| Budget Amount *help |
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2020: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2019: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2018: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2017: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
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| Outline of Final Research Achievements |
In this project, we constructed methods to control the near-infrared photoluminescence properties of single-walled carbon nanotubes (SWNTs) by chemical functionalization. We have achieved the emergence of new PL peaks of (6,5) SWNTs adducts from 1100 nm to 1268 nm depending on the functionalization methods and the reagents used. By designing the reagents, the addition patterns of SWNTs can be controlled kinetically or thermodynamically, which is supported by the results of theoretical calculations. In addition, we achieved chiral separation and optical resolution of the SWNTs adducts.
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