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Development of structured novel reaction system that effectively transform CO2 being exhausted from an industrial process

Research Project

Project/Area Number 17H01894
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental engineering and reduction of environmental burden
Research InstitutionShizuoka University

Principal Investigator

Fukuhara Choji  静岡大学, 工学部, 教授 (30199260)

Co-Investigator(Kenkyū-buntansha) 河野 芳海  静岡大学, 工学部, 准教授 (50334959)
渡部 綾  静岡大学, 工学部, 准教授 (80548884)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2019: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2018: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2017: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Keywords構造体触媒 / 膜分離 / メチルシクロヘキサン / メタン化反応 / 水素 / 反応システム / 触媒・化学プロセス / 再生可能エネルギー / 温室効果ガス削減 / 反応・分離 / 物質・熱移動 / 構造体触媒システム / 反応・分離工学
Outline of Final Research Achievements

The meaningful result obtained in this study is to find that the Pt/TiO2 catalyst exhibits excellent performance for methylcyclohexane (MCH) dehydrogenation, which is an energy carrier. Namely, the new catalyst system was found. Another important result is achievement of successfully treating a large amount of CO2 by modifying the morphology of the Ni/CeO2 structured catalyst for CO2 methanation, while effectively controlling the reaction heat energy. The third result is that this study succeeded in predicting the characteristics of a novel catalytic reaction system combining MCH dehydrogenation and CO2 methanation, and obtained a new guideline for chemical reaction engineering. These three results will contribute to the design of new catalytic reaction systems in the utilization filed of renewable energy.

Academic Significance and Societal Importance of the Research Achievements

低炭素社会の実現に向けて、再生可能エネルギー由来のクリーンな資源を用いてCO2の削減とその資源化と活用が求められている。本研究で得られた成果は、再エネ由来の水素キャリアから製造する水素を原料とし、産業プロセスから排出されるCO2の削減とそのメタン資源化を図る新しい触媒反応システムの提案につながるものである。それゆえ、得られた成果は今後の水素化社会と低炭素社会の構築に向けた技術開拓に貢献することが充分に期待できる。また、MCH脱水素反応やメタネーション反応に対して新しい触媒系と反応系が確立できたことは、当該分野における学術的活性化を促進する。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (40 results)

All 2020 2019 2018 2017 Other

All Int'l Joint Research (1 results) Journal Article (15 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 15 results) Presentation (22 results) (of which Int'l Joint Research: 22 results,  Invited: 2 results) Patent(Industrial Property Rights) (2 results)

  • [Int'l Joint Research] Chulalongkorn University/Mahidol University(Thailand)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Auto-methanation for transition-metal catalysts loaded on various oxide supports: A novel route for CO2 transformation at room-temperature and atmospheric pressure2020

    • Author(s)
      Fukuhara Choji、Kamiyama Asuka、Itoh Mikito、Hirata Nozomu、Ratchahat Sakhon、Sudoh Masao、Watanabe Ryo
    • Journal Title

      Chemical Engineering Science

      Volume: 219 Pages: 115589-115589

    • DOI

      10.1016/j.ces.2020.115589

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Theoretical study of oxygen adsorption energy on supported metal cluster using d-band center theory and HSAB concept2020

    • Author(s)
      Miura Kazuya、Watanabe Ryo、Fukuhara Choji
    • Journal Title

      Surface Science

      Volume: 696 Pages: 121601-121601

    • DOI

      10.1016/j.susc.2020.121601

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic uphill conversion of natural gas beyond the limitation of thermal reaction systems2020

    • Author(s)
      Shoji Shusaku、Peng Xiaobo、Yamaguchi Akira、Watanabe Ryo、Fukuhara Choji、Cho Yohei、Yamamoto Tomokazu、Matsumura Syo、Yu Min-Wen、Ishii Satoshi、Fujita Takeshi、Abe Hideki、Miyauchi Masahiro
    • Journal Title

      Nature Catalysis

      Volume: 3 Issue: 2 Pages: 148-153

    • DOI

      10.1038/s41929-019-0419-z

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deactivation factor of CuCl2-KCl/Al2O3 catalyst for ethylene oxychlorination in a commercial-scale plant2020

    • Author(s)
      Ohashi Tomokazu、Someya Sae、Mori Yoshihiko、Asakawa Tetsuo、Hanaya Makoto、Oguri Motohiro、Watanabe Ryo、Fukuhara Choji
    • Journal Title

      Applied Catalysis A: General

      Volume: 589 Pages: 117205-117205

    • DOI

      10.1016/j.apcata.2019.117205

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Analysis of Activation Energy of Hydrocarbon Oxidation Reaction Using Supported Pt Catalyst2019

    • Author(s)
      Miura Kazuya、Kimata Fumikazu、Watanabe Ryo、Fukuhara Choji
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 52 Issue: 6 Pages: 536-544

    • DOI

      10.1252/jcej.18we315

    • NAID

      130007665272

    • ISSN
      0021-9592, 1881-1299
    • Year and Date
      2019-06-20
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of active species for propane dehydrogenation with hydrogen sulfide co-feeding over transition metal catalyst2019

    • Author(s)
      Watanabe Ryo、Hirata Nozomu、Miura Kazuya、Yoda Yuta、Fushimi Yuya、Fukuhara Choji
    • Journal Title

      Applied Catalysis A: General

      Volume: 587 Pages: 117238-117238

    • DOI

      10.1016/j.apcata.2019.117238

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Auto-methanation Performance of Structured Ni-type Catalyst for CO2 Transformation2019

    • Author(s)
      Fukuhara Choji、Ratchahat Sakhon、Kamiyama Asuka、Sudoh Masao、Watanabe Ryo
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 5 Pages: 441-444

    • DOI

      10.1246/cl.190025

    • NAID

      130007642542

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Auto-methanation of Carbon Dioxide: A Novel Route for Transforming CO2 over Ni-based Catalyst2019

    • Author(s)
      Fukuhara Choji、Ratchahat Sakhon、Suzuki Yuji、Sudoh Masao、Watanabe Ryo
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 3 Pages: 196-199

    • DOI

      10.1246/cl.180894

    • NAID

      130007607581

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 物質・熱移動の促進による触媒反応場のプロセス強化(PI)2019

    • Author(s)
      福原長寿
    • Journal Title

      触媒

      Volume: 61 Pages: 9-15

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] DFT Study for Supported Pt Catalysts Focusing on the Chemical Potential2018

    • Author(s)
      Kazuya Miura, Fumikazu Kimata, Ryo Watanabe, Choji Fukuhara
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 16 Issue: 0 Pages: 209-213

    • DOI

      10.1380/ejssnt.2018.209

    • NAID

      130007381534

    • ISSN
      1348-0391
    • Year and Date
      2018-05-31
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An easy and effective method for the intercalation of hydrophobic natural dye into organo-montmorillonite for improved photostabilitycarbon capture2018

    • Author(s)
      Y.Kohno, T.Taguchi, M.Shibata, Y.Tomita, C.Fukuhara, Y.Maeda
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 116C Pages: 168-173

    • DOI

      10.1016/j.jpcs.2018.01.027

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of a powerful CO2 methanation process using a structured Ni/CeO2 catalyst2018

    • Author(s)
      S.Ratchahat, M.Sudoh, Y.Suzuki, W.Kawasaki, R.Watanabe, C.Fukuhara
    • Journal Title

      Journal of CO2 Utilization

      Volume: 24 Pages: 210-219

    • DOI

      10.1016/j.jcou.2018.01.004

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Active Species of Sulfated Metal Oxide Catalyst for Propane Dehydrogenation2017

    • Author(s)
      R.Watanabe, N.Hirata, C.Fukuhara
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 60 Issue: 5 Pages: 223-231

    • DOI

      10.1627/jpi.60.223

    • NAID

      130006039454

    • ISSN
      1346-8804, 1349-273X
    • Year and Date
      2017-09-01
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of a novel synthesis-gas production system combining with carbon capture2017

    • Author(s)
      W.Kawasaki, K.Hidenori, S. Ratchahat, R.Watanabe, C.Fukuhara
    • Journal Title

      Journal of CO2 Utilization

      Volume: 22 Pages: 91-96

    • DOI

      10.1016/j.jcou.2017.08.021

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 水素の製造と利用のための構造体触媒反応システム2017

    • Author(s)
      福原長寿
    • Journal Title

      水素エネルギーシステム

      Volume: 42(2) Pages: 76-82

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Auto-methanation of carbon dioxide with oxidation: a novel routefor CO2 transformation over supported metal catalyst2019

    • Author(s)
      Choji Fukuhara, Sakhon Ratchahat, Masao Sudoh, Ryo Watanabe
    • Organizer
      The 18th Asian Pacific Confederation of Chemical Engineering Congress
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structured Ni/CeO2 catalyst with high tolerant towards fluctuated operation of CO2 methanation2019

    • Author(s)
      Sakhon Ratchahat, Yuji Suzuki, Ryo Watanabe, Choji Fukuhara
    • Organizer
      The 8th Asia-Pacific Congress on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Auto-methanation of carbon dioxide: a novel route for CO2 transformation over Ni-based catalyst2019

    • Author(s)
      Choji Fukuhara, Sakhon Ratchahat, Asuka Kamiyama, Masao Sudoh, Ryo Watanabe
    • Organizer
      The 8th Asia-Pacific Congress on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of co-supplying H2S on propane degydrogenation peformance of Fe-based catalyst2019

    • Author(s)
      Ryo Watanabe, Yuta Yoda, Nozomu Hirata, Choji Fukuhara
    • Organizer
      The 8th Asia-Pacific Congress on Catalysis
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Auto-methanation over structured Ni-type catalyst for process intensification of carbon dioxide transformation2019

    • Author(s)
      Choji Fukuhara, Ryo Watanabe, Sakhon Ratchahat, Asuka Kamiyama, Masao Sudoh
    • Organizer
      6th european conference on environmental applications of advanced oxidation processes
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Auto-methanation of carbon dioxide over Ni-based catalyst: a novel route for CO2 transformation with oxidation2019

    • Author(s)
      Choji Fukuhara, Sakhon Ratchahat, Yuji Suzuki, Masao Sudoh, Ryo Watanabe
    • Organizer
      6th european conference on environmental applications of advanced oxidation processes
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A powerful CO2 methanation reactor with Ni/CeO2 structured catalyst: estimation of mass and heat transfer profiles2018

    • Author(s)
      Choji Fukuhara, Ryo Watanabe, Sakhon Ratchahat, Masao Sudoh
    • Organizer
      23rd International Conference on Chemical Reactors
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Co-feeding effect of H2S on propane dehydrogenation performance of transition metal (Fe, Co, Ni) catalysts2018

    • Author(s)
      Nozomu Hirata, Yuya Fushimi, Yoshiumi Kohno, Ryo Watanabe, Choji Fukuhara
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Alkali promotion of iron oxide based catalyst for water gas shift reaction2018

    • Author(s)
      Ryo Watanabe, Kengo Tajima, Yuya Fushimi, Nozomu Hirata, Choji Fukuhara
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A structured nickel-based catalyst with high performance and tolerance to coke deposition in naphthalene steam reforming for biomass-gasification process2018

    • Author(s)
      Choji Fukuhara, Ryo Watanabe, Kota Matsuzawa, Mio Yokoe, Kenji Asaoka, Hidekiyo Suyama, Shuichiro Suzuki
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of honeycomb-type Ru-based catalyst for NH3 decomposition, with mass processing ability of raw materials2018

    • Author(s)
      Masaki Kawase, Kimihito Suzuki, Ryo Watanabe, Choji Fukuhara
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of a novel catalytic reaction system consisting of dry reforming and carbon capture parts2018

    • Author(s)
      Yoshito Matsui, Wataru Kawasaki, Ryo Watanabe, Yoshiumi Kohno, Choji Fukuhara
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Advantage of structured catalyst system for CO2 methanation under extremely high flow rate2018

    • Author(s)
      Sakhon Ratchahat,Masao Sudoh,Yuji Suzuki,Ryo Watanabe,Choji Fukuhara
    • Organizer
      The 25th International Symposium on Chemical Reaction Engineering
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Estimation of heat and mass transfer of structured catalyst system for CO2 methanation2018

    • Author(s)
      Choji Fukuhara,Yuji Suzuki,Ryo Watanabe,Masao Sudoh,Sakhon Ratchahat
    • Organizer
      The 25th International Symposium on Chemical Reaction Engineering
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Advanced catalytic reforming system contributing to hydrogen production2018

    • Author(s)
      Choji Fukuhara
    • Organizer
      SCEJ 83nd Annual Meeting, International Symposium(K-4)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Investigation of CO2 methanation performance over a structured catalyst system under fluctuating reaction condition2017

    • Author(s)
      S.Ratchahat, M.Sudoh, Y.Suzuki, R.Watanabe, C.Fukuhara
    • Organizer
      The 47th Petrolium-Petrochemistry Symposium of JPI
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Innovative chemical reaction system contributing to issue of energy and environment2017

    • Author(s)
      Choji Fukuhara
    • Organizer
      The 8th Asian-Pacific Chemical Reaction Engineering Symposium (APCRE2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of honeycomb-type CO2 methanation reactor with advantage of hest and mass transfers2017

    • Author(s)
      S.Ratchahat, M.Sudoh, Y.Suzuki, R.Watanabe, C.Fukuhara
    • Organizer
      The 8th Asian-Pacific Chemical Reaction Engineering Symposium (APCRE2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Auto-thermal reforming property of Ni-based structured catalyst for dry reforming of methane2017

    • Author(s)
      K.Hirao, W.Kawasaki, Y.Kohno, R.Watanabe, C.Fukuhara
    • Organizer
      16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Sulfation treatment to transition metal oxide on propane dehydrogenation property2017

    • Author(s)
      N.Hirata, R.Watanabe, A.Maezawa, Y.Kohno, C.Fukuhara
    • Organizer
      16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of alkali metal addition to iron oxide structured catalyst for water gas shift property2017

    • Author(s)
      R.Watanabe, K.Tajima, N.Hirata, Y.Kohno, C.Fukuhara
    • Organizer
      16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] IR observation in methylcyclohexane dehydrogenation over Pt/TiO2 and Pt/Al2O3 catalysts2017

    • Author(s)
      K.Watanabe, Y.Bandai, R.Watanabe, Y.Kohno, C.Fukuhara
    • Organizer
      16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] メタンを製造する方法、及び製造システム2019

    • Inventor(s)
      福原長寿
    • Industrial Property Rights Holder
      福原長寿
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-160190
    • Filing Date
      2019
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] メタンを製造する方法、及び製造システム2018

    • Inventor(s)
      福原長寿
    • Industrial Property Rights Holder
      福原長寿
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-159398
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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