• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Exploration of novel quantum phenomena in non-Kramers Pr compounds by NMR

Research Project

Project/Area Number 17H02918
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionThe University of Tokyo

Principal Investigator

Masashi Takigawa  東京大学, 物性研究所, 教授 (10179575)

Project Period (FY) 2017-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2019: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2018: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2017: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Keywords核磁気共鳴 / 多極子 / スピン軌道相互作用 / 非クラマース系Pr化合物 / スピン軌道強結合系 / 非クラマース基底状態 / 重い電子系 / フラストレート磁性
Outline of Final Research Achievements

In this study, we performed Al-NMR, magnetization and specific heat measurements on the caged compound PrTi2Al20, which contains non-Kramers trivalent Pr ions. We obtained a ferro-quadrupole phase diagram, which is anisotropic with respect to the magnetic field. In particular, we found discontinuous switching of the ferro-quadrupole order parameter induced by weak magnetic fields around 2 tesla along [001] and [110] directions. We proposed a physical mechanism by using a phenomenological Landau theory and model calculations, assuming competition between the magnetic Zeeman energy and the anisotropic quadrupole interactions. We also performed oxygen NMR measurements on the double perovskite compound Ba2MgReO6 and obtained sufficient data to determine the multipole order parameters of the 5d electron system.

Academic Significance and Societal Importance of the Research Achievements

カゴ状化合物PrTi2Al20に対する詳細な明見NMR実験によって、非磁性の結晶場基底状態を持つ4f電子系における磁場誘起の四極子相転移を始めて発見した。また対称性に基づく理論的考察によって、磁場によるぜーまエネルギーと四極子間相互作用の異方的な磁場依存性の競合がこの現象の原因となっている可能性を指摘し、非クラマース系の理解の発展に貢献した。さらに研究対象を拡大して、二重ペロブスカイト化合の酸素サイトNMRに行うことにより、5d電子系における多極子秩序研究の進展に貢献した。

Report

(4 results)
  • 2020 Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (48 results)

All 2021 2020 2019 2018 2017 Other

All Int'l Joint Research (3 results) Journal Article (14 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 14 results,  Open Access: 4 results) Presentation (29 results) (of which Int'l Joint Research: 7 results,  Invited: 7 results) Remarks (2 results)

  • [Int'l Joint Research] Johns Hopkins 大学/NIST (国立標準技術研究所)(米国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Rutherford Appleton 研究所(英国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Laue Langevin 研究所(フランス)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Pressure-induced phase transition in the J1-J2 square lattice antiferromagnet RbMoOPO4Cl2021

    • Author(s)
      Takeda Hikaru、Yamauchi Touru、Takigawa Masashi、Ishikawa Hajime、Hiroi Zenji
    • Journal Title

      Physical Review B

      Volume: 103 Issue: 10 Pages: 104406-104406

    • DOI

      10.1103/physrevb.103.104406

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Field-Orientation Effect on Ferro-Quadrupole Order in PrTi2Al202020

    • Author(s)
      Kittaka Shunichiro、Taniguchi Takanori、Hattori Kazumasa、Nakamura Shota、Sakakibara Toshiro、Takigawa Masashi、Tsujimoto Masaki、Sakai Akito、Matsumoto Yosuke、Nakatsuji Satoru
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 89 Issue: 4 Pages: 043701-043701

    • DOI

      10.7566/jpsj.89.043701

    • NAID

      40022211746

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Regular-triangle trimer and charge order preserving the Anderson condition in the pyrochlore structure of CsW2O62020

    • Author(s)
      Okamoto Yoshihiko、Amano Haruki、Katayama Naoyuki、Sawa Hiroshi、Niki Kenta、Mitoka Rikuto、Harima Hisatomo、Hasegawa Takumi、Ogita Norio、Tanaka Yu、Takigawa Masashi、Yokoyama Yasunori、Takehana Kanji、Imanaka Yasutaka、Nakamura Yuto、Kishida Hideo、Takenaka Koshi
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1

