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eibunmei

Research Project

Project/Area Number 17H02724
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural chemistry
Research InstitutionKyoto University

Principal Investigator

Sakaguchi Hiroshi  京都大学, エネルギー理工学研究所, 教授 (30211931)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Keywordsナノ材料 / 表面重合 / 自己組織化 / ナノ炭素
Outline of Final Research Achievements

Two-dimensional graphene nanoribbons networks were fabricated from organic synthesized Z-bar linkage precursor molecules using our developed two-zone chemical vapor deposition technique. Two-dimensional graphene nanoribbons networks consist of fused wider GNR structures and ladder type structure via a C-C bond formation of adjacent GNRs. Upon a transition from the one-dimensional GNRs to two-dimensional graphene nanoribbons networks by an annealing, the electrical conductivities and carrier mobilities enhanced more than 5 orders magnitude. Additionally, 2D structures showed the significantly small thermal conductivities regarded as one of the most lowest values from carbon based materials.

Academic Significance and Societal Importance of the Research Achievements

本研究で明らかにした、二次元GNRネットワークはある程度の大きさの電気電導性と非常に低い熱伝導率を有しており、熱電材料としての有用性が示されたと考えられる。GNR鎖同士の脱水素縮環反応を利用した従来に無い広い幅を持つGNR構造や炭素―炭素単結合により形成した梯子型二次元炭素構造は、本研究で見出された新しい二次元ナノ炭素構造である。また、二次元ナノ炭素構造は、ある程度大きな電気伝導性と低い熱伝導性を持つことが示され、ボトムアップ合成GNRの熱電材料としての有用性を初めて示した研究と位置づけられる。これらの成果は、表面ボトムアップ合成GNRのエネルギー利用の可能性を示した研究である。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (35 results)

All 2020 2019 2018 2017

All Journal Article (18 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 18 results,  Open Access: 2 results) Presentation (16 results) (of which Int'l Joint Research: 8 results,  Invited: 12 results) Book (1 results)

  • [Journal Article] Fabrication and photocatalytic behavior of titanium oxide-gold nanoparticles composite ultrathin films prepared using surface sol-gel process2020

    • Author(s)
      S. Mitsukawa, T. Akiyama, M. Hinoue, K. Shima, T. Takishita, S. Higashida, N. Koyama, K. Sugawa, M. Ogawa, H. Sakaguchi, T. Oku
    • Journal Title

      Journal of Sol-Gel Science and Technology

      Volume: 93(3) Issue: 3 Pages: 563-569

    • DOI

      10.1007/s10971-019-05214-w

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bio-inspired Surface Catalysis to Produce Graphene Nanoribbons2019

    • Author(s)
      小島崇寛,Xu Zhen,坂口浩司
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 77 Issue: 6 Pages: 576-583

    • DOI

      10.5059/yukigoseikyokaishi.77.576

    • NAID

      130007662283

    • ISSN
      0037-9980, 1883-6526
    • Year and Date
      2019-06-01
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bottom‐Up On‐Surface Synthesis of Two‐Dimensional Graphene Nanoribbon Networks and Their Thermoelectric Properties2019

    • Author(s)
      T. Kojima, T. Nakae, Z. Xu, C. Saravanan, K. Watanabe, Y. Nakamura, H. Sakaguchi
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 14(22) Issue: 23 Pages: 4400-4407

    • DOI

      10.1002/asia.201901328

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of silver nanoplate on singlet exciton fission in rubrene polymer-composite films2019

    • Author(s)
      H. Yonemura, D. Aira, N. Asakura, K. Ezoe, H. Sakaguchi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SD Pages: SDDB03-SDDB03

    • DOI

      10.7567/1347-4065/ab51cc

    • NAID

      210000157451

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synergetic effect of silver nanoplate and magnetic field on photon upconversion based on sensitized triplet-triplet annihilation in polymer system2019

    • Author(s)
      Y. Noda, F. Shibata, S. Fukuda, G.S. Y. Lee, H. Sakaguchi, H. Yonemura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SD Pages: SDDB04-SDDB04

    • DOI

      10.7567/1347-4065/ab515b

    • NAID

      210000157433

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrostatic Repulsion-Induced Desorption of Dendritic Viologen-Arranged Molecules Anchored on a Gold Surface through a Gold-Thiolate Bond Leading to a Tunable Molecular Template2018

