• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of high-accuracy spatial resolution EELS and analysis of electronic state at interfaces

Research Project

Project/Area Number 17H02739
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials chemistry
Research InstitutionKyoto University

Principal Investigator

Kurata Hiroki  京都大学, 化学研究所, 教授 (50186491)

Co-Investigator(Kenkyū-buntansha) 治田 充貴  京都大学, 化学研究所, 助教 (00711574)
根本 隆  京都大学, 化学研究所, 助教 (20293946)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥15,080,000 (Direct Cost: ¥11,600,000、Indirect Cost: ¥3,480,000)
Fiscal Year 2019: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2018: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2017: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywords電子エネルギー損失分光法 / 電子顕微鏡 / 状態分析 / マッピング / 走査型透過電子顕微鏡 / 電子構造 / 界面状態分析
Outline of Final Research Achievements

We have developed a new method to map electronic structure information in two dimensions with atomic resolution. This is based on the multi-frame method that integrates a large number of spectrum image data. For the first time, we have succeeded in atomic resolution mapping of oxygen holes in a high temperature superconductor using a new method. We have developed a momentum-selective high spatial resolution STEM-EELS method suitable for exploring the directionality of anisotropic electronic structures such as interfaces, and have succeeded in the measurement of inner-shell excitation spectra with atomic level resolution depending on the oxygen bonding direction in SrTiO3.

Academic Significance and Societal Importance of the Research Achievements

元素分布だけでなく物質の電子構造情報を原子分解能で2次元マッピングが可能になったことは、局所領域の化学を探索するうえで強力なツールが開発されたものとして意義がある。さらに、異方的な電子構造を原子レベルで解析できる手法の開発は、これまで犠牲にされていた空間情報が明らかにされ、その有用性が広がった。このような分析手法の開発は、社会的に有用な様々な機能性材料を分析する基盤技術の進歩として意義がある。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (26 results)

All 2020 2019 2018 2017

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (21 results) (of which Int'l Joint Research: 8 results,  Invited: 12 results)

  • [Journal Article] Understanding ordered structure in hematite nanowhiskers synthesized via thermal oxidation of iron-based substrates2020

    • Author(s)
      Ming-Wei Lai and Hiroki Kurata
    • Journal Title

      Materials and Design

      Volume: 191 Pages: 108596-108596

    • DOI

      10.1016/j.matdes.2020.108596

    • NAID

      120006898052

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Extremely low count detection for EELS spectrum imaging by reducing CCD read-out noise2019

    • Author(s)
      Mitsutaka Haruta, Yoshifumi Fujiyoshi, Takashi Nemoto, Akimitsu Ishizuka, Kazuo Ishizuka, Hiroki Kurata
    • Journal Title

      Ultramicroscopy

      Volume: 207 Pages: 112827-112827

    • DOI

      10.1016/j.ultramic.2019.112827

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local quantification of coordination number for perovskite-related oxides using atomic resolution EELS maps2018

    • Author(s)
      Mitsutaka Haruta, Hiroki Higuchi, Takashi Nemoto, and Hiroki Kurata
    • Journal Title

      Appl. Phys. Lett.

      Volume: 113 Issue: 8

    • DOI

      10.1063/1.5041063

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Probing directionality of local electronic structure by momentum-selected STEM-EELS2018

    • Author(s)
      A. Yamaguchi, M. Haruta, T. Nemoto, and H. Kurata
    • Journal Title

      Appl. Phys. Lett.

      Volume: 113 Issue: 5

    • DOI

      10.1063/1.5040312

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic resolution two-dimensional mapping of hole in cuprate superconductor La2-xSrxCu4±δ2018

    • Author(s)
      Mitsutaka Haruta, Yoshifumi Fujiyoshi, Takashi Nemoto, Akimitsu Ishizuka, Kazuo Ishizuka, Hiroki Kurata
    • Journal Title

      Physical Review B

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Extraction of Local Coordination Structure and Crystal Field Splitting Using Crystal Field Multiplet Calculation2020

    • Author(s)
      M. Haruta
    • Organizer
      12th Asia-Pacific Microscopy Conference (APMC-2020)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 局所電子構造の精密計測2020

    • Author(s)
      治田 充貴
    • Organizer
      日本顕微鏡学会 超高分解能顕微鏡法分科会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] High Spatial Resolution Electronic State Analysis of Transition Metal Oxides2019