    • DOI

      10.1038/s41467-020-16873-7

    • NAID

      120006873092

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Robust atomic orbital in the cluster magnet LiMoO22020

    • Author(s)
      Katayama N.、Takeda H.、Yamaguchi T.、Yamada Y.、Iida K.、Takigawa M.、Ohta Y.、Sawa H.
    • Journal Title

      Physical Review B

      Volume: 102 Issue: 8

    • DOI

      10.1103/physrevb.102.081106

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultralow temperature NMR of CeCoIn52020

    • Author(s)
      Yamashita M.、Tashiro M.、Saiki K.、Yamada S.、Akazawa M.、Shimozawa M.、Taniguchi T.、Takeda H.、Takigawa M.、Shishido H.
    • Journal Title

      Physical Review B

      Volume: 102 Issue: 16 Pages: 165154-165154

    • DOI

      10.1103/physrevb.102.165154

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Field-Induced Switching of Ferro-Quadrupole Order Parameter in PrTi2Al202019

    • Author(s)
      Taniguchi Takanori、Hattori Kazumasa、Yoshida Makoto、Takeda Hikaru、Nakamura Shota、Sakakibara Toshiro、Tsujimoto Masaki、Sakai Akito、Matsumoto Yosuke、Nakatsuji Satoru、Takigawa Masashi
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 88 Issue: 8 Pages: 084707-084707

    • DOI

      10.7566/jpsj.88.084707

    • NAID

      40021971889

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] V51-NMR study on the S=12 square lattice antiferromagnet K2V3O82019

    • Author(s)
      Takeda H.、Yasuoka H.、Yoshida M.、Takigawa M.、Ghimire N. J.、Mandrus D.、Sales B. C.
    • Journal Title

      Physical Review B

      Volume: 100 Issue: 5

    • DOI

      10.1103/physrevb.100.054406

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Universal geometric frustration in pyrochlores2018

    • Author(s)
      Trump B. A.、Koohpayeh S. M.、Livi K. J. T.、Wen J.-J.、Arpino K. E.、Ramasse Q. M.、Brydson R.、Feygenson M.、Takeda H.、Takigawa M.、Kimura K.、Nakatsuji S.、Broholm C. L.、McQueen T. M.
    • Journal Title

      Nature Communications

      Volume: 9 Issue: 1 Pages: 2619-2619

    • DOI

      10.1038/s41467-018-05033-7

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Inelastic Neutron Scattering Study of the Spin Dynamics in the Breathing Pyrochlore System LiGa0.95In0.05Cr4O82018

    • Author(s)
      Yu Tanaka, Rafal Wawrzynczak, Manh Duc Le, Tatiana Guidi, Yoshihiko Okamoto, Takeshi Yajima, Zenji Hiroi, Masashi Takigawa, and Goeran J. Nilsen
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 87 Issue: 7 Pages: 073710-073710

    • DOI

      10.7566/jpsj.87.073710

    • NAID

      210000134889

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Field-enhanced quantum fluctuation in an S=1/2 frustrated square lattice2018

    • Author(s)
      Yamaguchi H.、Sasaki Y.、Okubo T.、Yoshida M.、Kida T.、Hagiwara M.、Kono Y.、Kittaka S.、Sakakibara T.、Takigawa M.、Iwasaki Y.、Hosokoshi Y.
    • Journal Title

      Physical Review B

      Volume: 98 Issue: 9 Pages: 094402-094402

    • DOI

      10.1103/physrevb.98.094402

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Classical Spin Nematic Transition in LiGa0.95In0.05Cr4O82017

    • Author(s)
      Wawrzynczak R.、Tanaka Y.、Yoshida M.、Okamoto Y.、Manuel P.、Casati N.、Hiroi Z.、Takigawa M.、Nilsen G.J.
    • Journal Title

      Physical Review Letters

      Volume: 119 Issue: 8

    • DOI

      10.1103/physrevlett.119.087201

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dynamics of bound magnon pairs in the quasi-one-dimensional frustrated magnet LiCuVO42017

    • Author(s)
      Nawa K.、Takigawa M.、Kramer S.、Horvatic、M.、Berthier C.、Yoshida M.、Yoshimura K.
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 13

    • DOI

      10.1103/physrevb.96.134423

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Collinear spin density wave order and anisotropic spin fluctuations in the frustrated J1-J2 chain magnet NaCuMoO4(OH)2017

    • Author(s)
      Nawa Kazuhiro、Yoshida Makoto、Takigawa Masashi、Okamoto Yoshihiko、Hiroi Zenji
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 17

    • DOI

      10.1103/physrevb.96.174433

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin dynamics in the high-field phases of volborthite2017

    • Author(s)
      M. Yoshida、K. Nawa、H. Ishikawa、M. Takigawa、M. Jeong、S. Kramer、M. Horvatic、C. Berthier、K. Matsui、T. Goto、S. Kimura、T. Sasaki、J. Yamaura、H. Yoshida、Y. Okamoto、Z. Hiroi
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 18

    • DOI

      10.1103/physrevb.96.180413

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] High pressure phases in the Shastry-Sutherland spin system SrCu2(BO3)22021

    • Author(s)
      M. Takigawa
    • Organizer
      International Workshop on Quantum Magnets in Extreme Conditions
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 17O-NMR測定で探るBa2MgReO6の多極子秩序2020

    • Author(s)
      武田晃, 渡辺亮, 瀧川仁, 平井大悟郎, 廣井善二
    • Organizer
      日本物理学会 2020年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Field-induced switching of ferro-quadrupole order parameter in PrTi2Al202019

    • Author(s)
      M. Takigawa
    • Organizer
      3rd Aisa-Pasific workshop on Quantum Magnetism
    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Field-induced switching of ferro-quadrupole order parameter in PrTi2Al202019

    • Author(s)
      M. Takigawa
    • Organizer
      ISSP Workshop on Topological Phases and Functionality of Correlated Electron Systems
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] PrT2Al20(T=Ti,V)のNQR測定2019

    • Author(s)
      磯前貴央, 武田晃, 瀧川仁, 酒井明人, 中辻知
    • Organizer
      日本物理学会 第74回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] PrV2Al20のNMR測定2019

    • Author(s)
      夏靖丁, 磯前貴央, 武田晃, 瀧川仁, 酒井明人, 中辻知
    • Organizer
      日本物理学会 第74回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] パイロクロア酸化物Cd2Re2O7のNMR2019

    • Author(s)
      米良伸義, 武田晃, 瀧川仁, 松林康仁, 平井大悟郎, 広井善二, 長谷川巧
    • Organizer
      日本物理学会 第74回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] High Pressure Phases in the Shastry-Sutherland spin system SrCu2(BO3)22018

    • Author(s)
      M. Takigawa
    • Organizer
      Kavli ITS & IOP, CAS Joint Workshop on Quantum Magnetism: Frustration, Low Dimensionality, Topology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effects of magnetic field on the ferro-quadrupole order in PrTi2Al202018

    • Author(s)
      Takigawa, Masashi
    • Organizer
      ISSP Workshop on Novel Phenomena in Quantum Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High Pressure Phases in the Shastry-Sutherland spin system SrCu2(BO3)22018

    • Author(s)
      Takigawa, Masashi
    • Organizer
      Kavli ITS & IOP, CAS Joint Workshop on Quantum Magnetism: Frustration, Low Dimensionality, Topology
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Field-induced switching of ferro-quadrupole order parameter in PrTi2Al202018

    • Author(s)
      Takigawa, Masashi
    • Organizer
      ISSP Workshop on Topological Phases and Functionality of Correlated Electron Systems
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 51V核NMR測定で探るスキルミオン物質GaV4Se8の磁気構造2018

    • Author(s)
      石川美咲, 武田晃, 瀧川仁, 藤間友理, 有馬孝尚
    • Organizer
      日本物理学会 第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] β型パイロクロア酸化物CsW2O6の単結晶NMR2018

    • Author(s)
      田中雄, 瀧川仁, 二木健太, 岡本佳比古, 竹中康司
    • Organizer
      日本物理学会 第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] S=1/2正方格子物質RbMoOPO4Clの圧力誘起磁気相の研究2018

