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Novel Solid-state Chemistry in Dimensional Crossover Region

Research Project

Project/Area Number 17H01196
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionKyoto University

Principal Investigator

Kitagawa Hiroshi  京都大学, 理学研究科, 教授 (90234244)

Co-Investigator(Kenkyū-buntansha) 前里 光彦  京都大学, 理学研究科, 准教授 (60324604)
大坪 主弥  京都大学, 理学研究科, 助教 (90601005)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥44,200,000 (Direct Cost: ¥34,000,000、Indirect Cost: ¥10,200,000)
Fiscal Year 2019: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
Fiscal Year 2018: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000)
Fiscal Year 2017: ¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Keywords金属錯体化学 / 無機化学 / 固体物性化学
Outline of Final Research Achievements

The unique physical properties are expected to exhibit by the geometrical structures existing in the dimensional crossing region, which has been predicted for a long time, mainly by physical property theorists. In this study, by using a rational construction method using coordination chemistry, various geometrical structures existing in the dimensional intersection region are synthesized, further material development is advanced, and novel physical properties hidden in the dimensional intersection region were promoted.

Academic Significance and Societal Importance of the Research Achievements

強い電子-格子相互作用や電子相関及び比較的大きな電子移動積分が導入可能な混合原子価金属錯体を基本骨格として、梯子構造を有する多彩な配位高分子群の設計・構築を行った。一次元電子系と二次元電子系の狭間に位置する梯子系は、鎖の本数や偶数・奇数鎖に強く依存した物性が発現されることが知られている。奇数鎖においてはギャップレスの磁性を示し、偶数鎖ではスピンギャップを示すことが知られており、将来的には量子デバイスへの応用が期待されている。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (33 results)

All 2020 2019 2018 2017

All Journal Article (18 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 18 results,  Open Access: 7 results,  Acknowledgement Compliant: 2 results) Presentation (15 results) (of which Int'l Joint Research: 15 results,  Invited: 15 results)

  • [Journal Article] The First Study on the Reactivity of Water Vapor in Metal-Organic Frameworks with Platinum Nanocrystals2019

    • Author(s)
      Ogiwara Naoki、Kobayashi Hirokazu、Concepcion Patricia、Rey Fernando、Kitagawa Hiroshi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 58 Issue: 34 Pages: 11731-11736

    • DOI

      10.1002/anie.201905667

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Solid-solution alloy nanoparticles of a combination of immiscible Au and Ru with a large gap of reduction potential and their enhanced oxygen evolution reaction performance2019

    • Author(s)
      Quan Zhang, Kohei Kusada, Dongshuang Wu, Naoki Ogiwara, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Shogo Kawaguchi, Yoshiki Kubota, Tetsuo Honma, Hiroshi Kitagawa
    • Journal Title

      Chemical Science

      Volume: 印刷中 Issue: 19 Pages: 5133-5137

    • DOI

      10.1039/c9sc00496c

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Conducting Coronene Cation Radical Salt Containing Magnetic Metal Ions2019

    • Author(s)
      Yoshida Yukihiro、Maesato Mitsuhiko、Saito Gunzi、Kitagawa Hiroshi
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 20 Pages: 14068-14074

    • DOI

      10.1021/acs.inorgchem.9b02080

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] The relationship between crystalline disorder and electronic structure of Pd nanoparticles and their hydrogen storage properties2019

    • Author(s)
      Seo Okkyun、Kim Jaemyung、Tayal Akhil、Song Chulho、Kumara L. S. R.、Dekura Shun、Kobayashi Hirokazu、Kitagawa Hiroshi、Sakata Osami
    • Journal Title

      RSC Advances

      Volume: 9 Issue: 37 Pages: 21311-21317

    • DOI

      10.1039/c9ra02942g

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Partial Substitution of Ag(I) for Cu(I) in Quantum Spin Liquid κ-(ET)2Cu2(CN)3, Where ET Is Bis(ethylenedithio)tetrathiafulvalene2019

    • Author(s)
      Yoshida Yukihiro、Maesato Mitsuhiko、Tomeno Shinya、Kimura Yojiro、Saito Gunzi、Nakamura Yuto、Kishida Hideo、Kitagawa Hiroshi
    • Journal Title

      Inorganic Chemistry

      Volume: 58 Issue: 8 Pages: 4820-4827

    • DOI

      10.1021/acs.inorgchem.8b03251

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Emergence of High ORR Activity through Controlling Local Density-of-States by Alloying Immiscible Au and Ir2019

    • Author(s)
      K. Kusada, D. Wu, T. Yamamoto, T. Toriyama, S. Matsumura, W. Xie, M. Koyama, S. Kawaguchi, Y. Kubota, H. Kitagawa
    • Journal Title

      Chemical Science

      Volume: 10 Issue: 18 Pages: 652-656

    • DOI

      10.1021/jacs.5b01100

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal Structure-dependent Thermal Stability and Catalytic Performance of AuRu3 Solid-solution Alloy Nanoparticles2018

    • Author(s)
      Zhang Quan、Kusada Kohei、Wu Dongshuang、Kawaguchi Shogo、Kubota Yoshiki、Kitagawa Hiroshi
    • Journal Title

      Chemistry Letters

      Volume: 47 Issue: 4 Pages: 559-561

    • DOI

      10.1246/cl.180047

    • NAID

      130006638876

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid-Solution Alloy Nanoparticles of the Immiscible Ir-Cu System with a Wide Composition Range for Enhanced Electrocatalytic Applications2018

    • Author(s)
      F. Wang, K. Kusada, D. Wu, T. Yamamoto, T. Toriyama, S. Matsumura, Y. Nanba, M. Koyama, H. Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 57 Issue: 17 Pages: 4505-4509

    • DOI

      10.1002/ange.201800650

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective control of fcc and hcp crystal structures in Au?Ru solid-solution alloy nanoparticles2018

    • Author(s)
      Zhang Quan、Kusada Kohei、Wu Dongshuang、Yamamoto Tomokazu、Toriyama Takaaki、Matsumura Syo、Kawaguchi Shogo、Kubota Yoshiki、Kitagawa Hiroshi
    • Journal Title

      Nature Communications

      Volume: 9 Issue: 1 Pages: 510-510

    • DOI

      10.1038/s41467-018-02933-6

    • NAID

      120006384171

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Double Enhancement of Hydrogen Storage Capacity of Pd Nanoparticles by 20 at% Replacement with Ir; Systematic Control of Hydrogen Storage in Pd-M Nanoparticles (M = Ir, Pt, Au)2018

    • Author(s)
      H. Kobayashi, M. Yamauchi, R. Ikeda, T. Yamamoto, S. Matsumura, H. Kitagawa
    • Journal Title

      Chemical Science

      Volume: 9 Issue: 25 Pages: 5536-5540

    • DOI

      10.1039/c8sc01460d

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] The electronic state of hydrogen in α phase of the hydrogen-storage material PdH(D)x: Does a chemical bond between palladium and hydrogen exist?2018

    • Author(s)
      S. Dekura, H. Kobayashi, R. Ikeda, M. Maesato, H. Yoshino, M. Ohba, T. Ishimoto, S. Kawaguchi, Y. Kubota, S. Yoshioka, S. Matsumura, T. Sugiyama, H. Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 57 Issue: 31 Pages: 9823-9827

    • DOI

      10.1002/anie.201805753

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper Substitution Induced CO Adsorption Site Change of a Ruthenium Catalyst for Highly Enhanced CO Oxidation Activity2018

    • Author(s)
      B. Huang, H. Kobayashi, T. Yamamoto, T. Toriyama, S. Matsumura, Y. Nishida, K. Sato, K. Nagaoka, M. Haneda, W. Xie, Y. Nanba, M. Koyama, F. Wang, S. Kawaguchi, Y. Kubota, H. Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 57 Issue: 25 Pages: 1-6

    • DOI

      10.1002/anie.201402680

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A highly crystalline oriented metal-organic framework thin film with an inorganic pillar2017

    • Author(s)
      Yuki Watanabe, Tomoyuki Haraguchi, Kazuya Otsubo, Osami Sakata, Akihiko Fujiwara, Hiroshi Kitagawa
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 73 Pages: 10112-10115

    • DOI

      10.1039/c7cc03828c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoscale crystalline architectures of Hofmann-type metal-organic frameworks2017

    • Author(s)
      Kazuya Otsubo, Tomoyuki Haraguchi, Hiroshi Kitagawa
    • Journal Title

      Coord. Chem. Rev.

      Volume: in press Pages: 123-138

    • DOI

      10.1016/j.ccr.2017.03.022

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Mixed-Valence Nickel Bis(azamacrocycle) Compounds with Ghost-Leg-type Sheets2017

    • Author(s)
      Ryota Hashiguchi, Kazuya Otsubo, Masato Maesato, Kunihisa Sugimoto, Akihiko Fujiwara, Hiroshi Kitagawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 56 Issue: 14 Pages: 3838-3841

    • DOI

      10.1002/anie.201610515

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Solid-Solution Alloying of Immiscible Ru and Cu with Enhanced CO Oxidation Activity2017

    • Author(s)
      B. Huang, H. Kobayashi, T. Yamamoto, S. Matsumura, Y. Nishida, K. Sato, K. Nagaoka, S. Kawaguchi, Y. Kubota, H. Kitagawa
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 13 Pages: 4643-4646

    • DOI

      10.1021/jacs.7b01186

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Discovery of Hexagonal Structured Pd-B Nanocrystals2017

    • Author(s)
      Kobayashi Keigo、Kobayashi Hirokazu、Maesato Mitsuhiko、Hayashi Mikihiro、Yamamoto Tomokazu、Yoshioka Satoru、Matsumura Syo、Sugiyama Takeharu、Kawaguchi Shogo、Kubota Yoshiki、Nakanishi Hiroshi、Kitagawa Hiroshi
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 23 Pages: 6578-6582

    • DOI

      10.1002/anie.201703209

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A compact low-temperature hydrogen ion beam apparatus for in situ physical property measurements2017

    • Author(s)
      Nakayama R.、Suzuki N.、Maesato M.、Nagaoka T.、Arita M.、Kitagawa H.
    • Journal Title

      Review of Scientific Instruments

      Volume: 88 Issue: 12 Pages: 123904-123904

    • DOI

      10.1063/1.5004517

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Density-of-States Engineering For New Nano-Materials2020

    • Author(s)
      北川宏
    • Organizer
      IISER TVM Frontier Symposium in Chemistry 2020 (FS-CHM 2020)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Conductiv Coordination Networkについて2019

    • Author(s)
      北川宏
    • Organizer
      UNIST 2019 Sspring Seminar
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] DOS Engineering for New Green Nano-materials2019

    • Author(s)
      北川宏
    • Organizer
      鄭州大学国際サマースクール
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Conductive Coordination Networks2019

    • Author(s)
      北川宏
    • Organizer
      7TH ASIAN CONFERENCE ON COORDINATION CHEMISTRY ACCC72019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Solid -state protonic in Coordination Polymers2019

    • Author(s)
      北川宏
    • Organizer
      2019 International Conference on Advanced Fibers and Polymer Materials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Conductive Coordination Networks2019

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      INTERNATIONAL CONFERENCE ON STRUCTURAL AND INORGANIC CHEMISTRY-II
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Inter-Element Fusion for New Nanomaterials on the Basis of DOS Engineering2018

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      19th International Symposium on the Reactivity of Solids (ISRS-19)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Confined Water Clusters and High Proton Conduction in Synthetic Hydrophobic Nanotubes2018

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      INDABA9
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] MOF Devices and Applications2018

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      AiMES2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Toward dimensional crossover on conductive coordination networks2018

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      AsCA2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrically conductive coordination networks2018

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      ACS National Meeting & Expo2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Conductive coordination networks2017

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      The 2nd Jaoan -US Bilateral Meeting on Coordination Chemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Highly Conductive Coordination Polymers2017

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      9th International Symposium on Nano & Supramolecular Chemistry(ISNSC9)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrically conductive MOFs2017

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      6th Asian Conference on Coordination Chemistry(ACCC6)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Dimensional crossover in coordination chemistry2017

    • Author(s)
      Hiroshi Kitagawa
    • Organizer
      Joint UK-Japan Symposium on Nanomaterials, Catalysis and Hydrogen Research
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2017-04-28   Modified: 2021-02-19  

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