    • Author(s)
      M. Haruta, and H. Kurata
    • Organizer
      International Conference of the Microscopy Society of Thailand (MST36)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High Energy Resolution Analysis by Monochromated STEM-EELS2019

    • Author(s)
      H. Kurata
    • Organizer
      International Conference of the Microscopy Society of Thailand (MST36)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 結晶場多重項計算を用いた局所配位構造の導出2019

    • Author(s)
      治田 充貴,新居 あおい,倉田 博基
    • Organizer
      日本顕微鏡学会第75回学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] CCDノイズ低減によるEELSスペクトルのSN比の改善2019

    • Author(s)
      治田 充貴,藤吉 好史,根本 隆,石塚 顕在,石塚 和夫,倉田 博基
    • Organizer
      日本顕微鏡学会第75回学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 内殻励起スペクトルの基礎と応用2019

    • Author(s)
      治田 充貴
    • Organizer
      第35回分析電子顕微鏡討論会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 電子顕微鏡:無機結晶からソフトマテリアルの観察2019

    • Author(s)
      倉田博基
    • Organizer
      2019年度新材料・新技術利用研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] STEM-EELSによる局所電子構造解析・電子状態マッピング2019

    • Author(s)
      治田 充貴
    • Organizer
      日本顕微鏡学会第62回シンポジウム
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] High resolution quantitative analysis of elemental ratio using STEM-EELS2018

    • Author(s)
      Mitsutaka Haruta and Hiroki Kurata
    • Organizer
      International conference on Microscopy & XXXIX Annual Meeting of Electron Microscope Society of India (EMSI2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] EELS mapping of chemical information2018

    • Author(s)
      Mitsutaka Haruta, Hiroki Higuchi, Takashi Nemoto and Hiroki Kurata
    • Organizer
      12th Japanese-Polish Joint Seminar on Micro and Nano Analysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Direct observation of hole in caprate superconductor using STEM-EELS2018

    • Author(s)
      M. Haruta, Y. Fujiyoshi, T. Nemoto, A. Ishizuka, K. Ishizuka, and H. Kurata
    • Organizer
      19th International Microscopy Congress (IMC19)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] モノクロメータ搭載STEM-EELS法によるCa2Fe1.07Mn0.93O5の局所電子構造解析2018

    • Author(s)
      新居あおい, 治田充貴, 倉田博基
    • Organizer
      日本顕微鏡学会第74回学術講演会
    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
  • [Presentation] ペロブスカイト関連酸化物における配位数の高分解能評価に関する研究2018

    • Author(s)
      樋口弘樹, 治田充貴, 根本隆, 倉田博基
    • Organizer
      日本顕微鏡学会第74回学術講演会
    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
  • [Presentation] 分析電子顕微鏡による局所状態分析2018

    • Author(s)
      倉田博基
    • Organizer
      第3回 固体化学フォーラム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Direct observation of hole in caprate superconductor using STEM-EELS2018

    • Author(s)
      M. Haruta, Y. Fujiyoshi, T. Nemoto, A. Ishizuka, K. Ishizuka, and H. Kurata
    • Organizer
      18th Internationa Microscopy Congress
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Distribution of electron hole in La2-xSrxCuO42017

    • Author(s)
      M. Haruta, Y. Fujiyoshi, T. Nemoto, A. Ishizuka, K. Ishizuka, and H. Kurata
    • Organizer
      8th International Workshop on Electron Energy Loss Spectroscopy and Related Techniques (EDGE 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Studying Ordered Defect Structures in α-Fe2O3 Nanowhiskers by Negative Spherical Aberration TEM and Monochromated STEM-EELS2017

    • Author(s)
      Ming-Wei Lai, Mitsutaka Haruta, Takashi Nemoto and Hiroki Kurata
    • Organizer
      日本顕微鏡学会第73回学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] La2-xSrxCuO4におけるホール分布2017

    • Author(s)
      治田充貴、藤吉好史、根本隆、石塚顕在、石塚和夫、倉田博基
    • Organizer
      日本顕微鏡学会第73回学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 精密構造観察と状態分析2017

    • Author(s)
      倉田博基
    • Organizer
      日本顕微鏡学会第60回記念シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 高エネルギー分解能STEM-EELSによる電子状態分析2017

    • Author(s)
      倉田博基
    • Organizer
      日本顕微鏡学会北海道支部講演会
    • Related Report
      2017 Annual Research Report
    • Invited

URL: 

Published: 2017-04-28   Modified: 2021-02-19  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi