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Exploration of Excited State Properties of Heteroporphyrins

Research Project

Project/Area Number 17H01190
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionNagoya University

Principal Investigator

Shinokubo Hiroshi  名古屋大学, 工学研究科, 教授 (50281100)

Project Period (FY) 2017-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥44,720,000 (Direct Cost: ¥34,400,000、Indirect Cost: ¥10,320,000)
Fiscal Year 2021: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2020: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2019: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2018: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2017: ¥20,800,000 (Direct Cost: ¥16,000,000、Indirect Cost: ¥4,800,000)
Keywordsポルフィリン / ヘテロ原子 / 芳香族性 / 反芳香族性 / 光物性 / 励起状態 / π電子化合物 / 光線力学療法 / 非線形光学応答 / 二重蛍光 / [2+2]環化付加 / 電気化学 / ヘテロ元素 / 金属錯体 / π共役 / 発光
Outline of Final Research Achievements

A variety of heteroatoms were introduced in the porphyrin skeleton to obtain novel heteroatom-embedded porphyrins via metal-templated synthesis. The heteroporphyrins exhibited aromaticity or antiaromaticity depending on the nature of introduced heteroatoms. The optical properties such as absorption and emission wavelengths and the excited state dynamics were also controlled by the proper choice of heteroatoms. In particular, diazaporphyrin derivatives effectively absorb near-infrared light and serve as potent photosensitizers for photodynamic therapy. An oxaporphyrin cobalt complex combined with a heme acquisition protein HasA strongly inhibited the growth of P. aeruginosa and multidrug-resistant P. aeruginosa.

Academic Significance and Societal Importance of the Research Achievements

機能性色素として多方面に応用されるポルフィリンに対してヘテロ原子を導入する方法を確立したことで、ポルフィリンの物性変調の手法を格段に拡大することができた。高性能な近赤外色素の開発につながる成果と言える。実際、窒素を導入したジアザポルフィリンが光線力学療法によるがん治療のための光増感剤として可能性をもつことを生物学的実験により示すことができた。

Report

(6 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (181 results)

All 2022 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (17 results) Journal Article (41 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 41 results,  Open Access: 4 results) Presentation (118 results) (of which Int'l Joint Research: 39 results,  Invited: 40 results) Remarks (4 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Int'l Joint Research] Yonsei Universityonsei(韓国)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] Montpellier University(フランス)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] Yonsei University(韓国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] University of Montpellier(フランス)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Karlsruhe Institute of Technology(ドイツ)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Western Washington University(米国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] 延世大学(韓国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] モンペリエ大学(フランス)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] カールスルーエ工科大学(ドイツ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] ウエスタンワシントン大学(米国)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Karlsruhe Institute of Technology(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Institut Charles Gerhardt de Montpellier/Institut des Biomolecules Max Mousseron(フランス)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Yonsei University(韓国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Western Washington University(米国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] University of Bath(英国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Montpellier大学(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Yonsei大学(韓国)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Diverse Crystal Structures of Ion Pairs Consisting of Oxaporphyrinium Cations and Pentacyanocyclopentadienide2022

    • Author(s)
      Takiguchi Asahi、Tanaka Hiroki、Maeda Hiromitsu、Shinokubo Hiroshi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 95 Issue: 5 Pages: 796-801

    • DOI

      10.1246/bcsj.20220026

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nitrogen Extrusion of Diazacorrphycenes to Azacorroles and Synthesis of Two Types of Copper 10-Azacorrole Complexes2022

    • Author(s)
      Yagi Atsumi、Okada Naoya、Fukui Norihito、Tanaka Hisaaki、Hatakeyama Takuji、Shinokubo Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 51 Issue: 3 Pages: 321-324

    • DOI

      10.1246/cl.210777

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Heme‐Acquisition Protein Reconstructed with a Cobalt 5‐Oxaporphyrinium Cation and Its Growth‐Inhibition Activity Toward Multidrug‐Resistant Pseudomonas aeruginosa2022

    • Author(s)
      Takiguchi Asahi、Sakakibara Erika、Sugimoto Hiroshi、Shoji Osami、Shinokubo Hiroshi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 61 Issue: 7 Pages: 202112456-202112456

    • DOI

      10.1002/anie.202112456

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 5-Thiaporphyrinium Cation: Effect of Sulphur Incorporation on Excited State Dynamics2022

    • Author(s)
      Takiguchi Aashi、Inai Naoto、Kang Seongsoo、Hagai Masaya、Lee Seokwon、Yanai Takeshi、Kim Dongho、Shinokubo Hiroshi
    • Journal Title

      Chemical Communications

      Volume: 58 Issue: 40 Pages: 5956-5959

    • DOI

      10.1039/d2cc00522k

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis and Tautomerization of 5-Azaporphyrinium Cations2022

    • Author(s)
      Takiguchi Asahi、Shinokubo Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 51 Issue: 6 Pages: 590-593

    • DOI

      10.1246/cl.220122

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Manganese(III) 5,15-diazaporphyrins: Synthesis, properties, and catalytic use for benzylic C?H fluorination2021

    • Author(s)
      Mori Shiho、Nishimura Tsubasa、Shinokubo Hiroshi、Miyake Yoshihiro
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 25 Issue: 10n12 Pages: 991-996

    • DOI

      10.1142/s1088424621500887

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ron hexamesityl-5,15-diazaporphyrin: synthesis, structure and catalytic use for direct oxidation of sp3 C–H bonds2021

    • Author(s)
      Tsubasa Nishimura ,Takahiro Sakurai ,Hiroshi Shinokubo , and Yoshihiro Miyake
    • Journal Title

      Dalton Transactions

      Volume: 50 Issue: 18 Pages: 6343-6348

    • DOI

      10.1039/d1dt00893e

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Complexation of 2,7-diazapyrene with boron for structural and electronic tuning2021

    • Author(s)
      Nakazato Takumi、Shinokubo Hiroshi、Miyake Yoshihiro
    • Journal Title

      Chemical Communications

      Volume: 57 Issue: 3 Pages: 327-330

    • DOI

      10.1039/d0cc07804b

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dinaphtho[1,8‐ bc :1′,8′‐ fg ][1,5]dithiocine Bisimide2021

    • Author(s)
      Tanaka Yuki、Tajima Keita、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Asian Journal of Organic Chemistry

      Volume: 10 Issue: 3 Pages: 541-544

    • DOI

      10.1002/ajoc.202000722

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox-induced reversible [2 + 2] cycloaddition of an etheno-fused diporphyrin2021

    • Author(s)
      Miyagawa Kazuya、Hisaki Ichiro、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Chemical Science

      Volume: 12 Issue: 14 Pages: 5224-5229

    • DOI

      10.1039/d1sc00438g

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Peripherally Arylated 2,8-Diazaperylenes from Anthracene Diimide: Synthesis and Oxidative Annulation2021

    • Author(s)
      Sakurai Takahiro、Nakazato Takumi、Shinokubo Hiroshi、Miyake Yoshihiro
    • Journal Title

      Organic Letters

      Volume: 23 Issue: 6 Pages: 2099-2103

    • DOI

      10.1021/acs.orglett.1c00253

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of an 18π Aromatic Norcorrole P(V) Complex2021

    • Author(s)
      Yoshida Takuya、Shafie Siham Asyiqin、Kawashima Hiroyuki、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Organic Letters

      Volume: 23 Issue: 7 Pages: 2826-2830

    • DOI

      10.1021/acs.orglett.1c00823

    • NAID

      120007175389

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and crystal packing structures of 2,7-diazapyrenes with various alkyl groups at 1,3,6,8-positions2020

    • Author(s)
      Takumi Nakazato, Wakana Matsuda, Tsuneaki Sakurai, Shu Seki, Hiroshi Shinokubo, Yoshihiro Miyake
    • Journal Title

      Chemistry Letters

      Volume: 49 Issue: 5 Pages: 465-468

    • DOI

      10.1246/cl.200083

    • NAID

      130007840170

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] meso‐Diazacorrphycenes: Neighboring Effect of Two Nitrogen Atoms2020

    • Author(s)
      Yagi Atsumi、Shinokubo Hiroshi
    • Journal Title

      Chemistry A European Journal

      Volume: 26 Issue: 37 Pages: 8210-8213

    • DOI

      10.1002/chem.202002053

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reactions of Antiaromatic Norcorrole Ni(II) Complex with Carbenes2020

    • Author(s)
      Liu Si-Yu、Fukuoka Takaki、Fukui Norihito、Shin Ji-Young、Shinokubo Hiroshi
    • Journal Title

      Organic Letters

      Volume: 22 Issue: 11 Pages: 4400-4403

    • DOI

      10.1021/acs.orglett.0c01402

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A 2-to-2′ 18-to-18′ doubly linked Ni(ii) norcorrole dimer: an effectively conjugated antiaromatic dyad2020

    • Author(s)
      Liu Si-Yu、Kawashima Hiroyuki、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 50 Pages: 6846-6849

    • DOI

      10.1039/d0cc02543g

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dinaphthothiepine Bisimide and Its Sulfoxide: Soluble Precursors for Perylene Bisimide2020

    • Author(s)
      Hayakawa Sakiho、Matsuo Kyohei、Yamada Hiroko、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Journal of the American Chemical Society

      Volume: 142 Issue: 27 Pages: 11663-11668

    • DOI

      10.1021/jacs.0c04096

    • NAID

      120006941029

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] as-Indaceno[3,2,1,8,7,6-ghijklm]terrylene as a near-infrared absorbing C70-fragment2020

    • Author(s)
      Tanaka Yuki、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 3873-3873

    • DOI

      10.1038/s41467-020-17684-6

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Aggregation‐Induced Emission in Tetrathia[8]circulene Octaoxides via Restriction of the Dynamic Motion of their Negatively Curved π‐Frameworks2020

    • Author(s)
      Murase Hiroyasu、Nagata Yuya、Akahori Shuhei、Shinokubo Hiroshi、Miyake Yoshihiro
    • Journal Title

      Chemistry An Asian Journal

      Volume: 15 Issue: 22 Pages: 3873-3877

    • DOI

      10.1002/asia.202001129

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Site-selective halogenation on meso-mesityl substituents of 10,20-dimesityl-5,15-diazaporphyrins with an AuX3/AgOTf combination2020

    • Author(s)
      Longevial Jean-Francois、Miyagawa Kazuya、Shinokubo Hiroshi
    • Journal Title

      Dalton Transactions

      Volume: 49 Issue: 42 Pages: 14786-14789

    • DOI

      10.1039/d0dt02727h

    • NAID

      120007145964

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron(III) 5,15-Diazaporphyrin Catalysts for the Direct Oxidation of C(sp3)?H Bonds2020

    • Author(s)
      Nishimura Tsubasa、Ikeue Takahisa、Shoji Osami、Shinokubo Hiroshi、Miyake Yoshihiro
    • Journal Title

      Inorganic Chemistry

      Volume: 59 Issue: 21 Pages: 15751-15756

    • DOI

      10.1021/acs.inorgchem.0c02166

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dual Emission of a Free‐Base 5‐Oxaporphyrinium Cation from its cis‐ and trans‐NH Tautomers2020

    • Author(s)
      Takiguchi Asahi、Kang Seongsoo、Fukui Norihito、Kim Dongho、Shinokubo Hiroshi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 60 Issue: 6 Pages: 2915-2919

    • DOI

      10.1002/anie.202013542

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Site‐Selective N‐Methylation of 5,15‐Diazaporphyrins: Reactive Cationic Porphyrinoids that Provide Isoporphyrin Analogues2020

    • Author(s)
      Chia Wen Xi、Nishijo Mayu、Kang Seongsoo、Oh Juwon、Nishimura Tsubasa、Omori Hiroto、Longevial Jean‐Fran?ois、Miyake Yoshihiro、Kim Dongho、Shinokubo Hiroshi
    • Journal Title

      Chemistry European Journal

      Volume: 26 Issue: 12 Pages: 2754-2760

    • DOI

      10.1002/chem.201905402

    • NAID

      120006848960

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis and properties of 5-aza-15-thiaporphyrins2020

    • Author(s)
      Yamashita Daisuke、Omori Hiroto、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 24 Issue: 01n03 Pages: 84-89

    • DOI

      10.1142/s108842461950069x

    • NAID

      120006848966

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of meso‐Alkyl‐Substituted Norcorrole Ni(II) Complexes and Conversion to 5‐Oxaporphyrins(2.0.1.0)2019

    • Author(s)
      Liu Si‐Yu、Tanaka Hiroko、Nozawa Ryo、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Chemistry A European Journal

      Volume: 25 Issue: 32 Pages: 7618-7622

    • DOI

      10.1002/chem.201901292

    • NAID

      120006732055

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins2019

    • Author(s)
      Takiguchi Asahi、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Organic Letters

      Volume: 21 Issue: 11 Pages: 3950-3953

    • DOI

      10.1021/acs.orglett.9b01066

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ni(II) 10-Boracorrole: An Antiaromatic Porphyrinoid Containing a Boron Atom at the meso-Position2019

    • Author(s)
      Omori Hiroto、Shinokubo Hiroshi
    • Journal Title

      Organometallics

      Volume: 38 Issue: 15 Pages: 2878-2882

    • DOI

      10.1021/acs.organomet.9b00303

    • NAID

      120006765138

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Three-dimensional Aromaticity in an Antiaromatic Cyclophane2019

    • Author(s)
      Ryo Nozawa, Jinseok Kim, Juwon Oh, AnnaKamping, Yemei Wang, Soji Shimizu, Ichiro Hisaki, Tim Kowalczyk, Heike Fliegl, Dongho Kim, Horoshi Shinokubo
    • Journal Title

      Nat. Comm.

      Volume: 10 Issue: 1 Pages: 3576-3576

    • DOI

      10.1038/s41467-019-11467-4

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 5,5,15,15‐Tetraoxo‐5,15‐Dithiaporphyrin as a Highly Electron‐Deficient Porphyrinic Ligand2019

    • Author(s)
      Yagi Atsumi、Kondo Takeshi、Yamashita Daisuke、Wachi Naruhiko、Omori Hiroto、Fukui Norihito、Ikeue Takahisa、Shinokubo Hiroshi
    • Journal Title

      Chemistry A European Journal

      Volume: 25 Issue: 68 Pages: 15580-15585

    • DOI

      10.1002/chem.201903639

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers2019

    • Author(s)
      Tajima Keita、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Organic Letters

      Volume: 21 Issue: 23 Pages: 9516-9520

    • DOI

      10.1021/acs.orglett.9b03699

    • NAID

      120006848968

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inserting Nitrogen: An Effective Concept To Create Nonplanar and Stimuli-Responsive Perylene Bisimide Analogues2019

    • Author(s)
      Hayakawa Sakiho、Kawasaki Ayumi、Hong Yongseok、Uraguchi Daisuke、Ooi Takashi、Kim Dongho、Akutagawa Tomoyuki、Fukui Norihito、Shinokubo Hiroshi
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 50 Pages: 19807-19816

    • DOI

      10.1021/jacs.9b09556

    • NAID

      120006848967

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s2019

    • Author(s)
      Shafie Siham A, Kawashima Hiroyuki, Miyake Yoshihiro, Shinokubo Hiroshi
    • Journal Title

      ChemPlusChem

      Volume: 84 Issue: 6 Pages: 623-626

    • DOI

      10.1002/cplu.201900068

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ni(II) 10-Phosphacorrole: A Porphyrin Analogue Containing Phosphorus at the Meso Position2019

    • Author(s)
      Omori Hiroto、Hiroto Satoru、Takeda Youhei、Fliegl Heike、Minakata Satoshi、Shinokubo Hiroshi
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 12 Pages: 4800-4805

    • DOI

      10.1021/jacs.8b13169

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of dihydropyrazine-fused porphyrin dimers2019

    • Author(s)
      A. Takiguchi, M. Wakita, S. Hiroto, H. Shinokubo
    • Journal Title

      Chem. Lett.

