(s)
      Guzman Diego、Isaacs Mauricio、Tsukuda Tatsuya、Yamazoe Seiji、Takahata Ryo、Schrebler Ricardo、Burgos Ana、Osorio-Roman Igor、Castillo Francisco
    • Journal Title

      Applied Surface Science

      Volume: 509 Pages: 145386-145386

    • DOI

      10.1016/j.apsusc.2020.145386

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Acid-Base Equilibrium of the Chromophore Counterion Results in Distinct Photoisomerization Reactivity in the Primary Event of Proteorhodopsin2019

    • Author(s)
      C. Chang, H. Kuramochi, M. Singh, R. Abe-Yoshizumi, T. Tsukuda, H. Kandori, T. Tahei*
    • Journal Title

      Phys Chem Chem Phys.

      Volume: 21(46) Issue: 46 Pages: 25728-25734

    • DOI

      10.1039/c9cp04991f

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Asymmetric aerobic oxidation of secondary alcohols catalyzed by poly(N-vinyl-2-pyrrolidone)-stabilized gold clusters modified with cyclodextrin derivatives2019

    • Author(s)
      Hirano Koto、Takano Shinjiro、Tsukuda Tatsuya
    • Journal Title

      Chemical Communications

      Volume: 55 Issue: 100 Pages: 15033-15036

    • DOI

      10.1039/c9cc06770a

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alkynyl-Protected Au22(C≡CR)18 Clusters Featuring New Interfacial Motifs and R-Dependent Photoluminescence2019

    • Author(s)
      Ito Shun、Takano Shinjiro、Tsukuda Tatsuya
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 10 Issue: 21 Pages: 6892-6896

    • DOI

      10.1021/acs.jpclett.9b02920

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reductive Activation of Small Molecules by Anionic Coinage Metal Atoms and Clusters in the Gas Phase2019

    • Author(s)
      Muramatsu Satoru、Tsukuda Tatsuya
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 14 Issue: 21 Pages: 3763-3772

    • DOI

      10.1002/asia.201901156

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Efficient and Selective Conversion of Phosphine-Protected (MAu8)2+ (M = Pd, Pt) Superatoms to Thiolate-Protected (MAu12)6+ or Alkynyl-Protected (MAu12)4+ Superatoms via Hydride Doping2019

    • Author(s)
      Takano Shinjiro、Ito Shun、Tsukuda Tatsuya
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 40 Pages: 15994-16002

    • DOI

      10.1021/jacs.9b08055

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Robust, Highly Luminescent Au13 Superatoms Protected by N-Heterocyclic Carbenes2019

    • Author(s)
      Narouz Mina R.、Takano Shinjiro、Lummis Paul A.、Levchenko Tetyana I.、Nazemi Ali、Kaappa Sami、Malola Sami、Yousefalizadeh Goonay、Calhoun Larry A.、Stamplecoskie Kevin G.、Hakkinen Hannu、Tsukuda Tatsuya、Crudden Cathleen M.
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 38 Pages: 14997-15002

    • DOI

      10.1021/jacs.9b07854

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Stoichiometric Formation of Open-Shell [PtAu24(SC2H4Ph)18]- via Spontaneous Electron Proportionation between [PtAu24(SC2H4Ph)18]2- and [PtAu24(SC2H4Ph)18]02019

    • Author(s)
      Suyama Megumi、Takano Shinjiro、Nakamura Toshikazu、Tsukuda Tatsuya
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 36 Pages: 14048-14051

    • DOI

      10.1021/jacs.9b06254

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of chemically modified gold and silver clusters in gas phase2019

    • Author(s)
      Hirata Keisuke、Tomihara Ryohei、Kim Kuenhee、Koyasu Kiichirou、Tsukuda Tatsuya
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 21 Issue: 32 Pages: 17463-17474

    • DOI

      10.1039/c9cp02622c

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Elucidating the Doping Effect on the Electronic Structure of Thiolate‐Protected Silver Superatoms by Photoelectron Spectroscopy2019

    • Author(s)
      Kim Kuenhee、Hirata Keisuke、Nakamura Katsunosuke、Kitazawa Hirokazu、Hayashi Shun、Koyasu Kiichirou、Tsukuda Tatsuya
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 34 Pages: 11637-11641

    • DOI

      10.1002/anie.201901750

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrathin Gold Nanowires and Nanorods2019

    • Author(s)
      Takahata Ryo、Tsukuda Tatsuya
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 8 Pages: 906-915

    • DOI

      10.1246/cl.190313

    • NAID

      130007687714

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structural Evolution of Iridium Oxide Cluster Anions IrnOm- (n = 5-8) with Sequential Oxidation: Binding Mode of O Atoms and Ir Framework2019

    • Author(s)
      R. Tomihara, K. Koyasu, T. Nagata, J. W. J. Wu, M. Nakano, K. Ohshimo, F. Misaizu, T. Tsukuda
    • Journal Title

      J. Phys. Chem. C

      Volume: 123 Issue: 24 Pages: 15301-15306

    • DOI

      10.1021/acs.jpcc.9b02935

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reduction-resistant [Au25(cyclohexanethiolate)18]0 with an Icosahedral Au13 Core2019

    • Author(s)
      Omoda Tsubasa、Takano Shinjiro、Tsukuda Tatsuya
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 8 Pages: 885-887

    • DOI

      10.1246/cl.190306

    • NAID

      130007687715

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Photoinduced Thermionic Emission from [M25(SR)18]- (M = Au, Ag) Revealed by Anion Photoelectron Spectroscopy2019

    • Author(s)
      Hirata Keisuke、Kim Kuenhee、Nakamura Katsunosuke、Kitazawa Hirokazu、Hayashi Shun、Koyasu Kiichirou、Tsukuda Tatsuya
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 20 Pages: 13174-13179

    • DOI

      10.1021/acs.jpcc.9b03455

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Trimetallic (HPd@M2Au8)3+ Superatoms (M = Ag, Cu) via Hydride-Mediated Regioselective Doping to (Pd@Au8)2+2019

    • Author(s)
      Hirai Haru、Takano Shinjiro、Tsukuda Tatsuya
    • Journal Title

      ACS Omega

      Volume: 4 Issue: 4 Pages: 7070-7075

    • DOI

      10.1021/acsomega.9b00575

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] xTunes: A new XAS processing tool for detailed and on-the-fly analysis2019

    • Author(s)
      Asakura Hiroyuki、Yamazoe Seiji、Misumi Teppei、Fujita Aki、Tsukuda Tatsuya、Tanaka Tsunehiro
    • Journal Title

      Radiation Physics and Chemistry

      Volume: 未定

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] クラスター間の自発的電子移動による開殻系クラスター[PtAu24(SC2H4Ph)18]-;の化学量論的生成2019

    • Author(s)
      陶山めぐみ・高野慎二郎・中村敏和・佃達哉
    • Journal Title

      ナノ学会会報,

      Volume: 18 Pages: 21-26

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structures of Chemically Modified Superatoms2019

    • Author(s)
      Tsukuda Tatsuya
    • Journal Title

      Molecular Science

      Volume: 13 Issue: 1 Pages: A0108

    • DOI

      10.3175/molsci.13.A0108

    • NAID

      130007696987

    • ISSN
      1881-8404
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Controlling Nanoparticles with Atomic Precision2019

    • Author(s)
      Jin Rongchao、Pei Yong、Tsukuda Tatsuya
    • Journal Title

      Accounts of Chemical Research

      Volume: 52 Issue: 1 Pages: 1-1

    • DOI

      10.1021/acs.accounts.8b00631

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] X-ray Absorption Spectroscopy on Atomically Precise Metal Clusters2019

    • Author(s)
      Yamazoe Seiji、Tsukuda Tatsuya
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 92 Issue: 1 Pages: 193-204

    • DOI

      10.1246/bcsj.20180282

    • NAID

      130007578564

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] N-heterocyclic carbene-functionalized magic-number gold nanoclusters2019

    • Author(s)
      Mina R. Narouz, Kimberly M. Osten, Phillip J. Unsworth, Renee W. Y. Man, Kirsi Salorinne, Shinjiro Takano, Masakazu Nambo, Hannu Hukkinen, Tatsuya Tsukuda, Cathleen M. Crudden et al
    • Journal Title

      Nature Chemistry

      Volume: - Issue: 5 Pages: 419-425

    • DOI

      10.1038/s41557-019-0246-5

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] X線吸収分光法による配位子保護金属クラスターの構造・結合の硬さ評価2019

    • Author(s)
      山添誠司、佃達哉
    • Journal Title

      ナノ学会会報

      Volume: 17 Pages: 43-47

    • NAID

      40021871372

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydride Doping of Chemically Modified Gold-Based Superatoms2018

    • Author(s)
      Takano Shinjiro、Hasegawa Shingo、Suyama Megumi、Tsukuda Tatsuya
    • Journal Title

      Accounts of Chemical Research

      Volume: 51 Issue: 12 Pages: 3074-3083

    • DOI

      10.1021/acs.accounts.8b00399

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Prominent hydrogenation catalysis of a PVP-stabilized Au34 superatom provided by doping a single Rh atom2018

    • Author(s)
      Hasegawa Shingo、Takano Shinjiro、Yamazoe Seiji、Tsukuda Tatsuya
    • Journal Title

      Chemical Communications

      Volume: 54 Issue: 46 Pages: 5915-5918

    • DOI

      10.1039/c8cc03123a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Collision-Induced Dissociation of Undecagold Clusters Protected by Mixed Ligands [Au11(PPh3)8X2]+ (X = Cl, C≡CPh)2018

    • Author(s)
      Tomihara Ryohei、Hirata Keisuke、Yamamoto Hiroki、Takano Shinjiro、Koyasu Kiichirou、Tsukuda Tatsuya
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 6 Pages: 6237-6242

    • DOI

      10.1021/acsomega.8b01096

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] An Au25(SR)18 Cluster with a Face-Centered Cubic Core2018

    • Author(s)
      Omoda Tsubasa、Takano Shinjiro、Yamazoe Seiji、Koyasu Kiichirou、Negishi Yuichi、Tsukuda Tatsuya
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 24 Pages: 13199-13204

    • DOI

      10.1021/acs.jpcc.8b03841

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydride-Doped Gold Superatom (Au9H)2+: Synthesis, Structure, and Transformation2018

    • Author(s)
      Takano Shinjiro、Hirai Haru、Muramatsu Satoru、Tsukuda Tatsuya
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 27 Pages: 8380-8383

    • DOI

      10.1021/jacs.8b03880

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydride-Mediated Controlled Growth of a Bimetallic (Pd@Au8)2+ Superatom to a Hydride-Doped (HPd@Au10)3+ Superatom2018

    • Author(s)
      Takano Shinjiro、Hirai Haru、Muramatsu Satoru、Tsukuda Tatsuya
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 39 Pages: 12314-12317

    • DOI

      10.1021/jacs.8b06783

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interconversions of Structural Isomers of [PdAu8(PPh3)8]2+ and [Au9(PPh3)8]3+ Revealed by Ion Mobility Mass Spectrometry2018

    • Author(s)
      Hirata Keisuke、Chakraborty Papri、Nag Abhijit、Takano Shinjiro、Koyasu Kiichirou、Pradeep Thalappil、Tsukuda Tatsuya
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 40 Pages: 23123-23128

    • DOI

      10.1021/acs.jpcc.8b04722

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Abstraction of the I Atom from CH3I by Gas-Phase Aun? (n = 1?4) via Reductive Activation of the C?I Bond2018

    • Author(s)
      Muramatsu Satoru、Koyasu Kiichirou、Tsukuda Tatsuya
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 12 Pages: 16874-16881

    • DOI

      10.1021/acsomega.8b02809

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 炭素含有アルミニウムクラスターAlnC2-の構造多様性2018

    • Author(s)
      鶴岡和幸、小安喜一郎、平林慎一、市橋正彦、佃達哉
    • Journal Title

      ナノ学会会報

      Volume: 17 Pages: 11-15

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 炭素担持金クラスターの構造と触媒作用の相関2018

    • Author(s)
      山添誠司、佃達哉
    • Journal Title

      触媒

      Volume: 60 Pages: 134-139

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient One-Pot Synthesis and pH-Dependent Tuning of Photoluminescence and Stability of Au18(SC2H4CO2H)14 Cluster2018

