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Radiocarbon dating of ancient iron artifacts with high precision: Extension of measurements from metal iron to rusty iron samples

Research Project

Project/Area Number 17H02017
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Cultural assets study and museology
Research InstitutionNagoya University

Principal Investigator

Nakamura Toshio  名古屋大学, 宇宙地球環境研究所, 名誉教授 (10135387)

Co-Investigator(Kenkyū-buntansha) 齋藤 努  国立歴史民俗博物館, 大学共同利用機関等の部局等, 教授 (50205663)
山田 哲也  公益財団法人元興寺文化財研究所, 研究部, 研究員 (80261212)
南 雅代  名古屋大学, 宇宙地球環境研究所, 教授 (90324392)
Project Period (FY) 2017-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Fiscal Year 2020: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2019: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2018: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Keywords放射性炭素 / 放射性炭素年代測定 / 古代鉄資料 / 鉄サビ部の年代測定 / 石英管燃焼法 / 鉄中炭素の回収率 / 加速器質量分析 / 14C年代の暦年較正 / 石英管封管燃焼法
Outline of Final Research Achievements

The age of ancient iron artifacts can be measured by using carbon component that was included during the iron-producing stage. To extract carbon in a form of CO2, a quartz tube was used for metal iron combustion and carbon recovery of almost 90% for 24 standard iron materials was attained. We analyzed several iron flakes collected from Japanese swords whose ages were estimated by the inscription on the sword surface or by the traditional judgment of their appearances. The 14C dates obtained were almost consistent with the judgments, suggesting that 14C dating is a useful tool to certificate the traditional value of the swords.
In addition, we analyzed rust nail samples from archeological sites in India in the same way as pure metal iron. The carbon contents of the rust nails were almost similar to those of metal iron samples. The obtained 14C ages were consistent with their archeological chronology, showing that 14C dating can be applied successfully to iron rust samples.

Academic Significance and Societal Importance of the Research Achievements

人類の文化発展の研究において、世界、また日本における鉄利用の歴史の編年は、非常に重要な研究テーマである。これまでは鉄資料自体の年代測定を実施することがきわめて限られていたため、鉄資料の編年において代替試料の年代測定で済ませて編年を行っていた。また日本刀では、刀に刻まれた文字の判読や刀の形状・刃紋などの概観を観察して鑑定士が判定してきた。このため古代鉄・日本刀の編年の信頼度が不十分なものとなっていた。本研究により、日本刀や各地で発掘される鉄試料について、金属鉄はもとより錆びた鉄についても、その製作年代が高精度・高確度で明らかになれば、鉄資料の編年研究が大きく進展するものと期待される。

Report

(5 results)
  • 2021 Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (47 results)

All 2022 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (4 results) Journal Article (19 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 2 results) Presentation (21 results) (of which Int'l Joint Research: 11 results,  Invited: 1 results) Book (3 results)

  • [Int'l Joint Research] Museum Bronbeek(オランダ)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Institute for Japanese Sword Craft(オランダ)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] Institute for Japanese Sword Craft(オランダ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Institute for Japanese Sword Craft(オランダ)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 加速器質量分析法による日本刀や古い鉄器類の放射性炭素年代測定.2022

    • Author(s)
      中村俊夫・江藤孝一・藤本隆雄・山田哲也・塚本敏夫・齋藤 努・清水康二・伊藤 茂・南 雅代
    • Journal Title

      年代測定研究

      Volume: 6 Pages: 27-34

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Summary of EA-AMS 8 Symposium held at Nagoya University, Japan2020

    • Author(s)
      Toshio Nakamura, Hiroyuki Kitagawa, Masayo Minami, Fusa Miyake, Masako Yamane, Yoko Saito-Kokubu, Natsuko Fujita, Takahiro Watanabe
    • Journal Title

      Proceedings of EA-AMS 8 & JAMS-22

      Volume: 1 Pages: 2-10

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Maintenance records in the last two decades of the HVEE 14C AMS system at Nagoya University2020

    • Author(s)
      Toshio Nakamura, Masayo Minami, Akiko Ikeda, Tomoko Ohta, Masami Nishida, Hiroyuki Kitagawa
    • Journal Title

      Proceedings of EA-AMS 8 & JAMS-22

      Volume: 1 Pages: 27-43

    • Related Report
      2019 Annual Research Report
  • [Journal Article] 長登銅山と皇朝十二銭2020

    • Author(s)
      齋藤 努
    • Journal Title

      學士會会報

      Volume: 940 Pages: 100-105

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Radiocarbon dating of textile components from historical silk costumes and other cloth products in the Ryukyu Islands, Japan.2019

    • Author(s)
      Toshio Nakamura, Takako Terada, Chikako Ueki, Masayo Minami
    • Journal Title

      Radiocarbon

      Volume: 61 (6) Issue: 6 Pages: 1663-1674

    • DOI

      10.1017/rdc.2019.105

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A suitable procedure for preparing of water samples used in radiocarbon intercomparison.2019

    • Author(s)
      Takahashi, H.A., Minami, M, Aramaki, T., Handa, H., Saito-Kokubu, Y., Itoh, S., Kumamoto, Y.
    • Journal Title

      Radiocarbon

      Volume: 61 Issue: 6 Pages: 1879-1887

    • DOI

      10.1017/rdc.2019.104

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Eruption age of the Haruna Futatsudake Pumice (Hr-FP), central Japan, by radiocarbon wiggle matching with special reference to a 14C dataset developed from a Japanese tree.2019

    • Author(s)
      Mitsuru Okuno, Toshio Nakumura, Minoru Sakamoto, Shinya Yatsuzuka, Teruki Oikawa, Nobuo Geshi, Yasuharu Hoshino, Toshihiko Takahash
    • Journal Title

      Quaternary International

      Volume: 527 Pages: 29-33

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 加速器質量分析(AMS)による和釘の製造年代2019

    • Author(s)
      永田和宏・古主康子・松原章浩・國分(齋藤)陽子・中村俊夫
    • Journal Title

      鉄と鋼

      Volume: 104 Pages: 488-491

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 古代近江の鉄生産 - 操業年代について -2019

    • Author(s)
      丸山竜平・中村俊夫
    • Journal Title

      名古屋大学年代測定研究

      Volume: 3 Pages: 50-55

    • NAID

      120006498147

    • Related Report
      2018 Annual Research Report
  • [Journal Article] 名古屋大学タンデトロンAMS 14Cシステムの現状と利用(2018)2019

    • Author(s)
      中村俊夫・南 雅代・増田公明・小田寛貴・三宅芙紗・池田晃子・栗田直幸・山根雅子・西田真砂美・藤沢純平・佐藤里名・酢屋徳啓・北川浩之
    • Journal Title

      名古屋大学年代測定研究

      Volume: 3 Pages: 73-81

    • NAID

      120006628015

    • Related Report
      2018 Annual Research Report
  • [Journal Article] 名古屋市守山区東谷山湿地から採取した堆積物柱状コア試料のAMS 14C年代2019

    • Author(s)
      中村俊夫
    • Journal Title

      名古屋市東谷山湿地ボーリング調査報告書

      Volume: 1 Pages: 13-21

    • Related Report
      2018 Annual Research Report
  • [Journal Article] 火山泥流に含まれる木片の14C不一致年代:前橋泥流と塚原泥流の例2019

    • Author(s)
      佐藤興平・南 雅代・中村俊夫・柴田 賢・安部 久・武者 巌・池田信二
    • Journal Title

      群馬県立自然史博物館研究報告

      Volume: 23 Pages: 57-64

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Vegetation Changes around Haven Lake, Adak Island, Central Aleutians, Alaska, Determined from Pollen Analysis2018

    • Author(s)
      Noguchi Makoto、Fujiki Toshiyuki、Okuno Mitsuru、Gualtieri Lyn、Hatfield Virginia、Sarata Brenn、Torii Masayuki、Wada Keiji、Nakamura Toshio、West Dixie
    • Journal Title

      Radiocarbon

      Volume: 60 Issue: 5 Pages: 1483-1492

    • DOI

      10.1017/rdc.2018.103

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 纒向遺跡出土のモモの核のAMS 14C年代測定2018

    • Author(s)
      中村俊夫
    • Journal Title

      纏向学研究

      Volume: 6 Pages: 67-73

    • Related Report
      2018 Annual Research Report
  • [Journal Article] 沖縄県伊江島のナガラ原第三貝塚およびカヤ原遺跡A地点から出土した貝殻および木炭の14C年代2018

    • Author(s)
      小元久仁夫・中村俊夫・松島義幸
    • Journal Title

      第四紀研究

      Volume: 57 Pages: 77-83

    • NAID

      130006733493

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 古代近江の鉄生産―操業年代について―2018

    • Author(s)
      中村俊夫・丸山竜平
    • Journal Title

      年代測定研究

      Volume: 2 Pages: 52-56

    • NAID

      120006498147

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 名古屋大学タンデトロンAMS 14Cシステムの現状と利用(2017)2018

    • Author(s)
      中村俊夫・南 雅代・増田公明・小田寛貴・池田晃子・山根雅子・栗田直幸・窪田 薫・西田真砂美・藤沢純平・方 雨・徳丸 誠・木田梨沙子・酢屋徳啓・北川浩之
    • Journal Title

      年代測定研究

      Volume: 2 Pages: 79-87

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Verification of the annual dating of the 10th century Baitoushan volcano eruption based on an AD 774-775 radiocarbon spike2018

    • Author(s)
      Masataka Hakozaki, Fusa Miyake, Toshio Nakamura, Katsuhiko Kimura, Kimiaki Masuda, Mitsuru Okuno
    • Journal Title

      Radiocarbon

      Volume: 60 (1) Pages: 261-268

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 炭化物の高確度14C年代測定のための試料調製法の検討2017

    • Author(s)
      南 雅代・冨山慎二・中村俊夫
    • Journal Title

      第19回AMSシンポジウム・2016年度「樹木年輪」研究会報告集

      Volume: 1 Pages: 82-85

    • Related Report
      2017 Annual Research Report
  • [Presentation] Radiocarbon dating of historical iron products with accelerator mass spectrometry.2021

    • Author(s)
      Nakamura, T. Eto, K., Fujimoto, T., Yamada, T. Saito, T., Minami, M.
    • Organizer
      15th International Conference on Accelerator Mass Spectrometry
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 加速器質量分析法による鉄器類の放射性炭素年代測定2021

    • Author(s)
      中村俊夫・江藤孝一・藤本隆雄・山田哲也・南 雅代
    • Organizer
      日本文化財学会第38回大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 名古屋大学AMS 14C測定の現状と応用研究(2020-2021)2021

    • Author(s)
      中村俊夫・南 雅・山根雅子・小田寛貴・池田晃子・小坂由紀子・ 西田真砂美・若杉勇輝・佐藤里名・澤田 陸・酢屋徳啓・北川浩
    • Organizer
      第33回タンデム加速器及びその周辺技術の研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 日本国内の象牙加工品の年代測定と象牙原産地の判別方法の基礎研究(I)2019

    • Author(s)
      中村俊夫・小池裕子・南 雅代・西田 伸
    • Organizer
      日本文化財科学会第36回大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 名古屋大学AMS 14C測定の現状と応用研究(2019)2019

    • Author(s)
      中村俊夫・南 雅代・小田寛貴・池田晃子・山根雅子・西田真砂美・若杉勇輝・佐藤里名・澤田 陸・酢屋徳啓・北川浩之
    • Organizer
      第32回タンデム加速器及びその周辺技術の研究会
    • Related Report
      2019 Annual Research Report
  • [Presentation] A chronological study of wooden columns excavated at the Mawaki archeological site of the Noto Peninsula, central Japan2019

    • Author(s)
      Toshio Nakamura, Masaaki Kanehara, Masayo Minami, Hideki Takada
    • Organizer
      INQUA-2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Present status and application studies with HVE 14C AMS system at Nagoya University (2017/18/19)2019

    • Author(s)
      Toshio Nakamura, Masayo Minami, Hirotaka Oda, Akiko Ikeda, Masako Yamane, Masami Nishida, Yuki Wakasugi, Rina Sato, Hitoshi Sawada and Hiroyuki Kitagawa
    • Organizer
      The 8th East Asia Accelerator Mass Spectrometry Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A plan on accurate radiocarbon dating of ivory products in Japan and estimation of the original areas for providing ivory for legal international trading of ivory products2019

    • Author(s)
      Toshio Nakamura, Hiroko Koike, Masayo Minami, Shin Nishida
    • Organizer
      The 8th East Asia Accelerator Mass Spectrometry Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Radiocarbon dating of the medieval silk costumes from Ryukyu Islands, Japan2018

    • Author(s)
      Toshio Nakamura, Takako Terada, Chikako Ueki and Masayo Minami
    • Organizer
      The 23rd International Radiocarbon Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Radiocarbon dating of carbonate hydroxyapatite in bones burned at low temperatures2018

    • Author(s)
      Minami, M., Kida, R., Kadowaki, S., Nakamura, T.
    • Organizer
      The 23rd International Radiocarbon Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Radiocarbon dating of burned bones collected from the Goytepe and Damjili Cave archeological sites in Azerbaijan2018

    • Author(s)
      Minami, M., Kida, R., Kadowaki, S., Nakamura, T.
    • Organizer
      The 3rd Korea-Japan Joint Workshop on Isotope-Ratio Mass Spectrometry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ABOx-SC法を用いた木片の高確度14C年代測定による前橋泥流堆積時期の再検討2018

    • Author(s)
      南 雅代・佐藤興平・中村俊夫
    • Organizer
      2018年度日本地球化学会第65回年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 纒向遺跡出土のモモの核の14C年代測定の成果2018

    • Author(s)
      中村俊夫
    • Organizer
      日本文化財科学会第35回大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 名古屋大学AMS 14C測定の現状と応用研究(2018)2018

    • Author(s)
      中村俊夫・南 雅代・増田公明・小田寛貴・池田晃子・栗田直幸・山根雅子・西田真砂美・酢屋徳啓・北川浩之
    • Organizer
      タンデム加速器及びその周辺技術の研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 名古屋大学タンデトロンAMS14Cシステムの現状と利用(2017)2018

    • Author(s)
      中村俊夫・南 雅代・増田公明・小田寛貴・池田晃子・栗田直幸・窪田 薫・西田真砂美・椋本ひかり・藤沢純平・方 雨・徳丸 誠・酢屋徳啓・北川浩之
    • Organizer
      年度第29回宇宙地球環境研究所シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Radiocarbon dating of Japanese swords with accelerator mass spectrometry2017

    • Author(s)
      Nakamura Toshio, Minami Masayo, Eto Koichi and Fujimoto Takao
    • Organizer
      14th International Conference on Accelerator Mass Spectrometry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Radiocarbon age offset observed in Japanese tree rings: Comparison of 14C ages from Japanese tree rings with IntCal13 datasets2017

    • Author(s)
      Nakamura Toshio, Masuda Kimiaki, Miyake Fusa, Hakozaki Masataka
    • Organizer
      14th International Conference on Accelerator Mass Spectrometry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Present status and application studies with 14C AMS system at Nagoya University (2015/16/17)2017

    • Author(s)
      Toshio Nakamura and Masayo Minami
    • Organizer
      7th International Conference on East Asian Accelerator Mass Spectrometry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 名古屋大学AMS 14C測定の現状と応用研究(2017)2017

    • Author(s)
      中村俊夫・南 雅代・増田公明・小田寛貴・池田晃子・栗田直幸・窪田 薫・西田真砂・椋本ひかり・藤沢純平・方 雨・徳丸 誠・酢屋徳啓・北川浩之
    • Organizer
      タンデム加速器及びその周辺技術の研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 名古屋大学タンデトロンAMSシステムの現状(2017年度)2017

    • Author(s)
      中村俊夫・南 雅代・増田公明・小田寛貴・池田晃子・栗田直幸・窪田 薫・西田真砂・椋本ひかり・藤沢純平・方 雨・徳丸 誠・酢屋徳啓・北川浩之
    • Organizer
      第20回日本加速器質量分析シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Assessment of decontamination from charcoal by ABA and ABOx with SC treatments: Redetermination of 14C date of charred wood from the Aira caldera, southern Kyushu, Japan2017

    • Author(s)
      Masayo Minami, Toshio Nakamura, Mitsuru Okuno
    • Organizer
      14th International Conference on Accelerator Mass Spectrometry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Book] 職人の技と分析科学2019

    • Author(s)
      齋藤努
    • Total Pages
      164
    • Publisher
      吉川弘文館
    • Related Report
      2018 Annual Research Report
  • [Book] 日本刀の刀匠が伝承する卸し鉄の浸炭と脱炭における条件の相違2019

    • Author(s)
      齋藤努
    • Total Pages
      345
    • Publisher
      ミシガン大学出版局(オンライン出版)
    • Related Report
      2018 Annual Research Report
  • [Book] 「日本刀の刀身を作る」『歴史研究と〈総合資料学〉』国立歴史民俗博物館編2018

    • Author(s)
      齋藤努
    • Total Pages
      208
    • Publisher
      吉川弘文館
    • ISBN
      9784642038720
    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2023-01-30  

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