      Volume: 48 Issue: 4 Pages: 371-373

    • DOI

      10.1246/cl.190002

    • NAID

      130007624435

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Diazachlorin and diazabacteriochlorin for one- and two-photon photodynamic therapy2018

    • Author(s)
      Longevial Jean-Francois、Yamaji Ayaka、Aggad Dina、Kim Gakhyun、Chia Wen Xi、Nishimura Tsubasa、Miyake Yoshihiro、Cl?ment Sebastien、Oh Juwon、Daurat Morgane、Nguyen Christophe、Kim Dongho、Gary-Bobo Magali、Richeter Sebastien、Shinokubo Hiroshi
    • Journal Title

      Chemical Communications

      Volume: 54 Issue: 98 Pages: 13829-13832

    • DOI

      10.1039/c8cc07489e

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] X-Shaped Cyclobutane-Linked Tetraporphyrins through a Thermal [2+2] Cycloaddition of Etheno-Fused Diporphyrins2018

    • Author(s)
      Tomohiro Nagai, Asahi Takiguchi, Masayuki Ueda, Kazuma Oda, Satoru Hiroto, Hiroshi Shinokubo
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 27 Pages: 8392-8395

    • DOI

      10.1021/jacs.8b04673

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nickel (II) pyrrocorphin: Enhanced binding ability in a highly reduced porphyrin complex2018

    • Author(s)
      Y. Ide, T. Kuwahara, S. Takeshita, R. Fujishiro, M. Suzuki, S. Mori, H. Shinokubo, M. Nakamura, K. Yoshinoe, T. Ikeue
    • Journal Title

      J. Inorg. Biochem.

      Volume: 178 Pages: 115-124

    • DOI

      10.1016/j.jinorgbio.2017.10.012

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structures of the Heme Acquisition Protein HasA with Iron(III)-5,15-Diphenylporphyrin and Derivatives Thereof as an Artificial Prosthetic Group2017

    • Author(s)
      Uehara Hiromu、Shisaka Yuma、Nishimura Tsubasa、Sugimoto Hiroshi、Shiro Yoshitsugu、Miyake Yoshihiro、Shinokubo Hiroshi、Watanabe Yoshihito、Shoji Osami
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 48 Pages: 15279-15283

    • DOI

      10.1002/anie.201707212

    • NAID

      120006382255

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of meso-Arylated Corrphycenes2017

    • Author(s)
      R. Nozawa, H. Shinokubo
    • Journal Title

      Org. Lett.

      Volume: 19 Issue: 18 Pages: 4928-4931

    • DOI

      10.1021/acs.orglett.7b02390

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 10-Silacorroles Exhibiting NIR Absorption and Emission2017

    • Author(s)
      H. Omori, S. Hiroto, H. Shinokubo
    • Journal Title

      Chem. Eur. J.

      Volume: 23 Issue: 33 Pages: 7866-7870

    • DOI

      10.1002/chem.201701474

    • NAID

      120006349126

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Acid-Mediated Migration of Bromide in an Antiaromatic Porphyrinoid: Preparation of Two Regioisomeric Ni(II) Bromonorcorroles2017

    • Author(s)
      H. Kawashima, S. Hiroto, H. Shinokubo
    • Journal Title

      J. Org. Chem.

      Volume: 82 Issue: 19 Pages: 10425-10432

    • DOI

      10.1021/acs.joc.7b01899

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 外周部に金属配位したテトラピリジルジアザポルフィリンパラジウム錯体の合成と物性2022

    • Author(s)
      櫻井 貴浩, 三宅 由寛, 忍久保 洋
    • Organizer
      日本化学会第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] テトラブロモジピリンを基盤とするβ位修飾ジアザポルフィリンの合成2021

    • Author(s)
      櫻井貴浩,西村翼, 三宅由寛,忍久保洋
    • Organizer
      第31回基礎有機化学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] オキサポルフィリニウムカチオンの構造・物性と生物活性2021

    • Author(s)
      瀧口 あさひ、榊原 えりか、杉本 宏、荘司 長三、忍久保 洋
    • Organizer
      第31回基礎有機化学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Facile Synthesis of Bilindione and Optical Property of 5-Oxaporphyrinium Cation2021

    • Author(s)
      瀧口 あさひ, Seongsoo Kang, 福井 識人, Dongho Kim, 忍久保 洋
    • Organizer
      11th International Conference on Porphyrins and Phthalocyanines (ICPP-11)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Property of 14,15-Diazacorrphycene Palladium Complex2021

    • Author(s)
      八木 篤実, 忍久保 洋
    • Organizer
      11th International Conference on Porphyrins and Phthalocyanines (ICPP-11)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 反芳香族ポルフィリン:ノルコロールの化学2021

    • Author(s)
      忍久保 洋
    • Organizer
      東北大学大学院理学研究科講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ビリンジオンの簡易合成法と5-オキサポルフィリニウムカチオンの光学特性2021

    • Author(s)
      Asahi Takiguchi, Seongsoo Kang, Norihito Fukui, Dongho Kim, Hiroshi Shinokubo
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] カルボニル基を挿入したペリレンビスイミド類縁体の合成と物性2021

    • Author(s)
      Mai Odajima, Keita Tajima, Norihito Fukui, Hiroshi shinokubo
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] アザインドール骨格をもつオクタアザ[8]サーキュレンの合成とそのプロトン化挙動2021

    • Author(s)
      Shuhei Akahori, Hiroshi Shinokubo, Yoshihiro Miyake
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 2,7-ジアザピレン骨格を基盤とする水素結合性有機構造体の構築2021

    • Author(s)
      Masahiro Odawara, Masanori Shichino, Ryotaro Matsuda, Hiroshi Shinokubo, Yoshihiro Miyake
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] インデノペリレンの合成と物性2021

    • Author(s)
      Masaki Kato, Norihito Fukui, Hiroshi Shinokubo
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] アクリジノアクリジンビスイミドの合成と物性2021

    • Author(s)
      Keita Tajima, Kyohei Matsuo, Hiroko Yamada, Shu Seki, Norihito Fukui, Hiroshi shinokubo
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Synthesis and Properties of 5-Oxaporphyrinium Cation and Its Application2021

    • Author(s)
      Asahi Takiguchi, Norihito Fukui, Hiroshi Shinokubo
    • Organizer
      GTR年次報告会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Synthesis and Property of 14,15-Diazacorrphycene Metal Complex2021

    • Author(s)
      Atsumi Yagi, Hiroshi Shinokubo
    • Organizer
      GTR年次報告会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 骨格内部が官能基化されたお椀型芳香族炭化水素によるフラーレン認識2021

    • Author(s)
      Yoshihiro Takeo, Masaki Kato, Norihito Fukui, Hiroshi Shinokubo
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ジナフトジチオシンビスイミドの合成と物性2021

    • Author(s)
      Yuki Tanaka, Keita Tajima, Norihito Fukui, Hiroshi shinokubo
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] A 2-to-2' 18-to-18' Doubly Linked Ni(II) Norcorrole Dimer: An Effectively Conjugated Antiaromatic Dyad2020

    • Author(s)
      Si-Yu Liu, Hiroyuki Kawashima, Norihito Fukui, Hiroshi Shinokubo
    • Organizer
      第10回CSJ化学フェスタ2020
    • Related Report
      2020 Annual Research Report
  • [Presentation] 2,8-ジアザペリレンの合成と物性2020

    • Author(s)
      Takahiro Sakurai,Takumi Nakazato, Hiroshi Shinokubo, Yoshihiro Miyake
    • Organizer
      若手オンラインシンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] 2,8-ジアザペリレンの合成と物性2020

    • Author(s)
      Takahiro Sakurai,Takumi Nakazato , Hiroshi Shinokubo, Yoshihiro Miyake
    • Organizer
      第47回有機典型元素化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ジアザ-s-インダセンの合成と物性2020

    • Author(s)
      Kensuke Hanida, Norihito Fukui, Hiroshi Shinokubo
    • Organizer
      若手オンラインシンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] アクリジノアクリジンビスイミドの合成と物性2020

    • Author(s)
      Keita Tajima, Kyohei Matsuo, Hiroko Yamada, Shu Seki, Norihito Fukui, Hiroshi shinokubo
    • Organizer
      第47回有機典型元素化学討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 三次元芳香族性の発現を目指して2020

    • Author(s)
      忍久保 洋
    • Organizer
      金沢大学
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] ビリンジオンの簡易合成法の開発と反応性の検証2020

    • Author(s)
      瀧口 あさひ
    • Organizer
      東京理科大学
    • Related Report
      2019 Annual Research Report
  • [Presentation] 14,15-ジアザコルフィセンパラジウム錯体の合成と物性2020

    • Author(s)
      八木 篤実
    • Organizer
      東京理科大学
    • Related Report
      2019 Annual Research Report
  • [Presentation] Synthesis, Structure, and Properties of Doubly Linked Norcorrole Dimer2020

    • Author(s)
      SI-Yu Liu
    • Organizer
      東京理科大学
    • Related Report
      2019 Annual Research Report
  • [Presentation] 近赤外吸収を示すC70部分骨格の合成と物性2020

    • Author(s)
      福井 識人
    • Organizer
      東京理科大学
    • Related Report
      2019 Annual Research Report
  • [Presentation] 硫黄挿入型ペリレンビスイミドの合成と物性2020

    • Author(s)
      福井 識人
    • Organizer
      東京理科大学
    • Related Report
      2019 Annual Research Report
  • [Presentation] 大環状ノルコロール二量体の合成2020

    • Author(s)
      川島 寛之
    • Organizer
      東京理科大学
    • Related Report
      2019 Annual Research Report
  • [Presentation] Fusion of Porphyrin Chemistry and Organic Chemistry2020

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      Commemorative symposium in Kyoto on the retirement of Prof. Atsuhiro Osuka
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ノルコロールNi錯体におけるメゾ位置換基の速度論的安定化効果の検証2020

    • Author(s)
      鵜飼 修作
    • Organizer
      東京理科大学
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジアザ-s-インダセンの合成と物性2020

    • Author(s)
      埴田 健介
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 3D Aromaticity Based on Antiaromatic Porphyrins2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      Let’s leap! Challenges in Organic Chemistry
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Exploration of Synthesis and Property of Novel Porphyrinoids2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      CBC SEMINAR
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Towards Three-Dimensional Aromaticity from Antiaromatic Porphyrinoid2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      10th International Conference on Materials for Advanced Technologies (ICMAT 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis, reactivity, and property of antiaromatic porphyrins2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      The 47th Naito Conference "C-H Bond Activation and Transformation"
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 反芳香族ポルフィリンから探る新たな芳香族性2019

    • Author(s)
      忍久保洋
    • Organizer
      大阪大学工学研究科応用化学専攻講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Towards Three-Dimensional Aromaticity from an Antiaromatic Porphyrinoid2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      The 18th International Symposium on Novel Aromatic Compounds (ISNA-18)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] [2+2] Cycloaddition of etheno-fused diporphyrins2019

    • Author(s)
      Kazuya Miyagawa
    • Organizer
      ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons"
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers2019

    • Author(s)
      Keita Tajima
    • Organizer
      ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons"
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins2019

    • Author(s)
      Asahi Takiguchi
    • Organizer
      ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons"
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins2019

    • Author(s)
      Asahi Takiguchi
    • Organizer
      The 18th International Symposium on Novel Aromatic Compounds (ISNA-18)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of meso-Alkyl-Substituted Norcorrole Ni Complexes and Conversion to 5-Oxaporphyrins(2.0.1.0)2019

    • Author(s)
      SI-Yu Liu
    • Organizer
      ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons"
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of meso-Alkyl-Substituted Norcorrole Ni Complexes and Conversion to 5-Oxaporphyrins(2.0.1.0)2019

    • Author(s)
      SI-Yu Liu
    • Organizer
      The 18th International Symposium on Novel Aromatic Compounds (ISNA-18)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of a cyclic norcorrole dimer2019

    • Author(s)
      Hiroyuki Kawashima
    • Organizer
      ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons"
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Stability and association behavior of a norcorrole Ni(II) complex with 3,5-di-tert-butylphenyl groups at meso positions2019

    • Author(s)
      Shusaku Ukai
    • Organizer
      ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons"
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 5,15-Dithiaporphyrin S,S-Tetraoxide as a Highly Electron-Deficient Porphyrinic Ligand2019

    • Author(s)
      Atsumi Yagi
    • Organizer
      ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons"
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ヘテロ原子挿入型ペリレンビスイミド類縁体の合成と物性2019

    • Author(s)
      早川咲穂
    • Organizer
      第13回分子科学討論会2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] ヘテロ原子挿入型ペリレンビスイミド類縁体の合成と物性2019

    • Author(s)
      早川咲穂
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Synthesis and Properties of Heteroatom-inserted Perylene Bisimide Analogues2019

    • Author(s)
      Norihito Fukui
    • Organizer
      The 80th Okazaki Conference, Chirality-induced spin selectivity and its related phenomena
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 近赤外吸収を示すC70部分骨格の合成と物性2019

    • Author(s)
      田中 佑宜
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 窒素架橋されたナフタレンモノイミド二量体の合成とその凝集誘起発光2019

    • Author(s)
      田島 慶太
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] [2+2] Cycloaddition of etheno-fused diporphyrins2019

    • Author(s)
      宮川 和弥
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 環状ノルコロール二量体の合成2019

    • Author(s)
      川島 寛之
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] New heterocorroles and norcorroles from dipyrrin metal complexes2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      Universite de Strasbourg
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New heterocorroles and norcorroles from dipyrrin metal complexes2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      Universite de Rennes 1
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New heterocorroles and norcorroles from dipyrrin metal complexes2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      Aix-Marseille Universite
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New heterocorroles and norcorroles from dipyrrin metal complexes2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      Universite de Montpellier
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New heterocorroles and norcorroles from dipyrrin metal complexes2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      Sorbonne Universite
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New porphyrins from dipyrrin metal complexes2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      University of Nice Sophia Antipolis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New heterocorroles and norcorroles from dipyrrin metal complexes2019

    • Author(s)
      Hiroshi Shinokubo
    • Organizer
      Ecole normale superieure de Lyon
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 新規ポルフィリンの合成と機能探索2019

    • Author(s)
      忍久保 洋
    • Organizer
      豊田工業大学
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 硫黄挿入型ペリレンビスイミドの合成と物性2019

    • Author(s)
      福井 識人
    • Organizer
      第46回有機典型元素化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジアザコルフィセンの合成と物性2019

    • Author(s)
      八木 篤実
    • Organizer
      第46回有機典型元素化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ノルコロール化学の最近の進展2019

    • Author(s)
      忍久保 洋
    • Organizer
      京都大学
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 5,15-ジアザポルフィリン金属錯体のN-メチル化反応2019

    • Author(s)
      西條真由
    • Organizer
      第30回基礎有機化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] N-メチル5,15-ジアザポルフィリン金属錯体の合成とその光物性2019

    • Author(s)
      西條真由
    • Organizer
      2019光化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Synthesis and Properties of Dialkoxybis(dipyrrin)s through Oxidative Cleavage of Norcorrole2019

    • Author(s)
      SHAFIE, Siham Asyiqin; KAWASHIMA, Hiroyuki; MIYAKE, Yoshihiro; SHINOKUBO, Hiroshi
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 5,15-ジアザポルフィリン金属錯体のN-メチル化反応2019

    • Author(s)
      西條 真由・西村 翼・CHIA Wen Xi・三宅 由寛・忍久保 洋
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ジアザポルフィリンマンガン錯体を用いたアルカンの直接的フッ素化反応2019

    • Author(s)
      森 しほ・西村 翼・忍久保 洋・三宅 由寛
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 5,15-ジアザポルフィリン鉄錯体のsp3 C-H酸化触媒としての利用2019

    • Author(s)
      西村 翼・渡辺 芳人・荘司 長三・忍久保 洋・三宅 由寛
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ヒドロキシオキソフロリン誘導体の合成と物性2019

    • Author(s)
      瀧口 あさひ・忍久保 洋
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Exploration of Antiaromatic Porphyrins2019

    • Author(s)
      H. Shinokubo
    • Organizer
      Core-to-Core and GTR Symposiumon Elements Function for Transformative Catalysis and Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ジヘテロポルフィリンの合成と物性2018

    • Author(s)
      忍久保洋
    • Organizer
      集合有機分子機能セミナー
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] メゾ位にリンを含む新規ポルフィリノイドの合成2018

    • Author(s)
      大森裕土・忍久保 洋
    • Organizer
      第45回有機典型元素化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ジアザポルフィリン鉄錯体を用いたアルカンの直接的酸化反応2018

    • Author(s)
      西村 翼・荘司 長三・渡辺 芳人・忍久保 洋・三宅 由寛
    • Organizer
      第49回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis and Properties of Diethoxybis(dipyrrin) through Oxidation of Norcorrole2018

    • Author(s)
      Siham Asyiqin Shafie・川島弘之・忍久保洋
    • Organizer
      第49回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 5,15-ジアザポルフィリン鉄錯体触媒を用いたアルカンの直接的酸化反応2018

    • Author(s)
      西 村 翼・荘司 長三・渡辺 芳人・忍久保 洋・三宅 由寛
    • Organizer
      第51回酸化反応討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] N-メチル-5,15-ジアザポルフィリン白金およびパラジウム錯体の合成と反応性2018

    • Author(s)
      西條真由・西村 翼・三宅由寛・忍久保洋
    • Organizer
      CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] 積み重ねて生みだす芳香族の新次元2018

    • Author(s)
      忍久保洋
    • Organizer
      CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属錯体の有機反応による新規ポルフィリン類縁体の合成と物性探求2018

    • Author(s)
      忍久保洋
    • Organizer
      第4回材料相模セミナー
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 流れに任せて2018

    • Author(s)
      忍久保洋
    • Organizer
      2018年π造形若手会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and properties of novel porphyrins from dipyrrins2018

    • Author(s)
      忍久保 洋
    • Organizer
      Hunan Normal University
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 遷移金属ジアザポルフィリン錯体触媒による sp3 C-H 結合の直接的酸化反応2018

    • Author(s)
      西 村 翼・荘司 長三・渡辺 芳人・忍久保 洋・三宅 由寛
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ポルフィリンにおける有機化学と無機化学の接点2018

    • Author(s)
      忍久保洋
    • Organizer
      第31回生物無機化学夏季セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Properties of Phosphorus(V) Norcorrole2018

    • Author(s)
      Siham Asyiqin Shafie・Takuya Yoshida・ Yoshihiro Miyake・Hiroshi Shinokubo
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis and Properties of meso-Alkyl Norcorroles2018

    • Author(s)
      Siyu Liu・Norihito Fukui・Hiroshi Shinokubo
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Diazachlorin and Diazabacteriochlorin for In Vivo Two Photon Photodynamic Therapy2018

    • Author(s)
      Ayaka Yamaji・Jean Francois Longevial・Dina Aggad・Gakhyun Kim・Wen Xi Chia・Tsubasa Nishimura・Yoshihiro Miyake・Se_bastien Cle_ment・Dongho Kim・Magali Gary-Bobo・Se_bastien Richeter・ Hiroshi Shinokubo
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ビススピロ骨格をもつポルフィリン二量体の合成2018

    • Author(s)
      瀧口あさひ・坪井秀夫・伊藤覚・廣戸聡・忍久保洋
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 反芳香族ポルフィリンから探る新たな芳香族性2018

    • Author(s)
      忍久保洋
    • Organizer
      有機合成夏期セミナー「明日の有機合成化学」
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Functionalization and Properties of Norcorroles2018

    • Author(s)
      H. Shinokubo
    • Organizer
      10th International Conference on Porphyrins and Phthalocyanines
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of novel porphyrins from dipyrrins2018

    • Author(s)
      H. Shinokubo
    • Organizer
      Supramolecular Chemistry of Nitrogen Ligands
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 新規ポルフィリン類縁体の合成と物性の探求2018

    • Author(s)
      忍久保洋
    • Organizer
      新潟大学大学院講演会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 可逆的に構造変化するポルフィリン二量体の合成とフラーレンとの包接挙動2018

    • Author(s)
      瀧口あさひ、廣戸聡、忍久保洋
    • Organizer
      第113回有機合成シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of N-methyl-5,15-diazaporphyrin exhibiting high electron accepting ability2018

    • Author(s)
      Chia Wen Xi, T. Nishimura, H. Omori, H. Shinokubo
    • Organizer
      第113回有機合成シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Exploration of Novel Porphyrins from Dipyrrin Precursors2018

    • Author(s)
      H. Shinokubo
    • Organizer
      Japanese-Spanish Post-Symposium in Organic Synthesis in Nagoya
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and properties of N-methyl-5,15-diazaporphyrin2018

    • Author(s)
      CHIA, Wen Xi; NISHIMURA, Tsubasa; OMORI, Hiroto; SHINOKUBO, Hiroshi
    • Organizer
      日本化学会第98会春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 5,15-ジアザポルフィリン鉄錯体を用いたアルカンの触媒的酸化反応2018

    • Author(s)
      西村翼、三宅由寛、忍久保洋
    • Organizer
      日本化学会第98会春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 可逆的に構造変化するポルフィリン二量体の合成とC60 との包接挙動2018

    • Author(s)
      瀧口あさひ、廣戸 聡、忍久保
    • Organizer
      日本化学会第98会春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] meso位にスルホニル基を有する新規ポルフィリノイドの合成と物性2018

    • Author(s)
      山下大輔・大森裕土・近藤剛資・和智成彦・忍久保洋
    • Organizer
      日本化学会春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 新しいポルフィリンの合成と物性・機能の探求2018

    • Author(s)
      忍久保 洋
    • Organizer
      島根大学理工特別コース講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 有機金属化学で挑むπ電子化合物の合成2018

    • Author(s)
      忍久保 洋
    • Organizer
      島根大学大学院理工学研究科講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Catalytic Oxidation of Alkanes Using Diazaporphyrin Metal Complexes2017

    • Author(s)
      西村翼、三宅由寛、忍久保洋
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ジアザポルフィリン鉄錯体の合成とアルカンの触媒的酸化反応への応用2017

    • Author(s)
      西村翼、三宅由寛、忍久保洋
    • Organizer
      第111回有機合成シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 縮環ポルフィリンの可逆的構造変化への試み2017

    • Author(s)
      瀧口あさひ、廣戸 聡、忍久保
    • Organizer
      第7回CS化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 可逆的に構造変化する縮環ポルフィリンの合成2017

    • Author(s)
      瀧口あさひ、廣戸 聡、忍久保
    • Organizer
      第48回中部化学関係学協会支部連合秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] アルキンの環化反応を利用した縮環ポルフィリン二量体の合成2017

    • Author(s)
      永井 智大・上田 真之・小田 一磨・廣戸 聡・忍久保 洋
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 5-アザ-15-チアポルフィリンおよびその酸化体の合成と物性2017

    • Author(s)
      山下大輔・大森裕土・忍久保洋
    • Organizer
      基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] meso位にスルホニル基を有する新規ポルフィリノイドの合成と物性2017

    • Author(s)
      山下大輔・大森裕土・近藤剛資・和智成彦・池上崇久・忍久保洋
    • Organizer
      典型元素化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化還元活性な新規ポルフィリン類縁体の創成と機能2017

    • Author(s)
      忍久保 洋
    • Organizer
      2017年電気化学秋季大会講演
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ジピリン元素ブロックを用いた新規ポルフィリン類縁体の合成2017

    • Author(s)
      忍久保 洋
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ジピリン金属錯体を前駆体とするポルフィリン類縁体の合成と物性・機能の探求2017

    • Author(s)
      忍久保 洋
    • Organizer
      筑波大学講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 新規縮環ポルフィリノイドの合成と物性2017

    • Author(s)
      忍久保 洋
    • Organizer
      京都大学理学研究科化学専攻特別セミナー
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Synthesis, Structures and Properties of Norcorrole Metal Complexes2017

    • Author(s)
      H. Shinokubo
    • Organizer
      6th Georgian Bay International Conference on Bioinorganic Chemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis, Structures, and Properties of Stacked Antiaromatic Porphyrins2017

    • Author(s)
      H. Shinokubo
    • Organizer
      231st ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and Properties of 10-Heterocorroles2017

    • Author(s)
      H. Shinokubo
    • Organizer
      231st ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Exploration of antiaromatic porphyrins2017

    • Author(s)
      H. Shinokubo
    • Organizer
      The 7th Sino-Japanese Symposium on Organic Chemistry for Young Scientists
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 10-Silacorroles Exhibiting Near-IR Absorption and Emission2017

    • Author(s)
      H. Omori, S. Hiroto, H. Shinokubo
    • Organizer
      17th International Symposium on Novel Aromatic Compounds
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] メゾ位にヘテロ原子を含む新規ポルフィリノイドの合成2017

    • Author(s)
      大森 裕土、廣戸 聡、武田 洋平、南方 聖司、忍久保 洋
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Remarks] 忍久保研究室ホームページ

    • URL

      http://www.chembio.nagoya-u.ac.jp/labhp/organic1/index.html

    • Related Report
      2021 Annual Research Report
  • [Remarks] 忍久保研究室

    • URL

      http://www.chembio.nagoya-u.ac.jp/labhp/organic1/index.html

    • Related Report
      2020 Annual Research Report
  • [Remarks] 研究テーマ:有機合成で拓く新しい分子の世界

    • URL

      http://www.chembio.nagoya-u.ac.jp/labhp/organic1/research.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 忍久保研ホームページ

    • URL

      http://www.apchem.nagoya-u.ac.jp/hshino/top.html

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] ジアザクロリン類縁体及びその製造方法2018

    • Inventor(s)
      忍久保 洋、山路 文香
    • Industrial Property Rights Holder
      国立大学法人法人名古屋大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report
    • Overseas

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Published: 2017-04-28   Modified: 2023-01-30  

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