    • Author(s)
      Itteboina Ramakrishna、Madhuri U. Divya、Ghosal Partha、Kannan Monica、Sau Tapan K.、Tsukuda Tatsuya、Bhardwaj Shweta
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 122 Issue: 5 Pages: 1228-1234

    • DOI

      10.1021/acs.jpca.7b10888

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Au25-Loaded BaLa4Ti4O15 Water-Splitting Photocatalyst with Enhanced Activity and Durability Produced Using New Chromium Oxide Shell Formation Method2018

    • Author(s)
      W. Kurashige, R. Kumazawa, D. Ishii, R. Hayashi, Y. Niihori, S. Hossain, L. V. Nair, T. Takayama, A. Iwase, S. Yamazoe, T. Tsukuda, A. Kudo, Y. Negishi
    • Journal Title

      J. Phys. Chem. C

      Volume: 印刷中 Issue: 25 Pages: 13669-13681

    • DOI

      10.1021/acs.jpcc.8b00151

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Size-Dependent Polymorphism in Aluminum Carbide Cluster Anions AlnC2-: Formation of Acetylide-Containing Structures2018

    • Author(s)
      Kazuyuki Tsuruoka, Kiichirou Koyasu , Shinichi Hirabayashi, Masahiko Ichihashi, Tatsuya Tsukuda
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 15 Pages: 8341-8347

    • DOI

      10.1021/acs.jpcc.7b12767

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold Ultrathin Nanorods with Controlled Aspect Ratios and Surface Modifications: Formation Mechanism and Localized Surface Plasmon Resonance2018

    • Author(s)
      Takahata Ryo、Yamazoe Seiji、Koyasu Kiichirou、Imura Kohei、Tsukuda Tatsuya
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 21 Pages: 6640-6647

    • DOI

      10.1021/jacs.8b02884

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lewis Base Catalytic Properties of [Nb10O28]6- for CO2 Fixation to Epoxide: Kinetic and Theoretical Studies2017

    • Author(s)
      Hayashi Shun、Yamazoe Seiji、Koyasu Kiichirou、Tsukuda Tatsuya
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 12 Issue: 13 Pages: 1635-1640

    • DOI

      10.1002/asia.201700534

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Suppressing Isomerization of Phosphine-Protected Au9 Cluster by Bond Stiffening Induced by a Single Pd Atom Substitution2017

    • Author(s)
      Yamazoe Seiji、Matsuo Shota、Muramatsu Satoru、Takano Shinjiro、Nitta Kiyofumi、Tsukuda Tatsuya
    • Journal Title

      Inorganic Chemistry

      Volume: 56 Issue: 14 Pages: 8319-8325

    • DOI

      10.1021/acs.inorgchem.7b00973

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correction to Suppressing Isomerization of Phosphine-Protected Au9 Cluster by Bond Stiffening Induced by a Single Pd Atom Substitution2017

    • Author(s)
      Yamazoe Seiji、Matsuo Shota、Muramatsu Satoru、Takano Shinjiro、Nitta Kiyofumi、Tsukuda Tatsuya
    • Journal Title

      Inorganic Chemistry

      Volume: 57 Issue: 1 Pages: 535-535

    • DOI

      10.1021/acs.inorgchem.7b03087

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Anion photoelectron spectroscopy of free [Au25(SC12H25)18]-2017

    • Author(s)
      Hirata Keisuke、Yamashita Keishiro、Muramatsu Satoru、Takano Shinjiro、Ohshimo Keijiro、Azuma Toshiyuki、Nakanishi Ryuzo、Nagata Takashi、Yamazoe Seiji、Koyasu Kiichirou、Tsukuda Tatsuya
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 36 Pages: 13409-13412

    • DOI

      10.1039/c7nr04641c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoassisted Homocoupling of Methyl Iodide Mediated by Atomic Gold in Low-Temperature Neon Matrix2017

