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Creation of optical functions below 200nm with ultra-wide band gap oxide semiconductor quantum structure

Research Project

Project/Area Number 17H01263
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionKyoto University

Principal Investigator

Fujita Shizuo  京都大学, 工学研究科, 教授 (20135536)

Co-Investigator(Kenkyū-buntansha) 尾沼 猛儀  工学院大学, 先進工学部, 教授 (10375420)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥44,070,000 (Direct Cost: ¥33,900,000、Indirect Cost: ¥10,170,000)
Fiscal Year 2019: ¥11,310,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥2,610,000)
Fiscal Year 2018: ¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2017: ¥15,990,000 (Direct Cost: ¥12,300,000、Indirect Cost: ¥3,690,000)
Keywords光物性 / 量子井戸 / 酸化物 / 深紫外 / 量子構造
Outline of Final Research Achievements

We developed an ultra-wide bandgap oxide semiconductor MgZnO and obtained deep ultraviolet cathodoluminescence covering the wavelengths below 200 nm. An environmental-friendly Mist CVD method was used for the growth, and appropriate choice of source materials allowed high-quality crystals. Internal quantum efficiency at room temperature was about 3% for MgZnO thin films with Mg composition of 0.92 emitting at 217 nm while was increased to about 13% with multiple quantum-well structure. The emission peak from the latter was 212 nm, which was shorter than that from the former, suggesting increased emission efficiency by quantum effect.

Academic Significance and Societal Importance of the Research Achievements

波長200 nm以下を含む深紫外領域の光は、殺菌、加工、光化学等の応用に不可欠である一方で、光源には水銀や希ガスの放電が一般に用いられている。これを固体を用いて実現することは、脱水銀や希少資源の保護に寄与するとともに、任意の波長での光源が得られるという社会的意義がある。また、深紫外領域における半導体の光物性研究という新しい学理の開拓に研究の学術的意義がある。成長にミストCVD法を用いることで、地球環境に優しい半導体技術の開拓に寄与するところが本研究の価値である。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (27 results)

All 2020 2019 2018 2017

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (23 results) (of which Int'l Joint Research: 10 results,  Invited: 4 results)

  • [Journal Article] Pure deep-ultraviolet cathodoluminescence from rocksalt-structured MgZnO grown with carbon-free precursors2019

    • Author(s)
      Kyohei Ishii, Mizuki Ono, Kentaro Kaneko, Takeyoshi Onuma, Tohru Honda, Shizuo Fujita
    • Journal Title

      Applied Physics Express

      Volume: 12 Issue: 5 Pages: 052011-052011

    • DOI

      10.7567/1882-0786/ab10e2

    • NAID

      210000155684

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Excitation-current-density and temperature dependences of deep UV cathodoluminescence in rocksalt-structured MgxZn1-xO films2019

    • Author(s)
      Mizuki Ono, Kyohei Ishii, Kentaro Kaneko, Tomohiro Yamaguchi, Tohru Honda, Shizuo Fujita, Takeyoshi Onuma
    • Journal Title

      Journal of Applied Physics

      Volume: 125 Issue: 22

    • DOI

      10.1063/1.5094684

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Impact of local arrangement of Mg and Zn atoms in rocksalt-structured MgxZn1-xO alloys on bandgap and deep UV cathodoluminescence peak energies2018

    • Author(s)
      T. Onuma, M. Ono, K. Ishii, K. Kaneko, T. Yamaguchi, S. Fujita, T. Honda
    • Journal Title

      Applied Physics Letters

      Volume: 113 Issue: 6

    • DOI

      10.1063/1.5031174

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deep-ultraviolet luminescence of rocksalt-structured MgxZn1-xO (x > 0.5) films on MgO substrates2018

    • Author(s)
      K. Kaneko, K. Tsumura, K. Ishii, T. Onuma, T. Honda, S. Fujita
    • Journal Title

      Journal of Electronic Materials

      Volume: 47 Issue: 8 Pages: 4356-4360

    • DOI

      10.1007/s11664-018-6303-9

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 岩塩構造MgZnO薄膜の時間分解フォトルミネッセンス分光2020

    • Author(s)
      工藤幹太, 石井恭平, 小野瑞生, 金子健太郎, 山口智広, 嶋紘平, 小島一信, 藤田静雄, 本田徹, 秩父重英, 尾沼猛儀
    • Organizer
      2020年第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Deep UV cathodoluminescence properties of rocksalt-structured MgZnO alloys2019

    • Author(s)
      Takeyoshi Onuma, Mizuki Ono, Kanta Kudo, Kyohei Ishii, Kentaro Kaneko, Shizuo Fujita, Tohru Honda
    • Organizer
      9th Asia-Pacific Workshop on Widegap Semiconductors
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Characterization of MgZnO thin films for deep ultraviolet light emitters2019

    • Author(s)
      Shizuo Fujita, Shoma Hoshi, Kyohei Ishii, Mizuki Ono, Kanta Kudo, Takeyoshi Onuma, Tohru Honda, Kentaro Kaneko
    • Organizer
      19th International Conference on II-VI Compounds and Related Materials
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Observation of deep UV cathodoluminescence from rocksalt-structured MgZnO alloys2019

    • Author(s)
      Takeyoshi Onuma, Mizuki Ono, Kanta Kudo, Kyohei Ishii, Kentaro Kaneko, Shizuo Fujita, Tohru Honda
    • Organizer
      4th International Workshop on Ultraviolet Materials and Devices
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Vacuum ultra violet light emission from MgZnO-based thin films and quantum wells2019

    • Author(s)
      Kentaro Kaneko, Kyohei Ishii, Mizuki Ono, Kanta Kudo, Takeyoshi Onuma, Tohru Honda, Shizuo Fujita
    • Organizer
      61st Electronic Materials Conference
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] VUV cathodoluminescence spectra of rocksalt-structured MgZnO/MgO quantum wells2019

    • Author(s)
      Kenta Kudo, Kyohei Ishii, Mizuki Ono, Yuki Fujiwara, Kentaro Kaneko, Tomohiro Yamaguchi, Tohru Honda, Shizuo Fujita, Takeyoshi Onuma
    • Organizer
      Compound Semiconductor Week 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Growth and deep UV luminescent properties of rocksalt-structured ultra-wide bandgap MgZnO on MgO substrates2019

    • Author(s)
      Kentaro Kaneko, Kyohei Ishii, Mizuki Ono, Kanta Kudo, Takeyoshi Onuma, Tohru Honda, Shizuo Fujita
    • Organizer
      Compound Semiconductor Week 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] MgO薄膜のホモエピタキシャル成長および光学特性2019

    • Author(s)
      星翔馬, 工藤幹太, 尾沼猛儀, 本田徹, 金子健太郎, 藤田静雄
    • Organizer
      2019年第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] MgO単結晶の真空紫外線領域のカソードルミネセンススペクトル2019

    • Author(s)
      工藤幹太, 星翔馬, 小野瑞生, 藤原有基, 金子健太郎, 山口智広, 本田徹, 藤田静雄, 尾沼猛儀
    • Organizer
      2019年第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Growth of rocksalt-structured MgZnO thin films and their optical properties2018

    • Author(s)
      K. Ishii, M. Ono, T. Onuma, K. Kaneko, S. Fujita
    • Organizer
      60th Electronic Materials Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bandgap fluctuation in rocksalt-structured MgxZn1-xO alloys2018

    • Author(s)
      T. Onuma, M. Ono, K. Ishii, K. Kaneko, T. Yamaguchi, S. Fujita, T. Honda
    • Organizer
      10th Int. Workshop Zinc Oxide and Other Oxide Semiconductors
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of rocksalt-structured MgZnO/MgO layered structures and their DUV light emission properties2018

    • Author(s)
      K. Ishii, M. Ono,T. Onuma, K. Kaneko, S. Fujita
    • Organizer
      2018 Materials Research Society Fall Meeting
    • Related Report
      2018 Annual Research Report
  • [Presentation] 岩塩構造MgxZn1-xOの吸収端の観測と電子状態計算2018

    • Author(s)
      尾沼猛儀, 小野瑞生, 石井恭平, 金子健太郎, 山口智広, 藤田静雄, 本田徹
    • Organizer
      2018年第65回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 岩塩構造MgxZn1-xOにおける深紫外線カソードルミネセンスの温度および励起密度依存性2018

    • Author(s)
      小野瑞生, 石井恭平, 金子健太郎, 山口智広, 本田徹, 藤田静雄, 尾沼猛儀
    • Organizer
      2018年第65回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 岩塩構造MgZnO/MgO積層構造の作製と深紫外発光2018

    • Author(s)
      石井恭平, 小野瑞生, 尾沼猛儀, 金子健太郎, 藤田静雄
    • Organizer
      2018年第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fabrication of rocksalt-MgZnO/MgO layered structure and the characteristic of DUV light emission2018

    • Author(s)
      K. Ishii, M. Ono, T. Onuma, K. Kaneko, S. Fujita
    • Organizer
      37th Electronic Materials Symposium
    • Related Report
      2018 Annual Research Report
  • [Presentation] 岩塩構造MgxZn1-xOの吸収端の観測と電子状態計算2018

    • Author(s)
      尾沼猛儀, 小野瑞生, 石井恭平, 金子健太郎, 山口智広, 藤田静雄, 本田徹
    • Organizer
      2018年春季応用物理学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 岩塩構造MgxZn1-xOにおける深紫外線カソードルミネセンスの温度および励起密度依存性2018

    • Author(s)
      小野瑞生, 石井恭平, 金子健太郎, 山口智広, 本田徹, 藤田静雄, 尾沼猛儀
    • Organizer
      2018年春季応用物理学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 岩塩構造MgZnO薄膜の成長と光物性2018

    • Author(s)
      石井恭平, 小野瑞生, 内田貴之, 神野莉衣奈, 尾沼猛儀, 金子健太郎, 藤田静雄
    • Organizer
      2018年春季応用物理学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Growth of rocksalt-structured MgZnO thin films and their optical properties2018

    • Author(s)
      K. Ishii, M. Ono, T. Onuma, K. Kaneko, and S. Fujita
    • Organizer
      60th Electronic Materials Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Deep-ultraviolet luminescence of rocksalt-structured MgxZn1-xO (x > 0.5) films on MgO substrates2017

    • Author(s)
      K. Kaneko, K. Tsumura, K. Ishii, T. Onuma, T. Honda, S. Fujita
    • Organizer
      18th Int. Conf. II-VI Compounds and Related Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Deep-UV emission properties of rocksalt-structured MgxZn1-xO films grown on MgO (001) substrates2017

    • Author(s)
      M. Ono, K. Ishii, T. Uchida, R. Jinno, K. Kaneko, T. Yamaguchi, T. Honda, S. Fujita, T. Onuma
    • Organizer
      36th Electronic Materials Symposium
    • Related Report
      2017 Annual Research Report
  • [Presentation] Study on growth of high quality MgZnO films on MgO substrates for DUV light emission2017

    • Author(s)
      K. Ishii, T. Onuma, T. Uchida, R. Jinno, K. Kaneko, S. Fujita
    • Organizer
      36th Electronic Materials Symposium
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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