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Light amplification due to resonant electronic Raman transitions in germanium and its application to interband lasers

Research Project

Project/Area Number 17H02773
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Crystal engineering
Research InstitutionThe University of Tokyo

Principal Investigator

Fukatsu Susumu  東京大学, 大学院総合文化研究科, 教授 (60199164)

Co-Investigator(Kenkyū-buntansha) 安武 裕輔  東京大学, 大学院総合文化研究科, 助教 (10526726)
Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2019: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2018: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Keywordsゲルマニウム / 共鳴電子ラマン遷移 / 光利得 / 量子閉じ込め / バレー選択励起 / バレー間散乱 / 円偏光フェムト秒励起相関法 / Germanane / 共鳴電子ラマン散乱 / 誘導ラマン過程 / バンド間遷移 / バンド間遷移レーザー / 共鳴誘導ラマン過程 / 共鳴電子ラマン利得 / 非自明な誘導放出光発生機構 / スプリットオフ正孔 / 前方散乱ポンプ・プローブ測定 / フェムト秒円偏光蛍光相関測定 / 半導体物性 / 光物性 / 結晶工学 / 電子・電気材料 / 量子エレクトロニクス
Outline of Final Research Achievements

The sought-after group-IV monolithic photofunctional integrated devices offer a wide range of applications such as optical interconnects to integrated CMOS circuits and autonomous vehicle sensors. The group-IV light emitters operating in the telecom bands have been challenged over time in this context. Here we investigate the physical properties of germanium (Ge) in an attempt to observe the first stimulated emission of radiation by designing the intervalley-scattering-controlled electronic-Raman (ER) gain that is unique to the valleytronic semiconductor Ge. The ER-mediated light amplification in strain-engineered Ge is demonstrated by (1) tuning in to a resonance between the split-off hole ER and the band-edge through optimized pumping, (2) tracking the ER dynamics by means of spin-sensitive ultrafast spectroscopy, (3) designing allied Ge allotropes, and (4) coupling the strained Ge to an optical resonator.

Academic Significance and Societal Importance of the Research Achievements

歪Geには疑似直接遷移化による顕著な光学特性・デバイス機能の向上が期待されている。しかし、現状、最も有力とされる本手法も必然的にバンドギャップ縮小を招き、その結果、意図しない中赤外領域へのエネルギーシフトが発生する。いきおいこれを克服することが喫緊の課題である。これに対して本研究は、未踏の新奇電子励起法を軸に高度光機能の発現に向けて非従来型の高機能構造の設計と戦略的な物性の制御を行うことでSWIR域におけるGeの光利得発現の実証を試みるものである。一方で単なる応用展開の模索にとどまることなく、Geの新しい光学特性や機能性は、新奇な半導体光物性の学理探求の契機となることが期待される。

Report

(4 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (35 results)

All 2020 2019 2018 2017 Other

All Journal Article (9 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 9 results,  Open Access: 2 results) Presentation (25 results) (of which Int'l Joint Research: 10 results,  Invited: 5 results) Remarks (1 results)

  • [Journal Article] Synthesis of a Black Dye with Absorption Capabilities Across the Visible-to-Near-Infrared Region: A MO-Mixing Approach via Heterometal Coordination of Expanded Porphyrinoid2020

    • Author(s)
      Wang Yue、Kai Hiroto、Ishida Masatoshi、Gokulnath Sabapathi、Mori Shigeki、Murayama Tomotaka、Muranaka Atsuya、Uchiyama Masanobu、Yasutake Yuhsuke、Fukatsu Susumu、Notsuka Yusuke、Yamaoka Yoshihisa、Hanafusa Mamiko、Yoshizawa Michito、Kim Gakhyun、Kim Dongho、Furuta Hiroyuki
    • Journal Title

      Journal of the American Chemical Society

      Volume: 142 Issue: 14 Pages: 6807-6813

    • DOI

      10.1021/jacs.0c01824

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ambipolar transistor action of germanane electric double layer transistor2019

    • Author(s)
      Yumiko Katayama, Ryoto Yamauchi, Yuhsuke Yasutake, Susumu Fukatsu, Kazunori Ueno
    • Journal Title

      Applied Physics Letters

      Volume: 115 Issue: 12

    • DOI

      10.1063/1.5094817

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Doubly N‐Confused Calix [6] phyrin Bis‐Organopalladium Complexes: Photostable Triplet Sensitizers for Singlet Oxygen Generation2019

    • Author(s)
      Poornenth Pushpanandan, Dong-Hoon Won, Shigeki Mori, Yuhsuke Yasutake, Susumu Fukatsu, Masatoshi Ishida, Hiroyuki Furuta
    • Journal Title

      Chemistry-An Asian Journal

      Volume: 1 Issue: 10 Pages: 1-1

    • DOI

      10.1002/asia.201801671

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Quantum-Enhanced Magneto-optic Measurements in a Dissipative Medium2019

    • Author(s)
      Youhei Okawa, Shiho Morimoto, Yuhsuke Yasutake, Susumu Fukatsu
    • Journal Title

      Quantum Information and Measurement (QIM) V: Quantum Technologie

      Volume: T5A.37 Pages: 1-2

    • DOI

      10.1364/qim.2019.t5a.37

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phosphorescent rhenium-dipyrrinates: efficient photosensitizers for singlet oxygen generation2019

    • Author(s)
      Neha Manav, Praseetha E Kesavan, Masatoshi Ishida, Shigeki Mori, Yuhsuke Yasutake, Susumu Fukatsu, Hiroyuki Furuta, Iti Gupta
    • Journal Title

      Dalton Transactions

      Volume: 48 Issue: 7 Pages: 2467-2478

    • DOI

      10.1039/c8dt04540b

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Hierarchical Hybrid Metal-Organic Frameworks: Tuning the Visible/Near-Infrared Optical Properties by a Combination of Porphyrin and Its Isomer Units2019

    • Author(s)
      Y. Yang, M. Ishida, Y. Yasutake, S. Fukatsu, C. Fukakusa, M-a. Morikawa, T. Yamada, N. Kimizuka, H. Furuta
    • Journal Title

      Inorg. Chem.

      Volume: 58 Issue: 7 Pages: 4647-4656

    • DOI

      10.1021/acs.inorgchem.9b00251

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electronic structure of the surface unoccupied band of Ge(001)-c(4×2): Direct imaging of surface electron relaxation pathways2017

    • Author(s)
      Kanasaki J.、Yamamoto I.、Azuma J.、Fukatsu S.
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 11 Pages: 115301-115301

    • DOI

      10.1103/physrevb.96.115301

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Autosurfactant of the second kind: Bi enables δ-doping of Bi in Si2017

    • Author(s)
      K. Murata, K. Miki, and S. Fukatsu
    • Journal Title

      Appl. Phys. Lett. 152104

      Volume: 111 Issue: 15 Pages: 152104-152104

    • DOI

      10.1063/1.5001154

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Singly and Doubly N-Confused Calix[4]phyrin Organoplatinum(II) Complexes as Near-IR Triplet Sensitizers2017

    • Author(s)
      Pushpanandan Poornenth、Maurya Yogesh Kumar、Omagari Toshihiro、Hirosawa Ryuji、Ishida Masatoshi、Mori Shigeki、Yasutake Yuhsuke、Fukatsu Susumu、Mack John、Nyokong Tebello、Furuta Hiroyuki
    • Journal Title

      Inorganic Chemistry

      Volume: 56 Issue: 20 Pages: 12572-12580

    • DOI

      10.1021/acs.inorgchem.7b02047

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Ultrathin-body GeOIの円偏光フォトルミネセンス2020

    • Author(s)
      公平 拓見、安武 裕輔、張 文馨、石井 裕之、入沢 寿史、内田 紀行、前田 辰郎、深津 晋
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 有機無機ペロブスカイトにおける光誘起局所構造相転移2020

    • Author(s)
      田中 陽、安武 裕輔、深津 晋
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Relevance of hidden Valleys in the Dequenching of Room-temperature-emitting Ge Layers2019

    • Author(s)
      Tetsuya Sakamoto, Yuhsuke Yasutake, Junichi Kanasaki, Susumu Fukatsu
    • Organizer
      AVS 66th International Symposium & Exhibition
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 伸長歪制御した面直ファブリペロー共振器中Geからの発光2019

    • Author(s)
      安武 裕輔、一色 史雄、 深津 晋
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Ultrathin-body GeOI の量子閉じ込め直接遷移端蛍光2019

    • Author(s)
      公平 拓見、安武 裕輔、張 文馨、石井 裕之、入沢 寿史、内田 紀行、前田 辰郎、深津 晋
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ゲルマニウムにおける励起電子系の超高速緩和動力学:エネルギー・運動量空間におけるバレー間散乱の重要性2019

    • Author(s)
      金崎 順一、山本 勇、東 純平、深津 晋、Sjakste Jelena、Vast Nathalie
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 有機無機ペロブスカイトのアンチストークス蛍光の温度依存性2019

    • Author(s)
      田中 陽、安武 裕輔、深津 晋
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 有機無機ペロブスカイト単結晶への光学的スピン注入2019

    • Author(s)
      Ren Zhaoli、安武 裕輔、深津 晋
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Quantum-Enhanced Magneto-optic Measurements in a Dissipative Medium2019

    • Author(s)
      Yohei Okawa, Shiho Morimoto, Yuhsuke Yasutake, Susumu Fukatsu
    • Organizer
      Quantum Information and Measurement (QIM) V: Quantum Technologies
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hot Carrier Dynamics in Multi-valleyed Semiconductors2019

    • Author(s)
      Yuhsuke Yasutake, Susumu Fukatsu
    • Organizer
      The 7th International Conference on Small Science
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hot Carrier Dynamics in Multi-valleyed Semiconductors2019

    • Author(s)
      Yuhsuke Yasutake, Susumu Fukatsu
    • Organizer
      International Conference on Small Science 2019
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electronic Raman Scattering in Ge Studied by Circular-Polarized Femtosecond Excitation Correlation2018

    • Author(s)
      Yuhsuke Yasutake, Susumu Fukatsu
    • Organizer
      2018 Material Research Society Fall Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 一軸伸長歪印加によるGe電子ラマン遷移増強のその場観察2018

    • Author(s)
      安武 裕輔、一色 史雄、 深津 晋
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電気二重層トランジスタ(EDLT)を用いたゲルマナン薄膜の金属的伝導2018

    • Author(s)
      山内 遼斗、佐藤 洋平、片山 裕美子、安武 裕輔、深津 晋、上野 和紀
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Ge直接遷移化の試みと光機能探索2018

    • Author(s)
      安武 裕輔
    • Organizer
      第6回フォトニクスのための材料研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Photon heterodyning and its applications2018

    • Author(s)
      Youhei Okawa, Fuminori Omura, Yuhsuke Yasutake, Susumu Fukatsu
    • Organizer
      Advanced Photon Counting Techniques XII
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electronic Raman Scattering in Ge Studied by Circular-Polarized Femtosecond Excitation Correlation Photoluminescence2018

    • Author(s)
      Yuhsuke Yasutake, Susumu Fukatsu
    • Organizer
      2018 Materials Research Soceity Fall Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Strain-engineered electronic Raman transitions in Ge2018

    • Author(s)
      Chang H. Yang, Yuhsuke Yasutake, Susumu Fukatsu
    • Organizer
      European Advanced Materials Congress
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electronic Raman scattering due to spin-orbit split-off band in tensilely-strained Ge2018

    • Author(s)
      Yuhsuke Yasutake, Susumu Fukatsu
    • Organizer
      2018 American Physical Society March Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 電気二重層トランジスタ(EDLT)を用いたゲルマナン薄膜の金属的伝導2018

    • Author(s)
      山内遼斗、佐藤洋平、片山裕美子、安武 裕輔、深津 晋、上野和紀
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 一軸伸長歪印加によるGe電子ラマン遷移増強のその場観察2018

    • Author(s)
      安武裕輔、一色史雄、深津 晋
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Surfactant-intercalant duality of Ca in toplogy-conversion epitaxy of Ge2017

    • Author(s)
      Yuhsuke Yasutake, Susumu Fukatsu
    • Organizer
      North American Conference on Molecular Beam Epitaxy 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 円偏光フェムト秒励起相関分光によるGeキャリア緩和過程の追跡2017

    • Author(s)
      安武裕輔、深津 晋
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ゲルマナン薄膜をチャネルとした電気二重層トランジスタ2017

    • Author(s)
      山内遼斗、佐藤洋平、片山裕美子、安武 裕輔、深津 晋、上野和紀
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Si(111)基板上 CaGe_2F_x 膜のエピタキシャル成長2017

    • Author(s)
      安武裕輔、深津 晋
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Remarks] 成果・情報発信用研究室ホームページ

    • URL

      http://park.itc.u-tokyo.ac.jp/fkatz/

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report

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Published: 2017-04-28   Modified: 2021-02-19  

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