    • Author(s)
      Muramatsu Satoru、Wu Xuan、Chen Mohua、Zhou Mingfei、Tsukuda Tatsuya
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 121 Issue: 44 Pages: 8408-8413

    • DOI

      10.1021/acs.jpca.7b08863

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structure Determination of a Water-Soluble 144-Gold Atom Particle at Atomic Resolution by Aberration-Corrected Electron Microscopy2017

    • Author(s)
      Azubel Maia、Koh Ai Leen、Koyasu Kiichirou、Tsukuda Tatsuya、Kornberg Roger D.
    • Journal Title

      ACS Nano

      Volume: 11 Issue: 12 Pages: 11866-11871

    • DOI

      10.1021/acsnano.7b06051

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ion Transport across Biological Membranes by Carborane-Capped Gold Nanoparticles2017

    • Author(s)
      Grzelczak Marcin P.、Danks Stephen P.、Klipp Robert C.、Belic Domagoj、Zaulet Adnana、Kunstmann-Olsen Casper、Bradley Dan F.、Tsukuda Tatsuya、Vi?as Clara、Teixidor Francesc、Abramson Jonathan J.、Brust Mathias
    • Journal Title

      ACS Nano

      Volume: 11 Issue: 12 Pages: 12492-12499

    • DOI

      10.1021/acsnano.7b06600

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dynamic Behavior of Rh Species in Rh/Al2O3 Model Catalyst during Three-Way Catalytic Reaction: An Operando X-ray Absorption Spectroscopy Study2017

    • Author(s)
      Asakura Hiroyuki、Hosokawa Saburo、Ina Toshiaki、Kato Kazuo、Nitta Kiyofumi、Uera Kei、Uruga Tomoya、Miura Hiroki、Shishido Tetsuya、Ohyama Junya、Satsuma Atsushi、Sato Katsutoshi、Yamamoto Akira、Hinokuma Satoshi、Yoshida Hiroshi、Machida Masato、Yamazoe Seiji、Tsukuda Tatsuya、Teramura Kentaro、Tanaka Tsunehiro
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 1 Pages: 176-184

    • DOI

      10.1021/jacs.7b07114

    • NAID

      120006394775

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Doping a Single Palladium Atom into Gold Superatoms Stabilized by PVP: Emergence of Hydrogenation Catalysis2017

    • Author(s)
      Hayashi Shun、Ishida Ryo、Hasegawa Shingo、Yamazoe Seiji、Tsukuda Tatsuya
    • Journal Title

      Topics in Catalysis

      Volume: 61 Issue: 1-2 Pages: 136-141

    • DOI

      10.1007/s11244-017-0876-z

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] コバルトクラスター負イオンの酸化過程におけるConOm-の魔法組成の出現とその起源2017

    • Author(s)
      冨原良平、小安喜一郎、佃達哉
    • Journal Title

      ナノ学会会報

      Volume: 16 Pages: 7-14

    • NAID

      40021379152

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Gas-phase studies on chemically-synthesized Au and Ag superatoms2020

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      Symposium on Size Selected Clusters
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electronic structures of ligand-protected Au/Ag superatoms2020

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      Gordon Research Conference; Towards Atomic Precision in Nanochemistry
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機修飾金属超原子―最近の進展から2019

    • Author(s)
      佃達哉
    • Organizer
      Ambitious物質科学セミナー
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 金属クラスターの化学2019

    • Author(s)
      佃達哉
    • Organizer
      第10回表面化学チュートリアル
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Chemically modified gold and silver superatoms: From liquid phase to gas phase2019

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      The 76th Fujihara Seminar, International Workshop on Designer Nanocluster Materials: From Gas Phase to Condensed Phase
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Characterization of ligand-protected gold and silver clusters in gas phase2019

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      International Symposium on Monolayer-Protected Clusters (ISMPC19)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Characterization of chemically modified gold and silver clusters in gas phase2019

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      2nd Asian Symposium on Nanoscience and Nanotechnology "Fundamentals and Applications of Nanoclusters and Nanoparticles"
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hydride-mediated transformations of gold-based superatoms2019

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      ChinaNANO2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 化学修飾された超原子と超原子分子2019

    • Author(s)
      佃達哉
    • Organizer
      東北大学理学部化学教室一般雑誌会講演会
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Chemically modified gold and silver superatoms: recent topics2019

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      Seminar at Shanxi Normal University
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Chemically modified gold and silver superatoms: recent topics2019

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      Seminar at Tsinghua University
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノの世界の美しさー超原子とその周期表―2019

    • Author(s)
      佃達哉
    • Organizer
      第4回駒場サイエンス倶楽部
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Photoelectron spectroscopy on chemically-modified coinage metal clusters in the gas phase2019

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      The 4th STEPS Symposium on Photon Science
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hydride-doped gold superatoms: synthesis, structure & transformation2019

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      Gordon Research Conference - Chemical Reactions at Surfaces
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Gold superatoms & superatomic molecules protected by ligands2019

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      The University of Tokyo - Jilin University Joint Symposium
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hydrogen-doped gold-based superatoms: synthesis, structure and transformation2018

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      2018 MRS Fall Meeting & Exhibit
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Single atom doping effect on catalysis of gold clusters2018

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      AsiaNano 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hydride doping to chemically-modified gold-based superatoms2018

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      The China-Japan-Singapore Symposium on Metal Nanoclusters and Biomaterial
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属クラスターの化学2018

    • Author(s)
      佃達哉
    • Organizer
      第9回表面化学チュートリアル
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ヒドリドをドープした金超原子:生成、構造、反応性2018

    • Author(s)
      佃達哉
    • Organizer
      シンポジウム「化学反応経路探索のニューフロンティア2018」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Gold Ultrathin Nanorods with Controlled Aspect Ratios & Surface Modifications: Formation Mechanism & Localized Surface Plasmon Resonance2018

    • Author(s)
      Ryo Takahata, Seiji Yamazoe, Kiichirou Koyasu, Kohei Imura, Tatsuya Tsukuda
    • Organizer
      第12回分子科学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Gold superatoms and superatomic molecules protected by ligands2018

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      IMS Distinguished Lectureship at LANL
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Single atom doping effect on catalysis of gold clusters2018

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      Seminar at the UNM Center for Micro-Engineered Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Chiroptical properties of ligand-protected gold clusters2018

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      The Third STEPS Symposium on Photon Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 貨幣金属クラスター触媒の精密合成と触媒性能2017

    • Author(s)
      佃達哉
    • Organizer
      日本表面科学会第2回関東支部講演大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Gold superatoms and superatomic molecules protected by ligands2017

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      RACI National Centenary Conference 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Protected Gold Superatoms with 6, 8, and 10e: Toward Periodic Table in Nanoscale2017

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      International Symposium on Monolayer-Protected Clusters (ISMPC17)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Gold superatoms and superatomic molecules protected by ligands2017

    • Author(s)
      Tatsuya Tsukuda
    • Organizer
      68th Annual Meeting of the International Society of Electrochemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金超原子・超原子分子の精密合成と放射光を用いた構造解析2017

    • Author(s)
      佃達哉
    • Organizer
      第6回 SPring-8 グリーンサスティナブルケミストリー研究会 第18 回 SPring-8 先端利用技術ワークショップ「金属ナノ粒子触媒開発の最前線―構造と機能の制御」
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 担持金属クラスター触媒の精密合成2017

    • Author(s)
      佃達哉
    • Organizer
      触媒シンポジウム「新しい触媒設計・触媒技術」
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Book] Physical Chemistry of Cold Gas-Phase Functional Molecules and Clusters2019

    • Author(s)
      Takayuki Ebata, Masaaki Fujii
    • Total Pages
      395
    • Publisher
      Verlag: Springer Singapore
    • ISBN
      9789811393709
    • Related Report
      2019 Annual Research Report
  • [Book] 金属クラスターの化学2017

    • Author(s)
      佃 達哉
    • Total Pages
      127
    • Publisher
      サイエンス社
    • ISBN
      9784781914060
    • Related Report
      2017 Annual Research Report
  • [Remarks] 東京大学理学系理学系研究科化学専攻化学反応研究室

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/chemreact/index.html

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report 2017 Annual Research Report

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Published: 2017-04-28   Modified: 2022-02-28  

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