    • Author(s)
      Takehiro Kawauchi, Takahiro Kojima, Hiroshi Sakaguchi, Tomokazu Iyoda
    • Journal Title

      Langmuir

      Volume: 34 Issue: 22 Pages: 6420-6427

    • DOI

      10.1021/acs.langmuir.8b00858

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] (Poly)terephthalates with Efficient Blue Emission in the Solid State2018

    • Author(s)
      M. Shimizu, R. Shigitani, T. Kinoshita, H. Sakaguchi
    • Journal Title

      Chemistry - An Asian Journal

      Volume: - Issue: 10 Pages: 1792-1800

    • DOI

      10.1002/asia.201801619

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 金属表面を巧みに利用したグラフェンナノリボンの合成-ボトムアップ法による精密合成2018

    • Author(s)
      小島崇寛,坂口浩司
    • Journal Title

      化学

      Volume: 73(2) Pages: 68-69

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Discrimination and Manipulation of Individual Heptahelicene Molecules on Cu(001) by Noncontact Atomic Force Microscopy2018

    • Author(s)
      Shiotari Akitoshi, Tanaka Koichi, Nakae Takahiro, Mori Shigeki, Okujima Tetsuo, Uno Hidemitsu, Sakaguchi Hiroshi, Sugimoto Yoshiaki
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 9 Pages: 4997-5003

    • DOI

      10.1021/acs.jpcc.8b00487

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] On-surface synthesis of graphene clusters from a Z-bar-linkage precursor with quaterphenylbranches2018

    • Author(s)
      Z. Xu, T. Kojima, W. Wang, K. Kaushik, A. Saliniemi, T. Nakae, H. Sakaguchi
    • Journal Title

      Materials Chemistry Frontiers

      Volume: 2(4) Issue: 4 Pages: 775-779

    • DOI

      10.1039/c7qm00577f

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Dibenzopentalane-linking Polymers under the Two-Zone CVD and Wet Conditions2017

    • Author(s)
      M. Saito, Y. Suda, S. Furukawa, T. Nakae, T. Kojima, H. Sakaguchi
    • Journal Title

      Chemistry Letters

      Volume: 46(8) Issue: 8 Pages: 1099-1101

    • DOI

      10.1246/cl.170396

    • NAID

      130005906995

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Wide graphene nanoribbons produced by interchain fusion of poly(p-phenylene) via two-zone chemical vapor deposition2017

    • Author(s)
      S. Song, T. Kojima, T. Nakae, H. Sakaguchi
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 52 Pages: 7034-7036

    • DOI

      10.1039/c7cc02849k

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strain-induced skeletal rearrangement of a polycyclic aromatic hydrocarbon on a copper surface2017

    • Author(s)
      Shiotari Akitoshi, Nakae Takahiro, Iwata Kota, Mori Shigeki, Okujima Tetsuo, Uno Hidemitsu, Sakaguchi Hiroshi, Sugimoto Yoshiaki
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1 Pages: 16089-16089

    • DOI

      10.1038/ncomms16089

    • NAID

      120006329156

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Interchain-linked Graphene Nanoribbons from Dibenzo[g,p]chrysene via Two-zone Chemical Vapor Deposition2017

    • Author(s)
      S. Song, G. Huang, T. Kojima, T. Nakae, H. Uno, H. Sakaguchi
    • Journal Title

      Chemistry Letters

      Volume: 46(10) Issue: 10 Pages: 1525-1527

    • DOI

      10.1246/cl.170614

    • NAID

      130006140003

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Orientation and Electronic Structures of Multilayered Graphene Nanoribbons Produced by Two-Zone Chemical Vapor Deposition2017

    • Author(s)
      T. Kojima, Y. Bao, C. Zhang, S. Liu, H. Xu, T. Nakae, K. P. Loh, H. Sakaguchi
    • Journal Title

      Langmuir

      Volume: 33(40) Issue: 40 Pages: 10439-10445

    • DOI

      10.1021/acs.langmuir.7b01862

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 機能性有機分子創成のための分子ひずみを駆使した表面合成法2017

    • Author(s)
      塩足亮隼,中江隆博,宇野英満,坂口浩司,杉本宜昭
    • Journal Title

      機能材料

      Volume: 37(12) Pages: 60-67

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Gold Nanoparticle on Photon Upconversion based on Sensitized Triplet-Triplet annihilation in Polymer Films2017

    • Author(s)
      H. Yonemura, Y. Naka, M. Nishino, H. Sakaguchi, S. Yamada
    • Journal Title

      Molecular Crystals and Liquid Crystals

      Volume: 654(1) Issue: 1 Pages: 196-200

    • DOI

      10.1080/15421406.2017.1358044

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Silver Nanoparticle on Singlet Exciton Fission in Rubrene Films2017

    • Author(s)
      H. Yonemura, Y. Futaoka, T. Taniguchi, H. Sakaguchi, S. Yamada
    • Journal Title

      Molecular Crystals and Liquid Crystals

      Volume: 654(1) Issue: 1 Pages: 209-213

    • DOI

      10.1080/15421406.2017.1358046

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 生物類似表面触媒作用を用いるナノ炭素細線の合成2019

    • Author(s)
      坂口浩司
    • Organizer
      2019年度分子研研究会「単分子有機化学の挑戦」
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Nature-Inspired On-Surface Synthesis of Graphene Nanoribbons2019

    • Author(s)
      S. Nobusue, H. Sakaguchi
    • Organizer
      International Congress on Pure & Applied Chemistry Yangon (ICPAC Yangon) 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 生物類似表面触媒作用を用いるナノ炭素細線の合成2019

    • Author(s)
      坂口浩司
    • Organizer
      第46回炭素材料学会年会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Preparation of Interchain-linked 2D Graphene Nanoribbons with Dibenzo[g,p]chrysene by Two-Zone Chemical Vapor Deposition2019

    • Author(s)
      Z. Pei, Z. Xu, K. Kaushik, S. Nobusue, T. Kojima, H. Sakaguchi
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] On-surface synthesis of graphene clusters from a quaterphenylbranched Z-bar-linkage precursor2019

    • Author(s)
      Z. Xu, Z. Pei, K. Kaushik, T. Kojima, S. Nobusue, H. Sakaguchi
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Biomimetic On-surface Growth of Graphene Nanoribbons2018

    • Author(s)
      H. Sakaguchi
    • Organizer
      CIMTEC 2018(8th Forum on New Materials)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 新規Z型前駆体モノマーを用いたナノ炭素材料の表面合成2018

    • Author(s)
      小島崇寛, Xu Zhen, 坂口浩司
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Biomimetic surface reaction toward Graphene Nanoribbons2018

    • Author(s)
      T. Kojima, Z. Xu, H. Sakaguchi
    • Organizer
      International Congress on Pure & Applied Chemistry Langkawi 2018(ICPAC Langkawi2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 生物模倣触媒作用を用いるグラフェンナノリボンの表面合成2018

    • Author(s)
      坂口浩司
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Bio-inspired on-surface fabrication of graphene nanoribbons2018

    • Author(s)
      H. Sakaguchi
    • Organizer
      Nano-Micro Conference 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nature-inspired on-surface synthesis of graphene nanoribbons2018

    • Author(s)
      S. Nobusue, H. Sakaguchi
    • Organizer
      Energy Materials and Nanotechnology (EMN AUCKLAND MEETING 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of functional nanocarbon molecules by surface-induced conformation-controlled mechanism2018

    • Author(s)
      T. Nakae, H. Sakaguchi
    • Organizer
      International Congress on Pure & Applied Chemistry (ICPAC) 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 生物模倣触媒を用いる機能性ナノ炭素細線の合成2017

    • Author(s)
      坂口浩司
    • Organizer
      応用物理学会関西支部平成29年度第1回 講演会「マテリアルデザインとグリーンデバイスの最前線~関西発、イノベーションと若手研究者からの発信~」
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Conformation-assisted synthesis of acene-type graphene nanoribbons on Au(111)2017

    • Author(s)
      T. Kojima, T. Nakae, H. Sakaguchi
    • Organizer
      International Symposium on Pure & Applied Chemistry (ISPAC)2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 生物模倣触媒によるグラフェンナノリボンの表面合成2017

    • Author(s)
      坂口浩司
    • Organizer
      第53回 フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Biomimetic on-surface synthesis of graphene nanoribbons2017

    • Author(s)
      H. Sakaguchi
    • Organizer
      Global Research Efforts on Energy and Nanomaterials (GREEN 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] Molecular Archtectonics: The Third Stage of Single Molecule Electronics2017

    • Author(s)
      T. Nakae, H. Sakaguchi
    • Total Pages
      539
    • Publisher
      Springer
    • ISBN
      9783319570952
    • Related Report
      2017 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

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