    • Author(s)
      武田晃, 山内徹, 吉田誠, 瀧川仁, 石川孟, 廣井善二
    • Organizer
      日本物理学会 第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] NMRと磁化測定によるPrTi2Al20の四極子相図2018

    • Author(s)
      谷口貴紀, 武田晃, 瀧川仁, 中村翔太, 榊原俊郎, 服部一匡, 辻本真規, 酒井明人,松本洋介,中辻知
    • Organizer
      日本物理学会 第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] S=1/2正方格子物質RbMoOPO4Clの圧力誘起磁気転移2018

    • Author(s)
      武田晃, 山内徹 ,吉田誠, 瀧川仁, 石川孟, 廣井善二
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] パイロクロア酸化物Cd2Re2O7のNMR2018

    • Author(s)
      米良伸義, 武田晃, 瀧川仁, 松林康仁, 平井大悟郎, 広井善二
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] CeCoIn5における超低温下NMR測定III2018

    • Author(s)
      山下穣, 田代光輝, 下澤雅明, 杉井かおり, 谷口貴紀, 武田晃, 瀧川仁, 宍戸寛明
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] NMRと磁化測定によるPrTi2Al20の四極子相図と多極子揺らぎに関する研究2018

    • Author(s)
      谷口貴紀, 武田晃, 瀧川仁, 中村翔太, 榊原俊郎, 服部一匡, 辻本真規, 酒井明人 ,松本洋介, 中辻知
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] β-YbAlB4のNMR2018

    • Author(s)
      渡邉亮, 武田晃, 瀧川仁, 鈴木慎太郎, 中辻知
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] NMRによるPrV2Al20の多極子秩序の検証2018

    • Author(s)
      磯前貴央, 武田晃, 瀧川仁, 酒井明人, 中辻知
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 磁場角度分解比熱・エントロピー測定からみたPrTi2Al20の四極子秩序2018

    • Author(s)
      橘高俊一郎, 谷口貴紀, 中村翔太, 榊原俊郎, 瀧川仁, 辻本真規, 酒井明人, 松本洋介, 中辻知
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 一次元フラストレート磁性体NaCuMoO4(OH)の飽和磁場近傍における磁気相図2018

    • Author(s)
      那波和宏, 吉田誠, SteffenKramer, MladenHorvatic, AnnaOrlova, 瀧川仁, 廣井善二
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ボルボサイトにおける隠れた秩序の観測2017

    • Author(s)
      小濱芳允, 石川孟A, 松尾明, 金道浩一, 瀧川仁, 広井善二
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 一次元フラストレート磁性体NaCuMoO4(OH)の飽和磁場近傍における二段相転移2017

    • Author(s)
      那波和宏, 吉田誠 ,SteffenKraemer, AnnaOrlova, MladenHorvatic, 瀧川仁, 廣井善二
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 51V核NMR測定でみたGaV4Se8のスキルミオン相の局所磁性2017

    • Author(s)
      石川美咲, 武田晃, 瀧川仁, 藤間友理, 有馬孝尚
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 核スピン格子緩和率測定で探る量子スピンアイスPr2Zr2O7の局所磁性2017

    • Author(s)
      武田晃, 瀧川仁, 木村健太, 中辻知
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ブリージングパイロクロア格子反強磁性体LiGaCr4O8の単結晶合成とNMR測定2017

    • Author(s)
      田中雄, 瀧川仁, 岡本佳比古, 広井善二
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] PrTi2Al20における磁場誘起相転移2017

    • Author(s)
      谷口貴紀, 武田晃, 瀧川仁, 中村翔太, 榊原俊郎, 辻本真規, 酒井明人, 中辻知
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Remarks] 瀧川研究室HP 業績

    • URL

      https://masashi.issp.u-tokyo.ac.jp/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 瀧川研究室HP 業績

    • URL

      http://masashi.issp.u-tokyo.ac.jp/

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2017-04-28   Modified: 2022-01-27  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi