• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Design of Environmentally Benign Nanohybrids through Precise Control of Intermolecular Interaction

Research Project

Project/Area Number 17H01221
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic and hybrid materials
Research InstitutionKyushu University

Principal Investigator

Takahara Atsushi  九州大学, 先導物質化学研究所, 教授 (20163305)

Co-Investigator(Kenkyū-buntansha) 高田 晃彦  九州大学, 先導物質化学研究所, 助教 (20254427)
檜垣 勇次  大分大学, 理工学部, 准教授 (40619649)
平井 智康  大阪工業大学, 工学部, 准教授 (60585917)
Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥43,550,000 (Direct Cost: ¥33,500,000、Indirect Cost: ¥10,050,000)
Fiscal Year 2020: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Fiscal Year 2019: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2018: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
Fiscal Year 2017: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Keywords無機ナノチューブ / イモゴライト / ハロイサイト / ハイブリッド化 / サクラン / セルロースナノ結晶 / セルロースナノファイバー / キトサン / オリゴペプチド / ピリドキサール-5'-リン酸 / ハイブリッド / 力学特性 / ハイドロゲル / 界面相互作用 / セルロース / ハイブリッド材料 / LBL / ガスバリア性 / レオロジー特性 / ナノセルロース / 有機無機ハイブリッド材 / 環境調和型高分子 / セルロースナノクリスタル / ポリビニルアルコール / 有機/ 無機ハイブリッド / 階層構造 / 有機無機ハイブリッド材料 / 天然無機ナノチューブ / 分子間相互作用 / 分子鎖凝集構造 / 交互積層膜 / 表面物性 / 低環境負荷高分子 / 分子間相互作 / 特性解析
Outline of Final Research Achievements

Imogolite, a natural aluminosilicate nanotube, has Si-OH on the inner wall surface and Al-OH groups on the outer surface, while halloysite has Si-O-Si on the outer surface and Al-OH groups on the inner lumen. With nanotubes, selective chemical modification of the nanotube surface or inner lumen is possible with organic molecule containing phosphate groups. Various (organic/inorganic) hybrids were prepared from polysaccharides and oligopeptides having functional groups that specifically interact with Al-OH. By utilizing the intermolecular interaction between inorganic nanotubes and organic polymers from natural origin, novel environmentally friendly hybrid materials were prepared and their structure-physical properties relationships were clarified.

Academic Significance and Societal Importance of the Research Achievements

本研究の実施により、これまで資源として有効活用されていなかったイモゴライトやハロイサイトが、多糖類などの生体高分子と複合化することにより新しい材料として活用できることを明らかにした。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (28 results)

All 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (2 results) Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results,  Open Access: 3 results) Presentation (15 results) (of which Int'l Joint Research: 9 results,  Invited: 9 results) Remarks (2 results)

  • [Int'l Joint Research] CNRS(フランス)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Ewha Womans University(韓国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Preparation of (Inorganic/Organic) Hybrid Hydrogel from Peptide Oligomer and Tubular Aluminosilicate Nanofiber2021

    • Author(s)
      3.M. Mukai, M. Takahara, A. Takada, A. Takahara
    • Journal Title

      RSC Advances

      Volume: 11 Issue: 9 Pages: 4901-4905

    • DOI

      10.1039/d0ra09514a

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure and Properties of Hybrid Film Fabricated by Spin-assisted Layer-by-Layer Assembly of Sacran and Imogolite Nanotubes2020

    • Author(s)
      1.L. Li, A. Takada, W. Ma, S. Fujikawa, M. Ariyoshi, K. Igata, M. Okajima, T. Kaneko, A. Takahara
    • Journal Title

      Langmuir

      Volume: 36 Issue: 7 Pages: 1718-1726

    • DOI

      10.1021/acs.langmuir.9b03626

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cationic Polymer Brush/Giant Polysaccharide Sacran Assembly: Structure and Lubricity2020

    • Author(s)
      Kosuke Igata, Tatsunori Sakamaki, Yoshihiro Inutsuka, Yuji Higaki, Maiko K. Okajima, Norifumi L. Yamada, Tatsuo Kaneko, Atsushi Takahara
    • Journal Title

      Langmuir

      Volume: ー Issue: 23 Pages: 6494-6501

    • DOI

      10.1021/acs.langmuir.0c00854

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic-Inorganic Hybrid Films Fabricated from Cellulose Fibers and Imogolite Nanotubes,2019

    • Author(s)
      L.-L. Li, Linlin, W. Ma, Wei, A. Takada, N. Takayama, A. Takahara
    • Journal Title

      Biomacromolecules

      Volume: 20 Issue: 9 Pages: 3566-3566

    • DOI

      10.1021/acs.biomac.9b00881

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and characterization of boronic acid- functionalized halloysite nanotube/poly(vinyl alcohol) nanocomposites2019

    • Author(s)
      M Mukai, W. Ma, K. Ideta., A. Takahara
    • Journal Title

      Polymer

      Volume: 178 Pages: 121581-121581

    • DOI

      10.1016/j.polymer.2019.121581

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic-Inorganic Hybrid Thin Films Fabricated by Layer-by-Layer Assembly of the Phosphorylated Cellulose Nanocrystal and Imogolite Nanotubes2018

    • Author(s)
      Linlin Li, Wei Ma, Yuji Higaki, Kazutaka Kamitani, Atsushi Takahara
    • Journal Title

      Langmuir

      Volume: 34 Issue: 44 Pages: 13361-67

    • DOI

      10.1021/acs.langmuir.8b03107

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Halloysite Nanotubes: Green Nanomaterial for Functional Organic-Inorganic Nanohybrids2018

    • Author(s)
      Ma Wei、Wu Hui、Higaki Yuji、Takahara Atsushi
    • Journal Title

      The Chemical Record

      Volume: 18 Issue: 7-8 Pages: 986-999

    • DOI

      10.1002/tcr.201700093

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Mechanically Enhanced Hyaluronic Acid Hybrid Hydrogels with Halloysite Nanotubes2017

    • Author(s)
      K. L. Park, W. Ma, Y. Higaki, A. Takahara
    • Journal Title

      Chemistry Letter

      Volume: 46 Issue: 8 Pages: 1217-1219

    • DOI

      10.1246/cl.170484

    • NAID

      130005906965

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Superamphiphobic Coatings from Combination of a Biomimetic Catechol-Bearing Fluoropolymer and Halloysite Nanotubes2017

    • Author(s)
      Wei Ma Yuji Higaki Atsushi Takahara
    • Journal Title

      Advanced Materials Interfaces

      Volume: 4 Pages: 1700907-1700907

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Polymer Hybrids from Imogolite Nanofiber2021

    • Author(s)
      A. Takahara
    • Organizer
      261 ACS Meeting, PMSE-Nanoclays
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of (polymer/tubular nano-clay) hybrids through precise interfacial structure control2020

    • Author(s)
      A. Takahara
    • Organizer
      The 4th -Asian Clay Conference
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of (polymer/tubular nano-clay) hybrids through precise interfacial structure control2019

    • Author(s)
      A. Takahara
    • Organizer
      3rd A3 Foresight Sympopsium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] DESIGN AND CHARACTERIZATION OF NOVEL (POLYMER/CLAY NANOTUBE) HYBRIDS2018

    • Author(s)
      Atsushi Takahara
    • Organizer
      55th Annual Meeting of The Clay Minerals Societ
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure and functional properties of novel (natural clay nanotube/polymer) nanocomposites2018

    • Author(s)
      Atsushi Takahara
    • Organizer
      256th ACS National Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Surface and Interface Properties oif Polyelectrolyte Brushes2018

    • Author(s)
      Atsushi Takahara
    • Organizer
      The 2nd symposium for A3 foresight program
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Takahararansparent Organic-Inorganic Hybrid Thin Film Fabricated by Layer-by-Layer Assembly of Phosphorylated Cellulose Nanocrystal and Imogolite Nanotubes2018

    • Author(s)
      Linlin Li, Wei Ma, Yuji Higaki, Atsushi Takahara
    • Organizer
      第67回高分子年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Catechol Bearing Polymers for Substrate Independent Adhesive Coatings2018

    • Author(s)
      Wei MA, Yuji HIGAKI, Atsushi TAKAHARA
    • Organizer
      第69回コロイドおよび界面化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Preparation and Characterization of Cellulose Nanofiber/Imogolite Nanotubes Hybrid Films2018

    • Author(s)
      Linlin Li, Wei Ma, Yuji Higaki, Atsushi Takahara
    • Organizer
      The 12th International Polymer Conference (IPC2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] Mechanical and Thermal Properties of Cellulose Nanofiber/Imogolite Hybrids2018

    • Author(s)
      Linlin Li, Wei Ma, Yuji Higaki, Atsushi Takahara
    • Organizer
      第28回 日本MRS年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Preparation of Boronic-Acid Modified Halloysite-Nanotube / Poly(vinylalcohol)Nanocomposites and Their Mechanical Properties2018

    • Author(s)
      Masaru Mukai,Atsushi Takahara
    • Organizer
      第28回 日本MRS年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Transparent Organic-Inorganic Hybrid Thin Film Fabricated by Layer-by-Layer Assembly of Phosphorylated Cellulose Nanocrystal and Imogolite Nanotubes2018

    • Author(s)
      Linlin Li, Wei Ma, Atsushi Takahara
    • Organizer
      The 2nd symposium for A3 foresight program
    • Related Report
      2018 Annual Research Report
  • [Presentation] MOLECULAR AGGREGATION STRUCTURE AND PHYSICOCHEMICAL PROPERTIES OF (IMOGOLITE/POLYMER) HYBRIDS2018

    • Author(s)
      A. Takahara
    • Organizer
      255th ACS National Meeting & Exposition
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design and Characterization of (Natural Clay Nanotube/Polymer) Hybrids2017

    • Author(s)
      A. Takahara
    • Organizer
      IUMRS ICMAT2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure and properties (Imogolite/biopolymer) hybrids2017

    • Author(s)
      A. Takahara
    • Organizer
      International Clay Conference 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 先導研高原研HP

    • URL

      http://takahara.ifoc.kyushu-u.ac.jp

    • Related Report
      2018 Annual Research Report
  • [Remarks] 先導物質化学研究所高原研究室HP

    • URL

      http://takahara.ifoc.kyushu-u.ac.jp

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2022-01-27  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi