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Advanced fractionation of biomass by phenol coating and the following dilute acid hydrolysis

Research Project

Project/Area Number 17H01919
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Design and evaluation of sustainable and environmental conscious system
Research InstitutionMie University

Principal Investigator

NONAKA HIROSHI  三重大学, 生物資源学研究科, 教授 (90422881)

Co-Investigator(Kenkyū-buntansha) 浅田 元子  徳島大学, 大学院社会産業理工学研究部(生物資源産業学域), 准教授 (10580954)
秀野 晃大  愛媛大学, 紙産業イノベーションセンター, 講師 (30535711)
Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2020: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2018: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Keywords木材 / バイオマス / 成分分離 / リグニン / ヘミセルロース / セルロース / フェノール / セルロースナノファイバー / biomass / lignin / cellulose / fractionation / phenol / wood / hemicellulose / cresol / バイオリファイナリー
Outline of Final Research Achievements

p-Cresol or 2,4-dimethylphenol was impregnated to wood meal or chip. Hemicellulose was converted to constituent sugars and furfurals by hydrothermal or weak acid prehydrolysis. The obtained pre-hydrolyzed wood consists of cellulose and lignin, and we succeeded in obtaining lignin with thermoplasticity and solvent solubility in high yield by alkaline treatment. Cellulose could also be recovered in high yield by applying low-temperature alkaline extraction at about 50 degree C. Lignin-containing cellulose nanofibers was produced by defibrillation using grinder from the materials obtained in this process. It was suggested that lignin could be used as a lignin epoxy resin curing agent.

Academic Significance and Societal Importance of the Research Achievements

バイオマス変換プロセスの成功には,セルロース,ヘミセルロース由来ケミカルのほか,有用リグニンを高収率で得ることが不可欠である。本研究では,ヘミセルロース構成単糖,熱可塑性・溶媒可溶性のリグニン,リグニン含量の少ないセルロースを高収率で得ることができており画期的である。製紙パルプ産業には,木材の酸加水分解後,クラフト法で脱リグニンを行い,高純度セルロースを得るDKP(Dissolving Kraft Pulp)プロセスがあり,このプロセスに本研究成果を適用し,モノフェノール類を担持した木材チップを投入すれば,早期に大規模実用化が見通せる点においても社会的意義が大きい。

Report

(5 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (22 results)

All 2021 2020 2019 2018 2017

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (20 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results)

  • [Journal Article] Fractionation of woody biomass with impregnation of monophenol by prehydrolysis and the subsequent soda cooking2019

    • Author(s)
      Hata Tomoyuki、Nonaka Hiroshi
    • Journal Title

      Bioresource Technology Reports

      Volume: 5 Pages: 178-184

    • DOI

      10.1016/j.biteb.2019.01.012

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dilute acid hydrolysis of p-cresol-impregnated wood meal2018

    • Author(s)
      Hata Tomoyuki、Nonaka Hiroshi
    • Journal Title

      Biomass Conversion and Biorefinery

      Volume: 8 Issue: 2 Pages: 339-343

    • DOI

      10.1007/s13399-017-0282-6

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] フェノール化リグニン含有針葉樹パルプの調製とナノ解繊に向けた検討2021

    • Author(s)
      秀野晃大,岡村 翔,野中 寛
    • Organizer
      第16回バイオマス科学会議
    • Related Report
      2020 Annual Research Report
  • [Presentation] モノフェノール含浸・希酢酸水熱処理木材チップのアルカリ抽出2021

    • Author(s)
      岡村 翔,野中 寛
    • Organizer
      第71回日本木材学会大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] モノフェノール含浸・希酢酸水熱処理によるスギリグニンの回収2020

    • Author(s)
      岡村 翔,野中 寛
    • Organizer
      第65回リグニン討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] p-クレゾール含浸木粉の前加水分解ソーダ法により得られたリグニンの特性の評価2020

    • Author(s)
      岡村 翔,野中 寛
    • Organizer
      第70回日本木材学会大会(鳥取)
    • Related Report
      2019 Annual Research Report
  • [Presentation] 前加水分解針葉樹クラフトパルプからのセルロースナノファイバーの調製と評価2019

    • Author(s)
      秀野晃大、野中寛
    • Organizer
      セルロース学会第26回年次大会(福岡大学)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Autohydrolysis of monophenols-impregnated wood2019

    • Author(s)
      T. Okamura, H. Nonaka
    • Organizer
      化学工学会第2回東海若手合宿(ホテルウェルネス鈴鹿路)
    • Related Report
      2019 Annual Research Report
  • [Presentation] Acetic acid prehydrolysis of p-cresol-impregnated softwood2019

    • Author(s)
      T. Okamura, H. Nonaka
    • Organizer
      The 7th Asian Biomass Science Conference(Koriyama)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 機能性リグノセルロースナノファイバー調製に向けた検討2019

    • Author(s)
      秀野晃大,岡村翔,野中寛
    • Organizer
      第15回バイオマス科学会議(郡山)
    • Related Report
      2019 Annual Research Report
  • [Presentation] p-クレゾール含浸木材の自動加水分解2019

    • Author(s)
      (三重大生資)○岡村 翔,(三重大院生資)野中 寛
    • Organizer
      第14回バイオマス科学会議(東広島)
    • Related Report
      2018 Annual Research Report
  • [Presentation] モノフェノール含浸木粉の自動加水分解2019

    • Author(s)
      (三重大生資)○岡村 翔,(三重大院生資)野中 寛
    • Organizer
      第69回日本木材学会大会(函館アリーナ)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 前加水分解処理したセルロースのソーダ蒸解特性2018

    • Author(s)
      (三重大生資)○岡村 翔,(三重大院生資)畠 智之,野中 寛
    • Organizer
      セルロース学会第25回年次大会(京都大学・宇治キャンパス)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 木質系バイオマスの全成分を利用するための取組2018

    • Author(s)
      野中 寛
    • Organizer
      みえバイオリファイナリー研究会公開セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Production of cellulose, hemi-derived sugars and functional lignin by dilute acid hydrolysis of wood meal with monophenol2018

    • Author(s)
      H. Nonaka, T. Hata
    • Organizer
      2nd International Conference on Bioresource Technology for Bioenergy, Bioproducts & Environmental Sustainability
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Wood fractionation and lignin valorization by prehydrolysis-alkaline cooking with phenols2018

    • Author(s)
      Nonaka, Hiroshi; Okamura, Tsubasa; Hata, Tomoyuki
    • Organizer
      8th Nordic Wood Biorefinery Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] クレゾール含浸木粉の希硫酸前加水分解プロセスにおける木材成分分離挙動2018

    • Author(s)
      畠 智之,野中 寛
    • Organizer
      第13回バイオマス科学会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] 木質系バイオマスの全成分を生かす研究開発2018

    • Author(s)
      野中 寛
    • Organizer
      JACI(新化学技術推進協会)エネルギー・資源技術部会 バイオマス分科会講演
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] モノフェノール含浸木粉を用いた前加水分解プロセスによる高機能性リグニンの取得2018

    • Author(s)
      畠 智之,野中 寛
    • Organizer
      第68回日本木材学会大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Wood component separation by dilute acid prehydrolysis with p-cresol2017

    • Author(s)
      H. Tomoyuki, H. Nonaka
    • Organizer
      253rd American Chemical Society (ACS) National Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] モノフェノールを担持した木粉の希硫酸加水分解2017

    • Author(s)
      畠 智之,野中 寛
    • Organizer
      第26回日本エネルギー学会大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 木質系バイオマスの真の利活用に向けたポイントと研究推進2017

    • Author(s)
      野中 寛
    • Organizer
      ケナフ協議会2017年度年会
    • Related Report
      2017 Annual Research Report
    • Invited

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Published: 2017-04-28   Modified: 2023-12-25  

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