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Homoepitaxial growth of hexagonal boron nitride on high quality HPHT substrates

Research Project

Project/Area Number 17H02748
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials engineering
Research InstitutionNational Institute for Materials Science

Principal Investigator

WATANABE Kenji  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主席研究員 (20343840)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2019: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2018: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2017: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Keywords六方晶窒化ホウ素 / 結晶成長 / 気相成長 / 格子欠陥 / 原子層科学 / 結晶工学 / 半導体超微細化 / 二次元原子層材料 / 光学特性
Outline of Final Research Achievements

We have studied homoepitaxial growth technique of hexagonal boron nitride (h-BN) on exfoliated h-BN substrates synthesized by high-pressure and high-temperature (HPHT) method. During the course of this research, the new characterization method for growth substrates based on photoluminescence imaging technique has developed. By employing the characterization system, we have given light of the 3D impurity/defect domain structure for h-BN grown by HPHT method, and confirmed that the crystallinity of the CVD layer can be improved compared with that of HPHT exfoliated substrates.

Academic Significance and Societal Importance of the Research Achievements

六方晶窒化ホウ素のc面内横方向成長(ラテラル成長)については、本研究でこれまで試行した限りにおいて、剥離転写基板の高さ調整、成長圧力条件、成長温度条件(900-1500℃)、基板種類(サファイア、モリブデン板、タングステン板)などで顕著な成長速度の増強はみられなかった。六方晶窒化ホウ素の大面積単結晶基板は将来的な2次元材料の応用だけではなく、六方晶窒化ホウ素自体の紫外発光材料応用や、赤外ナノフォトニクス応用においても重要である点に鑑み、今後さらなる研究が必要である。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (20 results)

All 2019 2018 2017 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (11 results) (of which Int'l Joint Research: 4 results,  Invited: 7 results) Remarks (8 results)

  • [Journal Article] Far-UV photoluminescence microscope for impurity domain in hexagonal-boron-nitride single crystals by high-pressure, high-temperature synthesis2019

    • Author(s)
      Watanabe Kenji、Taniguchi Takashi
    • Journal Title

      npj 2D Materials and Applications

      Volume: 3 Issue: 1 Pages: 40-44

    • DOI

      10.1038/s41699-019-0124-4

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Observation of impurity incorporated domain in h-BN single crystals2019

    • Author(s)
      渡邊賢司、谷口尚
    • Organizer
      Compound Semiconductor Week 2019 [CSW2019]
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Observation of Impurity Incorporated Domain in h-BN Single Crystals for Improvement of Crystal Quality2019

    • Author(s)
      渡邊賢司、谷口尚
    • Organizer
      International Workshop TOPOLOGY 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 六方晶窒化ホウ素の発光特性と応用展開2019

    • Author(s)
      渡邊賢司、谷口尚
    • Organizer
      電気学会パワー光源応用システム調査専門委員会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Observation of impurity incorporated regions in hexagonal boron nitride single crystals by high-pressure, high- temperature synthesis2019

    • Author(s)
      渡邊賢司、谷口尚
    • Organizer
      第38回電子材料シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高温高圧法により成長した六方晶窒化ホウ素単結晶の発光像観察2019

    • Author(s)
      渡邊賢司、谷口尚
    • Organizer
      第33回ダイヤモンドシンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] 六方晶窒化ホウ素(h-BN)の光物性と応用展開2018

    • Author(s)
      渡邊賢司
    • Organizer
      第148回結晶工学分科会研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Deep UV photoluminescence microscopysystem for exploring luminous properties of hexagonal boron nitride crystals2018

    • Author(s)
      渡邊賢司
    • Organizer
      3rd EU-JP Flagship Workshop on Graphene and 2D Materials
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Visualization of resonant second order Raman modes for n-GaN wafer bys patial mapping method2018

    • Author(s)
      渡邊賢司
    • Organizer
      第37回電子材料シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 六方晶窒化ホウ素の発光機構解明のためのホモエピタキシャル成長2018

    • Author(s)
      渡邊 賢司, 谷口 尚
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 六方晶窒化ホウ素の光物性と応用展開2017

    • Author(s)
      渡邊 賢司, 谷口 尚
    • Organizer
      グラフェンコンソーシアム第14回研究講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Raman spectroscopy study of homoepitaxially grown hexagonal boron nitride2017

    • Author(s)
      渡邊 賢司, 谷口 尚
    • Organizer
      International Workshop on UV Materials and Devices IWUMD-2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 窒化ホウ素の研究

    • URL

      http://www.nims.go.jp/personal/BN_research/index-j_BNR.html

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report 2017 Annual Research Report
  • [Remarks] Boron Nitride Research

    • URL

      http://www.nims.go.jp/personal/BN_research/index-e_BNR.html

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report 2017 Annual Research Report
  • [Remarks] 物質・材料研究機構 研究者情報

    • URL

      https://samurai.nims.go.jp/profiles/watanabe_kenji_aml?locale=ja

    • Related Report
      2019 Annual Research Report
  • [Remarks] 物質・材料研究機構 研究者情報(英語)

    • URL

      https://samurai.nims.go.jp/profiles/watanabe_kenji_aml?locale=en

    • Related Report
      2019 Annual Research Report
  • [Remarks] 物質・材料研究機構 研究者情報

    • URL

      http://samurai.nims.go.jp/WATANABE_Kenji_AML-j.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] 物質・材料研究機構 研究者情報(英語)

    • URL

      http://samurai.nims.go.jp/WATANABE_Kenji_AML-e.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] 物質・材料研究機構 研究者情報

    • URL

      http://samurai.nims.go.jp/WATANABE_Kenji_AML-j.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 物質・材料研究機構 研究者情報(英語)

    • URL

      http://samurai.nims.go.jp/WATANABE_Kenji_AML-e.html

    • Related Report
      2017 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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